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At least 145 records · Page 8

Impact of differences in the solar irradiance spectrum on surface reflectance retrieval with different radiative transfer codes

Surface reflectance retrieval from imaging spectrometer data as acquired with the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) has become important for quantitative analysis. In order to calculate surface reflectance from remotely measured radiance, radiative transfer codes such as 5S and MODTRAN2 play an increasing role for removal of scattering and absorption effects of the atmosphere. Accurate knowledge of the exo-atmospheric solar irradiance (E(sub 0)) spectrum at the spectral resolution of the sensor is important for this purpose. The present study investigates the impact of differences in the solar irradiance function, as implemented in a modified version of 5S (M5S), 6S, and MODTRAN2, and as proposed by Green and Gao, on the surface reflectance retrieved from AVIRIS data. Reflectance measured in situ is used as a basis of comparison.

Staenz, K.↗

Elemental Composition of 433 Eros: New Calibration of the NEAR-Shoemaker XRS Data

We present relative elemental abundances for six elements (Mg, Al, Si, S, Ca, Fe) in the surface layer of 433 Eros, derived from a new analysis of the solar induced fluorescence measured by the NEARShoemaker X ray Spectrometer (XRS).XRS derived elemental abundances have been presented before. However, calibration of XRS data depends critically on knowledge of the incident solar spectrum, which varies greatly on time scales of seconds to minutes. Unfortunately, the gas solar monitor carried by NEAR was inadequately calibrated prior to launch. The previously published XRS results were based partly on broadband measurements by the Earthorbiting GOES8 (Geostationary Operational Environmental Satellites) Xray detectors and partly on a preliminary solar monitor calibration carried out by the present authors. The new solar monitor calibration is based on a more recent set of physical models of the solar spectrum at various temperatures, an improved fitting procedure, analysis of a large number of flight spectra, and comparison with concurrent data from the GOES Xray detectors. In addition, the new analysis includes data from three solar flares not considered in earlier papers.

Lim, L. F.↗

Experimental solar radio spectrum analyzer (50-100 MHz)

Summarized is the work carried out under a NASA Grant covering the period 15 October 1977 to 14 January 1978. The grant provided funds for the acquisition of an experimental radio spectrum analyzer covering the band 50-100 MHz, for use in a program of solar radio observations. Components for the experimental analyzer were duly obtained, and the system was assembled, checked, and put into operation in early February 1978. The analyzer is working in an entirely satisfactory manner and, from the time that it has been put into operation, it has played an important part in the on-going research programs in solar radio astronomy being conducted.

Maxwell, A.↗

The Jovian Stratosphere in the ultraviolet

The center-of-disk reflectivity of Jupiter in the wavelength range from 1500 A to 3000 A was computed from 31 low dispersion IUE spectra taken during solar maximum in 1979/80. The spectra were normalized to a reflectivity scale with the improved solar spectrum of July, 1980. Consideration of wavelength shifts between different IUE spectra and within the solar spectrum improved the apparent noise, especially longward of 2000 A. Six out of seven ammonia bands between 1900 A and 2200 A were detected. A vertically inhomogeneous radiative transfer program is used to compute model reflectivities for various stratospheric compositions. In addition to ammonia, the abundance of acetylene is also well determined because these molecules show narrow absorption bands in the ultraviolet. The abundances of the other molecules in the models (C3H4, C2H4, C4H2, C2H6, C3H6) are very uncertain and therefore are quoted only as upper limits. The best model fit is consistent with infrared observations by Voyager IRIS.

Wagener, R.↗

Theoretical study of the dissociation energy and the red and violet band systems of CN

The dissociation energy (D sub O) of CN is determined to be 7.65 + or - 0.06 eV. This corresponds to delta H sub f (CN) = 105.3 + or - 1.5 kcal/mole, in excellent agreement with Engleman and Rouse (1975), but considerably larger than the recent value deduced from shock-tube studies by Colket (1984). The result is obtained not only from extensive ab initio MRCI calculations using a very large Gaussian basis set, but also from extrapolation of the directly computed value by comparison of computed and experimental results fo NO, C2, and N2. As an additional calibration of the methods, the D sub O value for CN was computed from the corresponding value for CN(-) using the experimental electron affinity data. The lifetime of the nu prime = 0 level of the violet (B 2 sigma + yields X 2 sigma +) system was computed to be 62.4 ns, in good agreement with both experiment and previous calculations. Lifetimes for the red (A 2 pi yields X 2 sigma +) system decrease with increasing nu prime, which is consistent both with the recent experiment and calculations. While the computed lifetimes are significantly longer that those obtained from the experiment, they are shorter than those deduced from an analysis of the solar spectrum. However the D sub O and f (sub OO) are consistent with Lambert's model for the solar spectrum.

Bauschlicher, Charles W., Jr.↗

High resolution rocket EUV solar spectrograph.

The design and performance of an Aerobee 150 rocket-borne solar spectrograph covering a wavelength range of 10 to 385 A are discussed. The spectrograph uses a gold-coated replica concave grating of 3-m radius with 1200 grooves/mm at an angle of incidence of 88 deg. The spectra are recorded on glass photographic plates making possible wavelength determination to 0.003 A if known standard wavelengths occur frequently enough. Special attention to scattered light made possible the photographing of the solar spectrum from 60 to 385 A without using filters to absorb the strong visible and UV sunlight, although the solar spectrum was also recorded through metal foil filters. In the laboratory the spectrograph has been used to record spectra of highly ionized metals with a resolution of 0.03 A or better.

Behring, W. E.↗

The Jovian ionospheric E region

A model of the Jovian ionosphere was constructed, that includes direct photoionization of hydrocarbon molecules. A high-resolution solar spectrum was synthesized from Hinteregger's solar maximum spectrum (F79050N), and high-resolution cross sections for photoabsorption by H2 bands in the range 842 to 1116 A were constructed. Two strong solar lines and about 30 percent of the continuum flux between 912 and 1116 A penetrate below the methane homopause despite strong absorption by CH4 and H2. It is found that hydrocarbons (mainly C2H2 are ionized at a maximum rate of 55/cu cm per sec at 320 km above the ammonia cloud tops. The hydrocarbon ions produced are quickly converted to more complex hydrocarbon ions through reactions with CH4, C2H2, C2H6, and C2H4. It is found that a hydrocarbon ion layer is formed near 320 km that is about 50 km wide with a peak density in excess of 10,000/cu cm.

Kim, Y. H.↗

Spectral effects on direct-insolation absorptance of five collector coatings

Absorptances for direct insolation of black chrome, black nickel, copper oxide, and two black zinc conversion selective coatings were calculated for a number of typical solar spectrums. Measured spectral reflectances were used while the effects of atmospheric ozone density, turbidity, and air mass were incorporated in calculated direct solar spectrums. Absorptance variation for direct insolation was found to be of the order of 1 percent for a typical range of clear-sky atmospheric conditions.

Hotchkiss, G. B.↗

A proposed update to the solar irradiance spectrum used in LOWTRAN and MODTRAN

The calibrated upwelling radiance spectra measured by AVIRIS are increasingly being analyzed with radiative transfer codes. Analysis of AVIRIS data with the LOWTRAN and MODTRAN radiative transfer codes has led to indications of an error in the solar irradiance spectra used by these codes. This paper presents evidence for the error and proposed update to the solar irradiance spectra used by LOWTRAN and MODTRAN.

Green, Robert O.↗

Calibration of the NEAR XRS Solar Monitor

The NEAR-Shoemaker X-ray spectrometer measured elemental abundance ratios for six elements (Mg, Al, Si, S, Ca, Fe) on the surface of 433 Eros by remote-sensing x-ray fluorescence spectroscopy (1,2). The fluorescent x-rays are excited by x-rays from the solar corona. Therefore, accurate knowledge of the incident solar spectrum was critically important to interpreting the fluorescence spectra received by the NEAR detectors in terms of elemental ratios on the asteroid's surface. NEAR, therefore, carried two additional X-ray spectrometers dedicated to monitoring the solar spectrum between 1 and 10 keV. One of these, a Si PIN photodiode, failed prior to orbit insertion. The second consisted of a gas-filled proportional counter similar to the asteroid-pointing detectors, but covered by a graded filter (3) intended to attenuate the incoming solar flux and increase the dynamic range of the detector. Unfortunately, the response of this filter as a function of solar incidence angle was not adequately determined in the laboratory prior to launch. The response function had to be calculated from the assumed properties of the graded filter.

Lim, L. F.↗

The influence of solar UV variations on climate

The effects on the terrestrial ozone abundance and temperature (and hence on the earth's climate) of periodic variations in the solar spectrum are investigated. Temporal variations of the solar UV spectrum are modeled in accordance with the measurements of Heath and Thekaekara (1977), and the spectrum at wavelengths greater than 2900 A is altered uniformly by small amounts so that the total luminosity remains constant with time. One-dimensional photochemical-radiative-convective models are used to predict the response of the earth's surface to the solar spectral changes. Results show that the data interpreted by Heath and Thekaekara to indicate that the solar UV flux varies by a factor of 2.5 at 1750 A from solar minimum to solar maximum are inconsistent with the historical records of ozone abundance. It is concluded, however, that if the amplitude of solar UV variations increases with increasing period, and if the spectral characteristics variations are similar to the well established solar UV variations over a solar rotation period, these variations could have a significant impact on the earth's climate and the biosphere.

Borucki, W. J.↗

A Wide Spectrum of Solar Science for After School Astronomy Club

After School Astronomy clubs are an important method of exposing students to astronomy at the critical middle school age when sparking an interest can inspire a lifelong career or hobby. We know that teachers complain that they can spend little time on astronomy in the classroom since they must teach to the test and the curriculum requirements do not have very extensive astronomy coverage. We also know that space is a very popular subject with students that can motivate them to join an after school club. One of the problems with after school astronomy clubs is that they don't often have a chance to observe the night sky. We propose to train club mentors on how to do daytime solar observing so students fulfill the IYA goal of looking through a telescope. We propose to provide a half day workshop for elementary and middle school teachers on starting and maintaining After School Astronomy clubs with special emphasis on observing the Sun not only in the visible spectrum but with radio waves and other parts of the spectrum as well. We will use NASA-oriented or NASA-funded educational materials and websites to bring a variety of ideas to the mentors and a broad knowledge of astronomy to the students. Attendees will be given an overview of the science of the Sun and how it can affect us on the Earth. They will be shown the dynamic nature of the Sun and what to look for to track the events happening there. The educators will be shown simple approaches to directly observing the Sun such as pinhole cameras, use of projection techniques with telescopes or binoculars, etc. They will be acquainted with sunspotter scopes and the advantages and disadvantages (such as expense) they pose for getting students involved. We will also point out the possibilities of using regular telescopes with solar filters and the specialized solar viewing telescopes such as the Coronado. Once the educators are comfortable with the simple approaches to viewing the Sun we will expose them to advanced topics such as remotely viewing the Sun using telescopes available on the web. Resources such as the Sun-Earth Viewer will allow them to study near real-time images of the Sun in multiple wavelengths. They will also be shown how they can monitor the Sun at radio wavelengths via remote telescopes or even how to purchase and build their own radio telescopes for hands-on monitoring of the Sun and other radio sources. We will conduct a brief evaluation of the participants knowledge of the Sun as they come into the workshop. We will also ask them to complete a brief knowledge survey at the end to determine if their knowledge and comfort level with solar science has improved significantly.

Mayo, Lou↗

Photocell heat engine solar power systems

A combined photocell heat engine concept is proposed for high efficiency solar energy conversion in space. In this concept the short wavelength portion of the solar spectrum is split by a dichroic filter and sent to a bank of photocells. The long wave-length remainder of the spectrum is used by the heat engine. This technique allows the photocells to operate with the minimum amount of waste heat, increasing their efficiency and reducing the amount of cooling required. The heat engine operates by direct absorption in a working fluid containing broadband absorber molecules or particulates. A window in the heat engine admits the long wave-lengths from the solar spectrum. The window may also reflect a portion of the internal gaseous reradiation spectrum (e.g., a heat mirror) to help reduce radiation losses. Flow-induced thermal gradients may also reduce reradiation losses in the case of optically thick working fluids. The efficiencies computed for the photocell heat engine solar energy converter can be as high as 42 percent.

Taussig, R. T.↗

Spectral reflectance properties of electroplated and converted zinc for use as a solar selective coating

The spectral reflectance properties of electroplated and chemically converted zinc were measured for both chromate and chloride conversion coatings. The reflectance properties were measured for various times of conversion and for conversion at various chromate concentrations. The values of absorptance, integrated over the solar spectrum, and of infrared emittance, integrated over black body radiation at 250 F were then calculated from the measured reflectance values. The interdependent variations of absorptance and infrared emittance were plotted. The results indicate that the optimum combination of the highest absorptance in the solar spectrum and the lowest emittance in the infrared of the converted electroplated zinc is produced by chromate conversion at 1/2 concentration of the standard NEOSTAR chromate black solution for 0.50 minute or by chloride conversion for 0.50 minute.

Mcdonald, G. E.↗

Spectral reflectance properties of electroplated and converted zinc for use as a solar selective coating

The spectral reflectance properties of electroplated and chemically converted zinc were measured for both chromate and chloride conversion coatings. The reflectance properties were measured for various times of conversion and for conversion at various chromate concentrations. The values of absorptance, alpha, integrated over the solar spectrum, and of infrared emittance, epsilon, integrated over black body radiation at 250 F were then calculated from the measured reflectance values. The interdependent variations of alpha and epsilon were plotted. The results indicate that the optimum combination of the highest absorptance in the solar spectrum and the lowest emittance in the infrared of the converted electroplated zinc is produced by chromate conversion at 1/2 concentration of the standard NEOSTAR chromate black solution for 0.50 minute or by chloride conversion for 0.50 minute.

Mcdonald, G. E.↗

Spectral reflectance properties of black chrome for use as a solar selective coating

The NASA-Lewis Research Center has determined that a widely available commercially electroplated decorative finish known as black chrome has desirable solar selective properties. Black chrome electroplated coating has high absorbtance in the solar spectrum and low emissivity in the 250 F blackbody thermal spectrum. The spectral reflectance properties of a commercially prepared black chrome on steel have been measured. Values are presented for reflectance of the black chrome, and compared with the reflectance of black paint and with two available samples of black nickel which had been prepared for solar selective properties. The reflectance of black chrome, of the two black nickels, and of black paint integrated over the solar spectrum for air mass 2 were 0.132, 0.123, 0.133, and 0.033, respectively. The reflectance of the black chrome, two black nickels, and of the black paint integrated over the blackbody spectrum for 250 F from 3 to 15 microns are 0.912, 0.934, 0.891, and 0.033, respectively. These reflectance measurements indicate absorptivity-to-emissivity values of 9.8, 13.8, 8.0, and 1.00, respectively.

Mcdonald, G. E.↗

Cryogenic Selective Surfaces

There are many challenges involved in deep-space exploration, but several of these can be mitigated, or even solved, by the development of a coating that can reject most of the Sun's energy and yet still provide some far-infrared heat emission. Such a coating would allow non-heat-generating objects in space to reach cryogenic temperatures without using an active cooling system. This would be a benefit to deep-space sensors that require low temperatures, such as the James Webb Telescope focal plane array. It would also allow the use of superconductors in deep space, which could lead to magnetic energy storage rings, lossless power delivery, or perhaps a large-volume magnetic shield against galactic cosmic radiation. But perhaps the most significant enablement achieved from such a coating would be the long-term storage in deep space of cryogenic liquids, such as liquid oxygen (LOX).In this report, we review the state of the art in low-temperature coatings and calculate the lowest temperatures each of these can achieve, demonstrating that cryogenic temperatures cannot be reached in deep space in this fashion. We then propose a new coating that does allow coated objects in deep space to achieve the very low temperatures required to store liquid oxygen or nitrogen. These new coatings consist of a moderately thick scattering layer (typically 5 mm) composed of a material transparent to most of the solar spectrum. This layer acts as a scatterer to the Sun's light, performing the same process as titanium dioxide in white paint in the visible. Under that layer, we place a metallic reflector, e.g. silver, to reflect long-wave radiation that is not well scattered. The result is a coating we call "Solar White," in that it scatters most of the solar spectrum just as white paint does for the visible. Our modeling of these coatings has shown that temperatures as low as 50 K can be reached for a coated object fully exposed to sunlight at 1 AU from the Sun and far from the Earth.In the second half of the report we explore a mission application of this coating in order to show that it allows LOX to be carried on a mission to Mars. Heat can reach a LOX tank in five ways: direct radiation from the Sun, scattered or reflected radiation from the Sun off of spacecraft components, radiation from nearby planets or the Moon, radiation from the infrared emission of other parts of the spacecraft, and conduction along support struts and flow lines. We discuss these and sum their total contribution when using a Solar White coating to demonstrate an architecture that allows the transportation of LOX to Mars. After this, other applications of Solar White are listed.

Cryogenic Materials↗