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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Thermal acclimation of plant photosynthesis and autotrophic respiration in a northern peatland

Peatlands contain one-third of global soil carbon (C), but the responses of peatland ecosystems to long-term warming are not well understood. Here, we pursue an emergent understanding of warming effects on ecosystem C fluxes at peatlands by constraining a process-oriented model, the terrestrial ECOsystem model, with observational data from a long-term warming experiment at the Spruce and Peatland Responses Under Changing Environments site. Model-based assessments show that ecosystem-level photosynthesis and autotrophic respiration exhibited significant thermal acclimation, with temperature sensitivities being linearly decreased with warming. Using the thermal-acclimated parameter values, simulated gross primary production, net primary production, and plant autotrophic respiration (R a ), were all lower than those simulated with non-thermal acclimated parameter values. In contrast, ecosystem respiration simulated with thermal acclimated parameter values was higher than that simulated with non-thermal acclimated parameter values. Net ecosystem CO 2 exchange was much higher after constraining model parameters with observational data from the warming treatments, releasing C at a rate of 28.3 g C m -2 yr -1 °C -1 . Our data-model integration study suggests that peatlands are likely to release more C than previously estimated. Earth system models may overestimate C uptake by peatlands under warming if physiological thermal acclimation of plants is not incorporated. Thus, it is critical to consider the long-term physiological thermal acclimation of plants in the models to better predict global C dynamics under future climate and their feedback to climate change.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1970

Thermal expansion of AlAs

Lattice parameter and thermal expansion of AlAs as function of temperature, indicating lattice match at 900 C with GaAs

Ettenberg, M.↗
DOE OSTI2024

On a Spectral Method for β -particle Bound Excitation Collisions in Kilonovae

The interaction of β-particles with the weakly ionized plasma background is an important mechanism for powering the kilonova (KN) transient signal from neutron star mergers. For this purpose, we present an implementation of the approximate fast-particle collision kernel, described by Inokuti following the seminal formulation of Bethe, in a spectral solver of the Vlasov–Maxwell–Boltzmann equation. In particular, we expand the fast-particle plane-wave atomic excitation kernel into coefficients of the Hermite basis, and derive the relevant discrete spectral system. In this fast-particle limit, the approach permits the direct use of atomic data, including optical oscillator strengths, normally applied to photon–matter interaction. The resulting spectral matrix is implemented in the MASS-APP spectral solver framework, in a way that avoids full matrix storage per spatial zone. We numerically verify aspects of the matrix construction, and present a proof-of-principle 3D simulation of a 2D axisymmetric KN ejecta snapshot. Our preliminary numerical results indicate that a reasonable choice of Hermite basis parameters for β-particles in the KN is a bulk velocity parameter u = 0, a thermal velocity parameter α = 0.5c, and a 9 × 9 × 9 mode velocity basis set (Hermite orders of 0–8 in each dimension). For interior-ejecta sample zones, we estimate that the ratio of thermalization from large-angle (≳2fdg5) bound excitation scattering to total thermalization is ~0.002–0.003.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2019

Machine Learning, Markov Chain Monte Carlo, and Optimal Algorithms to Characterize the AdvACT Kilopixel Transition-Edge Sensor Arrays

Next-generation focal planes comprising dozens of kilopixel transition-edge sensor (TES) arrays require new methods to rapidly screen candidate arrays, evaluate array non-idealities in the field, identify outlier devices for removal, and optimize the array performance in the field. We demonstrate robust methods to estimate TES parameters (critical temperatures and thermal conductivity parameters) and their uncertainties using a custom Markov Chain Monte Carlo (MCMC) algorithm. We also constrain systematic effects in estimating the TES parameters from non-isothermal current-voltage curves (IVs) at approximately a ~3% level. Additionally, for the first time, we have applied Machine Learning (ML) algorithms to tune detector arrays and optimize their performance.

Maria Salatino↗
NASA NTRS1980

Microwave radiometric determination of oceanographic and meteorological parameters

The thermal microwave brightness from the atmosphere over an ocean in the range 5-40 GHz is influenced primarily by the distribution of vapor and liquid water in the atmosphere and the temperature and wind speed at the sea surface. The Scanning Multichannel Microwave Radiometer (SMMR), which was carried aboard both the Nimbus-7 and Seasat satellites (both launched in 1978), measures this radiation at five frequencies to find these four parameters. A retrieval algorithm has been developed which, on simulated data, yields accuracies of 1.5 C in sea surface temperature, 0.9 m/s in wind speed, 4 mg/ sq cm of cloud liquid water content and 0.14gm/sq cm of precipitable water vapor. Results from the Seasat SMMR, while both preliminary and sparse, are consistent with these simulations.

Wilheit, T. T.↗
DOE OSTI2022

Project Report: High Frequency Axion LDRD - A Multiport Approach to Thermal Noise and Scattering Parameter Simulation of Cryogenic Experiments

In this report, a simple algorithm for detailed system-level thermal noise analysis is developed, demonstrated, and verified. This method uses noise-wave theory and noise covariance matrices to cascade noise and scattering parameters of multiport devices at different temperatures. This method addresses the effects of return loss, multiport isolation/coupling, and static temperature differentials between components, and will work in cases where the noise temperature is at or near the quantum noise limit. An ideal multidevice network will first be demonstrated to show that this method’s results are consistent with the Friis cascade when component parameters such as return loss and isolation are ideal. Following the ideal multidevice example, a cryogenic experiment is conducted to demonstrate that the proposed simulation method is successful when real data are used.

42 ENGINEERING↗
NASA NTRS2003

Sharp Refractory Composite Leading Edges on Hypersonic Vehicles

On-going research of advanced sharp refractory composite leading edges for use on hypersonic air-breathing vehicles is presented in this paper. Intense magnitudes of heating and of heating gradients on the leading edge lead to thermal stresses that challenge the survivability of current material systems. A fundamental understanding of the problem is needed to further design development. Methodology for furthering the technology along with the use of advanced fiber architectures to improve the thermal-structural response is explored in the current work. Thermal and structural finite element analyses are conducted for several advanced fiber architectures of interest. A tailored thermal shock parameter for sharp orthotropic leading edges is identified for evaluating composite material systems. The use of the tailored thermal shock parameter has the potential to eliminate the need for detailed thermal-structural finite element analyses for initial screening of material systems being considered for a leading edge component.

Walker, Sandra P.↗
NASA NTRS1993

Comparison of remote sensing measurements with a two-scale polarimetric emission and scattering model for sea surfaces

Recently, it has been observed that the brightness temperatures of sea surfaces correlate with the azimuth angle of the ocean wind vector, indicating that ocean wind direction can not only be retrieved from the microwave backscatter, but also from the brightness temperature measurements. In this paper, comparison of the theoretical result calculated from a two-scale emission and scattering model with the Seasat and SSM/I model functions and aircraft measurements is presented and potential applications of microwave polarimetry are discussed. In our two-scale model, the modified reflectivities of large scale surfaces are calculated by extending the small perturbation method to the second order for small scale perturbation with anisotropic directional spectrum. It was found that the modified reflectivities derived from the second-order scattered field agree excellently well with the results obtained from a Monte Carlo simulation technique which numerically calculates the polarimetric reflectivities of one-dimensional random rough surfaces with a power-law spectrum. Without the second-order correction, the modified reflectivities of the rough surfaces are significantly over-estimated and sign errors are observed in the third and fourth Stokes parameters for thermal emissions. The surface spectrum parameters and two-scale cutoff are selected so that the calculated scattering and emission signatures agree with the reported model functions for Seasat and SSM/I. Subsequently, the polarimetric signatures of sea surfaces are illustrated to indicate the possibility of reducing the number of azimuthal looks required for spaceborne sensors in the remote sensing of ocean wind by using the polarimetric information. Furthermore, it is found that contrary to the dependence of backscattering coefficients on incidence angles, polarimetric brightness temperatures display a stronger wind direction dependence in the near nadir-looking direction than away from nadir. Finally, we discuss the potential of a single-look polarimetric radiometer for wind retrieval.

Yueh, S. H.↗
NASA NTRS1999

Polar/Tide Observations of Field Aligned O(+) Flows at 5000 km Altitude over the Auroral Regions in Comparison to UVI Auroral Images

Measurements of thermal O(+) ion parameters from the Thermal Ion Dynamics Experiment (TIDE) on POLAR obtained near 5000 km altitude are compared with auroral images from the Ultra Violet Imager (UVI), for southern perigee passes. Ion parameters, including parallel velocity, density, and flux are combined with simultaneous auroral images to investigate relationships between their properties and the structure and brightness of the auroral forms. Results indicate field aligned upflowing O(+) ions over bright auroral regions and downward flows over dark regions. These and other relationships will be presented for several POLAR passes when both ion measurements and auroral images are observed under favorable conditions for comparison.

Stevenson, Benjamin Adam↗
NASA NTRS2000

POLAR Observations of Field Aligned O+ Flows at 5000 km Altitude Over the Polar Regions with Comparison to Auroral Images

Measurements of thermal 0+ ion parameters from the Thermal Ion Dynamics Experiment (TIDE) on POLAR obtained near 5000 km altitude are compared with auroral images from the Ultra Violet Imager (UVI), for southern perigee passes. Ion parameters, including parallel velocity, density, and flux are combined with multiple dayside and nightside auroral images to investigate relationships between O+ field aligned flows and the structure and brightness seen in the auroral forms. Results indicate field aligned upflowing O+ ions over regions of bright auroral activity and downward flows over dark regions. These and other relationships will be presented for several POLAR passes when both ion measurements and auroral images are observed under favorable conditions for comparison.

Stevenson, B. A.↗
DOE OSTI2024

Zentropy theory for accurate prediction of free energy, volume, and thermal expansion without fitting parameters

Based on statistical mechanics, a macroscopically homogeneous system, i.e., a single phase in the present context, is composed of many independent configurations that the system embraces. The macroscopical properties of the system are determined by the properties and statistical probabilities of those configurations with respect to external conditions. The volume of a single phase is thus the weighted sum of the volumes of all configurations. Consequently, the derivative of the volume to temperature of a single phase depends on both the derivatives of the volumes of every configuration to temperature and the derivatives of their statistical probabilities to temperature, with the latter introducing nonlinear emergent behaviors. It is shown that the derivative of the volume to the temperature of the single phase can be negative, i.e., negative thermal expansion, due to the symmetry-breaking non-ground-state configurations with smaller volumes than that of the ground-state configuration and the rapid increase of the statistical probabilities of the former, and negative thermal expansion can be predicted without fitting parameters from the zentropy theory that combines quantum mechanics and statistical mechanics with the free energy of each configuration predicted from quantum mechanics and the partition function of each configuration calculated from its free energy.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Accurate quantification of lattice temperature dynamics from ultrafast electron diffraction of single-crystal films using dynamical scattering simulations

In ultrafast electron diffraction (UED) experiments, accurate retrieval of time-resolved structural parameters, such as atomic coordinates and thermal displacement parameters, requires an accurate scattering model. Unfortunately, kinematical models are often inaccurate even for relativistic electron probes, especially for dense, oriented single crystals where strong channeling and multiple scattering effects are present. This article introduces and demonstrates dynamical scattering models tailored for quantitative analysis of UED experiments performed on single-crystal films. As a case study, we examine ultrafast laser heating of single-crystal gold films. Comparison of kinematical and dynamical models reveals the strong effects of dynamical scattering within nm-scale films and their dependence on sample topography and probe kinetic energy. Applying to UED experiments on an 11 nm thick film using 750 keV electron probe pulses, the dynamical models provide a tenfold improvement over a comparable kinematical model in matching the measured UED patterns. Also, the retrieved lattice temperature rise is in very good agreement with predictions based on previously measured optical constants of gold, whereas fitting the Debye–Waller factor retrieves values that are more than three times lower. Altogether, these results show the importance of a dynamical scattering theory for quantitative analysis of UED and demonstrate models that can be practically applied to single-crystal materials and heterostructures.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Steady Laminar Flame for 1-Step Thermal Decomposition Model of PBX 9501

We have recently developed a new 1-step thermal decomposition model of PBX 9501 high explosive. In this report, we examine the behavior of the model in 1-D steady laminar flame calculations. In particular, the dependencies of the steady laminar flame velocity on initial pressure, thermal conductivies and parameters of the thermal decomposition model are investigated. The results of our numerical calculations are compared to available experimental data.

42 ENGINEERING↗
DOE OSTI2025

Hierarchical microstructural parameters governing electrical and thermal conductivity in Al-based eutectic systems

Enhancing conductivity properties of aluminum alloys can drive superior performance and efficiency across diverse engineering applications, yet currently commercially available Al casting alloys are severely limited in electrical and thermal conductivity. There is a general understanding that the presence of any defects and alloying elements within Al will inevitably lower conductivity properties. However, there is a lack of comparative studies evaluating the intricate interplay between the microstructural parameters and conductivity properties across cast Al-based eutectic systems. Therefore, this study bridges this gap by conducting a comparative study across hypoeutectic alloy compositions consisting of 50 % primary Al and 50 % eutectic region to elucidate the key parameters that dictate conductivity properties. This research contributes to advancing the understanding of alloy design opportunities for high conductivity, high strength castable Al alloys.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Distinct Kinetic Signatures of Photodesorption from Metal Nanoparticles

Visible photon fluxes can influence the rate and selectivity of heterogeneously catalyzed reactions on metal nanoparticle surfaces. Models describing the influence of photon fluxes have typically introduced photon flux dependent apparent thermal kinetic parameters (reaction orders, activation energies, binding energies, etc.). This has relied on empirical fitting of reaction rate data, making mechanistic interpretations of how photon fluxes influence elementary step rates challenging and inconsistent with fundamental descriptions of photochemistry on metal surfaces developed from surface science studies. Using the CO adsorption–desorption quasi-equilibrium reaction on Pt/Al 2 O 3 catalysts as a model system, we measured steady state adsorbed CO (CO*) coverages under isothermal and isobaric (1 mbar CO) conditions as a function of temperature (473–573 K) and of 440 nm photon flux ((0.1–5.2) × 10 3 # hv Pt site –1 s –1 ) using in situ IR spectroscopy. Steady state CO* coverage on Pt was photon flux dependent with increasing photon flux causing decreasing coverage, consistent with photons driving CO* desorption rates faster than thermal CO* desorption rates. However, photon flux dependent CO* coverages were essentially temperature independent, inconsistent with models that describe photon effects using perturbations to apparent thermal kinetic parameters. Instead, 120 steady state CO* coverages as a function of temperature and photon flux are quantitatively described by a kinetic model in which the overall desorption rate is a summation of independent thermal and photon induced CO* desorption rates. Site-resolved analysis reveals distinct kinetic parameters for photon driven desorption of CO* from well-coordinated, under-coordinated, and highly under-coordinated Pt sites, with temperature-dependent apparent quantum efficiencies (AQE) consistent with temperature dependence of vibrational quanta distribution of adsorbed CO. The rigorous kinetic rate laws for independent photon and thermal driven pathways allow for predictive modeling of the influence of photon fluxes on the rates of CO* desorption under catalytic conditions. Further, the analysis provides evidence that steady state continuous wave photon fluxes can drive desorption/adsorption reactions on metal surfaces out of thermal equilibrium, reconciling surface science observations of molecular photodesorption with applied catalysis. The work establishes a general kinetic framework to be considered for photon driven processes on metals, and defines catalyst, reaction, and photon flux characteristic design principles for breaking Sabatier limitations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1987

Solar active region physical parameters inferred from a thermal cyclotron line and soft X-ray spectral lines

Simultaneous high-resolution observations of coronal loops were made at the 20-cm wavelength with the VLA and at soft X-ray wavelengths with the SMM FCS. The images obtained at both wavelengths have nearly identical sizes and ellipsoidal shapes, with the emission stretching between and across regions of opposite magnetic polarity in the underlying photosphere. The results indicate that the radiation at 20 cm and soft X-ray wavelengths originates from the same region, and that 20 cm maps can image X-ray coronal loops. The X-ray spectral lines were used to obtain values of electron temperature, T(e), of about 2.6 x 10 to the 6th K and electron density, N(e), of about 3.1 x 10 to the 9th/cu cm. These parameters were used to show that the layers emitting 20-cm radiation can be optically thick to either thermal bremsstrahlung or thermal gyroresonance radiation, depending upon unknown but plausible values of loop thickness, magnetic scale height, and magnetic field strength.

Lang, Kenneth R.↗