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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

The use of four-photon Raman spectroscopy for the remote sensing of natural objects

The results of the laboratory simulation of optical Kerr effect/Raman spectroscopy for the purpose of remote sensing are presented. The experimental setup is described, and measurements of the vibrational spectra of various liquids obtained. Attention is paid to the possibility of using the proposed method to detect trace hydrocarbons in water, and the spectrum of petroleum is obtained. Full-scale measurements using a laser spectrometer were made on the Black Sea.

Bunkin, A. F.↗
NASA NTRS2006

Observations over Hurricanes from the Ozone Monitoring Instrument

There is an apparent inconsistency between the total column ozone derived from the total ozone mapping spectrometer (TOMS) and aircraft observations within the eye region of tropical cyclones. The higher spectral resolution, coverage, and sampling of the ozone monitoring instrument (OMI) on NASA s Aura satellite as compared with TOMS allows for improved ozone retrievals by including estimates of cloud pressure derived simultaneously using the effects of rotational Raman scattering. The retrieved cloud pressures from OM1 are more appropriate than the climatological cloud-top pressures based on infrared measurements used in the TOMS and initial OM1 algorithms. We find that total ozone within the eye of hurricane Katrina is significantly overestimated when we use climatological cloud pressures. Using OMI-retrieved cloud pressures, total ozone in the eye is similar to that in the surrounding area. The corrected total ozone is in better agreement with aircraft measurements that imply relatively small or negligible amounts of stratospheric intrusion into the eye region of tropical cyclones.

Joiner, J.↗
DOE OSTI2022

Portable diagnostic package for Thomson scattering and optical emission spectroscopy on Princeton field-reversed configuration 2 (PFRC 2)

An Advanced Research Projects Agency-Energy funded diagnostic system has been deployed to the Princeton field-reversed configuration 2 (PFRC-2) device, located at Princeton Plasma Physics Laboratory. The Portable Diagnostic Package (PDP), designed at Oak Ridge National Laboratory, allows for the measurement of Thomson Scattering (TS) for electron density and temperature and Optical Emission Spectroscopy (OES) for ion temperature, impurity density, and ion velocity. A tunable spectrometer on the PDP with three gratings provides the flexibility to measure low (1 eV) and high (1000 eV) electron temperature ranges from TS. Additionally, using a second spectrometer, the OES diagnostic can survey light emission from various ion excitation levels for wide wavelength ranges. The electron density (<2 × 10 19 m –3 ) of plasmas generated in PFRC-2 has been below the PDP TS discrimination threshold, which has made TS signal detection challenging against a high-background of laser stray light. The laser stray light was iteratively reduced by making modifications to the entrance and exit geometry on PFRC-2. Rayleigh scattering experiments on PFRC have yielded the TS discrimination sensitivity to be >1 × 10 20 m –3 for the PDP. A recently implemented narrow-band notch spectral filter that masks the second harmonic 532 nm Nd:YAG laser wavelength has increased the system’s TS light discrimination sensitivity 65 times compared to the instance when the notch filter was not implemented. The hardware implementation including design changes to the flight tubes and Brewster windows will be discussed, along with results from Rayleigh and rotational Raman scattering sensitivity analyses, which were used to establish a quantitative figure of merit on the system performance. Further, the Raman scattering calibration with the notch filter has improved the PDP electron density threshold to 1 ± 0.5 × 10 18 m –3 .

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Demonstration of an x-ray Raman spectroscopy setup to study warm dense carbon at the high energy density instrument of European XFEL

We present a proof-of-principle study demonstrating x-ray Raman Spectroscopy (XRS) from carbon samples at ambient conditions in conjunction with other common diagnostics to study warm dense matter, performed at the high energy density scientific instrument of the European x-ray Free Electron Laser (European XFEL). We obtain sufficient spectral resolution to identify the local structure and chemical bonding of diamond and graphite samples, using highly annealed pyrolytic graphite spectrometers. Due to the high crystal reflectivity and XFEL brightness, we obtain signal strengths that will enable accurate XRS measurements in upcoming pump–probe experiments with a high repetition-rate, where the samples will be pumped with high-power lasers. Molecular dynamics simulations based on density functional theory together with XRS simulations demonstrate the potential of this technique and show predictions for high-energy-density conditions. Our setup allows simultaneous implementation of several different diagnostic methods to reduce ambiguities in the analysis of the experimental results, which, for warm dense matter, often relies on simplifying model assumptions. The promising capabilities demonstrated here provide unprecedented insights into chemical and structural dynamics in warm dense matter states of light elements, including conditions similar to the interiors of planets, low-mass stars, and other celestial bodies.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1976

Planetary astronomy

Color and spectral data from spectrometer observations and computerized analyses of asteroid spectra are discussed. Potential occultations of bright asteroids by the moon are summarized. Analysis of anisotropic scattering within Saturn's rings indicates that mineral contamination of the 120 particles cannot exceed 5 percent by weight, and that the rings formed from particle breakup rather than from particle condensation. Raman probe applications to Jupiter and Uranus atmospheres indicate the presence of aerosol particles. A review of Mariner 9 Mars cloud topography data establishes that most blue clouds are orographic uplift clouds composed of condensates, and that sporadic red clouds are associated with blue clouds or volcanoes and thus probably do not represent dust storm phenomena.

Source record↗
NASA NTRS2017

Field Exploration and Life Detection Sampling Through Planetary Analogue Sampling (FELDSPAR).

Exploration missions to Mars rely on rovers to perform analyses over small sampling areas; however, landing sites for these missions are selected based on large-scale, low-resolution remote data. The use of Earth analogue environments to estimate the multi-scale spatial distributions of key signatures of habitability can help ensure mission science goals are met. A main goal of FELDSPAR is to conduct field operations analogous to Mars sample return in its science, operations, and technology from landing site selection, to in-field sampling location selection, remote or stand-off analysis, in situ analysis, and home laboratory analysis. Lava fields and volcanic regions are relevant analogues to Martian landscapes due to desiccation, low nutrient availability, and temperature extremes. Operationally, many Icelandic lava fields are remote enough to require that field expeditions address several sampling constraints that are experienced in robotic exploration, including in situ and sample return missions. The Fimmvruhls lava field was formed by a basaltic effusive eruption associated with the 2010 Eyjafjallajkull eruption. Mlifellssandur is a recently deglaciated plain to the north of the Myrdalsjkull glacier. Holuhraun was formed by a 2014 fissure eruptions just north of the large Vatnajkull glacier. Dyngjusandur is an alluvial plain apparently kept barren by repeated mechanical weathering. Informed by our 2013 expedition, we collected samples in nested triangular grids every decade from the 10 cm scale to the 1 km scale (as permitted by the size of the site). Satellite imagery is available for older sites, and for Mlifellssandur, Holuhraun, and Dyngjusandur we obtained overhead imagery at 1 m to 200 m elevation. PanCam-style photographs were taken in the field by sampling personnel. In-field reflectance spectroscopy was also obtained with an ASD spectrometer in Dyngjusandur. All sites chosen were 'homogeneous' in apparent color, morphology, moisture, grain size, and reflectance spectra at all scales greater than 10 cm. Field lab assays were conducted to monitor microbial habitation, including ATP quantification, qPCR for fungal, bacterial, and archaeal DNA, and direct cell imaging using fluorescence microscopy. Home laboratory analyses include Raman spectroscopy and community sequencing. ATP appeared to be significantly more sensitive to small changes in sampling location than qPCR or fluorescence microscopy. Bacterial and archaeal DNA content were more consistent at the smaller scales, but similarly variable across more distant sites. Conversely, cell counts and fungal DNA content have significant local variation but appear relatively homogeneous over scales of 1 km. ATP, bacterial DNA, and archaeal DNA content were relatively well correlated at many spatial scales. While we have observed spatial variation at various scales and are beginning to observe how that variation fluctuates over time as biodiversity recovers after an eruption, we do not yet fully understand what parameters lead to the observed spatial variation. Home laboratory analyses will help us further understand the elemental and structural composition of the basaltic matrices, but further field analyses are vital for the understanding how temperature, moisture, incident radiation, and so forth influence the habitability of a microclimate.

Field↗
NASA NTRS1988

Insoluble organic material of the Orgueil carbonaceous chondrite and the unidentified infrared bands

Infrared spectra have been obtained of the acid insoluble residue, residue after heating in vacuum, and condensate of the Orgueil carbonaceous chondrite using an FTIR spectrometer. Bulk acid insoluble residue was pressed into KBr pellets and also heated under high vacuum to sublimate a volatile component onto KBr disks. The remaining nonvolatile organic component of the meteorite from such evaporations pressed into KBr pellets exhibits a spectral signature similar to that observed in emission from the Orion Nebula and found in Raman spectra of interplanetary dust particles. It also has an 11.3 micron band indicating polycyclic aromatic hydrocarbons (PAHs) having single hydrogens per peripheral aromatic ring. It is concluded that the nonvolatile material is similar to interstellar PAHs since the observed 11.3 micron unidentified infrared emission suggests interstellar PAHs have single hydrogens per peripheral aromatic ring.

Wdowiak, Thomas J.↗
NASA NTRS1998

Raman Lidar Measurements of Aerosol Extinction and Backscattering: Derivation of Aerosol Real Refractive Index, Single-Scattering Albedo, and Humidification Factor using Raman Lidar and Aircraft Size Distribution - Report 2

Aerosol backscattering and extinction profiles measured by the NASA Goddard Space Flight Center Scanning Raman Lidar (SRL) during the remote cloud sensing (RCS) intensive operations period (IOP) at the Department of Energy Atmospheric Radiation Measurement (ARM) southern Great Plains (SGP) site during two nights in April 1994 are discussed. These profiles are shown to be consistent with the simultaneous aerosol size distribution measurements made by a PCASP (Passive Cavity Aerosol Spectrometer Probe) optical particle counter flown on the University of North Dakota Citation aircraft. We describe a technique which uses both lidar and PCASP measurements to derive the dependence of particle size on relative humidity, the aerosol real refractive index n, and estimate the effective single-scattering albedo Omega(sub 0). Values of n ranged between 1.4-1.5 (dry) and 1.37-1.47 (wet); Omega(sub 0) varied between 0.7 and 1.0. The single-scattering albedo derived from this technique is sensitive to the manner in which absorbing particles are represented in the aerosol mixture; representing the absorbing particles as an internal mixture rather than the external mixture assumed here results in generally higher values of Omega(sub 0). The lidar measurements indicate that the change in particle size with relative humidity as measured by the PCASP can be represented in the form discussed by Hattel with the exponent gamma = 0.3 + or - 0.05. The variations in aerosol optical and physical characteristics captured in the lidar and aircraft size distribution measurements are discussed in the context of the meteorological conditions observed during the experiment.

Ferrare, R. A.↗
NASA NTRS2000

Optical Measurement and Visualization in High-Pressure, High-Temperature, Aviation Gas Turbine Combustors

Planar laser-induced fluorescence (PLIF), planar Mie scattering (PMie), and linear (1-D) spontaneous Raman scattering are applied to flame tube and sector combustors that burn Jet-A fuel at a range of inlet temperatures and pressures that simulate conditions expected in future high-performance civilian gas turbine engines. Chemiluminescence arising from C2 in the flame was also imaged. Flame spectral emissions measurements were obtained using a scanning spectrometer. Several different advanced concept fuel injectors were examined. First-ever PLIF and chemiluminescence data are presented from the 60-atm Gas turbine combustor facility.

Hicks, Yolanda R.↗
NASA NTRS2006

Simultaneous CARS and Interferometric Rayleigh Scattering

This paper reports for the first time the combination of a dual-pump coherent anti-Stokes Raman scattering system with an interferometric Rayleigh scattering system (CARS - IRS) to provide time-resolved simultaneous measurement of multiple properties in combustion flows. The system uses spectrally narrow green (seeded Nd:YAG at 532 nm) and yellow (552.9 nm) pump beams and a spectrally-broad red (607 nm) beam as the Stokes beam. A spectrometer and a planar Fabry-Perot interferometer used in the imaging mode are used to record the spectrally broad CARS spectra and the spontaneous Rayleigh scattering spectra, respectively. Time-resolved simultaneous measurement of temperature, absolute mole fractions of N2, O2, and H2, and two components of velocity in a Hencken burner flame were performed to demonstrate the technique.

Bivolaru, Daniel↗
NASA NTRSDate not supplied

Heating and Sampling Efficiency Evaluation for the Nephele Venus Cloud Sampling Mission Concept

Nephele is a descent probe concept with a unique combination of entry (3D-CC+HEEET), sampling (flow-through passive impactors), and optics (laser-induced breakdown spectroscopy, or LIBS, and surface-enhanced Raman spectroscopy, or SERS), technologies with two key innovations. The first is the integration of the aerosol sampling inlet into the aeroshell body, allowing the possibility of sampling during passive descent without separation. The second is the use of the aerosol capture surface as an optical analysis substrate, allowing fast-cadence aerosol analysis via a dual optical spectrometer instead of mass spectrometry. Although this concept shares some features with other efforts such as Cupid’s Arrow (single-body sample capture system), DAVINCI and Venera-D (use of an optical spectrometer), Nephele is unique in its physical integration of the sonde body, aerosol and gas sampler, and analysis instrumentation. This innovation is designed to eliminate the need for a controlled descent to achieve a detailed atmospheric aerosol transect, which offers in situ planetary science in a small spacecraft envelope. Aeroshell designs with inlets for free-falling sondes are well-understood, though not yet assessed for aerosol capture efficiency. A HEEET aeroshell with a specialized nose inlet material comprised of Carbon-Carbon is proposed for this mission concept.

Venus↗
NASA NTRSDate not supplied

Heating and Sampling Efficiency Evaluation for the Nephele Venus Cloud Sampling Mission Concept

Nephele [1] is a descent probe concept with a unique combination of entry (3D-CC+HEEET), sampling (flow-through passive impactors), and optics (laser-induced breakdown spectroscopy, or LIBS, and surface-enhanced Raman spectroscopy, or SERS), technologies with two key innovations (Figure 1). The first is the integration of the aerosol sampling inlet into the aeroshell body, allowing the possibility of sampling during passive descent without separation. The second is the use of the aerosol capture surface as an optical analysis substrate, allowing fast-cadence aerosol analysis via a dual optical spectrometer instead of mass spectrometry. Although this concept shares some features with other efforts such as Cupid’s Arrow [1] (single-body sample capture system), DAVINCI [2] and Venera-D [3] (use of an optical spectrometer), Nephele is unique in its physical integration of the sonde body, aerosol and gas sampler, and analysis instrumentation. This innovation is designed to eliminate the need for a controlled descent to achieve a detailed atmospheric aerosol transect, which offers in situ planetary science in a small spacecraft envelope. Aeroshell designs with inlets for free-falling sondes are well-understood, though not yet assessed for aerosol capture efficiency. A HEEET aeroshell with a specialized nose inlet material comprised of Carbon-Carbon is proposed for this mission concept.

Venus↗
NASA NTRS1987

The dependence of electroglow on the solar flux

Data from Voyager 2 UV spectrometer observations of electroglow at wavelengths below 110 nm in the atmospheres of Saturn, Jupiter, and Uranus are presented in extensive tables and graphs, analyzed statistically, and compared with the predictions of theoretical models. Findings reported include (1) a dependence (to within 10 percent) of electroglow intensity on the inverse square of heliocentric distance, (2) Uranian electroglow spectra consistent with Rayleigh-Raman scattering of sunlight, and (3) local-time electroglow variations suggesting a solar-flux-dependent excitation mechanism. Mechanisms involving the fluorescence of solar UV radiation in the H2 Lyman and Werner bands or H(-) photolysis are discussed.

Yelle, Roger V.↗
NASA NTRS2003

The Mars Underground Mole (MUM): A Subsurface Penetration Device with Infrared Reflectance and Raman Spectroscopic Sensing Capability

Searching for evidence of life on Mars will probably require access to the subsurface. The Martian surface is bathed in ultraviolet radiation which decomposes organic compounds, destroying possible evidence for life. Also, experiments performed by the Viking Landers imply the presence of several strongly oxidizing compounds at the Martian surface that may also play a role in destroying organic compounds near the surface. While liquid water is unstable on the Martian surface, and ice is unstable at the surface at low latitudes, recent results from the Mars Odyssey Gamma Ray Spectrometer experiment indicate that water ice is widely distributed near the surface under a thin cover of dry soil. Organic compounds created by an ancient Martian biosphere might be preserved in such ice-rich layers. Furthermore, accessing the subsurface provides a way to identify unique stratigraphy such as small-scale layering associated with lacustrine sediments. Subsurface access might also provide new insights into the Mars climate record that may be preserved in the Polar Layered Deposits. Recognizing the importance of accessing the subsurface of Mars to the future scientific exploration of the planet, the Mars Surveyor 2007 Science Definition Team called for drilling beneath the surface soils. Subsurface measurements are also cited as high priority in by MEPAG. Recognizing the importance of accessing the Martian subsurface to search for life, the European Space Agency has incorporated a small automated burrowing device called a subsurface penetrometer or Mole onto the Beagle 2 lander planned for 2003 launch. This device, called the Planetary Underground Tool (PLUTO), is a pointed slender cylinder 2 cm wide and 28 cm long equipped with a small sampling device at the pointed end that collects samples and brings them to the surface for analysis. Drawing on the PLUTO design, we are developing a larger Mole carrying sensors for identifying mineralogy, organic compounds, and water.

Stoker, C. R.↗
DOE OSTI2024

Asymmetric Rowland circle geometries for spherically bent crystal analyzers in laboratory and synchrotron applications

Spherically bent crystal analyzers (SBCAs) are the dominant high-resolution hard X-ray optic in the ongoing rebirth of laboratory-based X-ray absorption fine structure (XAFS) and X-ray emission spectroscopy (XES) as well as in synchrotron methods such as high energy resolution fluorescence detection (HERFD) and non-resonant X-ray Raman scattering (XRS). In the overwhelming majority of cases, SBCAs are implemented in a ‘symmetric’ configuration on the Rowland circle, wherein the diffracting crystal plane is nominally coincident with the analyzer surface. We report here comprehensive investigations of ‘asymmetric’ operation of SBCA on the Rowland circle, wherein the diffracting crystal plane is not coincident with the optical surface of the analyzer. First, we have developed a laboratory spectrometer for XAFS and XES that is specialized for asymmetric SBCA operation. Here we find several benefits, including the capacity to use a single SBCA over a very wide energy range via ‘hkl hopping’ and the frequent ability to eliminate Johann error, the most prevalent energy-broadening mechanism when using SBCA symmetrically on the Rowland circle. Second, we expand these ideas to synchrotron facilities with a demonstration study of HERFD and XRS where asymmetric operation also provided advantage. Our results suggest that large-array systems for HERFD augmented with an additional mechanical degree of freedom could streamline user operation and also indicate benefits to XRS in the asymmetric configuration, where larger solid angle, larger sample-to-detector distance, and decreased Johann error can be achieved simultaneously.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Calibration of the sub-aperture backscatter system on OMEGA EP

The sub-aperture backscatter (SABS) diagnostic on the OMEGA EP Laser System is a diagnostic that is used to measure the backscattered and sidescattered light during laser–plasma interaction experiments that are relevant to high-energy-density physics and inertial confinement fusion. The diagnostic collects stimulated Brillouin scattering (SBS) UV light at around 351 nm and stimulated Raman scattering (SRS) in the visible-light regime in the 420–720-nm-wavelength range and provides spectrally and temporally resolved information. Five 1-in. light collectors, composed of a lens, ground glass diffuser, and coupling into a 300-μm fiber, are positioned behind the last steering mirror on one of the four beamlines to catch a portion of the beam cross section (~1.5%) of the emission that is scattered into the beamline. The SRS light is collected in two light collectors, combined, and transported via graded index fibers to a streaked spectrometer. The SABS-SRS streak spectrometer has a temporal and spectral resolution of 100 ps and 1 nm, respectively. Three other light collectors collect, combine, and transport the SBS signal to a Hamamatsu high-voltage photodiode, where an oscilloscope digitizes the data, providing a time resolution of better than 1 ns. To obtain an absolute energy calibration of SRS measurements, light signals of known energy and wavelength were injected into the light collectors one at a time. The resulting counts on the streak camera charge-coupled device for SRS are then correlated with the incident fluence of scattered light at the light collector in order to allow a quantitative assessment of streak camera sensitivity to determine the energy of the scattered light during experiments. The measurements were performed in situ from the light collectors to the detectors. Other offline measurements provided the transmission of the optics between the target chamber center and the light collectors.

47 OTHER INSTRUMENTATION↗
NASA NTRS1980

Ultraviolet albedos of Uranus and Neptune

Observations on Uranus, Neptune, and four G-type stars which were obtained with the five channel ultraviolet spectrometer aboard the Astronomical Netherlands Satellite are reported. The paper uses these data to derive geometric albedos between 1800 and 3300 A for Uranus and between 2200 and 3300 A for Neptune. It is shown that the albedos are in good agreement with ground measurements near 3300 A and with OAO 2 measurements near 2500 A. In addition, it is noted that the albedos are smaller than theoretical predictions for deep pure H2 Rayleigh-Raman scattering atmospheres, which confirms earlier predictions that additional sources of ultraviolet absorption are required in the upper atmosphere of these planets. Consideration is given to the possibility that the Uranian atmosphere contains an extra absorber, noting that the identification of this absorber is difficult from broad-band spectrophotometric measurements.

Savage, B. D.↗
DOE OSTI2022

First Results from the Thomson Scattering Diagnostic on the Large Plasma Device

We present the first Thomson scattering measurements of electron density and temperature in the Large Plasma Device (LAPD), a 22 m long magnetized linear plasma device at the University of California Los Angeles (UCLA). The diagnostic spectrally resolves the Doppler shift imparted on light from a frequency-doubled Nd:YAG laser when scattered by plasma electrons. A fiber array coupled to a triple-grating spectrometer is used to obtain high stray light rejection and discriminate the faint scattering signal from a much larger background. In the center of the plasma column, the measured electron density and temperature are about ne≈1.5×1013 cm−3 and Te≈ 3 eV, respectively, depending on the discharge parameters and in good agreement with Langmuir probe data. Optical design considerations to maximize photon count while minimizing alignment sensitivity are discussed in detail and compared to numerical calculations. Raman scattering off of a quartz crystal probe is used for an absolute irradiance calibration of the system.

Kaloyan, Marietta (ORCID:0000000182593038)↗