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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Calendar Year 2022 Post-Closure Monitoring Letter Report (Rev. 1)

This letter serves as the annual post-closure letter for Corrective Action Unit 98, Frenchman Flat; CAU 97, Yucca Flat/Climax Mine; and CAU 99, Rainier Mesa/Shoshone Mountain for calendar year 2022. This letter will discuss the post-closure monitoring activities that occurred during CY 2022, identify any triggers reached, and summarize water usage on the Nevada National Security Site (NNSS) and surrounding hydrographic basins at the three CAUs.

54 ENVIRONMENTAL SCIENCES↗

Data Quality Objectives Supporting Radiological Air Emissions Monitoring for the PNNL-Richland Campus: North Campus Construction (Rev. 3)

Starting in fiscal year 2023, the north area of the PNNL-Richland Campus will undergo development. Initially, infrastructure (water, electrical) improvements will be installed. Later development includes the construction of several new office buildings. The area to be developed currently contains no buildings but does have two existing solar-powered ambient air sampling stations. Under the requirements of Washington State Department of Health Radioactive Air Emissions License -005, the PNNL-Richland Campus must operate and maintain a radiological air monitoring program. This revision documents and evaluates how the new North Campus construction impacts ambient air surveillance stations within the development region. This revision also considers current stack configurations and uses an updated environmental dispersion model and updated meteorological data. The DQO team concluded that one sampling station in the construction area will be relocated and the other remain in place. The evaluations conducted for this DQO also identified a third sampling station outside the development area that is recommended for relocation as a result of updated dispersion modeling. Recommended sites for the relocations are presented. Considerations for sampling in and around a construction zone are also addressed. Additionally, programmatic improvements to the ambient air sampling program were identified in the DQO process.

54 ENVIRONMENTAL SCIENCES↗

Measured Thernal and Fast Neutron Fluence Rates ATR Cycles 171B MP-2 (Rev. 0)

This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for ATR Cycle 171B which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Measured Thermal and Fast Neutron Fluence Rates ATR Cycles 171B AFC (Rev. 0)

This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for ATR Cycle 171B which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Measured Thermal and Fast Neutron Fluence Rates ATR Cycles 171B ATF (Rev. 0)

This report contains the thermal (2200 m/s) and fast (E>1MeV) neutron fluence rate data for ATR Cycle 171B which were measured by the Radiation Measurements Laboratory (RML) as requested by the Power Reactor Programs (ATR Experiments) Radiation Measurements Work Order.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Values of Recovered Uranium from HALEU Used Nuclear Fuels (Rev. 1)

The value of the recovered uranium (RU) from high assay low-enriched uranium (HALEU) used nuclear fuels was evaluated. Three utilizations of the recovered uranium were considered in this study, which include the cases that RU is used as a fissile material of nuclear fuel, RU is reused in the original advanced reactor after reenrichment, and RU is reused in conventional light water reactors after down-blending. In this study, the RU values were identified by comparing the cost of making a unit mass of fuel with RU versus the fuel cost with the equivalent fresh enriched uranium (EU). A series of bounding analyses for calculating the fuel costs were conducted using several selected reactor types, which include microreactors, advanced thermal reactors, and fast reactors having a burnup of 2 – 165 GWd/t (with residual U-235 content in discharged fuels of 0.8 - 19.6%). This study concludes that RU having a residual U-235 content higher than ~7% would cost less than the fresh EU. The affordability increases as the residual U-235 content in RU increases. For instance, the fuel cost with RU having the residual U-235 content of 19.6% is about 85% cheaper than the fuel cost with the equivalent fresh EU. This study observed that reusing RU after reenrichment in the original microreactor is impractical because the U-235 content in the re-enriched RU fuel would need to be higher than the limit for low-enriched uranium (<20%) to provide the same burnup performance due to parasitic absorption from U-236. It is noted that this study focused on the recovery of uranium only, and the value of other fissile materials (such as Pu) in the used nuclear fuel was not considered even though those are bred significantly in fast reactors. In addition, the impacts of uncertainties in the cost data and the value of RU of TRISO fuels were not evaluated in this study due to the limited information on the cost data uncertainties and the separation cost from TRISO fuels.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Management of the Three Mile Island Unit 2 Accident Corium and Severely Damaged Fuel Debris (Rev. 2)

The Three Mile Island, Unit Two (TMI-2) pressurized water reactor core underwent a significant meltdown in 1979 due to an untimely combination of maintenance problems that led to a loss of feedwater, followed by a series of operational misunderstandings and errors. Primary coolant discharging through a malfunctioning valve represented what was analyzed as a “small-break” loss-of-coolant accident (LOCA) and ultimately became a full core meltdown. The melted core recovery process required the development of a wide array of tools. After approximately three years of water management and other cleanup actions, the first views of the core revealed a much higher degree of damage than previously expected. Approximately 62 metric tons of the core had melted, leaving only 42 of the 177 fuel assemblies standing with fuel rods intact. The core to be recovered was composed of loose, gravel-like and granular particulate material and a central solidified mass of formerly molten fuel. Molten fuel had also penetrated some of the pressure vessel internals and resolidified below the main core support structure. Robotic tools that had been designed for the task were of limited effectiveness due to the range of material types and phases.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Management of the Three Mile Island Unit 2 Accident Corium and Severely Damaged Fuel Debris (Rev. 2)

The Three Mile Island, Unit Two (TMI-2) pressurized water reactor core underwent a significant meltdown in 1979 due to an untimely combination of maintenance problems that led to a loss of feedwater, followed by a series of operational misunderstandings and errors. Primary coolant discharging through a malfunctioning valve represented what was analyzed as a “small-break” loss-of-coolant accident (LOCA) and ultimately became a full core meltdown. The melted core recovery process required the development of a wide array of tools. After approximately three years of water management and other cleanup actions, the first views of the core revealed a much higher degree of damage than previously expected. Approximately 62 metric tons of the core had melted, leaving only 42 of the 177 fuel assemblies standing with fuel rods intact. The core to be recovered was composed of loose, gravel-like and granular particulate material and a central solidified mass of formerly molten fuel. Molten fuel had also penetrated some of the pressure vessel internals and resolidified below the main core support structure. Robotic tools that had been designed for the task were of limited effectiveness due to the range of material types and phases.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Fluence Capsules for the SAM-2 Experiment MPO# 00239221/SOW-17494, Rev. 0

The statement of work (SOW) applies to the fabrication and analysis of flux wire capsules that will be used in the SAM-2 experiment. This experiment is a drop-in design slated for irradiation in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). The 8 neutron fluence capsules will be used to determine the neutron exposure that the specimens have received. For Task 1 Pacific Northwest National Laboratory (PNNL) will prepare eight (8) neutron fluence monitors for irradiation in the ATR. Task 2 will involve analysis port-irradiation; the monitors will be returned to PNNL for analysis in FY21 after irradiation. The analysis report will include the neutron fluences and radiation damage calculations for all irradiated positions in the experiment.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Experience with Noble Metals During HLW Vitrification at FZK, Germany (Rev. 0)

The noble metals ruthenium (Ru), rhodium (Rh), and palladium (Pd) are present to various extents in defense and commercial high-level nuclear waste streams. Usually, their concentrations are higher in commercial waste. Ru, Rh, and Pd are sparingly soluble in silicate glass melts and they therefore form separate metal, oxide, or other phases. These phases are generally denser than the glass melt and tend to sediment to the bottom of the melter, where they form a "sludge" layer. Since the sludge layer has a higher electrical conductivity than the molten glass, accumulation of sludge can ultimately lead to electrical disruption of the operation of the melter. In addition, the sludge reduces the melt volume, which also changes the operational characteristics of the melter.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Corrosion Testing of Bubbler Materials for LAW Vitrification (Rev. 0)

This work involved crucible-scale corrosion tests using coupons of selected materials in the baseline glass formulations for the seven LAW Sub-Envelopes. The tests were performed with Inconel 690 and MA 758; per the Test Plan, selected tests were also performed with a proprietary high temperature alloy supplied by SRTC. Coupons of these materials were tested for their corrosion resistance to LAW baseline glasses in two test series: the first series was with a baseline glass only, the second series was with a baseline glass and an added salt layer.

36 MATERIALS SCIENCE↗

Regulatory Spike Testing of RPP-WTP LAW and HLW Glasses for Compliance with Land Disposal Restrictions, VSL-03R3760-1, Rev. 1

The United States Department of Energy’s (DOE’s) Hanford site is the current location of storage of about 50 million gallons of mixed waste. This waste is stored in underground tanks at the Hanford site and is both a listed and characteristic waste, as defined in 40 CFR Part 261, and a dangerous waste according to Chapter 173-303 of the Washington Administrative Code (WAC). The waste is also subject to the Land Disposal Restrictions (LDR) (40 CFR Part 268 and WAC 173-303-140). The River Protection Project - Waste Treatment Plant (RPP-WTP) will provide DOE with a means for treating this waste by vitrification (for subsequent disposal). The tank waste will be partitioned into low and high activity fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The ILAW product will be disposed of in an engineered facility on the Hanford site while the IHLW product will be directed to the national deep geological disposal facility for high level nuclear waste. The ILAW and IHLW products must meet a variety of requirements with respect to protection of the environment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Integrated Off-Gas System Tests on the DM1200 Melter with RPP-WTP LAW Sub-Envelope Bl Simulants, VSL-03R3851-1, Rev. 0 (Oct 2003)

The report documents melter and off-gas performance results obtained on the DM1200 melter during processing of LAW Sub-Envelope B1 feed. The principal objectives of the DM1200 melter testing were to demonstrate suitable processing and production rates for LAW B1 feed; characterize the glass product for elemental composition; measure elemental emission rates and decontamination factors (DFs) across the melter and off-gas treatment components; and provide additional data on the performance of the thermal catalytic oxidation and selective catalytic reduction (TCO/SCR) unit efficiency in treating organic emissions. The feed was spiked with organic compounds for part of the testing duration. All data were collected for use in engineering and system design purposes. No sampling and analysis to collect environmental data was performed during these tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Regulatory Testing of WTP HL W Glasses for Compliance with Delisting Requirements, VSL-03R3780-1, Rev. 1

(Part of the data collected for this work and discussed in this report was subject to data quality and bias issues. All the affected tests have subsequently been repeated, as directed by the Waste Treatment Plant Project, and new statistical analyses have been performed on the revised data set. A subsequently-issued report supercedes this report and describes the revised data, together with the revised composition-property models (Kot et al. 2004). The reader should refer to the new report for discussion of the revised data set and composition-property (TCLP cadmium release) models. None of the data for the spike glasses, designed for Case 1 and Case 2 COPCs testing, were affected by this issue.)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Noble Metals Testing on the DM1200 Pilot Melter System with AZ-101 HLW Simulants, VSL-03R3740-2, Rev. 0

This report documents the results obtained with respect to the behavior of noble metals in tests on the DM1200 HLW Pilot Melter during processing of simulated HLW AZ-101 feed. The principal objective of these tests was to collect data to determine the extent of retention of noble metals in the melter since that is an important uncertainty in determining the expected life of the WTP HLW melter. The present results constitute one part of an integrated testing strategy that has been developed to address this risk.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗