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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS2003

Silicate Stardust from Comets

Interplanetary dust particles (IDPs) collected in the Earth s stratosphere are 5-50 pm fragments of asteroids and comets. Anhydrous IDPs have escaped significant parent body hydrothermal alteration and are further distinct from meteorites in their greater abundances of volatile elements and C, fine grained (l00 - 500 nm) textures, and unequilibrated mineralogies. Many anhydrous IDPs contain high abundances interstellar organic compounds and grains of silicate stardust. These observations are consistent with properties of comets inferred from remote astronomical observations. Comets have been thought to be pristine aggregates of interstellar materials. However, spectroscopic observations of crystalline silicates in comets has challenged this notion, given their apparent absence in the interstellar medium.

Messenger, S.↗
NASA NTRS1999

Irradiated interplanetary dust particles as a possible solution for the deuterium/hydrogen paradox of Earth's oceans

Determining the source of Earth's oceans is a longstanding problem in planetary science. Possible sources of water include water ice or water of hydration of silicate minerals in the original material from which the bulk Earth accreted and water brought in by late-arriving planetesimals during the heavy bombardment period (4.5-3.8 Gyr ago) [Chyba, 1989, 1991]. Comets are an attractive source of water because their origin in the outer solar system is consistent with the long timescale for heavy bombardment. However, the high deuterium/hydrogen (D/H) ratio of the three comets that have been studied, Halley, Hyakutake, and Hale-Bopp, indicates that Earth must have had a source with a low-D/H ratio as well. Here we suggest that solar wind-implanted hydrogen on interplanetary dust particles (IDPs) provided the necessary low-D/H component of Earth's water inventory.

Non-NASA Center↗
NASA NTRS2013

What Should the FeO Content of a Terrestrial Planet Be?

Basalts from the Earth, the Moon, Mars, and Vesta are strongly depleted in elements that prefer to reside in the metallic state (siderophile elements). Therefore, it is believed that all these bodies have metallic cores. We do not yet have siderophile element analyses of venusian or mercurian basalts, but we assume that Venus, too, as a terrestrial planet, has a metallic core. For the Earth, Moon, Mercury, and Mars, the moments-of-inertia of these bodies are consistent with metallic cores of various sizes. Because Venus rotates so slowly, it may be difficult to determine the moment-of-inertia of Venus in order to confirm this assumption. However, despite many possible complexities, it seems likely that most of the major and minor terrestrial planets have experienced some sort of metal/silicate equilibration, and we will use this as a boundary condition. One immediate contrast between the Earth and Moon is the difference in FeO content between lunar and terrestrial basalts. Both bodies presumably formed near 1 AU and formed from the same feeding zone of planetesimals, judging by their oxygen isotopes [13]. If, for example, the Moon formed from the Earth by a giant impact, then this event must have occurred before high-pressure equilibria had the opportunity to deplete the Earth s mantle in FeO. Alternatively, the bulk silicate Moon may be dominated by material from the impactor. Regardless, it would be useful to know the pressures where FeO incorporation into a metallic core is not of interest. If the Giant Impact hypothesis is correct, this should set an upper limit for the size of the proto-Earth at the time of the impact.

Jones, John H.↗
NASA NTRS2023

Phyllosilicate Decomposition on Bennu Due to Prolonged Surface Exposure

The Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) mission to carbonaceous asteroid (101955) Bennu performed detailed mapping with a suite of instruments to characterize the composition and geology of its surface. Here we use data from the OSIRIS-REx Thermal Emission Spectrometer (OTES) instrument to investigate the relationship of OTES-derived spectral indices to other derived data products from OTES, the OSIRIS-REx Camera Suite (OCAMS), and the OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS) at global and local scales. We quantitatively confirm that high values of the OTES silicate stretching slope (from ∼10 to ∼12 μm) in midday spectra that are indicative of thin and/or patchy dust cover are strongly associated with low thermal inertia (high porosity), low albedo boulders on Bennu. These high porosity boulders have brecciated textures with embedded clasts that likely originated on Bennu's parent body or during its disruption. The high porosity of these boulders is a key factor in the local production of the dust or its entrapment, as some large, brecciated boulders with a lower porosity have little evidence of dust. A second OTES spectral parameter, the silicate bending band depth near 22.7 μm applied to early evening spectra, is not correlated to thermal inertia, but is weakly to strongly correlated to albedo, OVIRS-derived 1.05 μm and 2.74 μm band depths, OVIRS-derived hydrogen abundance, and modeled nanophase troilite abundance. In several regions on Bennu there is a strong spatial relationship between these parameters, whereby areas with shallower silicate bending bands also have shallower 1.05 μm and 2.74 μm bands and lower albedo with higher nanophase troilite abundances. These correlations, combined with analysis of the silicate bending band in laboratory experiments of space weathered and mildly heated carbonaceous chondrites, suggests that decreased silicate bending band depths signify decomposition of phyllosilicates, likely Fe-bearing, due to space weathering or mild heating (<600 °C) via solar radiation during Bennu's time in near-Earth space. There is a strong association of larger silicate bending band depths in areas dominated by small rocks and unresolved material and in areas with small (≤ 25 m) craters identified as the spectrally reddest on Bennu, suggesting that this material has been more recently exposed due to impact and/or mass wasting processes. The shallowest silicate bending depths are associated with larger rocks and boulders that appear to have the longest surface exposure history, although there is band depth variation among them suggesting either initial composition variation that resulted in different responses to space weathering or heating, or varied exposure history of individual boulders themselves. We predict that any grains returned from Bennu with a significant surface exposure history will be characterized by shallower 22.7 μm, 1.05 μm and 2.7 μm band depths and increased sulfide (troilite) abundance, as well as textural and chemical evidence for phyllosilicate dehydration.

Asteroids, surfaces↗
NASA NTRS2003

Comparative Planetary Mineralogy: Basaltic Plagioclase from Earth, Moon, Mars and 4 Vesta

Major, minor and trace element analysis of silicates has allowed for the study of planetary basalts in a comparative planetary mineralogy context. We continue this initiative by exploring the chemistry of plagioclase feldspar in basalts from the Earth, Moon, Mars and 4 Vesta. This paper presents new data on plagioclase from six terrestrial basalt suites including Keweenawan, Island Arc, Hawaiian, Columbia Plateau, Taos Plateau, and Ocean Floor; six lunar basalt suites including Apollo 11 Low K, Apollo 12 Ilmenite, Apollo 12 Olivine, Apollo 12 Pigeonite, Apollo 15 Olivine, and Apollo 15 Pigeonite; two basaltic martian meteorites, Shergotty and QUE 94201; and one unequilibrated eucrite, Pasamonte.

Karner, J. M.↗
NASA NTRS1992

Inheritance of silicate differentiation during lunar origin by giant impact

It is pointed out that the implication of the popular giant impact model of lunar origin (e.g., Hartmann and Davis, 1975; Cameron and Ward, 1976; Stevenson, 1987) is that any depth-related silicate differentiation within the impactor (and/or the earth) at the time of the impact must be partly inherited by the preferentially peripheral matter that forms the moon. This paper presents calculations of the magnitude of the net differentiation of the protolunar matter for a variety of elements and scenarios, with different assumptions regarding the geometries of the 'sampled' peripheral zones, the relative proportions of the earth-derived to impactor-derived matter in the final moon, and the degree to which the impactor mantle had crystallized prior to the giant impact. It is shown that these differention effects constrain the overall plausibility of the giant impact hypothesis.

Warren, Paul H.↗
NASA NTRS1992

The morphology of lava flows in planetary environments - Predictions from analog experiments

Computations are carried out of the rates of surface cooling and lateral flow of lavas extruded onto the surfaces of terrestrial planets and the outer planet satellites, and the likely flow morphologies predicted by extrapolation of the laboratory analog results are determined. Results of this approach are presented for the earth, Venus, Mars, the moon, and the silicate flows on Io. The experiments, which involved the spreading of a viscous liquid under gravity in the presence of a solidifying surface crust, revealed a set of four distinct surface morphologies.

Griffiths, Ross W.↗
NASA NTRS1991

Earth's core-mantle boundary - Results of experiments at high pressures and temperatures

Laboratory experiments document that liquid iron reacts chemically with silicates at high pressures (above 2.4 x 10 to the 10th Pa) and temperatures. In particular, (Mg,Fe)SiO3 perovskite, the most abundant mineral of earth's lower mantle, is expected to react with liquid iron to produce metallic alloys (FeO and FeSi) and nonmetallic silicates (SiO2 stishovite and MgSiO3 perovskite) at the pressures of the core-mantle boundary, 14 x 10 to the 10th Pa. The experimental observations, in conjunction with seismological data, suggest that the lowermost 200 to 300 km of earth's mantle, the D-double-prime layer, may be an extremely heterogeneous region as a result of chemical reactions between the silicate mantle and the liquid iron alloy of earth's core. The combined thermal-chemical-electrical boundary layer resulting from such reactions offers a plausible explanation for the complex behavior of seismic waves near the core-mantle boundary and could influence earth's magnetic field observed at the surface.

Knittle, Elise↗
NASA NTRS1984

Mineralogical-petrological characterization of near-earth asteroids

The mineralogy and petrology of 17 near-earth asteroids are characterized using reflectance spectroscopy with ground-based telescopes. Assuming the surfaces are composed of cosmically abundant materials, the presence of certain mineralogical species can be determined from diagnostic absorption features and spectral characteristics which have been studied under known laboratory conditions and understood in terms of crystal-field theory. With one possible exception, the surface composition of near-earth asteroids consists of common rock-forming minerals such as olivine, pyroxene, and phyllosilicates. Opaque components are present but cannot be mineralogically identified with existing experimental data. The spectrum of 2201 Oljato cannot be interpreted in terms of common rock-forming minerals and is examined for cometary features because its high orbital eccentricity suggests a possible relation to comets, but no common cometary features are identified. The predominance of mafic silicate absorption features in spectra of near-earth asteroids (compared to the majority of main-belt asteroids) may be a primary compositional feature or may be the signature of relatively fresher asteroid material.

Mcfadden, L. A.↗
NASA NTRS2005

Os-187/Os-188 and Highly Siderophile Element Systematics of Apollo 17 Aphanitic Melt Rocks

Introduction: Generally chondritic relative abundances and high absolute abundances of the highly siderophile elements (HSE: Ru, Rh, Pd, Re, Os, Ir, Pt, Au) in Earth s upper mantle provide strong evidence that these elements were added to the Earth following the last major interaction between its metallic core and silicate fraction. So called "late accretion" may have added materials comprising as much as 0.8% of the total mass of the Earth and possibly a similar proportion of mass to the Moon. We have begun to study the chemical nature of late accreted materials to the Earth - Moon system by examining the HSE contained in lunar impact-melt rocks. The HSE contained in melt rocks were largely added to the Moon during the period of time from the origin of the lunar highlands crust (4.4- 4.5 Ga) to the end of the late bombardment period (ca. 3.9 Ga). These materials provide the only direct chemical link to the late accretionary period. The chemical fingerprints of the HSE in late accreted materials may enable us to ascertain under what conditions and where in the solar system the late accreted materials formed. The Os-187/Os-188 ratios (reflecting long-term Re/Os), coupled with ratios of other HSE, can be diagnostic for identifying the nature of the impactor. A critical issue, however, will be deconvolving the exogenous from indigenous components.

Puchtel, I. S.↗
NASA NTRS2019

Molten Silicate Reactivity with Environmental Barrier Coating Materials for Gas Turbine Engine Applications

Rare earth (RE) disilicates are utilized in environmental barrier coatings (EBCs) to protect SiC-based ceramic matrix composites (CMCs) from destructive reactions with water vapor and other combustion species. These coating materials, however, degrade when exposed to molten silicate deposits primarily composed of calcium-magnesium aluminosilicates (CMAS). Coating materials are exposed to CMAS by engine ingestion of dust particulates from terrestrial sources during operation. Due to continual increases in engine operating temperature, it is important to understand the high temperature thermochemical mechanisms that drive corrosion of these materials. This work focuses on characterizing reaction products between disilicates and CMAS and optimizing coating chemistries to mitigate damage.

Stokes, Jamesa L.↗
NASA NTRS2016

Effect of Silicon on Activity Coefficients of Siderophile Elements (P, Au, Pd, As, Ge, Sb, and In) in Liquid Fe, with Application to Core Formation

Earth's core contains approximately 10 percent light elements that are likely a combination of S, C, Si, and O, with Si possibly being the most abundant. Si dissolved into Fe liquids can have a large effect on the magnitude of the activity coefficient of siderophile elements (SE) in Fe liquids, and thus the partitioning behavior of those elements between core and mantle. The effect of Si can be small such as for Ni and Co, or large such as for Mo, Ge, Sb, As. The effect of Si on many siderophile elements is unknown yet could be an important, and as yet unquantified, influence on the core-mantle partitioning of SE. Here we report new experiments designed to quantify the effect of Si on the partitioning of P, Au, Pd, and many other SE between metal and silicate melt. The results will be applied to Earth, for which we have excellent constraints on the mantle siderophile element concentrations.

Righter, K.↗
NASA NTRS2017

Effect of Silicon on Activity Coefficients of Platinum in Liquid Fe-Si, With Application to Core Formation

Earth's core contains approximately 10% of a light element that is likely a combination of S, C, Si, and O, with Si possibly being the most abundant light element. Si dissolved into Fe liquids can have a large effect on the magnitude of the activity coefficient of siderophile elements (SE) in Fe liquids, and thus the partitioning behavior of those elements between core and mantle. The effect of Si can be small such as for Ni and Co, or large such as for Mo, Ge, Sb, As. The effect of Si on many siderophile elements is unknown yet could be an important, and as yet unquantified, influence on the core-mantle partitioning of SE. Here we report new experiments designed to quantify the effect of Si on the partitioning of Pt (with Re and Ru in progress or planned) between metal and silicate melt. The results will be applied to Earth, for which we have excellent constraints on the mantle Pt concentrations.

Righter, K.↗
NASA NTRS1984

Is phosphorus predictably incompatible in igneous processes?

Siderophile element abundances are central to recent models for core formation in the Earth and Moon and the origin of the Moon. It is important to identify siderophile elements whose behavior in igneous processes is predictable, so that primary mantle abundances can be deduced by subtracting out the effects of igneous processes. Newsom's model for core formation in the Moon requires subchondritic P, and suggests that P was depleted due to volatility. Experiments were conducted to determine P olivine/liquid distribution coefficients. Preliminary results indicate that P can be compatible with olivine during rapid cooling, but is not during isothermal crystallization with long growth times, and tends to be expelled during annealing. It is therefore not likely that P is compatible under any widespread igneous conditions, and the incompatible behavior of P in lunar crustal rocks can be safety assumed. In addition, low fO2 is insufficient to cause P compatibility, so it is unlikely that P-rich silicates formed during the early evolution of the Earth or Moon. These results indicate that P is depleted in the Moon.

Goodrich, C. A.↗
NASA NTRS1984

Origin of the Moon

The similarities in siderophile abundances strongly suggest that the Moon was derived from the Earth's mantle after the Earth's core had formed. The energy required to remove material from the Earth's mantle and place it into geocentric orbit can be supplied most readily by impact processes during accretion of the Earth. Impacts of late-accreting, high-velocity planetismals would evaporate many times their masses of mantle material. These gases would be accompanied by a massive spray of shock-melted silicate droplets. It is suggested that the gases produced from such near-equatorial impacts were rapidly spun out into equatorial geocentric orbit. The evaporated material was selectively recondensed, and, accompanied by the shock melted, devolatilized silicate droplets, accreted to form a sediment ring of Earth-orbiting planetismals. This sediment ring also captured a significant proportion of Earth-bound planetismals. The Moon was formed by accretion from planetismals comprising the sediment ring.

Ringwood, A. E.↗
NASA NTRS2014

Core-Mantle Partitioning of Volatile Elements and the Origin of Volatile Elements in Earth and Moon

Depletions of volatile siderophile elements (VSE; Ga, Ge, In, As, Sb, Sn, Bi, Zn, Cu, Cd) in mantles of Earth and Moon, constrain the origin of volatile elements in these bodies, and the overall depletion of volatile elements in Moon relative to Earth. A satisfactory explanation has remained elusive [1,2]. We examine the depletions of VSE in Earth and Moon and quantify the amount of depletion due to core formation and volatility of potential building blocks. We calculate the composition of the Earth's PUM during continuous accretion scenarios with constant and variable fO2. Results suggest that the VSE can be explained by a rather simple scenario of continuous accretion leading to a high PT metal-silicate equilibrium scenario that establishes the siderophile element content of Earth's PUM near the end of accretion [3]. Core formation models for the Moon explain most VSE, but calculated contents of In, Sn, and Zn (all with Tc < 750 K) are all still too high after core formation, and must therefore require an additional process to explain the depletions in the lunar mantle. We discuss possible processes including magmatic degassing, evaporation, condensation, and vapor-liquid fractionation in the lunar disk.

Righter, Kevin↗