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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Control and Optimization of Energy Storage System in Power Distribution System

The widespread adoption of electric vehicles (EVs) and transportation electrification is encumbered by two chief barriers: i) the limited driving range of EVs in the market today and ii) inadequate fast-charging infrastructure for long-distance trips. Extreme fast charging (XFC) technology can recharge EVs in less than 10 minutes for 200 miles range. Firstly, a novel robust optimization-based mixed integer linear programming model is proposed to size a battery energy storage system (BESS) and PV system in an XFCS. In this part, it is assumed that the sizing and location of the XFCS are known. Secondly, the aforesaid assumption is relaxed, and a strategic multi-period coordinated planning model is proposed to optimally site and size BESS-assisted charging stations in a highway transportation network and PV systems in a power distribution network by considering the coupling between both networks. Optimal operation and control of BESS-assisted EV charging stations are vital to alleviate the adverse impact of extreme fast charging of EVs on the host power network. A joint solution is proposed to mitigate the steady state and transient impact of extremefast charging of EVs and ensure grid-friendly integration of XFCSs with the host grid. Lastly, to make the operation of the XFCS cost-effective, a multi-layered energy management framework is proposed for the XFCS by considering forecast uncertainties, monthly demand charges reduction, and BESS degradation.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Quantifying the Sensitive Parameters of the New Energy Vehicles in China

To achieve carbon neutrality by 2060, the Chinese government has put effort into decarbonizing the transportation sector. Consequently, China elaborated a new energy vehicle strategy promoting the production of electric vehicles and expanding into hydrogen (H2) vehicle technologies including fuel cell electric vehicles and H2 internal combustion engine vehicles. The Transportation Energy Analysis Model (TEAM) projects the market penetration as well as energy demand and greenhouse gas emissions in China up to 2050. By integrating the Monte Carlo simulation, this study tests the robustness of TEAM and investigates the key parameters that will shape passenger vehicle sales and emissions in the future. The results show that fuel cell cost, H2 price, and battery cost are the most sensitive parameters for H2 vehicle technologies.

Saafi, Mohamed Ali↗

Fast and Scalable Synthesis of LiNi 0.5 Mn 1.5 O 4 Cathode by Sol–Gel-Assisted Microwave Sintering

High-voltage spinel LiNi 0.5 Mn 1.5 O 4 (LNMO) is a promising cathode material for high-energy-density and high-power-density lithium-ion batteries (LIBs). The high cost of the currently available LIBs needs to be addressed urgently for wide application in the transport sector (electric vehicles, buses) and large-scale energy storage systems (ESS). Of significance, herein, novel fast and scalable microwave-assisted synthesis of LNMO is reported, which leads to a production cost cut. X-ray diffraction (XRD) analysis confirms the formation of the desired phase with high crystallinity. Field emission scanning (FE-SEM) and transmission electron microscopy (TEM) analyses indicate that the synthesized phase is of nanometric size (50–150 nm) due to an extremely short sintering time (20 min). The material synthesized at 750 °C shows a higher initial discharge capacity (130 mA h g -1 ) than that synthesized at 650 °C (115 mA h g -1 ). The materials heat treated at higher temperatures show better electrochemical performance in terms of initial capacity, rate capability, and improved cycling. The improved electrochemical performance of LNMO at 750 °C is attributed to the formation of a stable crystal structure, low charge transfer resistance at the electrode/electrolyte interface, high electrical conductivity due to the presence of a disorder structure, and improved ionic diffusivity.

25 ENERGY STORAGE↗

Surface Modification of Nickel-Rich Cathode Materials by Ionically Conductive Materials at Room Temperature

Nickel-rich cathode materials (LiNi x Mn y Co 1-x-y O 2 , NMC) are promising to push the limits of lithium-ion batteries to higher energy density. This approach is favored in practical applications including electric vehicles and aviation transportation. However, the instability of the NMC at charged state results in safety concerns and poor cycling stability. Surface coating is a practical and effective strategy to address this. Cubic Li7La3Zr2O12 (LLZO) is an ideal coating material regarding the low electron transfer rate and high Li+ conductivity. Thus, a LLZO coating layer can suppress the parasitic reactions in the electrode/electrolyte interface without deteriorating the lithium migration. However, high-temperature calcination seems to inevitably create the chemical couplings between NMC and LLZO, leading to the interdiffusion and degradation of NMC and LLZO crystal structures. This work presents a simple mechanochemical method to effectively coat LLZO on the NMC particle surface. Furthermore, the coated cathode demonstrates superior electrochemical performance compared with the pristine NMC cathode.

25 ENERGY STORAGE↗

Bilayer hybrid graphite anodes via freeze tape casting for extreme fast charging applications

Extreme fast charging (XFC) of lithium-ion batteries is critical for continuous market adoption of electric vehicles. However, mass transport limitations and sluggish kinetics lead to lithium plating in graphite anodes under fast charging conditions. One approach to address the mass transport limitation in graphite is to design low-tortuosity electrodes to enhance ionic transport. In this study, a bilayer hybrid structured electrode with directionally aligned channels was developed via freeze tape casting, which enables faster lithium ion diffusion through the graphite electrode. A scalable roll-to-roll process was designed in which slurry can be cast on any substrates for simple processing. Additionally, electrochemical impedance spectroscopy measurements indicated that the bilayer hybrid coating had both low tortuosity and short diffusion pathways, enabling XFC charging. Rate testing for the bilayer hybrid electrode indicated superior performance over the other coatings, exhibiting a ~20% improvement in the charge capacity compared with the conventional coating at 5C and 10 min total charging time. The bilayer hybrid electrode also demonstrated a 10% improvement in capacity retention compared with the conventional electrode after 1000 cycles at XFC conditions. This study demonstrates freeze tape casting as a scalable way to fabricate low-tortuosity electrodes for XFC applications.

25 ENERGY STORAGE↗

Extreme fast charge aging: Correlation between electrode scale and heterogeneous degradation in Ni-rich layered cathodes

Extreme fast charging (XFC) is a key requirement for the adoption of battery-based electric vehicles by the transportation sector. However, XFC has been shown to accelerate degradation, causing the capacity, life, and safety of batteries to deteriorate. There are no systematic studies in the open literature regarding aging modes in Ni-rich Li y Ni 0.a Mn 0.b Co 0.c O 2 (NMCabc) cathodes caused by fast charging. Herein, we report the effects of cathode composition and electrode loading in pouch cells containing NMC532, 622 and 811 paired with graphite and cycled under XFC conditions. The relative anisotropic volume change in the unit cell increases with Ni content in low-loading cells, while it levels up for all three NMC cathodes in high-loading cells because of substantial Li plating. The amounts of lithium plating and heterogeneity on the anode, determined by crystallographic phase quantification, were found to be correlated with electrode loading and cathode heterogeneity. The concentrations of the transition metals deposited on the anodes depend on NMCabc composition in a complex way. More particle cracking and surface degradation was found in NMC811. Here, the findings in this work provide a new understanding of the failure mechanisms and their practical implications for compositional tuning of future high-Ni NMCabc cathode materials during fast charging.

25 ENERGY STORAGE↗

Performance and Implementation Requirements for Residential EV Smart Charge Management Strategies

As the electrification of transportation expands, electric vehicle (EV) charging as residential loads will continue to grow. Residential EV charging has the potential to increase feeder peak loads and decrease voltage quality. As a result of this growing energy demand driven by EV, utilities may employ the use of smart charge management (SCM) controls to modify charging load profiles and mitigate these grid impacts. It is important that utilities understand both the potential benefits-as well as possible implementation challenges-before considering this technology as a solution to managing growing EV loads. In order for an SCM strategy to be an effective solution, the potential benefits must outweigh the implementation challenges. This study establishes and tests a novel framework to assess the implementation requirements of different SCM controls. It identifies a range of requirements specific to various SCM controls and implementation approaches to compare the relative challenges associated with the deployment of each. When paired with analysis on the effectiveness of the ability of each control to mitigate grid impacts from EV charging, this assessment is critical in comparing the value potential of different SCM controls.

ADVANCED PROPULSION SYSTEMS↗

Powertrain distribution based on total cost of ownership for privately owned vehicles and TNC in the Chicago metropolitan area

From a Total Cost of Ownership (TCO) standpoint, the lowest-cost powertrain option depends on driving conditions and number of miles driven over the lifetime of the vehicle. Studies looking at the value proposition of powertrain options traditionally assess the energy consumption based on standardized drive cycles. TCO is then calculated using average yearly Vehicle Miles Travelled (VMT). This approach which looks at TCO at the aggregate level, does not take into consideration the variations in driving patterns and the spread of VMT that exist in the vehicle population. In this study, we first determine the driving pattern of each vehicle in the Chicago metropolitan area. We then consider different powertrain options for each vehicle, calculate its associated TCO and provide a powertrain distribution based on lowest TCO. Vehicles under consideration are Privately Owned Vehicles (POV) and vehicles used by Transportation Network Companies (TNC).

Freyermuth, Vincent↗

Extreme Fast Charging: Effect of Positive Electrode Material on Crosstalk

Extreme fast charging (XFC) is a key requirement for the adoption of battery-based electric vehicles by the transportation sector. However, XFC has been shown to accelerate degradation, causing the capacity, life, and safety of batteries to deteriorate. We tested cells containing five positive electrode chemistries, LFP (olivine structure), LMO (spinel), LCO (layered), NMC811 (layered) and NCA (layered), using fast-charging protocols. After testing, the negative electrodes from cells containing positive electrodes crystallizing with a layered structure were found to have more lithium deposited on their surfaces. Further, those crystallizing with a layered structure also tended to have a larger increase in impedance than those crystallizing with a spinel or olivine structure. Characterization of the negative electrodes by X-ray photoelectron spectroscopy showed that using the concentrations of LiF and Li x PO y F z as metrics, the concentration of LiF in the SEI from the cell with different positive electrodes is LFP > LMO > LCO ~ NMC811 > NCA; and for Li x PO y F z , the order is LMO > LFP > NCA > NMC811 > LCO. Clearly, the positive-electrode material was influencing the amounts of these materials formed.

25 ENERGY STORAGE↗

Ballistic characterization of additively manufactured extrusion deposited thermoplastic composite plates

Additive manufacturing (AM) is rapidly emerging in high performance applications such as army ground vehicles, automotive and transportation. However, the response of AM parts/components to extreme loading such as high velocity impacts is less studied. In this work, the performance under ballistic impact of AM panels is evaluated using a medium velocity gas gun, generating projectile velocities up to 400 m/s. The preferential print orientation properties are considered in order to evaluate whether the panels exhibit isotropic or anisotropic behavior under impact. Surface morphology is investigated by milling the beads smooth on samples and comparing the impact on as-printed samples to those that are smoothed. The effect of nickel chromium micron (nichrome) wire embedded in the AM panels (during print) of polycarbonate-carbon fiber (PC-CF) and polycarbonate-glass fiber (PC-GF) are explored. Thermoplastic polyurethane-acrylonitrile butadiene styrene/carbon fiber (TPU-ABS/CF), Acrylonitrile butadiene styrene-carbon-fiber (ABS-CF) AM samples absorbed >50% of the impact energy. The ballistic performance was noted to be in the following order – ABS-CF > TPU-ABS/CF > PC. Scanning electron microscopy (SEM) was conducted to study the interface between the nichrome wire and the polymer-fiber matrix. This work is the first of its kind exploring into the capabilities of AM panels as ballistic materials. This study leads the way for developing AM panels that are easily manufactured and exhibit superior ballistic resistance.

Landrie, Dakota M.↗

High Temperature Optocoupler for 3D High Density Power Modules

The goal of this proposed research is to develop a reliable high-temperature optocouplers, which can operate at 250°C with at least ten-year lifetime, and replace isolation transforms as the galvanic isolation solution for the 3D integration of high density power modules. The electrification of future transportations (i.e., electric vehicles) will continuously drive the demand for high density power modules. Optocouplers (i.e., packaged light emitter and detector) as a promising candidate to replace bulky isolation transformers are highly desirable to facilitate the continuous scale-down of gate driver circuitry that will lead to 3D high density power modules and achieve disruptive performance in terms of thermal management, power density, power efficiency, reliability and operating environments. However, regular semiconductor optoelectronic materials and devices have significant difficulty functioning in the harsh environments designated for high density power module usage (such as operation at high temperatures). Ultimately, it is not the intrinsic properties of power devices that prevent their use at higher temperatures, but rather the low voltage electronics needed to drive them and the packaging that surrounds them. The typical operating temperature for optocouplers is only up to 100°C, due to the limitations of light emitting diode (LED) devices inside and packaging materials. A systematic characterization methodology will be developed to analyze the performance, lifetime and reliability of LED devices and distinguish multiple failure mechanisms at high temperatures. An original methodology of “design for reliability” will be developed to design the optoelectronic devices with high reliability and long lifetime at high temperatures. A new architecture of high temperature high reliable optocouplers will be developed, fabricated and demonstrated with continuous operating at 250°C. The development of efficient, reliable high density 3D power modules is the foundation for energy efficiency and energy reliability. Enabled with advanced 3D integration and packaging technologies, high density power module solutions can achieve much more superior performance over the conventional discrete solutions in terms of efficiency, thermal management and power density. The proposed concept of high temperature optocouplers as the galvanic isolation solution for high density power modules will bring together interdisciplinary research involving the wide bandgap materials, optoelectronics, high reliable device design, electronics packaging and power modules. A streamline of skilled personnel would be trained including graduate and undergraduate students, local engineers and scientists which are in great demand to both academia and optoelectronics industry. The proposed research topics, such as, solid state lighting and high temperature device reliability, are currently of major interest at the Department of Energy, in particular, Sandia National Laboratories. This project can enhance collaborations between the University of Arkansas (UA) and Sandia National Laboratories. The findings of the proposed research are expected to be integrated into high density 3-D power modules at the Engineering Research Center for Power Optimization for Electro-Thermal Systems (POETS).

42 ENGINEERING↗

Materials FY 2021 Annual Progress Report

The Materials Technology subprogram supports the VTO’s mission to accelerate the deployment of clean energy technology toward achieving net-zero emissions in the transportation sector. Lighter vehicles with more efficient powertrains reduce energy use, decrease greenhouse gas (GHG) emissions, and save consumers money.

33 ADVANCED PROPULSION SYSTEMS↗

Highly mobile robot for remote inspection

A robotic vehicle can include a plurality of motors coupled to a plurality of gearboxes, each gearbox of the plurality of gearboxes configured to be rotated, a plurality of nested driveshafts coupled to the plurality of gearboxes and including at least a first driveshaft and a second driveshaft, and a plurality of appendages operably coupled to the plurality of gearboxes. A particular appendage of the plurality of appendages can be configured to be rotated in response to a rotational motion of the first driveshaft. The robotic vehicle can include a plurality of wheels coupled to the plurality of appendages and configured to rotate about a plurality of wheel axles. Each wheel of the plurality of wheels can be configured to cause the robotic vehicle to be transported across a contacting surface in response to the rotational motion of the second driveshaft.

Crane, Carl D.↗

Dedicated short range communications used as fail-safe in autonomous navigation

Here in this paper, we have analyzed scenarios for leader-follower vehicle convoys that have the potential to be unsafe, hazardous, or even fatal in order to provide insight on dangerous driving conditions for autonomous vehicle platoons. These scenarios were created in a simulation software called Prescan, and are made to reflect the behavior of the vehicle dynamics and sensor characteristics of a real-world vehicle convoy that is currently being tested at the American Center for Mobility (ACM) and sponsored by the Department of Energy (DOE), National Renewable Energy Laboratory (NREL), the U.S. Army Combat Capabilities Development Command - Ground Vehicle Systems Center (U.S. Army CC-DEVCOM) and the Michigan Department of Transportation (MDOT). The follower vehicle in this study is tested under multiple scenarios, equipped with a Dedicated Short Range vehicle-to-vehicle communication system (DSRC), a radar-based adaptive cruise control system (ACC) and a precision global positioning system (GPS).

42 ENGINEERING↗

Performance Characterization of InCharge™ ICE-66 V2X Bidirectional DC Fast Charger

Vehicle-to-grid (V2G) technology extends the role of Plug-in Hybrid Vehicle’s (PHEV) and Battery Electric Vehicle’s (BEV) batteries beyond transportation by enabling bidirectional power transfer between the vehicle's onboard energy storage and the utility grid. Modern battery-powered vehicles are equipped with high-capacity battery packs that remain stationary and underutilized for the majority of their operational life. A vehicle used for daily commuting may be parked and connected to charging infrastructure for 18–20 hours per day, representing a significant untapped energy resource. When considered at scale, the aggregated storage capacity of a modest fleet of 10–15 vehicles within a single parking facility can reach the MWh range, sufficient to partially offset peak demand for a mid-size commercial building or contribute meaningful ancillary services to the local grid. The ability to charge during off-peak periods when electricity prices are low and discharge during peak demand when prices are high positions EV batteries as distributed energy arbitrage assets, with the potential to offset vehicle ownership and charging costs. Beyond energy arbitrage, V2G-capable assets can provide ancillary grid services through active and reactive power injections. Active power supports grid frequency regulation, while reactive power supports local voltage regulation. Together, these capabilities establish V2G as a technically promising and economically relevant pathway toward greater integration of battery-powered vehicles into the broader energy system.

33 ADVANCED PROPULSION SYSTEMS↗

RouteE API

This is the API endpoint for RouteE energy prediction, which can be used to get both single vehicle link or route energy estimates and transportation network-wide energy consumption estimates for a variety of vehicles. This enables external researchers and transportation engineers to access and utilize NREL's growing library of pre-trained vehicle models for prediction of transportation energy consumption. This API provides three endpoints: • /route: Energy estimation of a vehicle over a planning link or sequence of links (route). • /network: Network-wide estimation of energy consumption for all vehicle traffic in the desired area. • /compass: Energy-optimal “eco-routing” between input origin and destination coordinates (Currently in beta for Denver metro area only).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

RouteE API

This is the API endpoint for RouteE energy prediction, which can be used to get both single vehicle link or route energy estimates and transportation network-wide energy consumption estimates for a variety of vehicles. This enables external researchers and transportation engineers to access and utilize NREL's growing library of pre-trained vehicle models for prediction of transportation energy consumption. This API provides three endpoints: - /route: Energy estimation of a vehicle over a planning link or sequence of links (route). - /network: Network-wide estimation of energy consumption for all vehicle traffic in the desired area. - /compass: Energy-optimal “eco-routing” between input origin and destination coordinates (Currently in beta for Denver metro area only).

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗