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At least 145 records · Page 8

EMU Ventilation Loop Simulation and Assessment of Contamination of the EMU Sublimator Hydrophilic Coating

Controlling moisture is a critical function performed in the space suit during extra vehicular activity (EVA) missions. Currently, this function is carried out by a sublimator, which is coated with a hydrophilic material. Tests have shown that siloxane compounds can off gas from the helmet absorption pad extension (HAP-E) and helmet absorption band (HAB) when they are at elevated temperatures and initial testing indicated that siloxanes could damage the hydrophilic coating. Therefore, more representative testing was needed. Important test considerations were source and destination kinetics, system geometries, scrubbing efficacy by the activated charcoal from the Metox canister, and other benefits that derive from active condensation occurring on the hydrophilic coating during exposure. A ventilation loop that was originally constructed to test hardware for control of CO2 and trace contaminants under EVA conditions was modified to conduct the siloxane off gassing tests. A vacuum compatible acrylic chamber was installed to simulate the suit volume. A steel beaker located in the chamber contained the HAP-E and HAB materials and was heated with two band heaters. The flow exiting the chamber passed through a LiOH cannister, which contained carbon beds to simulate their function in the Metox. The flow then was directed into a smaller volume that contained a coupon, which was coated with the hydrophilic material and was maintained at 10°C (50°F). Moisture was injected upstream of the suit volume simulator to maintain the dew point between 12.7°C (55°F) and 18.3°C (65°F). The pressure was controlled to between 3.8 and 4.4 psia, and the flow was held at 6 acfm. The system was run for an equivalent of 25 ten-hour EVAs, where the HAP-E/HAB materials were changed out after each EVA. The effect of the potential off gassing on the coupon was measured after each EVA period.

PLSS↗

The ablation of graphitic materials in the sublimation regime.

A large variety of graphitic materials have been tested in an arc heated air stream at a surface pressure of 4.3 atm and a nominal surface temperature of 3925 K. Included were commercial and developmental grades of artificial graphites, both two and three dimensional carbon-carbon composites, composites seeded with refractory compounds, and several special materials such as pyrolytic graphite, mesophase graphite, glassy carbon, and natural graphite. ATJ graphite was used as a control material. Except for the seeded materials which had poor performance, the mass loss rate for all the man-made graphitic materials fell within the range of 17 per cent less to 30 per cent more than the rate for ATJ. Thus it is concluded that wide variations in constituents, processing, fabrication and structure have relatively little effect on the ablation performance of graphitic materials, at least under the conditions of the present tests. Particulate mass loss was observed for all the materials tested and is the dominant mechanism for mass removal at the present test conditions. It is suggested that this mechanism results from physical failure, primarily by compressive thermal stress.

Lundell, J. H.↗

Sublimate morphology on 74001 and 74002 orange and black glassy droplets

SEM-EDX analysis of the surface morphology of the 74001 and 74002 orange and black glassy droplets has revealed the presence of ubiquitous micromound coatings. Assuming that the diameter of an individual micromound is an indication of total coating thickness, then the thickness of this volatile and metal-rich layer ranges from less than 20 A to over 300 A in thickness. On rare droplets the micromound coating is partially covered by a sparse population of crystals and masses that are essentially NaCl in composition. Additionally, an irregular mass on the surface of one black droplet may contain free sulfur. Amoeboid masses of iron, some with incipient crystal faces, are also present on a few droplet surfaces. The above features, i.e., halite crystals, sulfur-rich masses and amoeboid iron, are rare; the more common occurrence of metals and volatiles is in the micromound coating. Based on our observations of several hundred spheres from both Apollo and Luna missions, the classic micromound coating is unique to the Apollo 15 green and Apollo 17 orange and black droplets. Although some investigators have proposed various impact sequences to produce these unique droplets, the volcanic fire fountain origin is favored.

Clanton, U. S.↗