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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

In Situ STEM-EELS observation of nanoscale interfacial phenomena in all-solid-state batteries

Behaviors of functional interfaces are crucial factors in the performance and safety of energy storage and conversion devices. Indeed, solid electrode–solid electrolyte interfacial impedance is now considered the main limiting factor in all-solid-state batteries rather than low ionic conductivity of the solid electrolyte. In this paper, we present a new approach to conducting in situ scanning transmission electron microscopy (STEM) coupled with electron energy loss spectroscopy (EELS) in order to uncover the unique interfacial phenomena related to lithium ion transport and its corresponding charge transfer. Our approach allowed quantitative spectroscopic characterization of a galvanostatically biased electrochemical system under in situ conditions. Using a LiCoO 2 /LiPON/Si thin film battery, an unexpected structurally disordered interfacial layer between LiCoO 2 cathode and LiPON electrolyte was discovered to be inherent to this interface without cycling. During in situ charging, spectroscopic characterization revealed that this interfacial layer evolved to form highly oxidized Co ions species along with lithium oxide and lithium peroxide species. These findings suggest that the mechanism of interfacial impedance at the LiCoO 2 /LiPON interface is caused by chemical changes rather than space charge effects. Finally, insights gained from this technique will shed light on important challenges of interfaces in all-solid-state energy storage and conversion systems and facilitate improved engineering of devices operated far from equilibrium.

25 ENERGY STORAGE↗

Gallium oxide semiconductor-based large volume ultrafast radiation hard spectroscopic scintillators

We report on the development of the first-ever inorganic radiation-hard moisture-insensitive large volume spectroscopic semiconductor-based scintillator with less than 2 ns decay time and light yields as high as 8000 ph/MeV. Despite extensive research into scintillator materials, the quest for an ideal scintillator combining ultrafast decay times (akin to BaF 2 and Yb-doped scintillators such as Lu 2 O 3 :Yb), high light yields (exceeding 2000 photons per MeV), spectroscopic capabilities, and exceptional radiation hardness remain unfulfilled. In this study, we demonstrate and report for the first time the viability of large-volume (up to 20 mm thickness) gallium oxide (β-Ga 2 O 3 ) semiconductor-based scintillators for applications requiring these properties. These β-Ga 2 O 3 scintillators were grown using the fast turnaround (~2 days) crucible-free optical float zone (FZ) technique. The high light yield and ultrafast decay time of these high-purity n-type semiconductors with free carrier concentration of 6 × 10 17 cm –3 are attributed to native defects, specifically oxygen vacancies (V O ) and gallium–oxygen vacancy pairs (V Ga –V O ), generated during optimized FZ growth. The ultrafast decay, along with high light yield, enables excellent timing resolution and high count rate detection for applications like time-of-flight positron emission tomography, physics experiments, and nuclear safety. The radiation hardness of these devices has been documented in a separate publication.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

On local isodynamicity in tokamaks

It is shown that local isodynamicity (i.e., the constancy of the absolute value of the magnetic field on a magnetic surface) can take place at the periphery of the tokamak near the separatrix with an internal X point. An isodynamic layer including several magnetic surfaces cannot exist in a tokamak because the safety factor q is too low and the shape of the surfaces is predetermined. The layered and global isodynamicity is possible in pinches with low values of q (Palumbo's configuration).

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Efficient and Zero Net Energy-Ready Plug Loads

Plug loads are the devices plugged into common electrical outlets. Modern buildings contain hundreds of these devices which, together, are responsible for at least 25 percent of the energy use in California buildings. Energy consumed by plug loads is increasing because the “Internet of Things” is, to a great extent, the “Internet of Plug Loads.” This project developed technologies that will reduce the energy use of plug loads. Two crosscutting strategies were investigated in detail: (1) technologies to reduce standby power use to near zero, and (2) methods to increase the use of direct current (DC) as a power source. Two new approaches to reduce standby to near zero were developed and have potential applicability to a wide range of devices. Prototype DC appliances were developed to demonstrate energy savings by bypassing power supplies and avoiding other losses. Networks of DC-powered devices can save even more energy and provide other benefits, such as resiliency during power outages. A unique category of energy-using devices was identified that provide life safety, health, and security to building occupants. Their installation or use is dictated by building codes, health providers, insurance companies, and other entities—none of whom would ordinarily prioritize energy efficiency. In the case of ground fault circuit interrupts (GFCIs), savings of 80 percent appear possible, simply by adopting the most efficient designs. Home medical equipment, particularly oxygen concentrators, are a rising category of energy use where significant savings are possible. This report also reviews the codes, standards, and other policies that affect energy use of plug loads.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Valveless Laser Processing

Los Alamos National Laboratory staff has developed a technique for testing inside hermetically sealed devices.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Development of Irradiation Test Devices for Transient Testing

The Transient Reactor Test facility (TREAT) resumed operations in 2017 in order to reclaim its crucial role in nuclear-heated fuel safety research. TREAT’s historic era of operation (1959-1994) was best known for integral-scale testing of large fuel specimens/bundles under postulated reactor plant accident conditions, but TREAT also supported smaller-scale phenomena identification tests that elucidated fundamental behaviors and paved the way for these integral-scale tests. Advances in modern computational capabilities and a resurgence of interest in novel reactor technologies have created an opportunity for emphasizing modernized science-based and separate effects tests once again at TREAT. An innovative approach to this type of testing has been developed to leverage minor radioactivity built-in during brief TREAT irradiations by arranging smaller fuel specimens in low activation hardware so that they can be easily extracted and shipped for post irradiation examination within weeks. This recently-established capability, termed the Minimal Activation Retrievable Capsule Holder (MARCH) irradiation vehicle system, includes capabilities for cost-effective simplified-environment testing of centimeter-scale fuel samples of various geometries, temperature-controlled irradiations of millimeter-size samples for lower-length-scale model development, liquid-metal bonded heat sink capsules for controlling transient temperature response in fuel rodlets, and an innovative approach to high throughput irradiation of transient sensors and instrumentation. The MARCH system’s capabilities will also set the foundation for fuel safety research performed in larger integral-scale test devices with coolant environments representing reactor plants. Based upon historic approaches, but modernized to meet current nuclear technology needs, these larger irradiation devices include flowing pressurized water (including the ability to depressurize to steam) as well liquid metal cooling loops for various fuel rod and small bundle specimens. Here, this paper describes the recently-established MARCH system and current trajectory to enabling advanced transient science with a suite of irradiation test devices.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Project 57 Air Monitoring Report: (Jan 1 - Dec 31 2018)

During the late 1950s, the Atomic Energy Commission (AEC) (now the U.S. Department of Energy [DOE]) conducted a series of safety experiments to determine if a nuclear device subjected to a large conventional explosives detonation would result in a nuclear yield. The AEC obtained temporary use of a large portion of western Emigrant Valley from the U.S. Department of Defense (DOD) for one of these experiments: Project 57. Following the Project 57 safety experiment, the AEC fenced the contaminated area and returned control of the surrounding land to the DOD. Emigrant Valley is part of the Nevada Test and Training Range (NTTR). For safety and security reasons, access to the NTTR is controlled using both physical (i.e., fences) and administrative (e.g., signs and postings) controls. Therefore, the public cannot access the Project 57 site and there are no known human receptors that routinely access the site. Project 57 was detonated on April 24, 1957, in Emigrant Valley approximately 13 mi (21 km) northeast of the north end of Yucca Flat. This test was undertaken to develop: (1) a means of estimating immediate distribution and long-term redistribution of plutonium dispersed during a nonnuclear detonation; (2) biomedical evaluation techniques for use in likely plutonium-laden environments; (3) methods of decontaminating ground areas, pavements, and building materials; and (4) alpha survey instruments and field monitoring procedures to promptly estimate contaminant deposition. Although the test did not result in the fission of nuclear materials, it did disseminate plutonium across the ground surface. Various radiological surveys have been performed in the area since Project 57 was conducted. The AEC delineated the area containing radioactive material based on radioactivity surveys performed shortly after the test was conducted. A designated Contamination Area (CA), marked by a fence, was established later. The distribution of americium-241 (Am-241) in the area was determined again in a 1997 flyover, which showed Am-241 ranging from as much as 70,000 counts per second (cps) at ground zero to background (<70 cps). This survey also documented Am-241 radioactivity on the ground surface beyond the east side CA fence at levels of up to 150 cps. In 2007, the DOE expanded the CA by posting “Contamination Area” signs 200 ft to 400 ft (60 m to 120 m) beyond the original fence, which formed a new CA boundary.

54 ENVIRONMENTAL SCIENCES↗

Recommended Actions to Improve Adapter Safety

With the rapid advancement and acceleration in the electric vehicle (EV) industry within the United States, major automakers and EV charging companies are increasingly adopting the North American Charging Standard (NACS) connector style, now officially known as J3400. This shift is expected to enhance charging infrastructure, providing a better customer experience by making it easier for all EV drivers to access a wider network of direct-current (DC) fast chargers (DCFCs). However, the adoption of the J3400 standard presents challenges for many EVs already on the roads and some currently coming off production lines that are equipped with the Combined Charging System (CCS) connector, which this report will refer to as the North American standard, CCS1. These vehicles will need adapters to use new or existing J3400 infrastructure. During this transition, several issues have emerged. Firstly, there is a need to standardize the new connector type to ensure it is interoperable, safe, and reliable. Second, existing CCS EV drivers need a way to access the J3400 network, which will require electric vehicle supply equipment (EVSE) or sites with both connector types, driver-provided adapters to physically convert from CCS to J3400, or EVSE with retained adapters designed for use with the EVSE. Third, adapter standards will need to be written to specify how they will be designed and what evaluations will be needed to ensure safe and reliable performance. To address these challenges, adapters that support different types of charging connectors will be essential. These adapters will play a crucial role in supporting the transition and ensuring continued service for legacy EVs with CCS inlets as the J3400 standard becomes the predominant one in the United States. Consequently, the National Charging Experience (ChargeX) Consortium has investigated and performed a teardown analysis on the different adapter versions on the market. The aim is to create a failure mode and effects analysis (FMEA) on what are expected to be the most common adapter types used in this transition. In order to support this work, we executed an FMEA exercise with the main goal of identifying gaps in the existing adapters' performance and conformance to the most common safety requirements of high-power and high-voltage devices. This effort focused on adapters provided by the driver, as these may present the highest safety and reliability risks. The recommendations made here apply to both retained and driver-provided adapters.

25 ENERGY STORAGE↗

Development of an international security standard for devices containing high-activity radioactive sources

Radioisotopes such as Cs-137 and Co-60 are utilized in various medical, industrial, and research applications. This radiological material can be a theft or sabotage target, which necessitates a certain level of security to adequately protect it. The presented work will explore the necessity of an international security standard for devices used in clinical settings that contain high activity radiological material and the facilities that contain these devices. This standard intends to complement existing safety standards; however, it serves a very different purpose: to reduce the threat of radiological theft and sabotage while taking into full consideration the effect on the patient, user safety, and patient workflow with the aim to minimize the unwanted effects of the security measures. The proposed standard will complement existing International Atomic Energy Agency (IAEA) guidance, published in the IAEA Nuclear Security Series. While those documents primarily focus on the state, competent authorities, and regulatory agencies, the proposed industry standard will involve device manufacturers, source producers, and medical staff.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

A Fully Integrated and Self-Powered Smartwatch for Continuous Sweat Glucose Monitoring

Wearable devices for health monitoring and fitness management have foreseen a rapidly expanding market, especially those for noninvasive and continuous measurements with real-time display that provide practical convenience and eliminated safety/infection risks. In this research, a self-powered and fully integrated smartwatch that consists of flexible photovoltaic cells and rechargeable batteries in the forms of a “watch strap”, electrochemical glucose sensors, customized circuits, and display units integrated into a “dial” platform is successfully fabricated for real-time and continuous monitoring of sweat glucose levels. The functionality of the smartwatch, including sweat glucose sensing, signal processing, and display, can be supported with the harvested/converted solar energy without external charging devices. The Zn-MnO 2 batteries serve as intermediate energy storage units and the utilization of aqueous electrolytes eliminated safety concerns for batteries, which is critical for wearable devices. Such a wearable system in a smartwatch fashion realizes integration of energy modules with self-powered capability, electrochemical sensors for noninvasive glucose monitoring, and in situ and real-time signal processing/display in a single platform for the first time. The as-fabricated fully integrated and self-powered smartwatch also provides a promising protocol for statistical study and clinical investigation to reveal correlations between sweat compositions and human body dynamics.

47 OTHER INSTRUMENTATION↗

Absorption of wireless radiation in the child versus adult brain and eye from cell phone conversation or virtual reality

Highlights: • More cell phone radiation is absorbed by children's inner brain tissues than adults’. • Children's radiofrequency radiation exposure should be reduced. • Further research to evaluate the risks to the eye from use of VR is urgently needed. • It is biologically relevant and feasible to reduce the standards’ averaging volume. • Current methods to determine wireless device compliance should be revised. Children's brains are more susceptible to hazardous exposures, and are thought to absorb higher doses of radiation from cell phones in some regions of the brain. Globally the numbers and applications of wireless devices are increasing rapidly, but since 1997 safety testing has relied on a large, homogenous, adult male head phantom to simulate exposures; the “Standard Anthropomorphic Mannequin” (SAM) is used to estimate only whether tissue temperature will be increased by more than 1 Celsius degree in the periphery. The present work employs anatomically based modeling currently used to set standards for surgical and medical devices, that incorporates heterogeneous characteristics of age and anatomy. Modeling of a cell phone held to the ear, or of virtual reality devices in front of the eyes, reveals that young eyes and brains absorb substantially higher local radiation doses than adults’. Age-specific simulations indicate the need to apply refined methods for regulatory compliance testing; and for public education regarding manufacturers' advice to keep phones off the body, and prudent use to limit exposures, particularly to protect the young.

54 ENVIRONMENTAL SCIENCES↗

Radiation Signature Training Device Gamma Equivalent Spheres

Radiation signature training device sources are a continuation of a previous effort to produce a highly enriched uranium equivalent sphere. The original research was designed and motivated to produce a Department of Transportation special form source that emulated the passive gamma signature of a solid metal highly enriched uranium sphere. In addition, the mass reduction (i.e., of the 235 U) minimized logistical costs (security, criticality safety, radiological safety and transportation requirements). Radiation signature training device sources expand on the original concept, redesigning the encapsulation in a modular fashion that allows a variety of loadings. The result is a reconfigurable special nuclear material source set that can vary greatly in the magnitude of the gamma flux and the isotopic distribution. Use of the source to test a variety of standards (N42.34-2015, N42.38-2015, N42.43-2015, N42.53-2018, N42.48-2018, DHS-TCS Backpack Based Radiation Detection Systems, DHS-TCS Handheld Instruments Used for the Detection and Identification of Radionuclides, DHS-TCS Vehicle Mounted Mobile Systems) will be discussed.

Blessinger, Christopher S.↗

Efficacy of an acoustic hailing device as an avian dispersal tool

Bird strikes are a major safety and financial concern for modern aviation. Audible stimuli are common bird dispersal techniques, but their effectiveness is limited by the saliency and relevance of the stimulus. Furthermore, high ambient sound levels present at airfields might require that effective audible stimuli rely more on total volume (i.e., exceeding physiological tolerances) than ecological relevance. Acoustic hailing devices (AHD) are capable of sound output with a narrow beam width and at volumes high enough to cause physical discomfort at long distances. We tested the effectiveness of an AHD as a dispersal tool on free-ranging birds recognized as hazardous to aviation safety at the Savannah River Site and Phinizy Swamp Nature Park in South Carolina and Georgia, respectively. Our study design included experimental trials with timed-interval counts of birds directly before and after AHD treatment. For most species, counts of birds associated with treatment periods (use of AHD) and control periods (no use of AHD) occurred on different days. Sound treatments yielded variable success at dispersing birds. Specifically, AHD treatment was effective for dispersing vultures (Coragyps atratus and Cathartes aura) and gulls (Laridae), and ineffective for dispersing blackbirds (Icteridae), diving ducks (Aythya, Bucephala, Oxyura), and coots (Fulica americana). These trials were conducted in a relatively quiet environment with birds that were unhabituated to excessive noise, and thus we cannot unequivocally recommend an AHD as a universally effective avian dispersing tool. Furthermore, future research should consider AHD testing integrated with other methods, as well as investigation of treatments that might be salient to specific target species.

60 APPLIED LIFE SCIENCES↗

Impact Study on the Methodology used for Photon- Heating Determination in Material-Testing Reactors

Determination of photon heating by calculation is an important issue for the Jules Horowitz Reactor (JHR), the next international Material-Testing Reactor (MTR) under construction at CEA Cadarache research center in the south of France. Accurate knowledge of photon heating in structure materials and irradiation devices is necessary for JHR design and safety studies. In this paper, we quantify the impact of different photon-heating calculation routes by comparing absorbed dose and KERMA calculations (Kinetic Energy Released per Mass) from two different Monte Carlo codes, TRIPOLI-4.9{sup R} and MCNP (Monte Carlo N-Particle transport code). These calculations are carried out in JHR-representative geometries with the nuclear-data library JEFF3.1.1 and the photon-data library EPDL97. Discrepancies amounting to up to 18% between absorbed dose and KERMA are found in JHR irradiation devices and are linked to charged-particle transport effects taking place in heterogeneous materials of small dimensions. In a JHR assembly cell, discrepancies of about 1% on photon KERMA and of about 3% on absorbed dose are highlighted between the two Monte Carlo codes. These latter discrepancies are small compared to typical sources of uncertainty for Monte Carlo calculation (for instance, nuclear data uncertainty) and are supposed to be due to differences in the processing of gamma-production data by neutron interactions and to differences in electromagnetic-shower models and implementation between the two codes. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Study on in situ calibration for neutron flux monitor in the Large Helical Device based on Monte Carlo calculations

Neutron monitoring is important to manage safety of fusion experiment facilities because neutrons are generated in fusion reactions. Monte Carlo simulations play an important role in evaluating the influence of neutron scattering from various structures and correcting differences between deuterium plasma experiments and in situ calibration experiments. We evaluated these influences based on differences between the both experiments at Large Helical Device using Monte Carlo simulation code MCNP5. A difference between the both experiments in absolute detection efficiency of the fission chamber between O-ports is estimated to be the biggest of all monitors. We additionally evaluated correction coefficients for some neutron monitors.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Initial Development of Fusion Magnet Simulation Capabilities for Performance and Safety Evaluation Using the MOOSE Framework

Fusion energy holds the promise of being a transformative technology as a carbon-neutral, sustainable source of energy. Whole device modeling and the development of fusion digital twins will be increasingly important for emerging fusion device concepts at both national laboratories and within the commercial fusion industry. However, meeting the challenge of whole device modeling of fusion energy devices requires robust, multiphysics, multiscale modeling and simulation technologies capable of running on large-scale supercomputers. Detailed analysis of individual systems at-scale is also required to ensure safe and efficient operation as well as provide the safety basis for future device designs and licensing activities. In a tokamak, toroidal and poloidal magnets confine and shape the fusion plasma to promote the fusion reaction. High plasma temperatures and high magnetic field requirements in modern design concepts (leading to high amounts of energy stored within each magnet) impose electrical, thermal, and mechanical loads on the magnet components, which in turn impacts the safety considerations of the magnet and their supporting systems. Idaho National Laboratory (INL) has a history of working in this space, including development and benchmarking of the Magnetic System Circuitry Analysis Program (MSCAP) and Magnet Arcing (MAGARC) codes to study magnet quench events; notably, MAGARC was used to study quenching during the ITER Engineering Design Activity. However, these legacy codes and capabilities are not parallel and scalable, and new tools are required for future advances in this area, which leads to the INL-developed Multiphysics Object-Oriented Simulation Environment (MOOSE) framework. Developed originally for fission reactor systems under United States Department of Energy, Office of Nuclear Energy modeling and simulation programs, the MOOSE framework has been well-suited to multiscale, multiphysics modeling and simulation needs for nuclear systems. The framework is open-source, well-tested, under continuous development and deployment, and developed to a Nuclear Quality Assurance, Level 1 software quality standard. MOOSE has also been used in the fusion space previously in several projects: INL’s Tritium Migration Analysis Program, Version 8 (TMAP8) for tritium migration, UK Atomic Energy Authority’s A Unified Resource for OpenMC (fusion) Reactor Applications (AURORA) code for fusion thermo-mechanical and neutronics analysis, and Argonne National Laboratory’s Cardinal for high-fidelity computational fluid dynamics and neutronics. However, to model superconducting magnets, several MOOSE enhancements are required: additions to the current MOOSE electromagnetic capabilities, new material libraries for superconductors of interest (such as YBCO), as well as fusion-specific models for thermo-mechanics. This talk will discuss initial development activities to build these capabilities in MOOSE, focusing on initial validation and benchmarking activities. Proposed coupling workflows and future work to support the simulation of fusion magnets and magnet structural assemblies for performance and safety evaluation in MOOSE will also be discussed.

70 - PLASMA PHYSICS AND FUSION TECHNOLOGY↗