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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Extraction of Beam-Spin Asymmetries from the Hard Exclusive π + Channel off Protons in a Wide Range of Kinematics

We have measured beam-spin asymmetries to extract the $\sin\phi$ moment $A_{LU}^{\sin\phi}$ from the hard exclusive $\vec{e} p \to e^\prime n \pi^+$ reaction above the resonance region, for the first time with nearly full coverage from forward to backward angles in the center-of-mass. The $A_{LU}^{\sin\phi}$ moment has been measured up to 6.6 GeV$^{2}$ in $-t$, covering the kinematic regimes of Generalized Parton Distributions (GPD) and baryon-to-meson Transition Distribution Amplitudes (TDA) at the same time. The experimental results in very forward kinematics demonstrate the sensitivity to chiral-odd and chiral-even GPDs. In very backward kinematics where the TDA framework is applicable, we found $A_{LU}^{\sin\phi}$ to be negative, while a sign change was observed near 90$^\circ$ in the center-of-mass. The unique results presented in this paper will provide critical constraints to establish reaction mechanisms that can help to further develop the GPD and TDA frameworks.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2023

Spin cutoff factor and level density for Ni 59 from an analysis of compound nuclear reactions

The spin cutoff parameter for 59 Ni has been studied from different types of experimental data, including neutron angular distributions from the 56 Fe(α,n) 59 Ni reaction, spin of discrete levels, the level density from the proton evaporation spectrum of the 54 Fe( 6 Li,p) 59 Ni reaction and neutron resonance spacing. Experimental data points were compared with calculations using models widely used in literature. It was found that the available empirical models overestimate data points in the energy region below the neutron separation energy, while microscopic calculations which take into account pairing correlations within Hartree-Fock +Bardeen-Cooper-Schrieffer approach are consistent with data. As a result, it confirmed earlier findings that pairing correlations play an important role and need to be taken into account when the spin cutoff parameter is calculated below the neutron separation energy.

(a,n) reaction↗
DOE OSTI2026

Grand Challenges and Opportunities in Stimulated Dynamic and Resonant Catalysis

Traditional heterogeneous catalysis is constrained by kinetic and thermodynamic limits, such as the Sabatier principle and reaction equilibrium. Dynamic and resonant catalysts hold promise to overcome these limitations by actively oscillating a catalyst’s physical or electronic structure at the time scale of the catalytic cycle, allowing programmable control over reaction pathways, and leading to improved rate and selectivity. External stimuli such as temperature swing, mechanical strain, electric charge, and light can perturb catalyst surfaces in different ways, altering adsorbate coverage, binding energies, and transition states beyond what steady-state catalysis allows. This work surveys the current state of dynamic catalysis, introduces the concept of “ stimulando ” characterization for observing transient dynamics, and outlines key modeling, mechanistic, and benchmarking strategies to advance the field toward improved chemical transformation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

First identification of resonant states in the {sup 45}V(p, {gamma}){sup 46}Cr reaction and their influence on the production of {sup 44}Ti in Core Collapse Supernovae

The observation of active 44Ti in supernova remnants offers the potential to solve one of the most debated questions in modern astrophysics, the exact underlying explosion mechanism of core collapse supernovae (CCSNe). In particular, a comparison between the predicted synthesized yield of 44Ti and the ejected flux is expected to allow for a determination of the mass cut of the star. Unfortunately, such comparisons are currently severely hindered by large uncertainties in the nuclear reactions governing the production and destruction of 44Ti. On this note, the astrophysical 45Vðp; γÞ46Cr reaction is expected to play a decisive role. We present the first experimental information on resonant states in the 45Vðp; γÞ46Cr reaction. Excitation energies have been measured with high precision for ten previously unknown, low-spin, proton-unbound states in 46Cr, and spin-parity-assignment constraints have been made using observed γ-decay patterns and shell-model calculations. We find that an l ¼ 1 resonance at 714 keV dominates the 45Vðp; γÞ46Cr reaction for the entire temperature range of α-rich freezeout. Moreover, the nominal rate is found to be ∼25–50% of previous estimates for T > 1.2 GK, indicating an increase in 44Ti production in CCSNe of ∼20–35%.

Cousins, C↗
DOE OSTI2023

A multidimensional study of the structure function ratio $\sigma_{LT'}$/$\sigma_0$ from hard exclusive $\pi^+$ electro-production off protons in the GPD regime

A multidimensional extraction of the structure function ratio σ LT' /σ 0 from the hard exclusive $\vec{e}$p → e'nπ+ reaction above the resonance region has been performed. The study was done based on beam-spin asymmetry measurements using a 10.6 GeV incident electron beam on a liquid-hydrogen target and the CLAS12 spectrometer at Jefferson Lab. The measurements focus on the very forward regime (t/Q 2 $\ll$ 1) with a wide kinematic range of x B in the valence regime (0.17 < x B < 0.55), and virtualities Q 2 ranging from 1.5 GeV 2 up to 6 GeV 2 . The results and their comparison to theoretical models based on Generalized Parton Distributions demonstrate the sensitivity to chiral-odd GPDs and the directly related tensor charge of the nucleon. In addition, the data is compared to an extension of a Regge formalism at high photon virtualities. It was found that the Regge model provides a better description at low Q 2 , while the GPD model is more appropriate at high Q 2 .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Accelerated Steam Methane Reforming by Dynamically Applied Charges

Catalyst design has traditionally focused on tuning active site properties to optimally bind reaction intermediates and balance the kinetic requirements of multiple competing chemical processes, as necessitated by the Sabatier principle. It has recently been proposed that for reactions following certain potential energy landscapes, the activity limit imposed by the Sabatier principle may be overcome by using programmed oscillations of surface electron density at the timescales of surface reactions (i.e., “catalytic resonance”). Here, we use a combination of density functional theory (DFT) simulations and transient kinetic models (TKMs) to simulate the kinetics of steam methane reforming (SMR) on Ru(211) surfaces under statically and dynamically applied charges. DFT-calculated binding energies of SMR intermediates and transition states exhibit strong sensitivity to positively applied charges and follow unique scaling relationships that deviate from linear periodic trends across transition metals. Our simulations demonstrate that applying a small positive charge to Ru dramatically enhances the steady-state turnover frequency (TOF) of SMR by up to 5 orders of magnitude above the TOF observed over neutral Ru. Thus, statically charging Ru catalysts may be an effective strategy to lower the temperature requirements for SMR. Dynamic square-wave oscillations in charge resulted in SMR catalytic resonance with an onset frequency f ∼ 106 Hz and the corresponding average TOFs exceeding the statically charged Ru surface by an additional 15%. Here, based on sensitivity analyses performed for the two end points of oscillation, we propose that dynamic TOF improvement beyond the Sabatier maximum can be expected when the system oscillates between two kinetic regimes that are uniquely controlled by distinct elementary steps.

Catalysts↗
DOE OSTI2026

Counter-propagating toroidal Alfvén eigenmodes in tokamaks

Mechanisms of destabilization of toroidal Alfvén eigenmodes (TAEs) in tokamaks are analyzed with the aim to reveal those leading to modes propagating in the direction opposite to plasma current, i.e. counter-propagating modes (ctr-TAE). Plasmas with fast-ions sources [such as neutral beam injection (NBI), ion cyclotron resonance heating, fusion reactions] and without them (Ohmic discharges) are considered. A particular NSTX-U experiment with NBI, where co- and counter-propagating TAEs were observed simultaneously (Podestà et al 2018 Nucl. Fusion 58 082023), is considered. It is concluded that both types of TAEs occurred because their destabilization was caused by the velocity anisotropy of beam ions, which overrode effects of spatial inhomogeneity of these ions.

Alfvénic instabilities↗
NASA NTRS1978

Mass spectrometry

A review of mass spectrometry in organic chemistry is given, dealing with advances in instrumentation and computer techniques, selected topics in gas-phase ion chemistry, and applications in such fields as biomedicine, natural-product studies, and environmental pollution analysis. Innovative techniques and instrumentation are discussed, along with chromatographic-mass spectrometric on-line computer techniques, mass spectral interpretation and management techniques, and such topics in gas-phase ion chemistry as electron-impact ionization and decomposition, photoionization, field ionization and desorption, high-pressure mass spectrometry, ion cyclotron resonance, and isomerization reactions of organic ions. Applications of mass spectrometry are examined with respect to bio-oligomers and their constituents, biomedically important substances, microbiology, environmental organic analysis, and organic geochemistry.

Burlingame, A. L.↗
NASA NTRS2002

A model of hollow cathode plasma chemistry

We have developed a new model of hollow cathode plasma chemistry based on the observation that xenon ion mobility is diffusion limited due to resonant charge exchange reactions. The model shows that vapor phase barium atoms are ionized almost immediately and electric fields accelerate the ions upstream from the emission zone. We have also applied the model to the orifice region, where the resultant ion generation profile correlates with previously reported orifice erosion.

hollow cathode↗
DOE OSTI2022

Role of low-lying resonances for the 10 Be(p,α) 7 Li reaction rate and implications for the formation of the Solar System

Evidence for the presence of short-lived radioactive isotopes when the Solar System formed is preserved in meteorites, providing insights into the conditions at the birth of our Sun. A low-mass core-collapse supernova had been postulated as a candidate for the origin of 10Be, reinforcing the idea that a supernova triggered the formation of the Solar System. We present a detailed study of the production of 10Be by the ν process in supernovae, which is very sensitive to the reaction rate of the major destruction channel, 10 Be(p,α) 7 Li. With data from recent nuclear experiments that show the presence of a resonant state in 11B at ≈193 keV, we derive new values for the 1 0 Be(p,α) 7 Li reaction rate, which are significantly higher than previous estimates. We show that, with the new 10 Be(p,α) 7 Li reaction rate, a low-mass CCSN is unlikely to produce enough 10 Be to explain the observed 10 Be/ 9 Be ratio in meteorites, even for a wide range of neutrino spectra considered in our models.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Diffractive Imaging of Conical Intersections Amplified by Resonant Infrared Fields

The fate of virtually all photochemical reactions is determined by conical intersections. These are energetically degenerate regions of molecular potential energy surfaces that strongly couple electronic states, thereby enabling fast relaxation channels. Their direct spectroscopic detection relies on weak features that are often buried beneath stronger, less interesting contributions. For azobenzene photoisomerization, a textbook photochemical reaction, we demonstrate how a resonant infrared field can be employed during the conical intersection passage to significantly enhance its coherence signatures in time-resolved Xray diffraction while leaving the product yield intact. Furthermore, this transition-state amplification holds promise to bring signals of conical intersections above the detection threshold.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Constraints on key O 17 ( α , γ ) Ne 21 resonances and impact on the weak s process

The efficiency of the slow neutron-capture process in massive stars is strongly influenced by neutron-capture reactions on light elements. At low metallicity, 16 O is an important neutron absorber, but the effectiveness of 16 O as a light-element neutron poison is modified by competition between subsequent 17 O(α,n) 20 Ne and 17 O(α,γ) 21 Ne reactions. The strengths of key 17 O(α,γ) 21 Ne resonances within the Gamow window for core helium burning in massive stars are not well constrained by experiment. This work presents more precise measurements of resonances in the energy range E c.m. = 612–1319 keV. We extract resonance strengths of ωγ 638 = 4.85 ± 0.79 μeV, ωγ 721 =13.1$^{+3.2}_{-2.4}$ μeV, ωγ 814 = 7.72 ± 0.55 meV, and ωγ 1318 = 136 ±13 meV, for resonances at E c.m. = 638, 721, 814, and 1318 keV, respectively. We also report an upper limit for the 612 keV resonance of ωγ < 140 neV (95% c.l.), which effectively rules out any significant contribution from this resonance to the reaction rate. From this work, a new 17 O(α,γ) 21 Ne thermonuclear reaction rate is calculated and compared to the literature. The effect of present uncertainties in the 17 O(α,γ) 21 Ne reaction rate on weak s-process yields are then explored using postprocessing calculations based on a rotating 20M ⊙ low-metallicity massive star. The resulting 17 O(α,γ) 21 Ne reaction rate is lower with respect to the preexisting literature and found to enhance weak s-process yields in rotating massive star models.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1972

Ion-atom association reactions in the rare gases.

A simple resonance theory of three-body ion-atom association reactions is presented. The reaction is considered as proceeding through the formation of a long lived orbiting resonance complex between the atom and the ion. The population of these quasi-bound states is estimated assuming thermal equilibrium. A stable molecular ion may then be formed upon deactivation of the complex by collision with a third body. Various simplifying approximations to the potential curves and surfaces are employed. Furthermore, the deactivation cross sections for the relevant complexes are estimated from the corresponding atomic 'sizes.' A simple analytical formula for the three-body rate constant is thus derived. Reasonable agreement with experiment is obtained for He(+) in He and fair agreement for other light systems.

Dickinson, A. S.↗
DOE OSTI2025

Extraction of the non-spin- and spin-transfer isovector responses via the 12 C ⁡( 10 Be, 10 B + 𝛾)⁢ 12 B reaction

The isovector response in 12 B was investigated via the 12 C ⁡( 10 Be, 10 B + 𝛾)⁢ 12 B* reaction at 100⁢𝐴MeV. By utilizing the 𝛾-decay properties of the 1.74 MeV 0 + and 0.718 MeV 1 + states in 10 B, the separate extraction of the non-spin-transfer (Δ⁢𝑆 = 0) and spin-transfer (Δ⁢𝑆 = 1) isovector responses up to an excitation energy of 50 MeV in 12 B in a single measurement is demonstrated. The experimental setup employed the S800 spectrometer to detect and analyze the 10 B ejectiles and the Gamma-Ray Energy Tracking In-beam Nuclear Array (GRETINA) for obtaining the Doppler-reconstructed spectrum for 𝛾 rays emitted in flight by 10 B. A 12 C foil was placed at the pivot point of the spectrograph. Here, the 12 B reaction product was not detected. Contributions from transitions associated with the transfer of different units of angular momentum in the non-spin- and spin-transfer responses were analyzed using a multipole decomposition analysis. The extracted non-spin-dipole (Δ⁢𝑆 = 0, Δ⁢𝐿 = 1) and spin-dipole (Δ⁢𝑆 = 1, Δ⁢𝐿 = 1) responses were found to be consistent with available data from other charge-exchange probes, validating the non-spin- and spin-transfer filters used. While statistical uncertainties and experimental resolutions were relatively large due to the modest intensity of the 10 Be secondary beam, the results show that, with the much higher intensities that will be available at new rare-isotope beam facilities, the ( 10 Be, 10 B + 𝛾) reaction and its Δ⁢𝑇 𝑧 = −1 partner, the ( 10 C, 10 B + 𝛾) reaction, are powerful tools for elucidating the isovector non-spin- and spin-transfer responses in nuclei.

Charge-exchange reactions↗
DOE OSTI2021

Proton capture on 34 S in the astrophysical energy regime of O-Ne novae

Nuclear reaction sensitivity studies have shown that the final isotopic abundance of O-Ne nova nucleosynthesis is dependent on the 34 S(p,γ) 35 Cl reaction at astrophysical energies corresponding to peak nova burning temperatures of 0.1–0.4 GK. Isotopic ratios of the S, Cl, and Ar products are all used in various methods of cosmochemical analysis of presolar meteoritic grains. Due to the lack of direct experimental data, the 34 S+p reaction rate has been estimated using statistical modeling or information from indirect nucleon transfer experiments. In order to provide direct reaction information, here the resonance strengths of several low energy resonances, E c.m. = 272–495 keV, in the 34 S(p,γ) 35 Cl reaction were measured for the first time in inverse kinematics using the DRAGON recoil separator located at TRIUMF, Canada’s Particle Accelerator Centre in Vancouver.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

Activation and surface reactions of CO and H 2 on ZnO powders and nanoplates under CO hydrogenation reaction conditions

Here, activation and surface reactions of CO and H 2 on ZnO powders and nanoplates under CO hydrogenation reaction conditions were (quasi) in situ studied using temperature programmed surface reaction spectra, diffuse reflectance Fourier transform infrared spectroscopy, inelastic neutron scattering spectroscopy and electron paramagnetic resonance. CO undergoes disproportion reaction to produce gaseous CO 2 and surface carbon adatoms, and adsorbs to form surface formate species. H 2 adsorption forms dominant irreversibly-adsorbed surface hydroxyl groups and interstitial H species and very minor surface Zn-H species. Surface formate species and hydroxyl groups react to produce CO 2 and H 2 , while surface carbon adatoms are hydrogenated by surface Zn-H species sequentially to produce CH(a), CH 2 (a), CH 3 (a) and eventually gaseous CH 4 . The ZnO nanoplates, exposing a higher fraction of Zn-ZnO(0001) and O-ZnO(000–1) polar facets, are more active than the ZnO powders to catalyze CO hydrogenation to CH 4 . These results provide fundamental understanding of the reaction mechanisms and structural effects of CO hydrogenation reaction catalyzed by ZnO-based catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Spin-parities of subthreshold resonances in the 18 F(p, α) 15 reaction

The 18 F(p,α) 15 O reaction is key to determining the 18 F abundance in classical novae. However, the cross section for this reaction has large uncertainties at low energies largely caused by interference effects. In this work, we resolve a longstanding issue with unknown spin-parities of subthreshold states in 19 Ne that reduces these uncertainties. The 20 Ne( 3 He, 4 He) 19 Ne neutron pick-up reaction was used to populate 19 Ne excited states, focusing on the energy region of astrophysical interest (≈ 6 – 7 MeV). The experiment was performed at the Triangle Universities Nuclear Laboratory using the high resolution Enge split-pole magnetic spectrograph. Spins and parities were found for states in the astrophysical energy range. In particular, the state at 6.133 MeV ($E^{cm}_{r}$ = –277 keV) was found to have spin and parity of 3/2 + and we confirm the existence of an unresolved doublet close to 6.288 MeV ($E^{cm}_{r}$ = –120 keV) with J π = 1/2 + and a high-spin state. Using these results, we demonstrate a significant factor of two decrease in the reaction rate uncertainties at nova temperatures.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗