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Water chemistry in flume channel and hyporheic zone (i.e., porewater) associated with: “Rethinking Aerobic Respiration in the Hyporheic Zone Under Variation in Carbon and Nitrogen Stoichiometry”

Dissolved oxygen (DO), total organic carbon (TOC), total nitrogen (TN), molecular data for organic matter, and biochemical reactions for surface water and porewater (i.e., hyporheic zone) collected from a water recirculating flume located at the University of Texas, Austin. The flume contained real river water from Lower Colorado River(Austin, TX) and clean sand. Hyporheic exchange in the flume was induced through The study aims to understand relationships between aerobic metabolism of organic matter and molecular characteristics of organic matter, such as thermodynamic signature and nitrogen content, through the extent of the hyporheic zone at 10 cm- resolution, and through time. During the experiment, organic matter (dry leaves) was added to the flume and removed after 24 hours. The water samples were collected before the addition of leaves, at the time of removal of leaves, and at hour 72. The water samples were analyzed using ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) and total organic carbon (TOC) and total nitrogen (TN) analysis. Dissolved oxygen content throughout the surface water and the hyporheic zone of the flume was measured with a large planar optode. This data package is associated with the publication ’ Rethinking Aerobic Respiration in the Hyporheic Zone Under Variation in Carbon and Nitrogen Stoichiometry’ published in Environmental Science and Technology (Turețcaia et al., 2023 https://doi.org/10.1021/acs.est.3c04765). The dataset is comprised of five folders (1) Diss_O2_pic, (2) input_files (3) output_files; (4) python_code; and (5) R_code . Diss_O2_pic contains siximages of dissolved oxygen distribution in a bedform at hours 0, 24, and 72 of the experiment conducted in a large recirculation flume. Images are in separate R and G channels (i.e., RGB). The input_files contains (1) a csv file with FTICR peaks identified within each sample, (2) a csv file with molecular information pertinent to FTICR data with Gibbs free energy calculations adjusted for environmental temperature, (3) a csv file containing concentrations of non-purgeable organic carbon measured throughout the experiment , (4) a csv file containing concentrations of total nitrogen measured throughout the experiment, (5) a csv file containing total biochemical reactions (i.e., transformations) identified in the dataset, (6) a csv containing transformation profiles, and (7) a csv file containing transformations with formulas, and (8) a jpg file with schematic representation of locations for sample collection. The output_files contains (1) and xlsx file containing percent biochemical reactions containing nitrogen identified across all 39 sample, (2) a csv file of merged FTICR data and molecular information files, (3) a csv files containing average Gibbs free energy within sampling domains and at each sampling location, (4) a csv file with average concentrations of dissolved oxygen across sampling locations at hour 0, (5) a csv file with average concentrations of dissolved oxygen across sampling locations at hour 24, (6) a csv file with average concentrations of dissolved oxygen across sampling locations at hour 72, (7) a csv file with percent chemical classes identified across sampling locations at hour 0, (8) a csv file with percent chemical classes identified across sampling locations at hour 24, (9) a csv file with percent chemical classes identified across sampling locations at hour 72, and (10) a csv file containing percent nitrogen containing biochemical reactions identified across sampling locations at hours 0, 24, and 72. The python_code contains seven ipynb files which are Jupyter Notebooks used for data analysis and figures generation. The R_code contains 3 R files with R code used for data analysis and figures generation. This data package contains the processed data used in the associated manuscript. This data has not been previously published.

54 ENVIRONMENTAL SCIENCES↗

Modelling TOVS radiances of synoptic systems

Two operational analysis models, produced by ECMWF and NMC, are compared against observed satellite radiances by converting the analyzed variables into synthetic radiances using a radiative transfer model (RTM). Observed TOVS satellite radiances are used as a ground truth, since they are the only source of continuous, synoptic-scale resolution observations available over the data-sparse tropical Pacific Ocean. It is assumed that if the analysis models correctly simulate atmospheric conditions, the observed and modelled radiance fields will have similar patterns and magnitudes. In each of seven TOVS channels examined, the mean temperature difference between the models was small, but the differences between the models and the observations were large. The mean temperature difference within each channel was larger than the standard deviation in most cases. The moisture channels of the RTM were sensitive to changes in moisture content, but none of the channels were significantly affected by changes in temperature. Single-day modelled radiance analyses contain synoptic information similar to the satellite observations. ECMWF is often too noisy, producing features not verified by the satellite; NMC is often too smooth. NMC more closely resembles the TOVS contours. Modelled water vapor channel analyses resemble observed monthly and composited observations well, but do not accurately reproduce the highly-variable single-day fields. ECMWF generally has more accurate gradients. Neither model simulates the tropics well. The water vapor channels, especially channel eleven (weighted at 700 mb), most closely resembled the tropical plume composite described by McGuirk and Ulsh. The only plume evidence found in the thermal or microwave channels, in either the observations or the models, was a composite trough situated in the correct location, extending from the mid-latitudes into the subtropics. This feature was not readily discernable until the definition and mature stages. Additional information besides the modelled temperatures would be required to produce an accurate forecast for the tropics. Model patterns more closely resembled the observations in the quiescent atmosphere, though the magnitudes were not any closer. ECMWF simulates the TOVS quiescent state better than NMC. The moisture channels continue to present the most realistic patterns. The models contained more detail in the tropics than was verified by the satellite observations, apparently trying to force an active ITCZ. Lag correlations showed TOVS to be more persistent than the models. TOVS also showed a smoother lag trend, but all products appeared to have adequate ability to react to changes in the atmosphere over time.

Coe, Thomas Eddy↗

Possible near-IR channels for remote sensing precipitable water vapor from geostationary satellite platforms

Remote sensing of troposheric water vapor profiles from current geostationary weather satellites is made using a few broadband infrared (IR) channels in the 6-13 micron region. Uncertainties greater than 20% exist in derived water vapor values just above the surface from the IR emission measurements. In this paper, we propose three near-IR channels, one within the 0.94-micron water vapor band absorption region, and the other two in nearby atmospheric windows, for remote sensing of precipitable water vapor over land areas, excluding lakes and rivers, during daytime from future geostationary satellite platforms. The physical principles are as follows. The reflectance of most surface targets varies approximately linearly with wavelength near 1 micron. The solar radiation on the sun-surface-sensor ray path is attenuated by atmospheric water vapor. The ratio of the radiance from the absorption channel with the radiances from the two window channels removes the surface reflectance effects and yields approximately the mean atmospheric water vapor transmittance of the absorption channel. The integrated water vapor amount from ground to space can be obtained with a precision of better than 5% from the mean transmittance. Because surface reflectances vary slowly with time, temporal variation of precipitable water vapor can be determined reliably. High spatial resolution, precipitable water vapor images are derived from spectral data collected by the Airborne Visable-Infrared Imaging Spectrometer, which measures solar radiation reflected by the surface in the 0.4-2.5 micron region in 10-nm channels and has a ground instantaneous field of view of 20 m from its platform on an ER-2 aircraft at 20 km. The proposed near-IR reflectance technique would complement the IR emission techniques for remote sensing of water vapor profiles from geostationary satellite platforms, especially in the boundary layer where most of the water vapor is located.

Gao, B.-C.↗

Storm-Associated Microwave Radiometric Signatures in the Frequency Range of 90-220 GHz

Radiometric measurements were made by a millimeter-wave imaging radiometer (MIR) at the frequencies of 89, 150, 183.3 +/- 1, 183.3 +/- 3, 183.3 +/- 7, and 220 GHz aboard the NASA ER-2 aircraft at an altitude of about 20 km over two rainstorms: one in the western Pacific Ocean on 19 January 1993 and another in southern Florida on 5 October 1993. These measurements were complemented by nearly simultaneous observations by other sensors aboard the same aircraft and another aircraft flying along the same path. Analysis of data from these measurements, aided by radiative transfer and radar reflectivity calculations of hydrometeor profiles, which arc generated by a general cloud ensemble model, demonstrates the utility of these frequencies for studying the structure of frozen hydrometeors associated with storms. Particular emphasis is placed on the three water vapor channels near 183.3 GHz. Results show that the radiometric signatures measured by these channels over the storm-associated scattering media bear a certain resemblance to those previously observed over a clear and fairly dry atmosphere with a cold ocean background. Both of these atmospheric conditions are characterized by a small amount of water vapor above a cold background. Radiative transfer calculations were made at these water vapor channels for a number of relative humidity profiles characterizing dry atmospheres over an ocean surface. The results are compared with the measurements to infer some characteristics of the environment near the scattering media. Furthermore, radiometric signatures from these channels display unique features for towering deep convective cells that could be used to identify the presence of such cells in storms.

Wang, James R.↗

Molecular To Mesoscale Targeting of Oxoanions with Multi-Tasking Hosts

Achieving a better understanding of anion interactions both in solution and crystalline state was the overarching goal of this project. Anions are everywhere throughout Nature and play important roles in biological and environmental processes. They can be beneficial or deleterious or both in different situations and concentrations. For either reason it is important to have molecules that can bind anions for key needs that benefit society. However, recognition of specific anions is challenging due to the diffuse nature of their negative charge(s) as well as their various shapes and sizes. Understanding the basic properties of anions and how they interact with other molecules and ions in surrounding environments is key to selective recognition. In this project multi-tasking molecules for selective binding of targeted anions were designed to achieve cooperativity and synergism in one rather than multiple host molecules, including (1) cation:anion pair hosts for anions with charges of -2 or greater; (2) pH and redox activated hosts for on-off binding and release; and (3) multiple anion capture in extended host networks. Our design strategy was to combine the use of simple inexpensive building blocks and high yield synthetic pathways to provide economically feasible scale-up for applications. Oxoanions representing multiple shapes and charges were chosen based on having the potential for significant impact on DOE separations needs. Amide/amine-based macrocycles and urea/amine-based chelates and macrocycles with multiple hydrogen bonding sites provided the basic anion-binding frameworks. Successful multi-tasking outcomes were forthcoming in all three tasks. In Task 1, successful ion pair binding for anions with multiple charges was achieved. Furthermore, the ion pair molecules were capable of extended interactions through supramolecular intertwining, like fishing nets for capturing pools of fish (also fitting with Task 3). In Task 2, molecules were synthesized possessing on-off switches. These included a pH sensitive sensor for on-off binding of anions in general, as well as an electrochemical sensor selective for sulfate capture. Three new classes of extended anion host networks capable of binding multiple ions was a major outcome of Task 3. These systems included: anion sensitive, fluorescent organogels; channel-forming macrocycles for studying anion-water including larger macrocyclic cluster sandwiches; and, the offshoot of Task 1, fishing net ion-pair networks for higher valent anions. These strategies can be expanded in the future to other ions and molecules for a better understanding of intermolecular and interionic interactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Statistical analysis and use of VAS radiance data

Researchers goals are to describe the information content of Vertical Atmospheric Sounder (VAS) radiance data, especially the 6.7 micrometers water vapor channel, to better interpret the atmosphere's water vapor structure from 6.7 micrometers imagery, and to investigate new analysis and forecasting techniques utilizing retrieved VAS soundings. Researchers made major progress toward these goals during FY-85. They are investigating 6.7 micrometer imagery on 6 to 7 March 1982, a day when special mesoscale ground truth data were collected during the 1982 atmospheric variability experiment/vertical amospheric sounder (AVE/VAS) field experiment. A dark (dry) image streak having mesoscale details was located over the special data region, and it provides the major focus of the case study. Mesoscale radiosonde-derived humidity data are found to verify fine scale features of the image that are not evident from the standard National Weather Service network. Thus, VAS imagery is a reliable detector of mesoscale moisture structure during this case. To investigate causes for the image streak, researchers are calculating water vapor budgets. Subsidence is found to be a factor in the current case as well; however, patterns of descent are not related to the jet streak according to traditional conceptual models. Thus, it appears that more research into jet stream dynamics is needed in order to better interpret 6.7 micrometer imagery.

Fuelberg, H. E.↗

Pressure Spike in The LBNF Absorber Core s Gun Drilled Cooling Channel from an Accident Beam Pulse

The LBNF Absorber consists of thirteen 6061-T6 aluminum core blocks. The core blocks are water cooled with de-ionized (DI) water which becomes radioactive during beam operations. The cooling water flows through gun-drilled channels in the core blocks. The cooling water is supplied by the LBNF Absorber Radioactive Water (RAW) cooling system which is designed as per ASME B31.3 Normal Fluid Service [1]. An uninhibited beam accident pulse striking the water channels was identified as a credible accident scenario. In this study, it is assumed that the beam pulse hits the Absorber directly without interacting with any of the other upstream beamline components. The beam parameters used for the LBNF beam are 120 GeV, 2.4 MW with a 1.2 s cycle time. The accident pulse lasts for 10 μs. The maximum energy is deposited in the 3rd aluminum core block. For the sake of simplicity, it is assumed that the accident pulse strikes the 1 in. ID water channel directly. The analysis here simulates the pressure rise in the water during and after the beam pulse and its effects on the aluminum piping components that deliver water to the core blocks. The weld strengths as determined by the Load and Resistance Factor Design (LRDF) and the Allowable Strength Design (ASD) are compared to the forces generated in the weld owing to the pressure spike. A transient structural analysis was used to determine the equivalent membrane, peak, and bending stresses and they were com-pared to allowable limits.

43 PARTICLE ACCELERATORS↗

Pressure Spike in The LBNF Absorber Core s Gun Drilled Cooling Channel from an Accident Beam Pulse

he LBNF absorber consists of thirteen 6061-T6 aluminum core blocks. The core blocks are water cooled with de-ionized (DI) water which becomes radioactive during beam operations. The cooling water flows through gun-drilled channels in the core blocks. The cooling water is supplied by the LBNF absorber radioactive water (RAW) cooling system which is designed as per ASME B31.3 normal fluid service. An uninhibited beam accident pulse striking the water channels was identified as a credible accident scenario. In this study, it is assumed that the beam pulse hits the absorber directly without interacting with any of the other upstream beamline components. The beam parameters used for the LBNF beam are 120 GeV, 2.4 MW with a 1.2 s cycle time. The accident pulse lasts for 10 µs. The maximum energy is deposited in the 3rd aluminum core block. For the sake of simplicity, it is assumed that the accident pulse strikes the 1 in. ID water channel directly. The analysis here simulates the pressure rise in the water during and after the beam pulse and its effects on the aluminum piping components that deliver water to the core blocks. The weld strengths as determined by the Load and Resistance Factor Design (LRDF) and the Allowable Strength Design (ASD) are compared to the forces generated in the weld owing to the pressure spike. A transient structural analysis was used to determine the equivalent membrane, peak, and bending stresses and they were compared to allowable limits.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Thermal and hydraulic considerations regarding the fate of water discharged by the outflow channels to the Martian northern plains

The identification of possible shorelines in the Martian northern plains suggests that the water discharged by the circum-Chryse outflow channels may have led to the formation of transient seas, or possibly even an ocean, covering as much as one-third of the planet. Speculations regarding the possible fate of this water have included local ponding and reinfiltration into the crust; freezing, sublimation, and eventual cold-trapping at higher latitudes; or the in situ survival of this now frozen water to the present day -- perhaps aided by burial beneath a protective cover of eolian sediment or lavas. Although neither cold-trapping at higher latitudes nor the subsequent freezing and burial of flood waters can be ruled out, thermal and hydraulic considerations effectively eliminate the possibility that any significant reassimilation of this water by local infiltration has occurred given climatic conditions resembling those of today. The arguments against the local infiltration of flood water into the northern plains are two-fold. First, given the climatic and geothermal conditions that are thought to have prevailed on Mars during the Late Hesperian (the period of peak outflow channel activity in the northern plains), the thickness of the cryosphere in Chryse Planitia is likely to have exceeded 1 km. A necessary precondition for the widespread occurrence of groundwater is that the thermodynamic sink represented by the cryosphere must already be saturated with ice. For this reason, the ice-saturated cryosphere acts as an impermeable barrier that effectively precludes the local resupply of subpermafrost groundwater by the infiltration of water discharged to the surface by catastraphic floods. Note that the problem of local infiltration is not significantly improved even if the cryosphere were initially dry, for as water attempts to infiltrate the cold, dry crust, it will quickly freeze, creating a seal that prevents any further infiltration from the ponded water above. The second argument against the local infiltration of flood water in the northern plains is based on hydraulic considerations. Repeated impacts have likely brecciated the Martian crust down to a depth of roughly 10 km. Given a value of permeability no greater than that inferred for the top 10 km of the Earth's crust (approximately 10(exp -2) darcies), a timescale as much as a billion years or more for the Martian groundwater system to achieve hydrostatic equilibrium, and the approximately 2-4 km elevation difference between the outflow channel source regions and the northern plains, the water confined beneath the frozen crust of the northern plains should have been under a significant hydraulic head. Thus, the existence of a hydraulic pathway between the ponded flood waters above the northern plains and the confined aquifer lying beneath it would not have led to the infiltration of flood water back into the crust, but rather the additional expulsion of groundwater onto the surface.

Clifford, S. M.↗

MPEX High Heat Flux Plasma Dump Design, Manufacture, and Articles Test

Here, the Material Plasma Exposure eXperiment (MPEX) device is a steady-state linear plasma device currently in the final design phase at the Oak Ridge National Laboratory. This device will reach ion fluences up to 10 31 m -2 and will be used to expose neutron-irradiated materials to divertor-relevant plasmas and to study the effects of plasma-material interactions. These studies will elucidate the complex effects of plasmas with divertor candidate materials capable of withstanding high heat flux and high fluences for next-generation fusion devices. Bidirectional plasma will be generated using a high-power (200 kW) helicon source. Plasma will be confined by superconducting magnets. The last plasma-facing component on the upstream side of the MPEX device is the dump, which has been designed to intercept plasma and energetic particles. The dump will have a total heat load of 9.2 kW. A copper alloy (Glidcop AL-15) was selected for use in the water-cooled flange design because of its high thermal conductivity, its retaining strength at elevated temperatures, and its ability to be used in the high-temperature braze joints used in this application. Titanium-zirconium-molybdenum (TZM) tiles are brazed to the Glidcop AL-15 flange using high-temperature braze alloy. External water-cooling channels are used on the dump flange to prevent water leakage inside the vacuum space. This article discusses the details of the high heat flux dump design, including the computational fluid dynamics (CFD) and structural analyses performed to validate the design to meet the operational requirements of the MPEX device.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Possible Near-IR Channels for Remote Sensing Precipitable Water Vapor from Geostationary Satellite Platforms

Remote sensing of tropospheric water vapor profiles from current geostationary weather satellites are made using a few broadband infrared (IR) channels in the 6 to 13- micrometers region. Uncertainties greater than 20 percent exist in derived water vapor values just above the surface from the IR emission measurements. In this paper, we propose three near-IR channels, one within the 0.94-micrometer water vapor band absorption region, and the other two in nearby atmospheric windows, for remote sensing of precipitable water vapor over land areas, excluding lakes and rivers, during daytime from future geostationary satellite platforms. The physical principles are as follows. The reflectance of most surface targets varies approximately linearly with wavelength near 1 micrometer. The solar radiation on the sun-surface-sensor ray path is attenuated by atmospheric water vapor...

Green, R. O.↗

Simulations of the effects of water vapor, cloud liquid water, and ice on AMSU moisture channel brightness temperatures

Radiative transfer simulations are performed to determine how water vapor and nonprecipitating cloud liquid water and ice particles within typical midlatitude atmospheres affect brightness temperatures T(sub B)'s of moisture sounding channels used in the Advanced Microwave Sounding Unit (AMSU) and AMSU-like instruments. The purpose is to promote a general understanding of passive top-of-atmosphere T(sub B)'s for window frequencies at 23.8, 89.0, and 157.0 GHz, and water vapor frequencies at 176.31, 180.31, and 182.31 GHz by documenting specific examples. This is accomplished through detailed analyses of T(sub B)'s for idealized atmospheres, mostly representing temperate conditions over land. Cloud effects are considered in terms of five basic properties: droplet size distribution, phase, liquid or ice water content, altitude, and thickness. Effects on T(sub B) of changing surface emissivity also are addressed. The brightness temperature contribution functions are presented as an aid to physically interpreting AMSU T(sub B)'s. Both liquid and ice clouds impact the T(sub B)'s in a variety of ways. The T(sub B)'s at 23.8 and 89 GHz are more strongly affected by altostratus liquid clouds than by cirrus clouds for equivalent water paths. In contrast, channels near 157 and 183 GHz are more strongly affected by ice clouds. Higher clouds have a greater impact on 157- and 183-GHz T(sub B)'s than do lower clouds. Clouds depress T(sub B)'s of the higher-frequency channels by suppressing, but not necessarily obscuring, radiance contributions from below. Thus, T(sub B)'s are less closely associated with cloud-top temperatures than are IR radiometric temperatures. Water vapor alone accounts for up to 89% of the total attenuation by a midtropospheric liquid cloud for channels near 183 GHz. The Rayleigh approximation is found to be adequate for typical droplet size distributions; however, Mie scattering effects from liquid droplets become important for droplet size distribution functions with modal radii greater than 20 micrometers near 157 and 183 GHz, and greater than 30-40 micrometers at 89 GHz. This is due mainly to the relatively small concentrations of droplets much larger than the mode radius. Orographic clouds and tropical cumuli have been observed to contain droplet size distributions with mode radii in the 30-40 micrometers range. Thus, as new instruments bridge the gap between microwave and infrared to frequencies even higher than 183 GHz, radiative transfer modelers are cautioned to explicitly address scattering characteristics of such clouds.

Muller, Bradley M.↗

Carbonate-sulfate volcanism on Venus?

Venusian canali, outflow channels, and associated volcanic deposits resemble fluvial landforms more than they resmeble volcanic features on Earth and Mars. Some canali have meandering habits and features indicative of channel migration that are very similar to meandering river channels and flood plains on Earth, venusian outflow channels closely resemble water-carved outflow channels on Mars and the Channeled Scabland in Washington, collapsed terrains at the sources of some venusian channels resemble chaotic terrains at the sources of martian outflow channels, venusian lava deltas are similar to bird's-foot deltas such as the Mississippi delta, and venusian valley networks indicate sapping. We have developed an alternative possibility that the lava had a water-like rheology and a melting point slightly greater than Venus' surface temperature, thus accounting for the unusual behavior of the lava. Unlike silicate lavas, some carbonatites (including carbonate-sulfate-rich liquids) have these properties; thus they can flow great distances while retaining a high fluidity, significant mechanical erosiveness, and substantial capacity to transport and deposit sediment. Venusian geochemistry and petrology are consistent with extensive eruptions of carbonatite lavas, which could have crustal and/or mantle origins. Venus' atmosphere (especially CO2, HCl, and HF abundances) and rocks may be in local chemical equilibrium, which suggests that the upper crust contains large amounts of calcite, anhydrite, and other salts. Chemical analyses indicate, according to some models, that Venusian rocks may contain 4-19% calcite and anhydrite. Mixtures of crustal salts could melt at temperatures a few tens to a few hundred Kelvins higher than Venus' surface temperature; hence, melting may be induced by modest endogenetic or impact heating. Salts may have many of the same geologic roles on Venus as water and ice have on Mars. A molten salt (carbonatite) 'aquifer' may exist beneath a few hundred meters to several kilometers of solidified salt-rich 'permafrost.' Many geologic features can be explained by carbonatite magmatism: (1) impact melting of crustal salts can explain crater outflows, (2) small, sustained eruptions from molten salt aquifers can explain sapping valleys, (3) large, sustained eruptions may explain canali and their flood plans, and (4) catastrophic outbursts amy have formed outflow channels and chaotic terrain. Landforms created by carbonate-rich lavas would be thermally stable on Venus' surface, though some minerals may weather to other solid substances.

Kargel, Jeffrey S.↗

Cloud Top Scanning radiometer (CTS): User's guide

The CTS maps the Earth's surface with a resolution of 0.1 km from an altitude of 18km with 60km side-to-side coverage of the field. It has three spectral channels. The 0.625 micrometer centered visual channel detects reflectance to within 1 percent. The 6.75 micrometer centered water vapor channel detects changes in temperature of less than one degree Kelvin at 175 K. The 11.5 micrometer centered infrared window channel detects changes of less one half degree Kelvin at 175 K. The data can be converted graphically into three display images of the scene. Values for scene temperature and albedo are calculated from calibration equations. The equations were derived from in-situ and laboratory measurements. Intercomparisons of the flight data temperatures with ground based and other remote sensor results established the certainty of the derived temperature values to within 3 K over a wide temperature range (180 to 320 K). The system performance, calibration, and operation is successful and the engineering information describing this system should prove useful to scientists and potential users of the data.

Brown, K. S.↗

Evaluation of Daytime Measurements of Aerosols and Water Vapor made by an Operational Raman Lidar over the Southern Great Plains

Raman lidar water vapor and aerosol extinction profiles acquired during the daytime over the Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site in northern Oklahoma (36.606 N, 97.50 W, 315 m) are evaluated using profiles measured by in situ and remote sensing instruments deployed during the May 2003 Aerosol Intensive Operations Period (IOP). The automated algorithms used to derive these profiles from the Raman lidar data were first modified to reduce the adverse effects associated with a general loss of sensitivity of the Raman lidar since early 2002. The Raman lidar water vapor measurements, which are calibrated to match precipitable water vapor (PWV) derived from coincident microwave radiometer (MWR) measurements were, on average, 5-10% (0.3-0.6 g/m(exp 3) higher than the other measurements. Some of this difference is due to out-of-date line parameters that were subsequently updated in the MWR PWV retrievals. The Raman lidar aerosol extinction measurements were, on average, about 0.03 km(exp -1) higher than aerosol measurements derived from airborne Sun photometer measurements of aerosol optical thickness and in situ measurements of aerosol scattering and absorption. This bias, which was about 50% of the mean aerosol extinction measured during this IOP, decreased to about 10% when aerosol extinction comparisons were restricted to aerosol extinction values larger than 0.15 km(exp -1). The lidar measurements of the aerosol extinction/backscatter ratio and airborne Sun photometer measurements of the aerosol optical thickness were used along with in situ measurements of the aerosol size distribution to retrieve estimates of the aerosol single scattering albedo (omega(sub o)) and the effective complex refractive index. Retrieved values of omega(sub o) ranged from (0.91-0.98) and were in generally good agreement with omega(sub o) derived from airborne in situ measurements of scattering and absorption. Elevated aerosol layers located between about 2.6 and 3.6 km were observed by the Raman lidar on May 25 and May 27. The airborne measurements and lidar retrievals indicated that these layers, which were likely smoke produced by Siberian forest fires, were primarily composed of relatively large particles (r(sub eff) approximately 0.23 micrometers), and that the layers were relatively nonabsorbing (omega(sub o) approximately 0.96-0.98). Preliminary results show that major modifications that were made to the Raman lidar system during 2004 have dramatically improved the sensitivity in the aerosol and water vapor channels and reduced random errors in the aerosol scattering ratio and water vapor retrievals by an order of magnitude.

Ferrare, Richard↗

Using the SPoRT POES/GOES Hybrid Product in OCONUS Forecasting

The SPoRT (Short-term Prediction and Research Transition) Program at the NASA/Marshall Space Flight Center has been providing unique NASA and NOAA data and techniques to partner Weather Forecast Offices (WFOs) for ten years. Data are provided in the Decision Support System used by WFO forecasters: AWIPS. For the last couple of years, SPoRT has been producing the POES/GOES Hybrid. This suite of products combines the strength ofl5- minute animations of GOES imagery - providing temporal continuity, with the higher resolution, relatively random availability, of polar orbiting (POES) imagery data. The product was first introduced with only MODIS data from NASA's Terra and Aqua satellites, but recently the VIIRS instrument onboard the Suomi-NPP satellite was added, providing better high-resolution coverage. These products represent SPoRT's efforts to prepare for higher resolution, higher frequency GOES-R imagery - as well as helping to move VIIRS (JPSS) data into the mainstream of weather forecasting. SPoRT generates 5 products for this dataset: Visible, Longwave Infrared (11 micrometers), Shortwave IR (3.7 micrometers), Water Vapor (6.7 micrometers), and Fog (Difference of 11 micrometer and 3.7 micrometer channels). The Water Vapor hybrid product has a Red-Blue-Green image from MODIS inlaid, since it provides even more qualitative information than water vapor alone. Animated examples of the products will be shown in this presentation. While the resolution at nadir of GOES imagery is nominally Han (4km for IR channels), the inlaid polar orbiter imagery has a resolution of 250m (lkm for IR channels). This has tremendous application in the continental US. However, in high latitudes, since the usefulness of GOES degrades poleward rapidly, the contrast of GOES and POES data is stark. The consistent temporal nature of GOES, even though at a reduced resolution at high latitudes, provides basic situational awareness, but the introduction of polar data is very helpful in seeing the big picture with clarity - even if only briefly. This presentation will offer real situations where these products helped forecasters make better informed decisions quickly. Plans to augment the product further with the addition of data from several A VHRR instruments will be described.

Smith, Matt↗

Determination of low-level precipitable water variability from split window channel radiance data

A technique has been developed for the quantitative definition of low-level precipitable water vapor from radiance measurements. High resolution data from the airborne Multispectral Atmospheric Mapping Sensor (MAMS) have been used in conjunction with this technique to define variability down to the lower end of the mesoscale. MAMS measures reflected radiation from the earth's surface and clouds in eight visible bands, and thermal emission from the earth's surface, clouds, and atmospheric water vapor in three IR bands. The present technique is found to be applicable to existing satellite sensors, but will not yield the mesoscale resolution furnished by the aircraft data.

Jedlovec, Gary J.↗