Search NASA⌕ Search

SEARCH · Search NASA

Results for “Surface Instability”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Thermal decomposition pathways of bulk electrolytes on vanadium oxide nanocrystals

The thermal stability of electrolytes at an elevated temperature induced by battery charge-discharge cycling is critical for the long cycling performance of a rechargeable battery. For many multivalent systems, such as rechargeable magnesium batteries, which offer great potential for high energy density and utilize earth-abundant resources, electrolyte instability and electrode surface passivation, arising from electrolyte decomposition, remain as major roadblocks. Understanding the electrolyte decomposition pathways at the electrode-electrolyte interface is essential to provide guidance in overcoming this challenge. In this work, in situ 13 C magic angle spinning nuclear magnetic resonance (MAS NMR) and first-principles calculations were used to investigate the thermal decomposition of the electrolyte in a system consisting of MgV 2 O 4 , a novel cathode for magnesium batteries, mixed with a bulk electrolyte consisting of magnesium bis(trifluoromethanesulfonyl)imide (Mg(TFSI) 2 ) in diglyme (G2). We show that significant electrolyte decomposition is observed in bulk 1.0 M Mg(TFSI) 2 in G2 mixed with nanometer sized MgV 2 O 4 powder at elevated temperatures. This observation is to mimic the possible thermal decomposition that might happen during battery cycling. We demonstrate that the MgV 2 O 4 surface is covered by a layer of decomposed G2 products. We conclude that the dominant reaction pathway for electrolyte decomposition is the thermal decomposition of the pure electrolytes at elevated temperatures, followed by adsorption of G2 decomposition products to the MgV 2 O 4 surface. The activation energy for the major decomposition pathway is obtained. In conclusion, this work highlights the importance of studying thermal decomposition of electrolytes for overall system stability and explores electrolyte stability at significantly elevated temperatures.

25 ENERGY STORAGE↗
DOE OSTI2026

A conservative discontinuous Galerkin algorithm for particle kinetics on smooth manifolds

A novel, conservative discontinuous Galerkin algorithm is presented for particle kinetics on manifolds. The motion of particles on the manifold is represented using both canonical and non-canonical Hamiltonian formulations. Our schemes apply to both formulations, but the canonical formulation results in a particularly efficient scheme that also conserves particle density and energy exactly. The collisionless update is coupled to a Bhatnagar-Gross-Krook (BGK) collision operator that provides a simplified model for relaxation to local thermodynamic equilibrium. An iterative scheme is constructed to ensure collisional invariants (density, momentum and energy) are preserved numerically. Rotation of the manifold is incorporated by modifying the Hamiltonian while ensuring a canonical formulation. Several test problems, including a kinetic version of the classical Sod shock problem, Kelvin-Helmholtz instability on the surfaces of a sphere and a hyperboloid, with and without rotations, are presented. A prospectus for further development of this approach to simulation of kinetic theory in general relativity is presented.

Discontinuous Galerkin↗
DOE OSTI2022

Signatures of a magnetic-field-induced Lifshitz transition in the ultra-quantum limit of the topological semimetal ZrTe 5

The quantum limit (QL) of an electron liquid, realised at strong magnetic fields, has long been proposed to host a wealth of strongly correlated states of matter. Electronic states in the QL are, for example, quasi-one dimensional (1D), which implies perfectly nested Fermi surfaces prone to instabilities. Whereas the QL typically requires unreachably strong magnetic fields, the topological semimetal ZrTe 5 has been shown to reach the QL at fields of only a few Tesla. Here, we characterize the QL of ZrTe 5 at fields up to 64 T by a combination of electrical-transport and ultrasound measurements. We find that the Zeeman effect in ZrTe 5 enables an efficient tuning of the 1D Landau band structure with magnetic field. This results in a Lifshitz transition to a 1D Weyl regime in which perfect charge neutrality can be achieved. Since no instability-driven phase transitions destabilise the 1D electron liquid for the investigated field strengths and temperatures, our analysis establishes ZrTe 5 as a thoroughly understood platform for potentially inducing more exotic interaction-driven phases at lower temperatures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2023

Density variance dynamics in disparate shock tubes

This report discusses two experiments which investigate thin layer, heavy curtain fragmentation from the perspective of a Reynolds-Averaged mix model, in drastically disparate experimental regimes. The first, the centimeter/millisecond-scale “Horizontal Shock Tube” (HST) is a compressed-gas piston-driven shock tube experiment. The second, the “Multishock thin layer” (Mshock) experiment performed at the National Ignition Facility, is a micrometer/nanosecond-scale laser-driven shock tube experiment. Both are situations in which a heavy plane layer (a ‘curtain’) is initially suspended in a lighter medium. After being shocked from at least one side, the layer translates while its interfaces evolve due to the excitation of the Richtmyer-Meshkov instability at its surfaces. The evolution of density variance, which initially exists only on the surface of the layer, as it comes to encompass the whole layer interior is used as a description of layer fragmentation and dissolution. These experiments have each been simulated in the Los Alamos National Laboratory multi-physics code xRAGE, which includes fundamental hydrodynamics, extended plasma physics and radiation effects which are important to drive the high-energy density experiment, and the Besnard-Harlow-Rauenzahn (BHR) turbulence model. In each, the principal diagnostic for comparison is an experimental metric for the density (co)variance, b, which tracks the moments of the density field at the curtain interfaces and body. Due to experimental constraints in different regimes (i.e. optical diagnostics can be deployed on conventional shock tubes, while the plasma shock tubes must be imaged by x-rays; interfaces can be imposed to specification on laser-driven experiments, which are stored in the solid phase, while conventional experiments have imperfect control of the flow fields which separate the layer, etc.) the experiments are not designed to be perfect scaled cognates of one another. However, despite the separation of six orders of magnitude of scaling in time, and four in space, we are able to demonstrate that the same turbulence model, operating in the same fashion in the same computer code, is able to reproduce results in each experiment, by tracking evolution due to common relevant physics. Additionally, we will present preliminary work toward density variance comparisons in a single-interface Richtmyer-Meshkov configuration, the conventional fluid “Vertical Shock Tube” (VST) experiment, and the Modal Initial Conditions (ModCons) campaign fielded at the OMEGA-EP laser facility.

42 ENGINEERING↗
NASA NTRS1974

A zero-gravity demonstration of the collision and coalescence of water droplets

The mechanics of the collision and coalescence of liquid droplets is one of the main research areas in the fields of nuclear physics, astrophysics, meteorology and fluid mechanics. The crew members on the Skylab 3 and 4 missions were requested to perform demonstrations of the collision and coalescence of water droplets under the low gravity environment at orbital altitude. In Skylab 4 two water droplets with equal volumes, 30 cu cm each, were used. A dark colored droplet (contaminated with grape drink) moving with a velocity of 3.14 cm/sec collided with a stationary pink colored droplet (contaminated with strawberry drink) and coalescence occurred. Theoretical models are proposed to study the various stages of the collision-coalescence processes. Special considerations are concentrated in the investigation of the bounce-coalescence and coalescence-instability processes. The surface tension of the coalesced droplets was calculated to be 52 dynes/cm in perfect agreement with laboratory measurements made after the flight using a reproduction of the liquids.

Hung, R. J.↗
NASA NTRS1975

Studies of rotating liquid floating zones on Skylab IV

Liquid zones of water, soap solution and soap foam were deployed between two aligned circular disks which were free to rotate about the zone axis in the microgravity environment of Skylab IV. Such a configuration is of interest in the containerless handling of melts for possible future space processing crystal growth experiments. Three basic types of zone surface deformation and instability were observed for these rotational conditions; axisymmetric shape changes under single disk rotation, nonaxisymmetric, whirling, C-modes for long zones with equal rotation of both disks, and capillary wave phenomena for short zones with equal rotation of both disks. The sources of these instabilities and the conditions promoting them are analyzed in detail from video tape recordings of the Skylab experiments.

Carruthers, J. R.↗
NASA NTRS1976

A new interpretation of luminous blue stars

A major revision of current theoretical ideas about the brightest blue stars must be made if Carson's (1976) radiative opacities are adopted in stellar models. Unlike earlier opacities, these exhibit a large 'bump' due to CNO ionization, which leads to very strong central condensation, convective instability, and pulsational instability in hot diffuse stellar envelopes. Despite a number of theoretical uncertainties, the new picture of the structure of very luminous stars is reasonably successful in accounting for a variety of previously unexplained observations. The stellar models for the phase of core hydrogen burning predict large radii and rather cool effective temperatures for O stars and a spreading out of the main-sequence band in the H-R diagram toward luminous cool supergiants for masses higher than about 20 solar masses. In massive X-ray binary systems, circular orbits and supergiant-like visual companions are expected to be quite common. Long-period variability is predicted to exist for massive blue supergiants of luminosity class Ia. The models for helium stars predict large radii and rather cool effective temperatures for Wolf-Rayet stars, as well as multimodal pulsational instability and, possibly, surface turbulence for these stars.

Stothers, R.↗
NASA NTRS1985

Instability of capillary jets with thermocapillarity

Long axisymmetric liquid zones are subject to axial temperature gradients which induce steady viscous flows driven by thermocapillarity. The approximately parallel flow in a cylindrical zone is examined for linearized instabilities. Capillary, surface-wave and thermal modes are found. Capillary breakup can be retarded or even suppressed for small Prandtl number and large Biot number B, which measures heat transfer from the liquid to the surrounding atmosphere. In the limiting case B approaches infinity the zone becomes an isothermal jet subject to axial 'wind stress' on its interface. It is then possible to suppress capillary breakup entirely so that one can maintain long coherent jets.

Xu, J.-J.↗
NASA NTRS1989

Curvature effects on the stability of laminar boundary layers on swept wings

The stability of the laminar boundary layer on a swept wing is examined. An improved linear stability theory which includes the effects of body and streamline curvature and compressibility is utilized for the calculations. The computed N-factor is correlated with the onset of transition. For this study, only test conditions where transition is due to the growth of highly amplified crossflow instabilities on convex surfaces are examined. The calculations show that the effect of the curvature terms is to dramatically reduce local amplification rates in regions where body and streamline curvature are large. For the cases where transition occurred ahead of the pressure minimum on the upper surface of the wing, the N-factor at transition onset is near 9 when the effects of body and streamline curvature are included in the computations. When the curvature terms are neglected, the average N-factor is about 17. The calculations show that traveling crossflow waves are most amplified.

Collier, F. S., Jr.↗
NASA NTRS2004

Novel Phenylethynyl Imide Silanes as Coupling Agents for Titanium Alloy

The durability of titanium (Ti) alloys bonded with high temperature adhesives such as polyimides has failed to attain the level of performance required for many applications. The problem to a large part is attributed to the instability of the surface treatment on the Ti substrate. Although Ti alloy adhesive specimens with surface treatments such as chromic acid anodization, Pasa-Jell, Turco, etc. have provided high initial mechanical properties, these properties have decreased as a function of aging at ambient temperature and faster, when aged at elevated temperatures or in a hot-wet environment. As part of the High Speed Civil Transport program where Ti honeycomb sandwich structure must perform for 60,000 hours at 177 C, work was directed to the development of environmentally safe, durable Ti alloy surface treatments.

Park, C.↗
NASA NTRS1989

The Kelvin-Helmholtz instability at the magnetopause and inner boundary layer surface

Observations by the vector electron spectrometer on the ISEE 1 spacecraft are used to directly check the incompressible hydromagnetic stability condition given by Hasegawa (1975), which indicates how stability is influenced by the velocity shear, density ratio, magnetic field, and the direction of the wave vector of the unstable wave mode. The magnetopause is generally found to be stable, by a large margin. In contrast, many cases of marginal stability or instability are found across density transitions in, and at the inner edge of, the boundary layer for wave vectors in plausible directions. It thus appears that the Kelvin-Helmholtz instability is of importance at the inner edge of the magnetospheric boundary layer, as predicted by MHP theory.

Ogilvie, Keith W.↗
DOE OSTI2021

Superconductivity from Luttinger surfaces: Emergent Sachdev-Ye-Kitaev physics with infinite-body interactions

The pairing of two electrons on a Fermi surface due to an infinitesimal attraction between them always results in a superconducting instability at zero temperature (T = 0). The equivalent question of pairing instability on a Luttinger surface (LS)—190a contour of zeros of the propagator—instead leads to a quantum critical point (QCP) that separates a non-Fermi liquid and superconductor. A surprising and little understood aspect of pair fluctuations at this QCP is that their thermodynamics maps to that of the Sachdev-Ye-Kitaev (SYK) model in the strong coupling limit. Here, we offer a simple justification for this mapping by demonstrating that (i) LS models share the reparametrization symmetry of the q → ∞ SYK model with q-body interactions close to the LS, and (ii) the enforcement of gauge invariance results in a $\frac{1}{√τ}$ (τ ~ T -1 ) behavior of the fluctuation propagator near the QCP, as is the feature of SYK conformal Green functions, but leaves the overall form of the free energy map robust.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1998

Convective Instability of a Gravity Modulated Fluid Layer with Surface Tension Variation

Gravity modulation of an unbounded fluid layer with surface tension variations along its free surface is investigated. In parameter space of (wavenumber, Marangoni number) modulation has a destabilizing effect on the unmodulated neutral stability curve for large Prandtl number, Pr, and small modulation frequency, Omega, while a stabilizing effect is observed for small Pr and large Omega. As Omega yields infinity, the modulated neutral stability curves approach the unmodulated neutral stability curve. At certain values of Pr and L2 multiple minima are observed and the neutral stability curves become highly distorted. Closed regions of subharmonic instability are also observed. Alternating regions of synchronous and subharmonic instability separated by very thin stable regions are observed in (1/Omega,g(sub 1)) space for the singly diffusive cases. Quasiperiodic behavior in addition to the synchronous and subharmonic responses, are observed for the case of a double diffusive fluid layer. Minimum acceleration amplitudes were observed to closely correspond with a subharmonic response, Lambda(sub im) = Omega/2 .

Skarda, J. Raymond Lee↗
DOE OSTI2021

Search for Q ~0 Order near a Forbidden Bragg Position in Bi 2.1 Sr 1.9 CaCu 2 O 8+x with Resonant Soft X-ray Scattering

Identifying what broken symmetries are present in the cuprates has become a major area of research. Many authors have reported evidence for so-called “Q ~ 0” order that involves broken inversion, mirror, chiral, or time-reversal symmetry that is uniform in space. Not all these observations are well understood and new experimental probes are needed. Here we use resonant soft x-ray scattering (RSXS) to search for Q ~ 0 order in Bi 2.1 Sr 1.9 CaCu 2 O 8+x (Bi-2212) by measuring the region of a forbidden Bragg peak, (0,0,3), which is normally extinguished by symmetry but may become allowed on resonance if valence band order is present. Using circularly polarized light, we found that this reflection becomes allowed on the CuL 3 resonance for temperatures T c < T < T*, though remains absent in linear polarization and at other temperatures. This observation suggests the existence of spatially uniform valence band order near the pseudogap temperature. In addition, we observed periodic oscillations in the specular reflectivity from the sample surface that resemble thin film interference fringes, though no known film is present. These fringes are highly resonant, appear in all polarizations, and exhibit a period that depends on the location where the beam strikes the sample surface. We speculate that these fringes arise from interaction between some intrinsic valence band instability and extrinsic structural surface morphologies of the material. Our study supports the existence of some kind of Q ~ 0 broken symmetry state in Bi-2212 at intermediate temperatures. Further studies using a microfocused beam, which could disentangle microscopic effects from macroscopic heterogeneities, are needed to ascertain the universality of the effect.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2019

Nonlinear Görtler Vortices and Their Secondary Instability in a Hypersonic Boundary Layer

Nonlinear development of the Görtler instability over a concave surface gives rise to a highly distorted inflectional flow field in the boundary layer that leads to both wall-normal and spanwise gradients in the flow. Such nonlinear structures are susceptible to strong, high-frequency secondary instabilities that may lead to the onset of laminar-turbulent transition. The present numerical study uses direct numerical simulations and linear secondary instability theory to investigate finite amplitude Görtler vortices and their secondary instability characteristics, respectively, in the hypersonic flow over an axisymmetric cone with a concave aft body. To complement previous studies in the literature wherein the Görtler instability was usually studied for a flat plate and initiated at some upstream location by imposing an eigenfunction as the inflow condition or by blowing and suction at the wall, the present investigation is focused on fully realizable Görtler instability that is excited by an azimuthally periodic array of surface protuberances. Furthermore, while the previous work had mostly focused on the secondary instability of Görtler vortices with cross-plane velocity contours that resembled bell-shaped structures, the present results confirm that fully developed mushroom structures also exist in the hypersonic regime when the Görtler vortex amplitude is sufficiently large. Computations further reveal that the dominant modes of secondary instability in these mushroom-shaped structures correspond to an antisymmetic (i.e., sinuous) “stem” mode that concentrates within the strong, nearly wall-normal internal shear layers surrounding the stem regions underneath the caps of the mushroom structures. Additionally, there exist a multitude of other significantly unstable secondary instability modes of both symmetric and antisymmetric types. Analogous to the secondary instability of crossflow vortices in hypersonic flows, secondary instability modes of both symmetric and antisymmetric types. Analogous to the secondary instability of crossflow vortices in hypersonic flows, secondary instability modes originating from the Mack mode instability play an important role during the nonlinear breakdown process.

Laminar turbulent transition↗
NASA NTRS1988

Simulation of fundamental atomization mechanisms in fuel sprays

Growth of instabilities on the liquid/gas interface in the initial region of fuel sprays is studied by means of numerical simulations. The simulations are based on solutions of the variable-density incompressible Navier-Stokes equations, which are obtained with a new numerical algorithm. The simulations give good agreement with analytical results for the instabilities on a liquid cylinder induced by surface tension and wind-induced instabilities. The effects of boundary layers on the wind-induced instabilities are investigated. It is found that a boundary layer reduces the growth rate for a single interface, and a comparison with inviscid theory suggests that boundary layer effects may be significantly more important than surface tension effects. The results yield a better estimate than inviscid theory for the drop sizes as reported for diesel sprays. Results for the planar jet show that boundary layer effects hasten the growth of Squire's 'symmetric' mode, which is responsible for jet disintegration. This result helps explain the rapid atomization which occurs in swirl and air-blast atomizers.

Childs, Robert, E.↗
NASA NTRS2021

A Computational Analysis of Boundary Layer Instability over the BOLT Configuration

The complex boundary layer flow over the BOLT flight configuration is known to exhibit multiple and potentially interacting instability mechanisms. This paper represents a continuation of our numerical investigation of the flow instabilities over the main test surface of the BOLT configuration by using state-of-the-art tools in multidimensional instability analysis. Specifically, the paper extends our previous computations by considering the separate effects of a nonzero angle of attack and a nonzero yaw on the modal instability characteristics of the boundary layer streaks adjacent to the minor-axis symmetry plane, specifically near both ends of the azimuthal region of a thick boundary layer in the middle, where this region rapidly changes to a thinner boundary layer on either side. At the t = 28.8767 s condition from the ascent part of the anticipated flight trajectory with a flight Mach number of M ∞ = 5.53 and unit Reynolds number of 4.25 x 10 6 /m, either type of departure from the design condition is shown to have a considerable impact on the structure of the basic state rollup within the region of interest and, hence, also on the amplification characteristics of instability waves within the resulting streaks. Yet, for a yaw angle of β = 4 degrees, the computations indicate only a slight reduction with respect to the peak N-factor of nearly 11 at the design condition of zero degrees yaw and zero degrees angle of attack. In contrast, an angle of attack equal to α = 4 degrees, the peak N-factor decreases to nearly 6 on the leeward side and increases above 16 on the windward side, making the onset of transition highly likely on the windward side. Computations also highlight the role of streak instabilities that originate as Mack mode disturbances and also demonstrate the potential pitfalls in using surface pressure sensors alone to gauge the magnitude of instability amplification.

Boundary layer transition↗