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NASA NTRS2002

A Study of Standing Pressure Waves Within Open and Closed Acoustic Resonators

The first section of the results presented herein was conducted on an axisymmetric resonator configured with open ventilation ports on either end of the resonator, but otherwise closed and free from obstruction. The remaining section presents the results of a similar resonator shape that was closed, but contained an axisymmetric blockage centrally located through the axis of the resonator. Ambient air was used as the working fluid. In each of the studies, the resonator was oscillated at the resonant frequency of the fluid contained within the cavity while the dynamic pressure, static pressure, and temperature of the fluid were recorded at both ends of the resonator. The baseline results showed a marked reduction in the amplitude of the dynamic pressure waveforms over previous studies due to the use of air instead of refrigerant as the working fluid. A sharp reduction in the amplitude of the acoustic pressure waves was expected and recorded when the configuration of the resonators was modified from closed to open. A change in the resonant frequency was recorded when blockages of differing geometries were used in the closed resonator, while acoustic pressure amplitudes varied little from baseline measurements.

Daniels, C.↗

NASA NTRS1992

Laser-spectroscopic measurement techniques for hypersonic, turbulent wind tunnel flows

A review is given of the nature, present status, and capabilities of two laser spectroscopic methods for the simultaneous measurement of temperature, density, and their fluctuations owing to turbulence in high speed wind tunnel flows. One method is based on the two frequency excitation of nitric oxide seeded into a nitrogen flow, using tunable dye lasers. The second, more recent method relies on the excitation of oxygen in air flows using a tunable, ArF excimer laser. Signal are obtained from both the laser induced fluorescence and from Raman scattering of the same laser pulse. Measurements are demonstrated in the turbulent boundary layer of a Mach-2 channel flow.

Mckenzie, Robert L.↗

NASA NTRS1998

Tone Noise and Nearfield Pressure Produced by Jet-Cavity Interaction

Cavity flow resonance can cause numerous problems in aerospace applications. While our long-term goal is to understand cavity flows well enough to devise effective cavity resonance suppression techniques, this paper describes a fundamental study of resonant tones produced by jet-cavity interaction at subsonic and supersonic speeds. Our specific jet-cavity configuration can also be used as a test bed for evaluating active and passive flow resonance control concepts. Two significant findings emerge from this study. 1) Originally, we expected that tones produced by jet-cavity interaction would resemble cavity tones or jet tones or would involve some simple combinations of each. The experimental data do not support these expectations: instead, the jet cavity interaction produce a unique set of tones. We propose simple yet and physically insightful correlations for these tones. Although the pressure patterns on the cavity floor display very complex variations with the Mach number for a length/depth = 8 cavity, the tones correspond to the acoustic modes of the cavity-independent of flow. For a length/ depth = 3 cavity, however, a surprise emerges: the pressure patterns on the cavity floor are not so complex but the tones depend significantly on the flow. Additionally, we examine the role of external feedback unique to jet-cavity interaction. 2) Previous research led us to expect that traditional classifications (open, transitional, or closed) for cavities in an infinite flight stream would be insensitive to small changes in Mach number and would depend primarily on cavity length/depth ratios. Use of the novel high resolution photoluminescent pressure sensitive paint shows that the classifications are actually quite sensitive to jet Mach number for a length/depth = 8 cavity. However, these classifications provide no guidance whatsoever for tone amplitude or frequency. Detailed experimental data and insights presented here will assist researchers who are performing numerical simulations of jet-cavity flows as a first step toward devising resonance suppression methods.

Raman, Ganesh↗

NASA NTRS1987

Raman spectroscopic investigations of Hg-Cd-Te melts

Raman scattering measurements are reported for a series of Hg sub1-xCd subxTe (with x less than or =0.2) materials from 295 K (room temperature) to 1126K (up to and above their liquidus temperatures), and for Hg sub1-xCd subxTe (x=0.3) at 285K. The samples were contained in high-temperature optically-flat fused silica cell. Variable temperature measurements were effected in a three-zone, high-temperature furnace equipped with optical windows, and monitored externally by three independently programmable temperature controllers. All studies were made in the backscattering geometry using the 5145 A line of an Ar+ ion laser, with incident power less than 250 mW, as the excitiation source. An intensity enhancement is observed for a mode in each of the compositions studied. The frequency of this mode varies with composition, 142/cm for HgTe, and 128/cm for both the Hg sub1-xCd subxTe (x=0.053 and 0.204) samples. In addition, a shift to lower frequency as a function of temperature is observed in all samples. This shift is most prominent for the x=0.053 sample. The temperature dependence of these modes as the liquidus temperatures are achieved and surpassed for these samples is presented as being associated with a structural transition in the Hg-rich compositions of the Hg sub1-xCd subxTe series. To our knowledge, this is the first reported study of Raman scattering by phonons in the melts of these materials.

Morrobel-Sosa, Anny↗

NASA NTRS1972

Vibrational spectra and structure of azomethane and azomethane-d6.

The infrared and Raman spectra of azomethane and azomethane-d(6) were examined in detail. Vibrational data provided definitive verification of a trans-structure with C(2h) symmetry. A vibrational assignment is proposed for the 24 fundamental modes based upon the observed contours, isotopic shift ratios, and group frequency correlations. Spectra of the polycrystalline samples indicate that there are at least four molecules per unit cell, since a number of the bands were observed to be split into doublets. The crystal also appeared to have a center of symmetry, since mutual exclusion was clearly operative.

Durig, J. R.↗

NASA NTRS1985

Raman spectra of solid benzene under high pressure

Raman spectra of solid benzene have been measured at room temperature up to about 140 kbar, using the diamond anvil cell. Effort has been focused upon the lattice vibration spectra at pressures above that of phase II. It is found that a change in slopes occurs in the frequency-pressure curves at about 40 kbar. Furthermore, a new band appears above 90 kbar. These features probably correspond respectively to the II-III phase transition, which has been reported previously, and a III-IV phase transition, reported here for the first time.

Thiery, M.-M.↗

NASA NTRS1991

Multiple Stokes wavelength generation in H2, D2, and CH4 for lidar aerosol measurements

Experimental results are reported of multiple Stokes generation of a frequency-doubled Nd:YAG laser in H2, D2, and CH4 in a focusing geometry. The energies at four Stokes orders were measured as functions of pump energy and gas pressure. The characteristics of the Stokes radiation generated in these gases are compared for optical production of multiple wavelengths. The competition between Raman components is analyzed in terms of cascade Raman scattering and four-wave mixing. The results indicate the possibility of using these generation processes for atmospheric aerosol measurements by means of multiwavelength lidar systems. Also, this study distinguishes between the gases, as regards the tendency to produce several wavelengths (H2,D2) versus the preference to produce mainly first Stokes radiation (CH4).

Chu, Zhiping↗

NASA NTRS1993

Development of phased twin flip-flop jets

The flip-flop nozzle is a device that can produce an oscillating jet flow without any moving parts. There is now a renewed interest in such nozzles due to their potential for use as excitation devices in practical applications. An experiment aimed at developing twin flip-flop jets that operate at prescribed frequencies and phase differences was performed. The phasing was achieved using two different nozzle interconnection schemes. In one configuration the two jets flapped in-phase and in another they flapped out-of-phase with respect to each other. In either configuration the frequencies of oscillation of both jets were equal. When one of the jets was run at a constant high velocity and the velocity of the second jet was increased gradually, the higher velocity jet determined the frequency of oscillation of both jets. The two flip-flop jet configurations described could be used to excite a primary jet flow in either an anti-symmetric (sinuous) or a symmetric (varicose) mode.

Raman, Ganesh↗

NASA NTRS1994

Mixing and Noise Benefit Versus Thrust Penalty in Supersonic Jets Using Impingement Tones

This paper reports the results of an experimental investigation on the effect of impingement tones generated by obstacles of various geometries on the spreading of a supersonic jet flow. A rectangular supersonic jet was produced using a convergent-divergent nozzle that was operated near its design point (with shocks minimized). The immersion of obstacles in the flow produced an intense impingement tone which then propagated upstream (as feedback) to the jet lip and excited the antisymmetric hydrodynamic mode in the jet, thus setting up a resonant self-sustaining loop. The violent flapping motion of the jet due to excitation of the antisymmetric mode, combined with the unsteady wakes of the obstacles, produced large changes in jet mixing. It was possible to control the frequency and amplitude of the impingement tone excitation by varying the nozzle-to-obstacle distance and the obstacle immersion. By proper shaping of the obstacles it was possible to reduce the thrust penalty significantly.

Raman, Ganesh↗

NASA NTRS1989

Multiple relaxation and inhomogeneous broadening in resonance enhanced Raman scattering - Application to tunable infrared generation

The solutions for the imaginary susceptibility of the Raman field transition with arbitrary relaxation rates and field strengths are examined for differing sets of relaxation rates with emphasis on alkali metal vapors which have spontaneous emission dominated relaxation. The model is further expanded to include Doppler broadening and used to predict the peak gain as a function of detuning for a frequency doubled alexandrite laser-pumped cesium vapor gain cell.

Ryan, J. C.↗

NASA NTRS1975

Vibrational spectra and structure of biphosphine and biphosphine-d4

Infrared and Raman spectra have been obtained for biphosphine and biphosphine-d4 in both solid and vapor phases. From the spectral data, it is concluded that only one conformer exists in both solid and fluid phases and that this is the gauche conformer. A normal-coordinate analysis has also been performed, in which the 24 vibrational frequencies of the two isotopes have been fitted by 10 force constants to an overall average error of 1.0%. The PED indicates that there is practically no mixing of the normal modes in the P2H4 molecule but the P-P stretch and the PD2 wagging modes are extensively mixed for the P2D4 molecule.

Odom, J. D.↗

NASA NTRS2006

The Dryline on 22 May 2002 during IHOP_2002: Convective-Scale Measurements at the Profiling Site

A detailed analysis of the structure of a double dryline observed over the Oklahoma panhandle during the first International H2O Project (IHOP_2002) convective initiation (CI) mission on 22 May 2002 is presented. A unique and unprecedented set of high temporal and spatial resolution measurements of water vapor mixing ratio, wind, and boundary layer structure parameters were acquired using the National Aeronautics and Space Administration (NASA) scanning Raman lidar (SRL), the Goddard Lidar Observatory for Winds (GLOW), and the Holographic Airborne Rotating Lidar Instrument Experiment (HARLIE), respectively. These measurements are combined with the vertical velocity measurements derived from the National Center for Atmospheric Research (NCAR) Multiple Antenna Profiler Radar (MAPR) and radar structure function from the high-resolution University of Massachusetts frequency-modulated continuous-wave (FMCW) radar to reveal the evolution and structure of the late afternoon double-dryline boundary layer. The eastern dryline advanced and then retreated over the Homestead profiling site in the Oklahoma panhandle, providing conditions ripe for a detailed observation of the small-scale variability within the boundary layer and the dryline. In situ aircraft data, dropsonde and radiosonde data, along with NCAR S-band dual-polarization Doppler radar (S-Pol) measurements, are also used to provide the larger-scale picture of the double-dryline environment. Moisture and temperature jumps of about 3 g kg(sup -1) and 1 -2 K, respectively, were observed across the eastern radar fine line (dryline), more than the moisture jumps (1-2 g kg(sup -1)) observed across the western radar fine line (secondary dryline). Most updraft plumes observed were located on the moist side of the eastern dryline with vertical velocities exceeding 3 m s(sup -1) and variable horizontal widths of 2-5 km, although some were as wide as 7-8 km. These updrafts were up to 1.5 g kg(sup -1) moister than the surrounding environment. Although models suggested deep convection over the Oklahoma panhandle and several cloud lines were observed near the dryline, the dryline itself did not initiate any storms over the intensive observation region (IOR). Possible reasons for this lack of convection are discussed. Strong capping inversion and moisture detrainment between the lifting condensation level and the level of free convection related to an overriding drier air, together with the relatively small near-surface moisture values (less than 10 g kg(sup -1)), were detrimental to CI in this case.

Demoz, Belay↗

NASA NTRS1995

Raman Spectroscopy as a Method for Mineral Identification on Lunar Robotic Exploration Missions

The sharp, nonoverlapping Raman bands for plagioclase, pyroxene, and olivine would be advantageous for on-surface, active mineralogical analysis of lunar materials. A robust, light-weight, low-power, rover-based Raman spectrometer with a laser exciting source, entirely transmission-mode holographic optics, and a charge-coupled device (CCD) detector could fit within a less than 20 cm cube. A sensor head on the end of an optical fiber bundle that carried the laser beam and returned the scattered radiation could be placed against surfaces at any desired angle by a deployment mechanism; otherwise, the instrument would need no moving parts. A modem micro-Raman spectrometer with its beam broadened (to expand the spot to 50-micrometer diameter) and set for low resolution (7/cm in the 100-1400/cm region relative to 514.5-nm excitation), was used to simulate the spectra anticipated from a rover instrument. We present spectra for lunar mineral grains, less than 1 mm soil fines, breccia fragments, and glasses. From frequencies of olivine peaks, we derived sufficiently precise forsterite contents to correlate the analyzed grains to known rock types and we obtained appropriate forsterite contents from weak signals above background in soil fines and breccias. Peak positions of pyroxenes were sufficiently well determined to distinguish among orthorhombic, monoclinic, and triclinic (pyroxenoid) structures; additional information can be obtained from pyroxene spectra, but requires further laboratory calibration. Plagioclase provided sharp peaks in soil fines and most breccias even when the glass content was high.

Wang, Alian↗

NASA NTRS1975

Tunable lasers and their application in analytical chemistry

The impact that laser techniques might have in chemical analysis is examined. Absorption, scattering, and heterodyne detection is considered. Particular emphasis is placed on the advantages of using frequency-tunable sources, and dye solution lasers are regarded as the outstanding example of this type of laser. Types of spectroscopy that can be carried out with lasers are discussed along with the ultimate sensitivity or minimum detectable concentration of molecules that can be achieved with each method. Analytical applications include laser microprobe analysis, remote sensing and instrumental methods such as laser-Raman spectroscopy, atomic absorption/fluorescence spectrometry, fluorescence assay techniques, optoacoustic spectroscopy, and polarization measurements. The application of lasers to spectroscopic methods of analysis would seem to be a rewarding field both for research in analytical chemistry and for investments in instrument manufacturing.

Steinfeld, J. I.↗

NASA NTRS1983

Measurements of a supersonic velocity in a nitrogen flow using inverse Raman spectroscopy

Results are presented for supersonic molecular flow-velocity measurements using inverse Raman spectroscopy. The flow velocity, temperature, and density of flowing N2 molecules are measured because of potential wind-tunnel applications. Uncertainties of less than 5% are found for the velocity measurements, while the uncertainties are about 10% for the temperature and density measurements. The laser probe is stabilized by using I2 fluorescence, and I2 saturated absorption is utilized to provide an absolute frequency reference. Differential detection techniques are employed to reduce detection noise.

Herring, G. C.↗

NASA NTRS1986

Infrared absorption and emission characteristics of interstellar PAHs

The mid-infrared interstellar emission spectrum with features at 3.28, 6.2, 7.7, 8.7 and 11.3 microns is discussed in terms of the Polycyclic Aromatic Hydrocarbon (PAH) hypothesis, which is based on the suggestive, but inconclusive comparison between the interstellar emission spectrum with the infrared absorption and Raman spectra of a few PAHs. The fundamental vibrations of PAHs and PAH-like species which determine the IR and Raman properties are discussed. Interstellar IR band emission is due to relaxation from highly vibrationally excited PAHs excited by ultraviolet photons. The excitation/emission process is described and the IR fluorescence from one PAH, chrysene, is traced. Generally, there is sufficient energy to populate several vibrational levels in each mode. Molecular vibrational potentials are anharmonic and emission from these higher levels will fall at lower frequencies and produce weak features to the red of the stronger fundamentals. This process is also described and can account for some spectroscopic details of the interstellar emission spectra previously unexplained. Analysis of the interstellar spectrum shows that PAHs contain between 20 and 30 carbon atoms are responsible for the emission.

Barker, J. R.↗

NASA NTRS1987

Infrared absorption and emission characteristics of interstellar PAHs

Allamandola, L. J.↗

NASA NTRS1991

Control of an axisymmetric turbulent jet by multi-modal excitation

Experimental measurements of naturally occurring instability modes in the axisymmetric shear layer of high Reynolds number turbulent jet are presented. The region up to the end of the potential core was dominated by the axisymmetric mode. The azimuthal modes dominated only downstream of the potential core region. The energy content of the higher order modes (m is greater than 1) was significantly lower than that of the axisymmeteric and m = + or - 1 modes. Under optimum conditions, two-frequency excitation (both at m = 0) was more effective than single frequency excitation (at m = 0) for jet spreading enhancement. An extended region of the jet was controlled by forcing combinations of both axisymmetric (m = 0) and helical modes (m = + or - 1). Higher spreading rates were obtained when multi-modal forcing was applied.

Raman, Ganesh↗