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At least 145 records · Page 8

15-minute Parker River gap-filled tide height and salinity data, PIE LTER, Plum Island Sound, MA (2014–2023), for ELM PFLOTRAN modeling

This dataset contains 15-minute tide height and salinity data from the Typha site along the Parker River, part of the Plum Island Ecosystems Long Term Ecological Research (PIE LTER) site in Plum Island Sound, Massachusetts (MA) 2014-2023. Tide height (in NAVD88) was compiled from measurements conducted at the mouth of Plum Island Sound and corrected for time lags. Gap-filling of missing periods were done by fitting tidal constituents to the time series. Salinity was measured (and is stored on ESS DIVE ) in 2022 and 2023 using HOBO U24-002 conductivity loggers. River discharge is the most important control on tidal river water salinity at the location (Vallino & Hopkinson, 1998). An artificial neural network was trained to predict river water salinity at the location using Parker River discharge (USGS station 01101000, Parker River at Byfield, MA) and gap-filled salinity observations from a long-term monitoring station ca. 3km downstream from the Typha site (LTER station ‘Middle Road’) as input variables to create continuous time series information. The data set was used in the spin up and simulations of a land surface model coupled to a biogeochemical reaction network (ELM PFLOTRAN) assessing impacts of hydrology and salinity input on methane fluxes in 2022 and 2023 (Sulman et al., 2024). Metadata files ELMPFLOTRAN_tide_salinity_dd.csv and ELMPFLOTRAN_tide_salinity_flmd.csv provide details on site location, data variables, and QA/QC methods .

54 ENVIRONMENTAL SCIENCES↗

AmeriFlux FLUXNET-1F US-ORv Olentangy River Wetland Research Park

This is the AmeriFlux Management Project (AMP) created FLUXNET-1F version of the carbon flux data for the site US-ORv Olentangy River Wetland Research Park. This is the FLUXNET version of the carbon flux data for the site US-ORv Olentangy River Wetland Research Park produced by applying the standard ONEFlux (1F) software. Site Description - The ORWRP site is a 21-ha large-scale, long-term wetland campus facility that is owned by Ohio State University. It is designed to provide teaching, research, and service related to wetland and river science and ecological engineering. The site has been developed in several phases: Phase 1 (1992 - 1994) - Construction of two 2.5-acre deepwater marshes and a river water delivery system began, with pumps installed on the floodplain to bring water from the Olentangy River. In May 1994, one wetland was planted with marsh vegetation, while the other remained as an unplanted control; Phase 2 (1994 - 1999) - Development of a research and teaching infrastructure took place with the construction of boardwalks, a pavilion, and a compound. The creation of the 7-acre naturally flooded oxbow was also included; Phase 3 (2000 - 2003) - As a research building was created, three additional wetlands were created in the vicinity of the building, including a stormwater wetland that receives runoff from the roof of the building; Phase 4 - The current phase involves research access to the Olentangy River.

Bohrer, Gil↗

Comparative Study of Hydrology and Icemelt in Three Nepal River Basins Using the Glacio-Hydrological Degree-Day Model (GDM) and Observations From the Advanced Scatterometer (ASCAT)

An assessment of the water supply and its seasonal and annual changes over the century in the High Mountain Asia (HMA) region is of increasing interest due to its potential impact on one-sixth of the global population. In order to understand the changing hydrology and snow and ice melt, we used remotely sensed Advanced Scatterometer (ASCAT) observations of glacier melt (GM) and a distributed and gridded Glacio-hydrological Degree-day Model (GDM) in three river basins: Tamor, Trishuli and Marsyangdi. The GDM-estimated contribution of snowmelt, icemelt, rainfall and baseflow in river flows is found to be most accurate in the Trishuli River basin, with Nash-Sutcliffe efficiency (NSE) between the estimated and observed discharges of 0.81 and volume differences of -0.5%, and reasonably accurate in the Tamor River basin, with NSE of 0.69 and volume difference of -7.51%. Similarly, NSE of 0.81 and volume difference of 4.64% in Marsyangdi River basin. We find strong similarities in the timing of glacier melting using the GDM and from observations from the ASCAT GM, determining the seasonal start of glacier melting to within 6 days on average. In all basins ASCAT GM observes melting at higher elevations relative to GDM, average of 5,328 m a.s.l. Systematic differences in glacier melting area determined by modeling and satellite observations indicate ASCAT may have suboptimal resolution, view geometry and/or polarimetry for delineating glacier melting at the process-scale in complex topography, especially in the ablation zone. This is the first step in examining the remote sensing products that could potentially be incorporated into hydrologic models to increase the accuracy of the hydrologic flow as well as the ability to estimate river discharge in other basins with limited data.

54 ENVIRONMENTAL SCIENCES↗

A Small Warm Tributary Provides Prespawning Resources for Colorado Pikeminnow in a Cold Dam-Regulated River

Abstract Riverine habitat mosaics, including tributaries, are an important reason the Green River subbasin supports the largest remaining population of federally endangered Colorado Pikeminnow Ptychocheilus lucius in the Colorado River Basin. Upstream Colorado Pikeminnow distribution is limited by Flaming Gorge Dam and few typically occurred in the reach immediately downstream of the dam, which is the reach most affected by thermal and hydrologic alterations. However, fish captures and passive integrated transponder (PIT) antenna sampling of previously tagged individuals from 2011 to 2021 revealed seasonal congregations of up to 75 Colorado Pikeminnow annually in the mouth of Vermillion Creek, a small tributary in the regulated reach. Approximately 11% (N = 93 individuals) of the entire 2017–2018 Green River basin population were encountered in Vermillion Creek over the 11-y study, an underestimate of use considering that untagged fish were not detected by antennas. Colorado Pikeminnow used Vermillion Creek primarily when Green River spring flows from Flaming Gorge Dam were high and cold in May through mid-June when the confluence was a large, deep backwater warmer than the main channel and supported forage fishes. Intra-annual encounters revealed seasonal residence times for individual Colorado Pikeminnow up to 91 d, and multiple inter-annual encounters indicated site fidelity. Frequent detections of individual Colorado Pikeminnow in a Yampa River spawning area soon after their detections in Vermillion Creek indicate this tributary may be an important resource for reproductive adults. The intensive and basin-wide PIT tagging and detection program for Colorado Pikeminnow enhanced our understanding of the importance of small habitat nodes such as Vermillion Creek in the Green River drainage network. Understanding and protecting these seasonally available riverine habitat mosaics used for prespawning conditioning may assist with recovery of Colorado Pikeminnow.

Biodiversity & Conservation↗

Modeling the microplastic distribution along the Delaware River Estuary: Accumulation patterns and hydrodynamic influences

Microplastic pollution is an escalating environmental concern, particularly in densely populated estuary regions, where it poses significant threats to aquatic life and human health. The dispersion patterns of microplastic particles along estuaries are influenced and complicated by multiple environmental factors such as river flow, tidal mixing, salt intrusion, and estuarine circulation. This study examines the accumulation and dispersion patterns by modeling three typical classes of microplastics in the Delaware River Estuary: synthetic fibers, sinking plastic films, and rising plastic pellets. Our findings reveal specific areas with high microplastic accumulation for each type. Notably, the upper estuary regions exhibit significant retention of rising microplastics, associated with a region with reduced along-thalweg velocities downstream of Trenton, NJ and upstream of Philadelphia, PA. Conversely, synthetic fibers and sinking plastic films accumulate in the flow convergence zone near the bottom salinity front, typically downstream of Philadelphia. All of the microplastic accumulation hot spot locations are controlled by the balance of river discharge and salinity intrusions. During the dry season, microplastic accumulation hot spots shift upstream in the estuary, whereas in the wet season, the strong river discharge pushes them downstream. Furthermore, on the other hand, tidal mixing, settling, and resuspension processes strongly impact the spreading of microplastics along the river.

Delaware River Estuary↗

Spatial Study 2021: Sensor-Based Time Series of Surface Water Temperature, Specific Conductance, Total Dissolved Solids, pH, and Dissolved Oxygen from across Multiple Watersheds in the Yakima River Basin, Washington, USA (v3)

This dataset supports a broader study examining the drivers of spatial variability in sediment respiration rates in the Yakima River Basin. The dataset provides two-hour time series hydrological and water chemistry sensor data, manual chamber open channel respiration data, handheld sensor water chemistry data, river substrate grain size photos, general environmental context photos, and field metadata (including qualitative information on instream and river corridor characteristics) collected during the same two-week period at 47 sites within multiple rivers throughout the Yakima River Basin in Washington, USA. Grain size photos can be used to improve estimates of channel substrate D50 data. Related sample-based water chemistry data are published separately at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/1898914.This dataset is comprised of four main folders, one containing three sensor-specific subfolders and the others containing photographs. The SFA_SpatialStudy_2021_SensorData main data folder includes file-level metadata (FLMD), data dictionary (dd), installation methods, field metadata, Ultrameter water chemistry data, field data collection protocols, international generic sample number (IGSN) mapping file, and a readme file. The “Sensor_Manual_Specifications” subfolder contains pdf files from the manufacturer of each sensor with details on the sensor specifications. Each sensor subfolder (BarotrollAtm, MantaRiver, and MinidotManualChamber) contains a sensor data subfolder for timeseries data and a subfolder for plots and summary statistics. The BarotrollAtm Data subfolder contains In Situ Rugged BaroTROLL pressure and temperature data. The MantaRiver Data subfolder contains Eureka Manta+ 35B multisonde temperature, specific conductance, and pH data. The MinidotManualChamber Data subfolder contains PME MiniDOT Logger dissolved oxygen (mg/L and percent saturation) and temperature data. The folder SFA_SpatialStudy_2021_EnvironmentalContextPhotos contains environmental context photographs and videos. The folders SFA_SpatialStudy_2021_SedimentQuadratPhotos_Part1 and SFA_SpatialStudy_2021_SedimentQuadratPhotos_Part2 contain sediment quadrat photographs. All files are .csv, .pdf, .R, .jpg, .jpeg, .mp4, or .mov. This data package was originally published September 2022. It was updated January 2023 (modified files) and June 2024 (new and modified files). See the change history in data package readme for more details.We acknowledge the Yakama Nation as owners and caretakers of the lands where we collected these data. We thank the Confederated Tribes and Bands of the Yakama Nation Tribal Council and Yakama Nation Fisheries for working with us to facilitate sample collection and optimization of data usage according to their values and worldview.

54 ENVIRONMENTAL SCIENCES↗

WHONDRS Surface Water Chemistry and Organic Matter Characterization along the St. Lawrence River's Inland to Coastal Gradient, Eastern North America (v2)

This dataset supports a broader study examining the inland (Lake Ontario) to coastal (North Atlantic Ocean) geochemistry gradient along the St. Lawrence River in Canada and the United States. The St. Lawrence River is unique in that it contains the convergence of multiple water masses with distinct water signatures that mix only slightly as the river flows downstream. The dataset provides dissolved organic carbon (DOC) and organic matter characterization data generated from surface water. Samples were collected by researchers on board the Lampsilis research vessel (l’Université du Québec à Trois-Rivières) and small boats (St. Lawrence River Institute of Environmental Sciences, Cornwall) at 94 locations across and along the St. Lawrence River to capture longitudinal and transverse variation. Related data were collected and will be published separately in collaboration with the MicrEAU Laboratory (François Guillemette; l’Université du Québec à Trois-Rivières) and the Exploration of Coastal Hydrobiogeochemistry Across a Network of Gradients and Experiments (EXCHANGE) program. This dataset is comprised of one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data (5) surface water sampling protocol; (6) readme; (7) methods codes; (8) international geo-sample number (IGSN) mapping file; and (9) folder of high resolution characterization of organic matter via 12 Tesla Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) through the Environmental Molecular Sciences Laboratory (EMSL; https://www.pnnl.gov/environmental-molecular-sciences-laboratory). The FTICR folder contains two subfolders, one containing the .xml data files and the other containing instructions for using Formularity (https://omics.pnl.gov/software/formularity) and an R script to process the data based on the user's specific needs. All files are .csv, .pdf, .R, .ref, or .xml. The data package was originally published in November 202. It was updated in April 2025 (v2; modified files). See the change history section in the readme for details.

54 ENVIRONMENTAL SCIENCES↗

Spatial Study 2022: Surface Water Samples, Cotton Strip Degradation, and Hydrologic Sensor Data across the Yakima River Basin, Washington, USA (v3)

This dataset supports a broader study examining the drivers of spatial variability in sediment respiration rates in the Yakima River Basin. The dataset provides data and photos generated from sample collection during the same one-week period at 48 sites within multiple rivers throughout the Yakima River Basin in Washington, USA. The contents include surface water geochemistry data; river substrate grain size photos; stream depth data; manual chamber open channel respiration data; and field metadata (including qualitative information on instream and river corridor characteristics). Grain size photos can be used to improve estimates of channel substrate D50 data. The dataset also includes tensile strength and photos from cotton strip field degradation experiments; five-week sensor time series temperature, dissolved oxygen, pressure, pH, specific conductance, chlorophyll A, and turbidity data; plots of the sensor data; and R scripts used to generate the plots. Samples collected during this study were labeled as “Second Spatial Study” or “SSS.” A subset of data from the SSS samples were published in the contiguous United States (CONUS)-Scale Model-Sample (CM) study data package available at https://data.ess-dive.lbl.gov/view/doi:10.15485/1923689 that presents data from across the CONUS. SSS data published in the CM data package were not included in this data package. They include dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC), total nitrogen (TN), grain size, aerobic sediment respiration, dissolved oxygen (DO), and temperature. Parent IDs and Site IDs are consistent between the SSS and CM data packages, and they can be mapped directly so data across packages can be used together. Additionally, sensor data from a similar 2021 spatial study can be found at https://data.ess-dive.lbl.gov/view/doi:10.15485/1892052 and 2021 sample data can be found at https://data.ess-dive.lbl.gov/view/doi:10.15485/1898914. The 2021 spatial study had some sites in common with this 2022 spatial study. This dataset is comprised of three photo folders and one main data folder with six subfolders. The photo folders contain photographs and videos of cotton strip retrieval and sediment quadrats. The main data folder consists of (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) total suspended solids (TSS) data and cotton strip tensile strength data and averages; (5) field protocol; (6) readme; (7) methods codes; (8) international generic sample number (IGSN) mapping file; (9) sensor installation methods summary; (10) stream depth and averages; and (11) Ultrameter data and averages. The Sonar subfolder consists of Sonar time-series depth data and a processing script. The BarotrollAtm, DepthHOBO, MantaRiver, miniDOT, and miniDOTManualChamber subfolders contain time-series data, plots, and summary files. All files are .csv, .pdf, .txt, .R, .Rmd, .jpg, .jpeg, .AVI, .mp4, or .mov. The data package was originally published in April 2023. It was updated in August 2023 (v2; modified files) and September 2024 (v3; modified files). See the change history section in the readme for details. We acknowledge the Yakama Nation as owners and caretakers of the lands where we collected these data. We thank the Confederated Tribes and Bands of the Yakama Nation Tribal Council and Yakama Nation Fisheries for working with us to facilitate sample collection and optimization of data usage according to their values and worldview.

54 ENVIRONMENTAL SCIENCES↗

Model Inputs, Outputs, and Scripts associated with: “Combined effects of stream hydrology and land use on basin-scale hyporheic zone denitrification in the Columbia River Basin”

This data package is associated with the publication “Combined effects of stream hydrology and land use on basin‐scale hyporheic zone denitrification in the Columbia River Basin”, published in Water Resource Research (Son et al.2022) available at https://doi.org/10.1029/2021WR031131. This data package includes the key model inputs/outputs of the river corridor model for the Columbia River Basin (CRB) and the model source codes used in the manuscript. The model is a carbon-nitrogen-coupled river corridor model (RCM), and the model is used to quantify hyporheic zone (HZ) denitrification at the NHDPLUS stream reach scales. The RCM used in this study combines empirical substrate models derived from observations and three microbially driven reactions, including two-step denitrification and aerobic respiration, are considered within the HZ. The key input data of the model are exchange flux, residence time, and stream solute (dissolved organic carbon (DOC), dissolved oxygen (DO), and nitrate concentrations). These inputs are constant over time and represent long-term averaged values. This study uses the RCM to explore the spatial patterns of HZ denitrification across reaches with different sizes and land use in the CRB. Our main objective is to use the RCM as a virtual reality model, and the machine-learning models as surrogates that encapsulate the complexities of the physics-based model while identifying the importance of different variables that are not evident in the model conceptualization. We do not include a direct comparison of the modeled HZ denitrification and measurements; however, the RCM can capture the overall spatial patterns of the HZ denitrification because the model inputs and its reaction networks are based on well-established theory and a physical-based model. The combination of the model-based predictions and a machine-learning approach (e.g., random forest) is used to improve our understanding of what variables of the model are associated with spatial patterns of the modeled denitrification across reaches with different sizes and land uses, and to develop a proxy model using measurable variables to reproduce the simulated patterns.This dataset contains five folders: (1) model_inputs, (2) model_outputs, (3) Rscripts, (4) figures, and (5) model_codes. It also contains a readme, file level metadata (FLMD), and data dictionary (dd). Please see the FLMD for a list of all the files contained in this data package and descriptions for each. The model_inputs folder contains the model inputs used to drive the model simulations. The model_outputs folder contains key model output files from the river corridor model. The Rscripts folder contains the Rscripts for pre- and post- processing model results. The figures folder contains the raw figures associated with the manuscript. The model_codes folder includes key model source codes/input files. All files are .jpg, .jpeg, .out, .e, .od, .dat, .sub, .F90, .0, .R, .sbx, .cpg, .sbn, .shx, .shp, .dbf, .prj, .tfw, .tif, .xml, .pdf, or .csv.

54 ENVIRONMENTAL SCIENCES↗

Impacts of Alternative Operations and Renewable Energy Deployment on Columbia River Hydropower

The Columbia River Treaty Tribes in the Pacific Northwest - the Nez Perce, Umatilla, Warm Springs, and Yakama - hold treaty-reserved fishing rights for the Columbia River, one of the world's most productive salmon rivers and a critical resource for these tribes. However, the tribes have expressed that current operating regimes of hydropower dams throughout the Columbia River Basin (CRB) do not fully account for tribal fishing rights and have negatively impacted fish populations. Four tribes acting together through the Columbia River Inter-Tribal Fish Commission (CRITFC)'s 2022 Energy Vision stated that current power system models often do not fully account for the many constraints faced by hydropower facilities in the CRB. As the deployment of variable renewable energy (VRE) like solar and wind continues to increase, power system flexibility will become increasingly important. As a result, there is a growing need to better understand the true capabilities of the hydropower generation fleet while accurately accounting for ecological constraints (Northwest Power and Conservation Council 2022). Understanding hydropower's role in a future grid with a higher share of VRE can inform water resources planning to address ecological needs. The goal of this study is to examine the impacts of alternative hydropower operation rules and weather variability on hydropower generation and grid operations in VRE and transmission infrastructure deployment scenarios. The study evaluates how hydropower scheduling practices can reduce ecological impacts to the region's salmon populations. More specifically, the study examines the impact of today's dam water release rules (called "adjusted base water rules" in this study) and new, ecologically informed water release rules (called "ecosystem water rules" in this study) on two VRE scenarios (current renewable energy levels and higher renewable energy levels) using six weather years for each scenario (2008-2013). CRITFC developed the ecosystem water rules, which capture a portion of the changes they recommend for CRB hydropower operations. These analyses use a water resource planning model (OASIS) and a production cost model (PLEXOS) to simulate CRB reservoir cascade and Western Interconnection power grid operation.

13 HYDRO ENERGY↗

Warming of the lower Columbia River , 1853 to 2018

Abstract Water temperature is a critical ecological indicator; however, few studies have statistically modeled century‐scale trends in riverine or estuarine water temperature, or their cause. Here, we recover, digitize, and analyze archival temperature measurements from the 1850s onward to investigate how and why water temperatures in the lower Columbia River are changing. To infill data gaps and explore changes, we develop regression models of daily historical Columbia River water temperature using time‐lagged river flow and air temperature as the independent variables. Models were developed for three time periods (mid‐19th, mid‐20th, and early 21st century), using archival and modern measurements (1854–1876; 1938–present). Daily and monthly averaged root‐mean‐square errors overall are 0.89°C and 0.77°C, respectively for the 1938–2018 period. Results suggest that annual averaged water temperature increased by 2.2°C ± 0.2°C since the 1850s, a rate of 1.3°C ± 0.1°C/century. Increased water temperatures are seasonally dependent. An increase of approximately 2.0°C ± 0.2°C/century occurs in the July–Dec time‐frame, while springtime trends are statistically insignificant. Rising temperatures change the probability of exceeding ecologically important thresholds; since the 1850s, the number of days with water temperatures over 20°C increased from ~5 to 60 per year, while the number below 2°C decreased from ~10 to 0 days/per year. Overall, the modern system is warmer, but exhibits less temperature variability. The reservoir system reduces sensitivity to short‐term atmospheric forcing. Statistical experiments within our modeling framework suggest that increased water temperature is driven by warming air temperatures (~29%), altered river flow (~14%), and water resources management (~57%).

54 ENVIRONMENTAL SCIENCES↗

Advancing river corridor science beyond disciplinary boundaries with an inductive approach to catalyse hypothesis generation

Abstract A unified conceptual framework for river corridors requires synthesis of diverse site‐, method‐ and discipline‐specific findings. The river research community has developed a substantial body of observations and process‐specific interpretations, but we are still lacking a comprehensive model to distill this knowledge into fundamental transferable concepts. We confront the challenge of how a discipline classically organized around the deductive model of systematically collecting of site‐, scale‐, and mechanism‐specific observations begins the process of synthesis. Machine learning is particularly well‐suited to inductive generation of hypotheses. In this study, we prototype an inductive approach to holistic synthesis of river corridor observations, using support vector machine regression to identify potential couplings or feedbacks that would not necessarily arise from classical approaches. This approach generated 672 relationships linking a suite of 157 variables each measured at 62 locations in a fifth order river network. Eighty four percent of these relationships have not been previously investigated, and representing potential (hypothetical) process connections. We document relationships consistent with current understanding including hydrologic exchange processes, microbial ecology, and the River Continuum Concept, supporting that the approach can identify meaningful relationships in the data. Moreover, we highlight examples of two novel research questions that stem from interpretation of inductively‐generated relationships. This study demonstrates the implementation of machine learning to sieve complex data sets and identify a small set of candidate relationships that warrant further study, including data types not commonly measured together. This structured approach complements traditional modes of inquiry, which are often limited by disciplinary perspectives and favour the careful pursuit of parsimony. Finally, we emphasize that this approach should be viewed as a complement to, rather than in place of, more traditional, deductive approaches to scientific discovery.

54 ENVIRONMENTAL SCIENCES↗

Modeling framework for evaluating the impacts of hydrodynamic pressure on hydrologic exchange fluxes and residence time for a large-scale river section over a long-term period

Quantifying hydrologic exchange fluxes (HEF) at the river and subsurface interface and their residence times (RT) in subsurface are important for managing the water quality and ecosystem health in dynamic river corridor systems. In this study, a modeling framework is developed for coupling the three-dimensional (3D) multi-phase surface, subsurface flow transport, and numerical tracer model for RT in a large-scale river section over a long period. The framework is utilized to evaluate the impacts of hydrodynamic pressure on HEFs and RT for a 30 km section of the Columbia River in Washington State over a three-year period. Based on comparisons between model simulations with and without considering hydrodynamic pressure, we found that hydrodynamic pressure increases the net HEFs by 7% with river gaining water from the subsurface domain, and leads to slight reduction of RT.

54 ENVIRONMENTAL SCIENCES↗

Modeling Terrestrial Dissolved Organic Carbon Loading to Western Arctic Rivers

The mobilization and land-to-ocean transfer of dissolved organic carbon (DOC) in Arctic watersheds is intricately linked with the region's climate and water cycle, and furthermore at risk of changes from climate warming and associated impacts. This study quantifies model-simulated estimates of runoff, surface and active layer leachate DOC concentrations and loadings to western Arctic rivers, specifically for basins that drain into coastal waters between and including the Yukon and Mackenzie Rivers. Model validation leverages data from other field measurements, synthesis studies, and modeling efforts. The simulations effectively quantify DOC leaching in surface and subsurface runoff and broadly capture the seasonal cycle in DOC concentration and mass loadings reported from other studies that use river-based measurements. A marked east-west gradient in simulated spring and summer DOC concentrations of 24 drainage basins on the North Slope of Alaska is captured by the modeling, consistent with independent data derived from river sampling. Simulated loadings for the Mackenzie and Yukon show reasonable agreement with estimates of DOC export for annual totals and four of the six seasonal comparisons. Nearly equivalent loading occurs to rivers which drain north to the Beaufort Sea and west to the Bering and Chukchi Seas. The modeling framework provides a basis for understanding carbon export to coastal waters and for assessing impacts of hydrological cycle intensification and permafrost thaw with ongoing warming in the Arctic.

54 ENVIRONMENTAL SCIENCES↗

River systems under peaked stress

The change in the global energy production mix towards variable renewable energy sources requires efficient utilization of regulated rivers to optimise hydropower operations meet the needs of a changing energy market. However, the flexible operation of hydropower plants causes non-natural, sub-daily fluctuating flows in the receiving water bodies, often referred to as ‘hydropeaking’. Drastic changes in sub-daily flow regimes undermine attempts to improve river system health. Environmental decision makers, including permitting authorities and river basin managers facing the intense and increasing pressure on river environments, should consider ecosystem services and biodiversity issues more thoroughly. The need for research innovations in hydropeaking operation design to fulfil both the water and energy security responsibilities of hydropower is highlighted. Our paper outlines optimized hydropeaking design as a future research direction to help researchers, managers, and decision-makers prioritize actions that could enable better integration of river science and energy system planning. The goal of this is to find a balanced hydropower operation strategy.

54 ENVIRONMENTAL SCIENCES↗

pyflowline: a mesh-independent river network generator for hydrologic models

River networks are crucial in hydrologic and Earth system models. Accurately representing river networks in spatially distributed hydrologic models requires considering the model's spatial discretization and computational mesh. However, current methods of generating river networks for hydrologic models do not typically support unstructured meshes. Unstructured meshes offer numerous advantages over traditional, structured meshes. To overcome this limitation, we developed PyFlowline, a Python package that generates mesh-independent river networks. With PyFlowline, hydrologic modelers can generate conceptual river networks and their topological relationships for both structured and unstructured meshes.

47 OTHER INSTRUMENTATION↗

Using Community Science to Reveal the Global Chemogeography of River Metabolomes

River corridor metabolomes reflect organic matter (OM) processing that drives aquatic biogeochemical cycles. Recent work highlights the power of ultrahigh-resolution mass spectrometry for understanding metabolome composition and river corridor metabolism. However, there have been no studies on the global chemogeography of surface water and sediment metabolomes using ultrahigh-resolution techniques. Here, we describe a community science effort from the Worldwide Hydrobiogeochemistry Observation Network for Dynamic River Systems (WHONDRS) consortium to characterize global metabolomes in surface water and sediment that span multiple stream orders and biomes. We describe the distribution of key aspects of metabolomes including elemental groups, chemical classes, indices, and inferred biochemical transformations. We show that metabolomes significantly differ across surface water and sediment and that surface water metabolomes are more rich and variable. We also use inferred biochemical transformations to identify core metabolic processes shared among surface water and sediment. Finally, we observe significant spatial variation in sediment metabolites between rivers in the eastern and western portions of the contiguous United States. Our work not only provides a basis for understanding global patterns in river corridor biogeochemical cycles but also demonstrates that community science endeavors can enable global research projects that are unfeasible with traditional research models.

54 ENVIRONMENTAL SCIENCES↗

The Straightening of a River Meander Leads to Extensive Losses in Flow Complexity and Ecosystem Services

To assist river restoration efforts we need to slow the rate of river degradation. This study provides a detailed explanation of the hydraulic complexity loss when a meandering river is straightened in order to motivate the protection of river channel curvature. We used computational fluid dynamics (CFD) modeling to document the difference in flow dynamics in nine simulations with channel curvature (C) degrading from a well-established tight meander bend (C = 0.77) to a straight channel without curvature (C = 0). To control for covariates and slow the rate of loss to hydraulic complexity, each of the nine-channel realizations had equivalent bedform topography. The analyzed hydraulic variables included the flow surface elevation, streamwise and transverse unit discharge, flow velocity at streamwise, transverse, and vertical directions, bed shear stress, stream function, and the vertical hyporheic flux rates at the channel bed. The loss of hydraulic complexity occurred gradually when initially straightening the channel from C = 0.77 to C = 0.33 (i.e., the radius of the channel is three-times the channel width), and additional straightening incurred rapid losses to hydraulic complexity. Other studies have shown hydraulic complexity provides important riverine habitat and is positively correlated with biodiversity. This study demonstrates how hydraulic complexity can be gradually and then rapidly lost when unwinding a river, and hopefully will serve as a cautionary tale.

54 ENVIRONMENTAL SCIENCES↗