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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

IUE observations of comets P/Brorsen-Metcalf and Okazaki-Levy-Rudenko

Comet P/Brorsen-Metcalf (1989c) was observed with the International Ultraviolet Explorer (IUE) on several dates from 27 July 1989 through 5 August 1989; comet Okazaki-Levy-Rudenko (1989r) was observed in low dispersion with IUE on 2 and 22 December 1989. The water production rates for P/Brorsen-Metcalf were derived from OH measurements using the vectorial model of Festou (1981). Included also are the water production rates for Okazaki-Levy-Rudenko. Two estimates of the water production rate from the O I emission around 1304 A(octogons) are included. The ultraviolet continuum was not reliably measurable in comet P/Brorsen-Metcalf in most of the spectra, but Afp is approximately 30 cm for 2 August. For the comet Okazaki-Levy-Rudenko, an Afp = 50 cm was derived for 22 December. Both comets have very little dust compared to other recently observed comets. The ratio of CS to water production rates are presented. Relative to water, both comets had less CS than P/Halley in the same range of heliocentric distances. The CS production rates were obtained from a Haser model, assuming a short-lived parent (CS2). Because the dynamic range of the IUE spectrographs are limited, not all species can be measured in each spectrum. The P/Brorsen-Metcalf spectra from 31 July and 3 August were obtained from the NSSDC Archives. Due to the observing technique used for these spectra, the exposure time and hence, the brightnesses and derived quantities have a small uncertainty associated with them.

Roettger, E. E.↗
NASA NTRS1985

Rocket observation of the ultraviolet spectrum of Comet Halley

An ultraviolet sounding rocket telescope/spectrograph experiment observed Comet Halley on Feb. 26, 1986, 17 days after perihelion. From the long-slit spectra, the production rates of O, C, and CO are calculated. The derived water production rate is a lower limit of 5.0 x 10 to the 29th/s and the volume mixing ratio of CO to H2O is 21 percent. The predicted brightness distribution from a radial outflow model with H2O and CO as parent molecules are in accordance with the measured spatial profiles of O I and CO emissions. The ratio of the production rates of CO to C is 2.7 which is consistent with the carbon source being the photodissociation of CO. However, the radial outflow model which best fits the CO data predicts significantly weaker C I emissions than was observed. A better fit to the carbon data is found when an inner coma source of C at a rate of 3 percent of the water production rate is included in the model.

Woods, T. N.↗
NASA NTRS1976

On the calculation of cosmic-ray exposure ages of stone meteorites

Abundances of cosmic ray-produced noble gases and Al-26, including some new measurements, have been compiled for some 23 stone meteorites with exposure ages less than 3,000,000 yr. Concentrations of cosmogenic He, Ne, and Ar in these meteorites have been corrected for differences in target element abundances by normalization to L-chondrite chemistry. Combined noble gas measurements in depth samples of the Keyes and St. Severin chondrites are utilized to derive equations for normalizing the production rates of cosmogenic He-3, Ne-21, and Ar-38 in chondrites to an adopted 'average' shielding. The measured unsaturated AL-26 concentrations and the calculated equilibrium Al-26 for these meteorites are combined to estimate exposure ages. These exposure ages are statistically compared with chemistry- and shielding-corrected concentrations of cosmogenic He, Ne, and Ar to derive absolute production rates for these nuclides, which are found to be roughly 25% higher than production rates used in the past. From these production rates and relative chemical correction factors, production rates for other classes of stone meteorites are derived.

Cressy, P. J., Jr.↗
NASA NTRS1984

Modeling of the silane FBR system

Development of a mathematical model for fluidized bed pyrolysis of silane that relates production rate and product properties (size, size distribution, presence or absence of fines) with bed size and operating conditions (temperature, feed concentration, flow rate, seed size, etc.) and development of user oriented algorithm for the model are considered. A parameter sensitivity study of the model was also developed.

Dudokovic, M. P.↗
NASA NTRS1981

Spectroscopy of Comet P/Encke in 1980 - 1981

Digital spectroscopic scans of P/Comets Encke, Stephan-Oterma, and Gunn were obtained with a sky-subtraction scanner system. Quantiative fluxes for the cometary emission bands of CN, C3, C2, NH2, and the 'D OI red auroral line are presented for P/Encke. The most straight-forward and model-independent line flux to interpret is the lambda lambda 6300, 6364 forbidden oxygen doublet. After an NH2 blending correction, the oxygen production rate may be directly measured from the Lick small-aperture fluxes. The oxygen production rates increased rapidly with decreasing heliocentric distance for both P/Encke and P/Stephan-Oterma. A rough power-law exponent in r with n = approximately -2.5 describes the change in oxygen production for P/Encke. Compared to the water production rates inferred from IUE satellite spectra showing the lambda 3080 OH band, these oxygen production rates are consistently lower by a factor of 11. This implies a common origin for the two species; H2O is the likely sole OI ID parent.

Spinrad, H.↗
NASA NTRS1991

The 15 years of comet photometry: A comparative analysis of 80 comets

In 1976, a program of narrowband photometry of comets was initiated that has encompassed well over 400 nights of observations. To date, the program has provided detailed information on 80 comets, 11 of which were observed during multiple apparitions. The filters (initially isolating CN, C2, and continuum and later including C3, OH, and NH) as well as the detectors used for the observations were changed over time, and the parameters adopted in the reduction and modeling of the data have likewise evolved. Accordingly, we have re-reduced the entire database and have derived production rates using current values for scalelengths and fluorescence efficiencies. Having completed this task, the results for different comets can now be meaningfully compared. The general characteristics that are discussed include ranges in composition (molecular production rate ratios) and dustiness (gas production compared with Af(rho)). Additionally an analysis of trends on how the production rates vary with heliocentric distance and on pre- and post-perihelion asymmetries in the production rates of individual comets. Possible taxonomic groupings are also described.

Osip, David J.↗
NASA NTRS1988

Collisional quenching of cometary emission in the 18 centimeter OH transitions

A model of collisional quenching of the OH 2Pi(3/2) J = 3/2 Lambda doublet in cometary comae is presented. It is found that collisions with ions and electrons in the outer coma have a strong quenching effect on the Swings-effect inversion of the Lambda doublet that is responsible for the OH radio emission at 18 cm wavelength. For the conditions of Halley's comet, collisional quenching should lead radio observers to systematically underestimate the OH parent production rate by a factor of approximately 3 relative to its actual value, and in general, radio-derived production rates should always be less than or equal to UV-derived production rates, which are relatively unaffected by this process. The observation that UV production rates exceed those derived by radio techniques is well known; the direct measurement of this ratio, using a consistent coma model, should provide information about the ion and electron content of the cometary coma.

Schloerb, F. Peter↗
NASA NTRS1978

An analysis of the coma of comet Bennett 1970 II

Brightness profiles for emission features of H2O(+) in comet Bennett 1970 II are analyzed, taking into account the role of chemical reactions in the coma. By comparing the rates of transport processes derived from the brightness profile with known chemical rate constants, upper limits on the abundances and production rates of H2O, CH4, NH3, and other possible coma constituents are found. The derived upper limit on the H2O production rate inside 10 to the 4th power km is less than the observed OH production rate averaged over the coma of this comet. It is concluded that the brightness profiles of H2O(+) and OH in comet Bennett 1970 II which are presently available are inconsistent with production of OH primarily by photodissociation of H2O molecules sublimating from the nucleus. The existence of an extended source of H2O is not ruled out.

Oppenheimer, M.↗
DOE OSTI2025

R&D Effort of Geologic Hydrogen Production at the National Renewable Energy Lab (NREL)

Geologic hydrogen (geoH2) is an emerging technology with massive current market interest and distinct potential to change the paradigm of hydrogen production. Two major subsurface processes influence the amount of geoH2 that are available for energy extraction: 1) geochemical reactions of H2O and Fe2+-bearing rocks which can produce hydrogen in the subsurface environment, where 2) various active microbial communities consume hydrogen as an energy source before the hydrogen reaches the surface. The net gain of hydrogen from these two competing processes dictates the production rate of geoH2. A recent study (Templeton et al., 2024) suggested that for most natural geoH2 systems, five orders of magnitude of production rate enhancement are needed to make geoH2 production economical in the near term. Effective enhancement of the production rate requires an in-depth understanding of the two geoH2 processes, in order to promote the H2-generating geochemical processes and suppress the H2-consuming microbial processes. However, current significant knowledge gaps in these two processes hinders the efforts to formulate strategies to enhance geoH2 production. The National Renewable Energy Laboratory (NREL) is a U.S. Department of Energy National Laboratory with the core mission of leading research, innovation, and strategic partnership to deliver solutions for a clean energy based economy. NREL's extensive research portfolio in hydrogen, bioenergy, geothermal, industrial decarbonization, and energy analysis makes us well positioned to conduct interdisciplinary research and facilitate technology deployment in the geoH2 space. In this presentation, we will discuss ongoing geoH2 research and engagement efforts at NREL, including: 1) geochemical investigation to understand the reaction mechanisms and production rate and potential of different source minerals and rocks, 2) microbiological investigation to understand methanogenesis and acetogenesis in the subsurface geoH2 environment, and identify effective inhibitors for these microbial processes, and 3) preliminary analysis for geoH2 production in the State of Minnesota, where abundant Fe-rich rocks for stimulated geoH2 production and ample opportunity to utilize geoH2 in transforming iron and steel industries are currently available.

08 HYDROGEN↗
NASA NTRS1988

Effect of solar proton events in 1978 and 1979 on the odd nitrogen abundance in the middle atmosphere

Daily average solar proton flux data for 1978 and 1979 are used in a proton energy degradation scheme to derive ion pair production rates and atomic nitrogen production rates. The latter are computed in a form suitable for inclusion in an atmopheric, two-dimensional, time-dependent photochemical model. Odd nitrogen distributions are computed from the model, including atomic nitrogen production from solar protons, and are compared with baseline distributions. The comparisons show that the average effect of the solar protons in 1978 and 1979 was to cause changes in odd nitrogen only above 10 mbar and at latitudes only above about 50 deg in both hemispheres. The influence of the solar proton-produced odd nitrogen on the local abundance of odd nitrogen depends primarily on the background odd nitrogen abundance as well as the altitude and season.

Jackman, Charles H.↗
NASA NTRS1979

Novel duplex vapor: Electrochemical method for silicon solar cells

The scaled up chemical reactor for a SiF4-Na reaction system is examined for increased reaction rate and production rate. The reaction system which now produces 5 kg batches of mixed Si and NaF is evaluated. The reactor design is described along with an analysis of the increased capacity of the Na chip feeder. The reactor procedure is discussed and Si coalescence in the reaction products is diagnosed.

Nanis, L.↗
NASA NTRS2017

Hypervolatiles in a Jupiter-Family Comet: Observations of 45P/Honda-Mrkos-Pajdusakova Using iSHELL at the NASA-IRTF

We used the new high spectral resolution cross-dispersed facility spectrograph, iSHELL, at the NASA Infrared Telescope Facility on Maunakea, HI, to observe Jupiter-family comet (JFC) 45P/Honda-Mrkos-Pajdusakova. We report water production rates, as well as production rates and abundance ratios relative to H2O, for eight trace parent molecules (native ices), CO, CH4, H2CO, CH3OH, HCN, NH3, C2H2, and C2H6, on 2 days spanning UT 2017 January 6/7 and 7/8, shortly following perihelion. Trace species were measured simultaneously with H2O and/or OH prompt emission, a proxy for H2O production, thereby providing a robust and consistent means of establishing the native ice composition of 45P. Its favorable geocentric radial velocity (approximately minus 35 kilometers per second) permitted sensitive measures of the "hypervolatiles" CO and CH4, which are substantially undercharacterized in JFCs. Our results represent the most precise ground-based measures of CO and CH4 to date in a JFC, providing a foundation for building meaningful statistics regarding their abundances. The abundance ratio for CH4 in 45P (0.79 percent plus or minus 0.06 percent relative to H2O) was consistent with its median value as measured among Oort Cloud comets, whereas CO (0.60 percent plus or minus 0.04 percent) was strongly depleted. Compared with all measured comets, HCN (0.049 percent plus or minus 0.012 percent) was strongly depleted, CH3OH (3.6 percent plus or minus 0.3 percent) was enriched, and the remaining species were consistent with their respective median abundances. The volatile composition measured for 45P could indicate processing of ices prior to their incorporation into its nucleus. Spatial analysis of emissions suggests enhanced release of more volatile species into the sunward-facing hemisphere of the coma.

DiSanti, Michael A.↗
DOE OSTI2021

Vapor-Phase Cyclohexene Epoxidation by Single-Ion Fe(III) Sites in Metal–Organic Frameworks

Heterogeneous catalysts supported on metal–organic frameworks (MOFs), which possess uniform porosity and crystallinity, have attracted significant interest for recent years due to the ease of active-site characterization via X-ray diffraction and the subsequent relation of the active site structure to the catalytic activity. We report the syntheses, structures, and oxidation catalytic activities of single-ion iron catalysts incorporated into the zirconium MOF NU-1000. Single-ion iron catalysts with different counteranions were anchored onto the Zr node through postsynthetic solvothermal deposition. Crystallographic characterization of the resulting MOFs (NU-1000-Fe-Cl and NU-1000-Fe-NO 3 ) revealed that, while both frameworks have similar Fe coordination, the distance between Fe and the Zr 6 node differs significantly between the two. Lastly, the product rate profiles of the two catalysts for vapor-phase cyclohexene epoxidation demonstrate different initial rates and product formations, likely originating from the different Fe–O distances.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Compositional Variation Tests on DuraMelter 100 with LAW Sub-Envelope C1 Feed (LAWC22 Glass) in Support of the LAW Pilot Melter (Final Report)

This report provides the results from tests that were performed on a DM100 system with LAW Sub-Envelope Cl and Al feeds in support of the subsequent Pilot Melter tests. The principal objectives of the DM100 tests were to determine the processing characteristics as the simulated melter feed transitioned from the LAW Sub-Envelope Cl to the Sub-Envelope Al composition and to determine the effect of bubbling rate on production rate.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
NASA NTRS1981

Formation of organic molecules on Titan

A mechanism is proposed for the formation of complex organic nitrogen compounds in the dense lower atmosphere of Titan. The mechanism is based on three-body association reactions with HCNH(+) ions formed by the reaction of N(+) with CH4, which lead to the production of ethyl cyanide, vinyl cyanide and cyanoacetylene. Calculations for a model atmosphere consistent with the preliminary interpretation of Voyager 1 data for the region of maximum cosmic ray activated chemistry, corresponding to a temperature between 150 and 160 K and a pressure of 20 mbar, are presented which show substantial organic nitrile and hydrogen cyanide production rates. Based on these production rates, it is expected that significant equilibrium concentrations of these compounds will be found on Titan.

Capone, L. A.↗
NASA NTRS1982

On the interaction of auroral protons with the earth's atmosphere

The interaction of energetic auroral protons with the atmosphere is investigated. The results of a random number algorithm that describes the proton-hydrogen interconversion reactions as the beam loses energy are adopted to construct an energy deposition curve applicable over a wide range of initial proton energies. Ionization rates and production rates of ejected electrons are computed and emission rates of hydrogen Balmer alpha and beta lines are evaluated using recently available low energy cross-sections.

Rees, M. H.↗
NASA NTRS1992

Propagation of cosmic-ray nuclei in a diffusing galaxy with convective halo and thin matter disk

A diffusion model for cosmic-ray propagation in the galaxy that includes the effects of convection in the halo is presented. Calculations are made for 13 primary and secondary nuclei with rigidities between 1 and 1000 GV using interaction loss rates, secondary production rates, and radioactive decay on the basis of recent new cross-section measurements. It is found that, in order to fit the rather weak radial dependence of cosmic-ray protons derived from gamma-ray data, the radial profile of the cosmic-ray sources must also have a weak radial dependence. It is suggested that convection perpendicular to the disk of the Milky Way Galaxy may not be important even at rigidities less than a few GV. The obtained limits on halo thicknesses are consistent with what can be determined for the distribution of cosmic-ray electrons in the halo based on the distribution of radio synchrotron emission in this and other galaxies.

Webber, W. R.↗
NASA NTRS1992

Major outburst of periodic Comet Halley at a heliocentric distance of 14 AU

The properties and evolution of the major outburst experienced by Comet Halley at 14 AU during February-March 1991 are studied. It is found that the observed halo is a segment of a conical surface populated by solid particles ejected from a localized, temporarily activated region on the sunlit hemisphere of the spinning nucleus. The total mass of the ejecta was at least 10 exp 12 g and CO was probably the prime driver, accelerating the smallest grains to a terminal velocity of about 45 m/s. The mass loading of the gas flow by particulate matter is enormous, with the mass production rate exceeding the expected production rate of CO by a factor of several tens.

Sekanina, Z.↗