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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Realization of a gas puff imaging system on the Wendelstein 7-X stellarator

A system for studying the spatiotemporal dynamics of fluctuations in the boundary of the W7-X plasma using the “Gas-Puff Imaging” (GPI) technique has been designed, constructed, installed, and operated. This GPI system addresses a number of challenges specific to long-pulse superconducting devices, such as W7-X, including the long distance between the plasma and the vacuum vessel wall, the long distance between the plasma and diagnostic ports, the range of last closed flux surface (LCFS) locations for different magnetic configurations in W7-X, and management of heat loads on the system’s plasma-facing components. The system features a pair of “converging–diverging” nozzles for partially collimating the gas puffed locally ≈135 mm radially outboard of the plasma boundary, a pop-up turning mirror for viewing the gas puff emission from the side (which also acts as a shutter for the re-entrant vacuum window), and a high-throughput optical system that collects visible emission resulting from the interaction between the puffed gas and the plasma and directs it along a water-cooled re-entrant tube directly onto the 8 × 16 pixel detector array of the fast camera. The DEGAS 2 neutral code was used to simulate the Hα (656 nm) and HeI (587 nm) line emission expected from well-characterized gas-puffs of H2 and He and excited within typical edge plasma profiles in W7-X, thereby predicting line brightnesses used to reduce the risks associated with system sensitivity and placement of the field of view. Operation of GPI on W7-X shows excellent signal-to-noise ratios (>100 at 2 Mframes/s) over the field of view for minimally perturbing gas puffs. The GPI system provides detailed measurements of the two-dimensional (radial and poloidal) dynamics of plasma fluctuations in the W7-X edge and scrape-off layer and in and around the magnetic islands outside the LCFS that make up the island divertor configuration employed on W7-X.

Instruments & Instrumentation↗

Motion Tracking Above and Below Water Dataset

This data set includes one trial of above and under water motion tracking measurements from a Qualysis motion tracking system. The Qualisys native .qtm file can be opened by the Qualisys Track Manager software. Data from this file has been exported to a tab separated value (.tsv) file which is a generic ASCII file format that can be read by a text editor, MATLAB, Excel, etc... Also exported is a native MATLAB formatted file (.mat) which can be loaded directly into MATLAB. The trial is from a three body wave energy converter device, using the underwater system for the central nacelle data, and above water system for the fore and aft floats.

16 TIDAL AND WAVE POWER↗

Spent Crystalline Silicotitanate Storage Study

Washington River Protection Solutions is working to support initial production of immobilized low-activity waste (LAW) by feeding Hanford tank supernate from tank farms to the Hanford Waste Treatment and Immobilization Plant (WTP) LAW Facility. This goal incorporates the design of a Tank-Side Cesium Removal (TSCR) system, which filters tank waste supernate to remove suspended solids and then removes Cs by processing it through crystalline silicotitanate (CST) ion exchange media manufactured by Honeywell UOP, LLC. The 137 Cs-depleted product is intended to be sent to the WTP for vitrification. The Cs-loaded CST columns will be stored indefinitely, with a goal of eventual CST removal and treatment. Thus, the spent CST needs to be recoverable. The testing described herein looks to potential upset process conditions where CST storage may be required before various rinse steps are completed. This study evaluated upset conditions at three sequential processing steps envisioned for TSCR (feed, 0.1 M NaOH rinse, water rinse), and in-column drying with compressed air (normal end step) to assess impacts on the nature of the CST bed. Testing was conducted at the small scale (12-mL bed volume); simulated AP-105 tank waste was used as the feed. Following process disruption, the CST bed was dried in place at 70 °C. Post-dried CST bed physical properties (angle of repose, penetration depth, particle morphological changes) were measured to evaluate how CST moved and flowed. The testing is intended to provide a preliminary assessment of issues that may arise from desiccation of CST with the indicated salt solutions in place. Since these were small-scale tests, the processing conditions will not match full scale conditions exactly; however, the tests do provide insight into the impact of stopping processing at an earlier step than normal. Except for the feed that was dried in-place, all other process stop-conditions showed the CST bed flowed well after drying. At this small scale, CST beds would not present an issue for retrievability. The feed that was dried in place had solidified into a rock-hard monolith with no movement possible. Samples had to be chipped from the surface.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Mapping snow depth and volume at the alpine watershed scale from aerial imagery using Structure from Motion

Time series mapping of snow volume in the mountains at global scales and at resolutions needed for water resource management is an unsolved challenge to date. Snow depth mapping by differencing surface elevations from airborne lidar is a mature measurement approach filling the observation gap operationally in a few regions, primarily in mountain headwaters in the Western United States. The same concept for snow depth retrieval from stereo- or multi-view photogrammetry has been demonstrated, but these previous studies had limited ability to determine the uncertainties of photogrammetric snow depth at the basin scale. For example, assessments used non-coincident or discrete points for reference, masked out vegetation, or compared a subset of the fully snow-covered study domain. Here, using a unique data set with simultaneously collected airborne data, we compare snow depth mapped from multi-view Structure from Motion photogrammetry to that mapped by lidar at multiple resolutions over an entire mountain basin (300 km 2 ). After excluding reconstruction errors (negative depths), SfM had lower snow-covered area (~27%) and snow volume (~16%) compared to lidar. The reconstruction errors were primarily in areas with vegetation, shallow snow (< 1 m), and steep slopes (> 60°C). Across the overlapping snow extent, snow depths compared well to lidar with similar mean values (< 0.03 m difference) and snow volume (± 5%) for output resolutions of 3 m and 50 m, and with a normalized median absolute deviation of 0.19 m. Our results indicate that photogrammetry from aerial images can be applied in the mountains but would perform best for deeper snowpacks above tree line.

54 ENVIRONMENTAL SCIENCES↗

A multirate mass transfer model to represent the interaction of multicomponent biogeochemical processes between surface water and hyporheic zones (SWAT-MRMT-R 1.0)

Abstract. Surface water quality along river corridors can be modulated by hyporheic zones (HZs) that are ubiquitous and biogeochemically active. Watershed management practices often ignore the potentially important role of HZs as a natural reactor. To investigate the effect of hydrological exchange and biogeochemical processes on the fate of nutrients in surface water and HZs, a novel model, SWAT-MRMT-R, was developed coupling the Soil and Water Assessment Tool (SWAT) watershed model and the reaction module from a flow and reactive transport code (PFLOTRAN). SWAT-MRMT-R simulates concurrent nonlinear multicomponent biogeochemical reactions in both the channel water and its surrounding HZs, connecting the channel water and HZs through hyporheic exchanges using multirate mass transfer (MRMT) representation. Within the model, HZs are conceptualized as transient storage zones with distinguished exchange rates and residence times. The biogeochemical processes within HZs are different from those in the channel water. Hyporheic exchanges are modeled as multiple first-order mass transfers between the channel water and HZs. As a numerical example, SWAT-MRMT-R is applied to the Hanford Reach of the Columbia River, a large river in the United States, focusing on nitrate dynamics in the channel water. Major nitrate contaminants entering the Hanford Reach include those from the legacy waste, irrigation return flows (irrigation water that is not consumed by crops and runs off as point sources to the stream), and groundwater seepage resulting from irrigated agriculture. A two-step reaction sequence for denitrification and an aerobic respiration reaction is assumed to represent the biogeochemical transformations taking place within the HZs. The spatially variable hyporheic exchange rates and residence times in this example are estimated with the basin-scale Networks with EXchange and Subsurface Storage (NEXSS) model. Our simulation results show that (1), given a residence time distribution, how the exchange fluxes to HZs are approximated when using MRMT can significantly change the amount of nitrate consumption in HZs through denitrification and (2) source locations of nitrate have a different impact on surface water quality due to the spatially variable hyporheic exchanges.

58 GEOSCIENCES↗

New Beginnings: Optimising Waste and End-state at UK Nuclear Sites to Enable Environmental Permit surrender (the GRR) - 20193

The decommissioning of nuclear sites involves the management of large volumes of radioactive waste, other conventional waste, and the clean-up of land and groundwater contamination. In the UK, the disposal of radioactive waste from nuclear sites is regulated by the Environment Agency (England), Natural Resources Wales (Wales) and the Scottish Environment Protection Agency (Scotland). All three environment agencies seek to make sure that the generation and disposal of radioactive waste is optimised: ensuring impacts to people are 'as low as reasonably achievable' (ALARA). With a large proportion of UK nuclear sites embarking on decommissioning, the environment agencies have collaboratively developed new guidance: the 'Management of radioactive waste from the decommissioning of nuclear sites: Guidance on the Requirements for Release from radioactive substances regulation' (referred to as the GRR)[1]. The environment agencies worked in liaison with the Office for Nuclear Regulation (ONR), the UK nuclear safety regulator, and the UK government body responsible, the Nuclear Decommissioning Authority (NDA). Prior to finalising the guidance, a 12 month trial was completed at three of the NDA's nuclear sites, enabling the environment agencies to test their draft GRR guidance against 'real world scenarios' and the challenge of incorporating its requirements into decommissioning plans. Experience gained during the trial was incorporated into the current version of the GRR, published in July 2018. The GRR represents the 'new beginning' of this paper's title because for the first time, the UK environmental regulators have expressed in detail their requirements for surrender of environmental permits for nuclear sites. The GRR provides a framework for a UK nuclear site to plan, assess and justify its management of radioactive waste and deliver through decommissioning, an optimal, environmentally safe and sustainable end-state. This paper will describe the requirements and technical standards within the GRR, the establishment of defensible clean-up criteria and the production of a Waste Management Plan (WMP), supported by a Site-Wide Environmental Safety Case (SWESC). It will describe the experience gleaned by operators and regulators during the trial and it will highlight current work by regulators to implement the new approach proportionately. Finally, this paper will look forward and outline planned amendments to legislation in the UK affecting nuclear sites that should enable the full benefits of the GRR to be realised in the future. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Achieving the End State for the Pahute Mesa Corrective Action Units at the Nevada National Security Site - 20355

Underground nuclear testing at the Nevada National Security Site (NNSS) ended in 1992. To address the impact of radionuclide contamination from underground nuclear testing on the groundwater resources of Nevada, the U.S. Department of Energy (DOE) Environmental Management (EM) Nevada Program created the Underground Test Area (UGTA) activity to characterize the radionuclides in groundwater, understand the nature and extent of radionuclide migration, and forecast the distribution of radionuclides in groundwater for 1,000 years. The UGTA activity is regulated by the Federal Facility Agreement and Consent Order (FFACO), an agreement negotiated between the Nevada Division of Environmental Protection (NDEP), DOE, and the U.S. Department of Defense (DoD). DOE is close to achieving the end state (closure in place with monitoring and institutional control) for three of the five UGTA corrective action units (CAUs) on the NNSS. A number of challenges remain to achieve the end state of the other two CAUs, both located on Pahute Mesa. Pahute Mesa was the location of 82 underground nuclear tests, less than 10% of the total number of tests on the NNSS. Yet, Pahute Mesa contains slightly more than 60% of the total radionuclides (in curies). Based on groundwater sampling in monitoring wells, two radionuclide plumes have migrated several kilometers (km) in groundwater from selected test cavities and have crossed the boundary of the NNSS (yet remain within the boundaries of Federally controlled land). The path to achieve the end state continues to evolve as more data are collected and a better understanding of radionuclide migration in groundwater is developed. DOE has invested in drilling and sampling more than 50 characterization and monitoring groundwater wells over the past 25 years. The data indicate that the primary radionuclide of concern is tritium as it is about 89% of the total radionuclide inventory (in curies). As well, only tritium has been measured in groundwater outside of cavities at concentrations exceeding the Safe Drinking Water Act (SDWA) standard. For one of the tritium plumes that has migrated across the NNSS boundary, the average rate of migration has been measured as about 45 meters (m) per year with the rate of migration at the leading edge of the plume of about 85 meters per year. At that rate of migration, the tritium plume will decay to safe levels and not reach the publicly accessible environment at concentrations above the SDWA standard. Other radionuclides, at concentrations below the SDWA standards, will be monitored to ensure they remain at safe levels. Consequently, the end state path forward for Pahute Mesa has evolved to take full advantage of the data from the monitoring network to constrain uncertainty in model forecasts and to reduce reliance on probabilistic simulations. The focus of the end state approach relies on developing a monitoring well network that is protective of human health by increasing confidence that no radionuclide plume in the groundwater will migrate undetected to the accessible environment, located about 22 km from the nearest up-gradient underground nuclear test. Using the measured data to remove uncertainty, the evaluation of radionuclide migration from Pahute Mesa is directed toward meeting the goals of the end state. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A critical review of operational strategies for the management of harmful algal blooms (HABs) in inland reservoirs

Occurrences of freshwater harmful algal blooms (HABs) are increasing on a global scale, largely in part due to increased nutrient input and changing climate patterns. While reservoir management strategies that can influence phytoplankton are known, there is no published guideline or protocol for the management of harmful algal blooms. There is a need to establish what factors are the predominant drivers of blooms, and how common reservoir management strategies specifically influence each factor. The following literature review seeks to establish the benefits and drawbacks of operational management strategies that currently exist. The main focus is altering hydrodynamic conditions (hypolimnetic withdrawals, surface flushing, pulsed inflow, artificial mixing), in order to induce environmental changes within the reservoir itself. Since excess nutrients are one of the biggest contributors to worsening bloom conditions, internal nutrient dynamics and reduction are also discussed. Additionally, we review the predominant seasonal factors (stratification, light, temperature, and wind) that affect likelihood of bloom occurrence and duration. In conclusion, the ultimate objective of this review is to increase understanding of the relationships between HAB drivers and reservoir operations in order to inform the development of data, modeling, and management strategies for the prevention and mitigation of blooms.

54 ENVIRONMENTAL SCIENCES↗

Bayesian Poroelastic Aquifer Characterization From InSAR Surface Deformation Data. Part I: Maximum A Posteriori Estimate

Characterizing the properties of groundwater aquifers is essential for predicting aquifer response and managing groundwater resources. In this work, we develop a high-dimensional scalable Bayesian inversion framework governed by a three-dimensional quasi-static linear poroelastic model to characterize lateral permeability variations in groundwater aquifers. In this work, we determine the maximum a posteriori (MAP) point of the posterior permeability distribution from centimeter-level surface deformation measurements obtained from Interferometric Synthetic Aperture Radar (InSAR). The scalability of our method to high parameter dimension is achieved through the use of adjoint-based derivatives, inexact Newton methods to determine the MAP point, and a Mat´ern class sparse prior precision operator. Together, these guarantee that the MAP point is found at a cost, measured in number of forward/adjoint poroelasticity solves, that is independent of the parameter dimension. We apply our methodology to a test case for a municipal well in Mesquite, Nevada, in which InSAR and GPS surface deformation data are available. We solve problems with up to 320,824 state variable degrees of freedom (DOFs) and 16,896 parameter DOFs. A consistent treatment of noise level is employed so that the aquifer characterization result does not depend on the pixel spacing of surface deformation data. Our results show that the use of InSAR data significantly improves characterization of lateral aquifer heterogeneity, and the InSAR-based aquifer characterization recovers complex lateral displacement trends observed by independent daily GPS measurements.

54 ENVIRONMENTAL SCIENCES↗

Developing a Decision Support System for Regional Agricultural Nonpoint Salinity Pollution Management: Application to the San Joaquin River, California

Environmental problems and production losses associated with irrigated agriculture, such as salinity, degradation of receiving waters, such as rivers, and deep percolation of saline water to aquifers, highlight water-quality concerns that require a paradigm shift in resource-management policy. New tools are needed to assist environmental managers in developing sustainable solutions to these problems, given the nonpoint source nature of salt loads to surface water and groundwater from irrigated agriculture. Equity issues arise in distributing responsibility and costs to the generators of this source of pollution. This paper describes an alternative approach to salt regulation and control using the concept of “Real-Time Water Quality management”. The approach relies on a continually updateable WARMF (Watershed Analysis Risk Management Framework) forecasting model to provide daily estimates of salt load assimilative capacity in the San Joaquin River and assessments of compliance with salinity concentration objectives at key monitoring sites on the river. The results of the study showed that the policy combination of well-crafted river salinity objectives by the regulator and the application of an easy-to use and maintain decision support tool by stakeholders have succeeded in minimizing water quality (salinity) exceedances over a 20-year study period.

real-time management economics↗

Nuclear Decontamination Evolution and Revolution - 20349

Decontamination, one of the oldest practices in the nuclear industry, is about to change. While no single approach to decontamination is appropriate in all situations, decontamination of highly contaminated surfaces is historically viewed as difficult and/or marginally effective and fixatives and strippable coatings are often called on to manage time sensitive contamination control issues. The deferral of proper decontamination can lead to accumulated concentrations of radioactive material increasing the risk of cross-contamination of workers and equipment while also increasing radiation levels, which further discourages decontamination. The results of the subject testing demonstrate that superior decontamination factors are readily achievable and the ALARA benefit of decontamination is viable through advanced decontamination technologies in conjunction with innovative application techniques. The collateral benefits will save countless radiological man-hours and personnel radiological exposure. The appropriate use of radiological decontamination techniques can prevent or limit the adverse effects of highly radioactive contamination in the work area. High levels of radiological contamination are typically associated with some of the most physically demanding work in the nuclear industry. Additionally, working in highly contaminated environments increases the risk of exposure to elevated levels of airborne radioactivity and radiation from the source term of the contamination, particularly in hard to reach areas or complex equipment. Veolia's Alaron Nuclear Services (Alaron), a fully integrated nuclear facility, has provided the nuclear industry waste treatment, consolidation, repackaging, and broad decontamination services for almost 35 years. In looking at solutions for its customers, as well as for their own facility, Alaron has recently collaborated with Environmental Alternatives, Inc. (EAI), which has provided innovative solutions addressing difficult nuclear decontamination and industrial cleaning challenges since 1989. This broad range of experience along with the products to support the work created an ideal partner for Alaron's needs at their facility. The benefits of collaboration were immediately recognizable to the management of both companies although the decontamination challenge was significant. Due to the nature of the services offered, contamination at the Alaron facility is routine. The recent decontamination experience at Alaron utilized an innovative surfactant process that quickly produces remarkably higher decontamination factors for both removable surface contamination and fixed contamination. Considering the time to decontaminate areas historically designated for high radiological hazard work, the results from this decontamination effort not only reduced contamination levels but also significantly lowered exposure rates in the working environment. The relative ease with which the surfactant is applied, combined with extraordinary decontamination test results, indicates the potential to alter current radiological work processes in a way that improves worker comfort, and removes radiological engineering barriers, allowing Alaron to complete complex radiological tasks more efficiently and effectively. In a series of two simple applications of the decontamination agent to contaminated high bay vertical surfaces, as well as a variety of horizontal and vertical surfaces with variable porousness and surface sealants, there was an overall reduction in removable contamination of approximately 73% with a reduction in area dose of approximately 93%. The results indicate additional reduction in fixed contamination with application of the surfactant. These values are much higher than experienced with more traditional decontamination agents. In conjunction with demonstrating EAI's surfactant on room surfaces, additional studies were conducted on complex geometry equipment including waste processing equipment, tools, and heavily contaminated parts normally handled from Alaron's customers. Evaluations were made with straight application of EAI's surfactant as well as adding additional techniques to the treatment which afforded revolutionary improvements in the levels of contamination removed. Successful decontamination with up to 95% reduction in removable contamination with just one application were demonstrated in several of the trials. This paper outlines the planned approach to use this technology, the variety of surfaces and equipment treated, and the results of the decontamination efforts. Furthermore, this paper discusses options for pretreatment of certain heavily contaminated equipment prior to employees handling and/or working with the equipment. The potential for dose saving and the reduced risk of cross-contamination with the added benefit of lower PPE requirements, produces an enormous potential for cost and time savings. Attendees will benefit from Alaron's experiences and more fully understand the capabilities of EAI's decontamination process. With the variety of contamination agents, forms and surfaces on which the technology was demonstrated, the information will be valuable to a broad cross-section of industry users. The significance of this report demonstrates superior decontamination factors are achievable utilizing the next evolution of decontamination technology and that the ALARA benefits of decontamination are available through advanced and modern decontamination efforts. The collateral benefits will save countless radiological man-hours and valuable personnel radiological exposure. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Science Plan for the Deployment of the Third ARM Mobile Facility to the Southeastern United States at the Bankhead National Forest, Alabama (AMF3 BNF)

In 2018, the U.S. Department of Energy (DOE) held a workshop for the Atmospheric Radiation Measurement (ARM) (Mather and Voyles 2013) user facility to discuss critical climate challenges and locations where key ARM Mobile Facility (AMF) observational assets could impact Earth system modeling (ESM). As an outcome, the southeast United States (SE U.S.) was identified as a high-priority region to target climate-process studies that promote a deeper understanding of the climate system and bolster ARM interactions with the community to drive ESM advancement. The DOE ARM user facility is a globally recognized leader in deploying and operating strategically located observation sites around the world for studying the properties of aerosols and clouds and their interaction with radiation, precipitation, and the Earth’s surface. In partnering with the DOE Atmospheric System Research (ASR) program, ARM solicited a multi-agency Site Science Team approach to provide input and close interaction with ARM management towards a successful SE U.S. deployment of the ARM third Mobile Facility (AMF3) (Miller et al. 2016). These efforts included identifying key locations, science drivers and instruments, and measurement strategies to address the wider climate-process needs and ESM improvement. Community input served a vital role in establishing, refining, and informing the relevant drivers and decisions regarding this AMF3 deployment. The team has identified Northern Alabama (N. AL) as regionally representative to unlock the key opportunities that will improve our understanding and model representation of aerosol, cloud, and land surface processes and their couplings in the SE U.S. A defining aspect of the AMF3 deployment is its commitment to long-term (anticipated five-year) observations to mitigate potential seasonal-to-annual variability that often limits appropriate attribution of phenomena to local or larger-scale processes. The proposed location may leverage nearby surface networks and multi-agency and partner assets to enrich this multi-year deployment. One motivation is to understand the role of spatiotemporal variability (thermodynamic, land-surface) across aspects of the climate system, with our AMF3 team anticipating future demands on characterizing the relationships between local-to-regional cloud development and surface processes across a diverse patchwork of natural, managed, and urban landscapes as found throughout the N. AL regions. The main site targets an intact, representative, forested region – the Bankhead National Forest (BNF) – underscoring further team commitment to regionally important land atmosphere two-way interactive studies “from the canopy to the clouds”, with enhanced tower instrumentation augmenting traditional ARM capabilities adjacent to this site. Multiple supplemental sites will also be distributed across this region, prioritizing added needs for biodiversity. Anticipated high-priority cloud science themes will target N. AL as a regional SE U.S. hotbed for high-impact weather, convective cloud onset, and shallow to-deep cloud transitioning. Anticipated aerosol drivers will focus on chemical processes that control the evolution of organic aerosol, the seasonality and spatial distribution of water vapor and particle-phase water, and its role on aerosol optical properties. Anticipated land atmosphere drivers consider the two-way feedbacks between surface influence on aerosols, clouds, and precipitation properties and the associated radiative impacts on plant physiology and canopy-scale fluxes. Emphasis will include the study of the impact of surface processes on aerosols via precursor emission, and on clouds via moisture flux and thermal development.

Doppler lidar, aerosols, convection↗

Science Plan for the Deployment of the Third ARM Mobile Facility to the Southeastern United States at the Bankhead National Forest, Alabama (AMF3 BNF)

In 2018, the U.S. Department of Energy (DOE) held a workshop for the Atmospheric Radiation Measurement (ARM) (Mather and Voyles 2013) user facility to discuss critical climate challenges and locations where key ARM Mobile Facility (AMF) observational assets could impact Earth system modeling (ESM). As an outcome, the southeast United States (SE U.S.) was identified as a high-priority region to target climate-process studies that promote a deeper understanding of the climate system and bolster ARM interactions with the community to drive ESM advancement. The DOE ARM user facility is a globally recognized leader in deploying and operating strategically located observation sites around the world for studying the properties of aerosols and clouds and their interaction with radiation, precipitation, and the Earth’s surface. In partnering with the DOE Atmospheric System Research (ASR) program, ARM solicited a multi-agency Site Science Team approach to provide input and close interaction with ARM management towards a successful SE U.S. deployment of the ARM third Mobile Facility (AMF3) (Miller et al. 2016). These efforts included identifying key locations, science drivers and instruments, and measurement strategies to address the wider climate-process needs and ESM improvement. Community input served a vital role in establishing, refining, and informing the relevant drivers and decisions regarding this AMF3 deployment. The team has identified Northern Alabama (N. AL) as regionally representative to unlock the key opportunities that will improve our understanding and model representation of aerosol, cloud, and land-surface processes and their couplings in the SE U.S. A defining aspect of the AMF3 deployment is its commitment to long-term (anticipated five-year) observations to mitigate potential seasonal-to-annual variability that often limits appropriate attribution of phenomena to local or larger-scale processes. The proposed location may leverage nearby surface networks and multi-agency and partner assets to enrich this multi-year deployment. One motivation is to understand the role of spatiotemporal variability (thermodynamic, land-surface) across aspects of the climate system, with our AMF3 team anticipating future demands on characterizing the relationships between local-to-regional cloud development and surface processes across a diverse patchwork of natural, managed, and urban landscapes as found throughout the N. AL regions. The main site targets an intact, representative, forested region – the Bankhead National Forest (BNF) – underscoring further team commitment to regionally important land-atmosphere two-way interactive studies “from the canopy to the clouds”, with enhanced tower instrumentation augmenting traditional ARM capabilities adjacent to this site. Multiple supplemental sites will also be distributed across this region, prioritizing added needs for biodiversity. Anticipated high-priority cloud science themes will target N. AL as a regional SE U.S. hotbed for high-impact weather, convective cloud onset, and shallow-to-deep cloud transitioning. Anticipated aerosol drivers will focus on chemical processes that control the evolution of organic aerosol, the seasonality and spatial distribution of water vapor and particle-phase water, and its role on aerosol optical properties. Anticipated land-atmosphere drivers consider the two-way feedbacks between surface influence on aerosols, clouds, and precipitation properties and the associated radiative impacts on plant physiology and canopy-scale fluxes. Emphasis will include the study of the impact of surface processes on aerosols via precursor emission, and on clouds via moisture flux and thermal development.

54 ENVIRONMENTAL SCIENCES↗

Sustainable lead management in halide perovskite solar cells

Despite the rapid development of perovskite solar cells (PSCs) toward commercialization, the toxic lead (Pb) ions in PSCs pose a potential threat to the environment, health and safety. Managing Pb via recycling represents a promising approach to mitigating its toxicity. However, managing Pb from commonly used organic solvents has been challenging due to the lack of suitable Pb adsorbents. Here, we report a new adsorbent for both separation and recovery of Pb from PSC pollutants. The synthesized iron-incorporated hydroxyapatite possesses a strongly negatively charged surface that improves electrostatic interaction through surface-charge delocalization, thus leading to enhanced Pb adsorption. Finally, we demonstrate the feasibility of a complete Pb management process, including the purification of Pb-containing non-aqueous solvents below 15 parts per 10 9 , a level compliant with the standards of the US Environmental Protection Agency, as well as recycling of 99.97% of Pb ions by forming lead iodide.

14 SOLAR ENERGY↗

Practices Implemented by DOE Better Plants Program Partners to Mitigate COVID-19

Screening for symptoms, maintaining physical distance, sanitizing surfaces, wearing appropriate face masks, maintaining good personal hygiene, and reconfiguring HVAC air management are the major activities that the DOE BP partners have implemented to mitigate COVID-19. This article shares some specific practices that BP program partners have implemented for these activities. The energy impact of some practices has also been discussed and some rules of thumb have been provided to estimate energy penalties.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Autonomous light management system for a window and method of controlling light transmission

An autonomous light management system for a window includes an electrochromic film stack comprising an electrochromic layer on a first transparent electrode, an ion storage layer on a second transparent electrode, and an electrolyte sandwiched between the ion storage and electrochromic layers. The electrochromic film stack exhibits a transmissive state or an absorptive state depending on charging or discharging of the electrochromic layer. The light management system further comprises an array of power units disposed on a front surface of the electrochromic film stack, where each power unit comprises at least one solar microcell. Collectively, the solar microcells cover an area no greater than about 6% of a total area of the front surface. The array of power units is configured to control the charging and discharging of the electrochromic layer, thereby manipulating light transmission through the electrochromic film stack.

Yoder, Mikayla A.↗

Assessing the Potential for Inadvertent Human Intrusion at the Area 3 and Area 5 Radioactive Waste Management Sites on the Nevada National Security Site, Nye County, Nevada

This paper recommends an approach to inadvertent human intrusion (IHI) at the Area 3 and Area 5 Radioactive Waste Management Sites (RWMSs) on the Nevada National Security Site (NNSS). IHI analysis uses the consequences of an individual inadvertently contacting buried waste to set waste concentration limits for near-surface disposal of low-level radioactive waste (LLW). Regulatory agencies are increasingly applying risk-informed decision-making to LLW waste management (NRC 2006). Risk-informed decision-making combines scientific risk assessment with stakeholder values and perceptions to determine a level of acceptable risk. Risk considers not only the consequences of an event, but also its probability of occurring.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

X-Band Radar and Surface-Based Observations of Cold-Season Precipitation in Western Colorado’s Complex Terrain

Abstract Hydrologic processes associated with intermountain cold-season precipitation in the Upper Colorado River basin have important impacts on avalanche forecasting and water resource management. However, traditional weather radar networks struggle with observations in this complex terrain. Data collected during the Study of Precipitation, the Lower Atmosphere, and the Surface for Hydrometeorology (SPLASH) and its sister campaign, Surface Atmosphere Integrated Field Laboratory (SAIL) in the East River watershed of western Colorado, are used to examine a multistorm period from 23 December 2021 to 1 January 2022 that contributed 35% of the total winter precipitation in this watershed. Dual-polarization X-band radar and disdrometer measurements show ∼30-mm differences in precipitation amount at two sites in proximity over four distinct storm events within the period. Wind patterns, synoptic forcings, microphysical characteristics of precipitation, and surface meteorology are analyzed to explain the observed spatial variability of cold-season precipitation in complex mountainous terrain. Analysis shows that differences over time within this event are mainly accounted for by synoptic forcings, such as frontal passages; differences between sites are accounted for by the impact of variations in local wind patterns on precipitation microphysics. Patterns of surface precipitation intensity are compared and found to be correlated with X-band radar signatures; a relationship between a strong dendritic growth stage and intense low-density surface precipitation is reinforced by this study. This relationship demonstrates the importance of particle growth mechanisms on surface snowfall patterns in high-altitude complex terrain, underscoring the importance of realistic microphysical parameterizations. Significance Statement The amount and density of snowpack from western Colorado winter storms have significant impacts on water resources in the Upper Colorado River basin. Snowpack characteristics are affected by small-scale differences in how snow forms in the atmosphere. These differences are hard to study in the complex terrain of the Rockies, but data from the SPLASH and SAIL field campaigns allows us to investigate how snow crystal formation and mountain-driven wind patterns affect snow near the surface. Our study finds that snow crystal growth varies over small space and time scales and is likely controlled by the terrain beneath a given location and resultant local wind patterns. These results imply that predicting snowpack in the Rockies requires properly representing local wind patterns and crystal growth processes in models.

Heflin, Stella↗