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At least 145 records · Page 8

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NASA NTRS1989

A survey of upwind methods for flows with equilibrium and non-equilibrium chemistry and thermodynamics

Several versions of flux-vector split and flux-difference split algorithms were compared with regard to general applicability and complexity. Test computations were performed using curve-fit equilibrium air chemistry for an M = 5 high-temperature inviscid flow over a wedge, and an M = 24.5 inviscid flow over a blunt cylinder for test computations; for these cases, little difference in accuracy was found among the versions of the same flux-split algorithm. For flows with nonequilibrium chemistry, the effects of the thermodynamic model on the development of flux-vector split and flux-difference split algorithms were investigated using an equilibrium model, a general nonequilibrium model, and a simplified model based on vibrational relaxation. Several numerical examples are presented, including nonequilibrium air chemistry in a high-temperature shock tube and nonequilibrium hydrogen-air chemistry in a supersonic diffuser.

Grossman, B.↗

NASA NTRS1989

Nonequilibrium flow computations. I - An analysis of numerical formulations of conservation laws

Modern numerical techniques employing properties of flux Jacobian matrices are extended to general, nonequilibrium flows. Generalizations of the Beam-Warming scheme, Steger-Warming and van Leer Flux-vector splittings, and Roe's approximate Riemann solver are presented for 3-D, time-varying grids. The analysis is based on a thermodynamic model that includes the most general thermal and chemical nonequilibrium flow of an arbitrary gas. Various special cases are also discussed.

Liu, Yen↗

NASA NTRS1990

Users Manual for the NASA Lewis Ice Accretion Prediction Code (LEWICE)

LEWICE is an ice accretion prediction code that applies a time-stepping procedure to calculate the shape of an ice accretion. The potential flow field is calculated in LEWICE using the Douglas Hess-Smith 2-D panel code (S24Y). This potential flow field is then used to calculate the trajectories of particles and the impingement points on the body. These calculations are performed to determine the distribution of liquid water impinging on the body, which then serves as input to the icing thermodynamic code. The icing thermodynamic model is based on the work of Messinger, but contains several major modifications and improvements. This model is used to calculate the ice growth rate at each point on the surface of the geometry. By specifying an icing time increment, the ice growth rate can be interpreted as an ice thickness which is added to the body, resulting in the generation of new coordinates. This procedure is repeated, beginning with the potential flow calculations, until the desired icing time is reached. The operation of LEWICE is illustrated through the use of five examples. These examples are representative of the types of applications expected for LEWICE. All input and output is discussed, along with many of the diagnostic messages contained in the code. Several error conditions that may occur in the code for certain icing conditions are identified, and a course of action is recommended. LEWICE has been used to calculate a variety of ice shapes, but should still be considered a research code. The code should be exercised further to identify any shortcomings and inadequacies. Any modifications identified as a result of these cases, or of additional experimental results, should be incorporated into the model. Using it as a test bed for improvements to the ice accretion model is one important application of LEWICE.

Ruff, Gary A.↗

NASA NTRS1990

Liquid-Vapor Equilibrium of Multicomponent Cryogenic Systems

Liquid-vapor and solid-vapor equilibria at low to moderate pressures and low temperatures are important in many solar system environments, including the surface and clouds of Titan, the clouds of Uranus and Neptune, and the surfaces of Mars and Triton. The familiar cases of ideal behavior are limiting cases of a general thermodynamic representation for the vapor pressure of each component in a homogeneous multicomponent system. The fundamental connections of laboratory measurements to thermodynamic models are through the Gibbs-Duhem relation and the Gibbs-Helmholtz relation. Using laboratory measurements of the total pressure, temperature, and compositions of the liquid and vapor phases at equilibrium, the values of these parameters can be determined. The resulting model for vapor-liquid equilibrium can then conveniently and accurately be used to calculate pressures, compositions, condensation altitudes, and their dependencies on changing climatic conditions. A specific system being investigated is CH4-C2H6-N2, at conditions relevant to Titan's surface and atmosphere. Discussed are: the modeling of existing data on CH4-N2, with applications to the composition of Titan's condensate clouds; some new measurements on the CH4-C2H6 binary, using a high-precision static/volumetric system, and on the C2H6-N2 binary, using the volumetric system and a sensitive cryogenic flow calorimeter; and describe a new cryogenic phase-equilibrium vessel with which we are beginning a detailed, systematic study of the three constituent binaries and the ternary CH4-C2H6-N2 system at temperatures ranging from 80 to 105 K and pressures from 0.1 to 7 bar.

Thompson, W. Reid↗

NASA NTRS1991

A pressure control analysis of cryogenic storage systems

Self-pressurization of cryogenic storage tanks due to heat leak through the thermal protection system is examined along with the performance of various pressure control technologies for application in microgravity environments. Methods of pressure control such as fluid mixing, passive thermodynamic venting, and active thermodynamic venting are analyzed using the homogeneous thermodynamic model. Simplified equations suggested may be used to characterize the performance of various pressure control systems and to design space experiments.

Lin, C.-S.↗

NASA NTRS1991

Autogenous pressurization of cryogenic vessels using submerged vapor injection

Experimental results are reported for submerged injection pressurization and expulsion tests of a 4.89 cu m liquid hydrogen tank. The pressurant injector was positioned near the bottom of the test vessel to simulate liquid engulfment of the pressurant gas inlet; a condition that may occur in low-gravity conditions. Results indicate a substantial reduction in pressurization efficiency, with pressurant gas requirements approximately five times greater than ideal amounts. Consequently, submerged vapor injection should be avoided as a low-gravity autogenous pressurization method whenever possible. The work presented herein validates that pressurent requirements are accurately predicted by a homogeneous thermodynamic model when the submerged injection technique is employed.

Stochl, Robert J.↗

NASA NTRS1991

A pressure control analysis of cryogenic storage systems

Lin, C.-S.↗

NASA NTRS1991

Solution and shock-induced exsolution of argon in vitreous carbon

To add to the knowledge of noble gas solution and exsolution in carbonaceus material, experiments were performed on vitreous carbon. Ar-rich vitreous carbon samples were prepared under vapor-saturated conditions using argon as the pressurizing medium. Solubility data were obtained for temperatures of 773 to 973 K and pressures of 250 to 1500 bars. Up to 7 wt pct Ar was dissolved in the carbon. The solubility data were compared to a thermodynamic model of argon atoms dissolving into a fixed population of 'holes' in the carbon. Two variations of the model yielded estimates of the enthalpy of solution of Ar in vitreous carbon equal to about -4700 cal/mole. Preliminary shock experiments showed that 28 percent of the total argon was released by driving 4 GPa shocks into the argon-rich carbon. It was demonstrated that shock-induced argon loss is not simply caused by the impact-induced diminution of grain size. The present value of shock pressure required for partial impact devolatilization of Ar from carbon is below the range (5-30 GPa) at which H2O is released from phyllosilicates.

Gazis, Carey↗

NASA NTRS1992

Chemistry of the outer planets

Various aspects were studied of past or present chemistry in the atmospheres of the outer planets and their satellites using lab simulations. Three areas were studied: (1) organic chemistry induced by kinetically hot hydrogen atoms in the region of Jupiter's atmosphere containing the ammonia cirrus clouds; (2) the conversion of NH3 into N2 by plasmas associated with entry of meteors and other objects into the atmosphere of early Titan; and (3) the synthesis of simple hydrocarbons and HCN by lightning in mixtures containing N2, CH4, and NH3 representing the atmospheres of Titan and the outer planets. The results showed that: (1) hot H2 atoms formed from the photodissociation of NH3 in Jupiter's atmosphere could account for some of the atmospheric chemistry in the ammonia cirrus cloud region; (2) the thermalization of hot H2 atoms in atmospheres predominated by molecular H is not as rapid as predicted by elastic collision theory; (3) the net quantum loss of NH3 in the presence of a 200 fold excess of H2 is 0.02, much higher than was expected from the amount of H2 present; (4) the conversion of NH3 into N2 in plasmas associated with infalling meteors is very efficient and rapid, and could account for most of the N2 present on Titan; (5) the yields of C2H2 and HCN from lightning induced chemistry in mixtures of CH4 and N2 is consistent with quenched thermodynamic models of the discharge core; and (6) photolysis induced by the UV light emitted by the gases in the hot plasmas may account for some, if not most, of the excess production of C2H6 and the more complex hydrocarbons.

Scattergood, Thomas W.↗

NASA NTRS1992

Venus surface mineralogy - Observational and theoretical constraints

Earth-based, earth-orbital, and spacecraft observations of the atmosphere and surface of Venus, thermodynamic models of atmosphere-lithosphere interactions, and where available kinetic data on relevant gas-solid reactions to place constraints on the mineralogy of the surface of Venus are used. Which minerals and mineral assemblages are stable on the surface of Venus and which, if any, of these minerals are involved in controlling the abundances of reactive gases in the atmosphere of Venus. It is concluded by identifying key issues facing us today about the mineralogy and geochemistry of the surface of Venus and suggest experimental, observational, and theoretical studies that can improve knowledge of these important questions are discussed.

Fegley, Bruce, Jr.↗

NASA NTRS1993

Lewis Research Center battery overview

The topics covered are presented in viewgraph form and include the following: the Advanced Communications Technology Satellite; the Space Station Freedom (SSF) photovoltaic power module division; Ni/H2 battery and cell design; individual pressure vessel (IPV) nickel-hydrogen cell testing SSF support; the LeRC Electrochemical Technology Branch; improved design IPV nickel-hydrogen cells; advanced technology for IPV nickel-hydrogen flight cells; a lightweight nickel-hydrogen cell; bipolar nickel-hydrogen battery development and technology; aerospace nickel-metal hydride cells; the NASA Sodium-Sulfur Cell Technology Flight Experiment; and the lithium-carbon dioxide battery thermodynamic model.

Odonnell, Patricia↗

NASA NTRS1993

The influence of the hydrologic cycle on the extent of sea ice with climatic implications

Multi-temporal satellite images, field observations, and field measurements were used to investigate the mechanisms by which sea ice melts offshore from the Mackenzie River delta. Advanced Very High Resolution Radiometer (AVHRR) satellite data recorded in 1986 were analyzed. The satellite data were geometrically corrected and radiometrically calibrated so that albedo and temperature values could be extracted. The investigation revealed that sea ice melted approximately 2 weeks earlier offshore from the Mackenzie River delta than along coasts where river discharge is minimal or non-existent. There is significant intra-delta variability in the timing and patterns of ice melt. An estimation of energy flux indicates that 30 percent more of the visible wavelength energy and 25 percent more of the near-infrared wavelength energy is absorbed by water offshore of the delta compared to coastal areas with minimal river discharge. The analysis also revealed that the removal of sea ice involves the following: over-ice-flooding along the coast offshore from river delta channels; under-ice flow of 'warm' river water; melting and calving of the fast ice; and, the formation of a bight in the pack ice edge. Two stages in the melting of sea ice were identified: (1) an early stage where heat is supplied to overflows largely by solar radiation, and (2) a later stage where heat is supplied by river discharge in addition to solar radiation. A simple thermodynamic model of the thaw process in the fast ice zone was developed and parameterized based on events recorded by the satellite images. The model treats river discharge as the source of sensible heat at the base of the ice cover. The results of a series of sensitivity tests to assess the influence of river discharge on the near shore ice are presented.

Dean, Kenneson G.↗

NASA NTRS1993

Stratospheric chlorine injection by volcanic eruptions - HCl scavenging and implications for ozone

Because the output of volatile chlorine during a major volcanic event can greatly exceed the annual anthropogenic emissions of chlorine to the atmosphere, the fate of volcanic chlorine must be known. Although numerous observations have shown that volcanoes do not significantly contribute to the stratospheric chlorine burden, no quantitative explanation has been published. Hydrogen chloride (HCl) scavenging processes during the early phases of a volcanic eruption are discussed. A plume dynamics and thermodynamics model is used to show that HCl removal in condensed supercooled water can reduce HCl vapor concentrations by up to four orders of magnitude, preventing substantial stratospheric chlorine injection.

Tabazadeh, A.↗

NASA NTRS1991

Autogenous pressurization of cryogenic vessels using submerged vapor injection

Experimental results are reported for submerged injection pressurization and expulsion tests of a 4.89 cu m liquid hydrogen tank. The pressurant injector was positioned near the bottom of the test vessel to simulate liquid engulfment of the pressurant gas inlet, a condition that may occur in low-gravity conditions. Results indicate a substantial reduction in pressurization efficiency with pressurant gas requirements approximately five times greater than ideal amounts. Consequently, submerged vapor injection should be avoided as a low-gravity autogenous pressurization method whenever possible. The work presented herein validates that pressurant requirements are accurately predicted by a homogeneous thermodynamic model when the submerged injection technique is employed.

Stochl, Robert J.↗

NASA NTRS1993

An experimental study of trace element partitioning between olivine, orthopyroxene and melt in chondrules - Equilibrium values and kinetic effects

Mineral/melt partition coefficients were measured using an ion microprobe for 32 elements in orthopyroxene and olivine in equilibrium and dynamic crystallization experiments on compositions corresponding to chondrules. The mineral/melt partition coefficients calculated from the measured concentrations for both olivine and orthopyroxene show very little change between equilibrium experiments and dynamic experiments with cooling rates of up to 100 C/h. The results provide a self-consistent set of partition coefficients that can be used in thermodynamic models of equilibrium and kinetic partitioning between olivine, orthopyroxene, and melt. These data can be used in models of partial melting and crystal fractionation in olivine- and orthopyroxene-rich systems, such as chondrules. The results may also be applicable to mantle peridotites, komatiitic and picritic lavas, and ultramafic intrusions.

Kennedy, A. K.↗

NASA NTRS1993

Discovery Venera surface: Atmosphere geochemistry experiments mission concept

The phenomenal increase in our understanding of Venus provided by the Magellan Mission has raised a series of focused, fundamental scientific questions about the geochemistry of the surface of Venus, the nature of the lower atmosphere, and the relationship of the lower atmosphere and surface. First, surface geochemical measurements from the Venera/Vega spacecraft showed that widely spaced regions of the venusian plains are made of basalts; thus basalts are significant and may be the only component of the venusian crust. But we lack information on the composition of several key elements of Venus geology: (1) Tessera terrain (which may be outcrops of continental-like non-basaltic crustal material) and steep-sided domes/festoons are promising candidates for non-basaltic geochemically evolved material. The composition of the lower part of the Venusian crust is unknown: however, ejecta from large venusian craters provides us with the possibility of sampling this material on the surface; (2) bulk chemistry (structure and dynamics) of the venusian atmosphere are known. The altitude profiles of water vapor content and minor admixtures relevant to redox conditions in the lower atmosphere (less than 20 km altitude) remain uncertain. Lack of that knowledge means that we do not understand the fine chemical structure of the main mass of the Venusian atmosphere; and (3) thermodynamic models predict that igneous materials on the surface of Venus should react with gases of the venusian atmosphere. But because the water vapor content and redox conditions in the lower atmosphere are not well known, we do not understand the nature of venusian weathering: oxidation, sulfatization, carbonatization, and hydration. The answers to these questions are critical to the understanding of Venus, the most Earth-like of the terrestrial planets.

Surkov, Yuri A.↗

NASA NTRS1995

Numerical study to assess sulfur hexafluoride as a medium for testing multielement airfoils

A methodology is described for computing viscous flows of air and sulfur hexafluoride (SF6). The basis is an existing flow solver that calculates turbulent flows in two dimensions on unstructured triangular meshes. The solver has been modified to incorporate the thermodynamic model for SF6 and used to calculate the viscous flow over two multielement airfoils that have been tested in a wind tunnel with air as the test medium. Flows of both air and SF6 at a free-stream Mach number of 0.2 and a Reynolds number of 9 x 10(exp 6) are computed for a range of angles of attack corresponding to the wind-tunnel test. The computations are used to investigate the suitability of SF6 as a test medium in wind tunnels and are a follow-on to previous computations for single-element airfoils. Surface-pressure, lift, and drag coefficients are compared with experimental data. The effects of heavy gas on the details of the flow are investigated based on computed boundary-layer and skin-friction data. In general, the predictions in SF6 vary little from those in air. Within the limitations of the computational method, the results presented are sufficiently encouraging to warrant further experiments.

Bonhaus, Daryl L.↗

NASA NTRS1995

Supertough Stainless Bearing Steel

Composition and processing of supertough stainless bearing steel designed with help of computer-aided thermodynamic modeling. Fracture toughness and hardness of steel exceeds those of other bearing steels like 440C stainless bearing steel. Developed for service in fuel and oxidizer turbopumps on Space Shuttle main engine. Because of strength and toughness, also proves useful in other applications like gears and surgical knives.

Olson, Gregory B.↗