Proton and Electron Effects in Thermal Control Materials Final Report
Radiation effects of electrons and protons on reflectance and degradation properties of specular and diffuse thermal control materials
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Radiation effects of electrons and protons on reflectance and degradation properties of specular and diffuse thermal control materials
Thermophysical property measurements were made under transient heating conditions on several materials being considered for use in SCOUT rocket motors. The materials included were ATJ graphite, MX 2600 silica phenolic, FM 5272 cellulose phenolic, and two carbon-carbon composites: CARBITEX 700 and RPP-4. The ATJ was included as a reference or base line material to check performance of the transient tests as it was not expected to be sensitive to heating rate. Measurements included in the program were thermal conductivity, strength, compressive stress-strain (carbon-carbon only), thermal expansion and the effective thermal expansion under partially restrained conditions. Development of this latter measurement was a major part of the program. It consisted of partially restraining the expansion of a specimen as it was heated, measuring the load and strain which occurred (together with a simultaneous modulus determination by superimposing a small cyclic load) and using these quantities to calculate what the effective thermal expansion would have to be to produce the observed stress and deformation. For materials which are sensitive to heating rate, such as reinforced phenolics, it was believed that this would provide a more realistic determination of the thermal expansion as it more nearly simulates the conditions experienced in end use.
A systematic study of the effects of thermal conduction and radiation (Cox-Tucker type) on the dynamic response of a coronal loop is presented. The study is based on a one-fluid hydrodynamic description of a magnetic flux loop subject to a sudden localized heating, simulating the flare energy release. Numerical results are obtained for the heating of a full loop at one end and symmetrical heating at both ends. The results show that: (1) the basic response is the propagation of a hydrodynamic shock; (2) thermal conduction (Coulomb type) has significant effects; and radiation has only minor influence unless the density exceeds 10 to the 11th per cu cm. It is noted that the uniform flaring of a loop is associated with heating of long duration. Short pulse-like heating results in the nonuniform brightening and propagation of luminous fronts similar to that sometimes observed in flare loops.
This report documents sodium chemistry characterization and the initiation of forced‑convection sodium exposure experiments for two structural materials for sodium‑cooled fast reactors (SFRs): Alloy 709 (solution‑annealed and with an additional 775 °C/10 h precipitation treatment) and laser powder bed fusion (LPBF) 316H stainless steel tensile specimens printed with an as‑built surface condition. The sodium exposure experiment was conducted in a forced‑convection sodium loop with two vessels operated at 550 °C and 600 °C, and a cold trap maintained at <130 °C. Carbon activity in sodium was quantified using a nickel‑foil equilibration method. Initial post‑exposure evaluation after ~1,000 h indicates negligible thickness change for Alloy 709 and a small but measurable mass decrease. To isolate thermal effects from sodium effects, parallel thermal‑aging experiments were performed on Alloy 709 at 550 °C and 600 °C. Baseline tensile tests at room temperature, 550 °C, and 600 °C show expected reduction in strength with increasing temperature and serration tensile curves at elevated temperatures, consistent with dynamic strain aging. After 3,000 h thermal aging, Alloy 709 exhibits modest strengthening and reduced ductility at 550 °C. Together, these results establish the loop chemistry conditions and provide the initial corrosion and mechanical property results for ongoing long‑duration sodium exposure of Alloy 709 and LPBF 316H stainless steel.
Thermal and air environment effects on mechanical properties of graphite/polyimide laminates
The purpose of the present paper is to describe an application of the IITRI compression test fixture at elevated temperature (589K) was described as well as the present compressive moduli and ultimate strains of HTS/PMR-15 graphite/polyimide material. Considerable care was taken in specimen fabrication to minimize back-to-back strain variations due to specimen bending. The effects of specimen width and temperature were studied for various laminate orientations. The IITRI specimen was analyzed using three dimensional finite elements to determine the magnitude and location of stress concentrations to assess their potential effects on measured moduli and ultimate strains. Stress concentrations are of concern since end constraints, free-edge effects, and thermal effects add to the three dimensional nature of stresses in a specimen.
The design of metal-vapor vacuum-arc switches (MVSs) for electromagnetic launchers is discussed, and preliminary results are presented for an experimental MVS. The general principles of triggered-vacuum-gap and vacuum-interrupter MVSs are reviewed, and the requirements of electromagnetic launchers are analyzed. High-current design problems such as electrode erosion, current sharing, magnetic effects, and thermal effects are examined. The experimental MVS employs stainless-steel flanges, a glass vacuum vessel, an adjustable electrode gap, autonomous internal magnetic-field coils, and a tungsten-pin trigger assembly. Some results from tests without magnetic augmentation are presented graphically.
Results are presented on computations of three-point upper and lower bounds on the effective thermal expansion coefficient, the effective constant-pressure specific heat, and the effective constant-volume specific heat of statistically isotropic suspensions of mutually impenetrable spheres. The effect of polydispersivity in sphere size on the thermoelastic properties is investigated by considering the cases of both equisized and multisized spheres. For reasons of mathematical analogy, the results obtained for the effective thermal expansion coefficient translate immediately into equivalent results for the hygroscopic expansion coefficient.
Some illustrative results obtained from work accomplished under the aerothermoelasticity work breakdown structure (WBS) element of the National Aerospace Plane (NASP) Technology Maturation Program (TMP) are presented and discussed. The objectives of the aerothermoelasticity element were to develop analytical methods applicable to aerospace plane type configurations, to conduct analytical studies to identify potential problems, to evaluate potential solutions to problems, and to provide an experimental data base to verify codes and analytical trends. Work accomplished in the three areas of experimental data base, unsteady aerodynamics, and integrated analysis methodology are described. Some of the specific topics discussed are: (1) transonic wind tunnel aeroelastic model tests of cantilever delta wing models, of an all-moveable delta-wing model, and of aileron buzz models; (2) unsteady aerodynamic theory correlation with experiment and theory improvements; and (3) integrated analysis methodology results for thermal effects on vibration, for thermal effects on flutter, and for improving aeroelastic performance by using active controls.
An electrochemical Ni-H2 battery model has been expanded to include thermal effects. A thermal energy conservation equation was derived from first principles. An electrochemical and thermal coupled model was created by the addition of this equation to an existing multiphase, electrochemical model. Charging at various rates was investigated and the results validated against experimental data. Reaction currents, pressure changes, temperature profiles, and concentration variations within the cell are predicted numerically and compared with available data and theory.
The production of heavy metal fluoride (HMF) glasses, and the effects of thermal treatments on the HMF glasses are investigated. ZrF4, BaF2, AlF3, LaF3, and NaF were utilized in the synthesis of zirconium-barium-lanthanum-aluminum-sodium fluoride glass. The purity of these starting materials, in particular ZrF4, is evaluated using XRD analysis. The data reveal that low temperature heating of ZrF4-H2O is effective in removing the water of hydration, but causes the production of ZrF4 and oxyfluorides; however, dehydration followed by sublimation results in the production of monoclinic ZrFe without water or oxyfluoride contaminants.
We present a study of the kinetic properties of the electron velocity distribution functions within magnetic clouds, since they are the dominant thermal component. The study is based on high time resolution data from the GSFC WIND/SWE electron spectrometer and the Berkeley 3DP electron plasma instruments. Recent studies on magnetic clouds have shown observational evidence of anti-correlation between the total electron density and electron temperature, which suggest a polytrope law P(sub e) = alpha(Nu(sub e) (sup gamma)) for electrons with the constant gamma approximates 0.5 < 1. This anti-correlation and small polytropic gamma-values is interpreted in the context of the presence of highly non-Maxwellian electron distributions (i.e. non-thermal) within magnetic clouds. These works suggested that the non-thermal electrons can contribute as much as 50% of the total electron pressure within magnetic clouds. We have revisited some of the magnetic cloud events previously studied and attempted to quantify the nature of the non-thermal electrons by modeling the electron velocity distribution function using a kappa distribution function to characterize the kinetic non-thermal effects. If non-thermal tail effects are the source for the anti-correlation between the moment electron temperature and density and if the kappa distribution is a reasonable representative model of non-thermal effects, then the electron velocity distribution within magnetic clouds should show indication for small K-values when gamma < 1.
Time dependence of laser rod focal length, measuring thermal lensing effects
The effect of thermally induced porosity on the mechanical properties of an as-hot-isostatically pressed and heat-treated pressing made from low carbon Astroloy is examined. Tensile, stress-rupture, creep, and low cycle fatigue tests were performed and the results were compared with industrial acceptance criteria. It is shown that the porous pressing has a porosity gradient from the rim to the bore with the bore having 1-1/2% greater porosity. Mechanical properties of the test ring below acceptance level are tensile reduction in area at room temperature and 538 C and time for 0.1% creep at 704 C. It is also found that the strength, ductility, and rupture life of the rim are slightly inferior to those of the rim of the sound pressings, while those of the bore are generally below the acceptable level. At strain ranges typical of commercial aircraft engines, the low cycle fatigue life of the rim of the porous pressings is slightly lower than that of the sound pressings.
The effect of thermal convection on the shape of solid-liquid interface was investigated in experiments conducted in a transparent Bridgman-type directional solidification furnace. The relationship was numerically modeled using a standard 2D finite-difference approach, with the solid-liquid deformable interface approximated by a blocking-off technique. The directional solidification furnace was used with pure succinonitrile (which is also transparent) contained in a long square ampoule made of borosilicate glass. With the furnace in the vertical configuration, a flat interface was observed, in agreement with the model. On the other hand, a highly distorted interface was obtained in the horizontal configuration; the numerical results showed a strong recirculating cell in front of the interface due to natural thermal convection. The results indicate that thermal convection is responsible for the interface distortion.
Aluminum-Lithium (Al-Li) alloys offer significant performance benefits for aerospace structural applications due to their higher specific properties compared with conventional Al alloys. For example, the application of Al-Li alloy 2195 to the space shuffle external cryogenic fuel tank resulted in weight savings of over 7,000 lb, enabling successful deployment of International Space Station components. The composition and heat treatment of 2195 were optimized specifically for strength-toughness considerations for an expendable cryogenic tank. Time-dependent properties related to reliability, such as thermal stability, fatigue, and corrosion, will be of significant interest when materials are evaluated for a reusable cryotank structure. Literature surveys have indicated that there is limited thermal exposure data on Al-Li alloys. The effort reported here was designed to establish the effects of thermal exposure on the mechanical properties and microstructure of Al-Li alloys C458, L277, and 2195 in plate gages. Tensile, fracture toughness, and corrosion resistance were evaluated for both parent metal and friction stir welds (FSW) after exposure to temperatures as high as 300 F for up to 1000 hrs. Microstructural changes were evaluated with thermal exposure in order to correlate with the observed data trends. The ambient temperature parent metal data showed an increase in strength and reduction in elongation after exposure at lower temperatures. Strength reached a peak with intermediate temperature exposure followed by a decrease at highest exposure temperature. Friction stir welds of all alloys showed a drop in elongation with increased length of exposure. Understanding the effect of thermal exposure on the properties and microstructure of Al-Li alloys must be considered in defining service limiting temperatures and exposure times for a reusable cryotank structure.
An analysis was performed to predict the thermal distortion of the solar dynamic concentrator for Space Station Freedom in low earth orbit and to evaluate the effects of that thermal distortion on concentrator on-orbit performance. The analysis required substructural finite element modeling of critical concentrator structural subsystems, structural finite element modeling of the concentrator, mapping of thermal loading onto the structural finite element model, and the creation of specialized postprocessors to assist in interpreting results. Concentrator temperature distributions and thermally induced displacements and slope errors and the resulting receiver flux distribution profiles are discussed. Results determined for a typical orbit indicate that concentrator facet rotations are less than 0.2 mrad and that the change in facet radius due to thermal flattening is less than 5 percent. The predicted power loss due to thermal distortion effects is less than 0.3 percent. As a consequence the thermal distortions of the solar dynamic concentrator in low earth orbit will have a negligible effect on the flux distribution profiles within the receiver.
Grey gas approximation of thermal radiation effect on Venus atmospheric model circulation