Search NASA⌕ Search

SEARCH · Search NASA

Results for “current density”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Failure Process During Fast Charging of Lithium Metal Batteries with Weakly Solvating Fluoroether Electrolytes

While improving the lithium metal (Li) Coulombic efficiency has been a focus for electrolyte design, the performance under high current densities is less studied yet highly relevant for practical applications. Here, we evaluate the charge-rate-dependent cycling stability using three types of weakly solvating fluoroether electrolytes. Although good cycle life was achieved in all three electrolytes under low current densities, they all exhibited a soft shorting behavior above various threshold current densities (between 2 and 5.2 mA cm –2 ). In this study, we attributed the current-dependent electrode morphology to both Li growth and residual solid electrolyte interface (rSEI) growth processes. In early cycles, Li morphology guided the formation of rSEI structures. In later cycles, the rSEI structure partially impacted Li growth. Under low current densities, the rSEI was inhomogeneous with large voids for subsequent bulky lithium growth. Under high current densities, the rSEI became more dense, which aggravated the high-surface/volume-ratio Li growth through and on the top of the rSEI. Among the three weakly solvating fluoroether electrolytes, the ones with lower ionic conductivity were observed to short within fewer cycles and at lower charge current densities. Our work suggests that fast ion transport in electrolytes may be a desirable feature for the stable operation at >1C charging in high-energy-density lithium metal batteries.

25 ENERGY STORAGE↗
DOE OSTI2024

Influence of Annealing Temperature on the OER Activity of NiO(111) Nanosheets Prepared via Microwave and Solvothermal Synthesis Approaches

Earth-abundant transition metal oxides are promising alternatives to precious metal oxides as electrocatalysts for the oxygen evolution reaction (OER) and are intensively investigated for alkaline water electrolysis. OER electrocatalysis, like most other catalytic reactions, is surface-initiated, and the catalyst performance is fundamentally determined by the surface properties. Most transition metal oxide catalysts show OER activities that depend on the predominantly exposed crystal facets/surface structure. Therefore, the design of synthetic strategies to obtain the most active crystal facets is of significant research interest. In this work, rock salt NiO OER catalysts with (111) predominantly exposed facets were synthesized by a solvothermal (ST) method either heated under supercritical or microwave-assisted (MW) conditions. Particular emphasis was placed on the influence of the post annealing temperature on the structural configuration and OER activity to compare their catalytic performances. The as-prepared electrocatalysts are pure α-Ni hydroxides which were converted to rock salt NiO (111) nanosheets with hexagonal pores after heat treatment at different temperatures. The OER activity of the electrodes has been evaluated in 0.1 M KOH using geometric and intrinsic current densities via normalization by the disk area and BET area, respectively. The lowest overpotential at a geometric current density of 10 mA/cm 2 is found for samples pretreated by heating between 400 and 500 °C with a catalyst loading of 115 μg/cm 2 . Despite the very similar nature of the catalysts obtained from the two methods, the ST electrodes show a higher geometric and intrinsic current density for 500 °C pretreatment. The MW electrodes, however, achieve an optimal geometric current density for 400 °C pretreatment, while their intrinsic current density requires pretreatment over 600 °C. Interestingly, pretreated electrodes show consistently higher OER activity as compared to the poorly crystalline/less ordered hydroxide as-prepared electrocatalysts. Thus, our study highlights the importance of the synthesis method and pretreatment at an optimal temperature.

36 MATERIALS SCIENCE↗
NASA NTRS1978

Chatanika radar observations of ionospheric and field-aligned currents

A method for estimating field-aligned current densities from ground-based measurements of the horizontal ionospheric currents at two or more latitudes using the Chatanika incoherent scatter radar is presented. It is assumed that the one-dimensional divergence of the horizontal currents approximates the current density of a field-aligned current sheet. The field-aligned current densities found via radar data agree with those given by simultaneous magnetic observations by the Triad satellite. It is noted that downward or upward field-aligned currents having densities of 10 to the -6th to 10 to the -5th A/sq m are achieved in the evening or morning sector. The densities are further increased during periods of increased geomagnetic activity and when current directions are reversed. This reversal generally occurs during auroral oval expansion.

Kamide, Y.↗
DOE OSTI2025

Mechanistic and Mitigation-Strategy Insights into NaCl and CaCl 2 Contamination of Proton-Exchange-Membrane Water Electrolysis Using Continuum Modeling

Cationic contaminants are detrimental to proton-exchange-membrane water electrolyzers (PEMWEs). To obtain insight, a 1-D, nonisothermal, multiphase continuum cell model including cationic contamination is developed. Simulations of steady-state cell performance predict decreased performance due to an increase in kinetic overpotential associated with the hydrogen-evolution reaction, which was attributed to decreased protonic-activity within the cathode catalyst layer from proton supplantation with contaminant cations. The accumulation and extent of cation exchange in the cathode catalyst layer depends on the operating current density due to migration. Simulations of cell recovery of potential suggest that a contaminated cell can recover approximately 78% (450 mV) with 24 h of constant current density operation at 2 A cm –2 , with higher current densities accelerating reduced recovery times. Parametric studies show that anode-side acidification at lower current densities inhibit cation contaminant adsorption, and cathode-side acidification at larger current densities facilitate the expulsion of adsorbed cations; for a cathode-side pH of 6 and 5, the cell can recover an additional 10% and 100% performance, respectively. Overall, the model serves as a framework for modeling other aspects of PEMWE systems to address durability and performance aspects, which can assist in improving the viability of the technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2012

Particle Acceleration in Dissipative Pulsar Magnetospheres

Pulsar magnetospheres represent unipolar inductor-type electrical circuits at which an EM potential across the polar cap (due to the rotation of their magnetic field) drives currents that run in and out of the polar cap and close at infinity. An estimate ofthe magnitude of this current can be obtained by dividing the potential induced across the polar cap V approx = B(sub O) R(sub O)(Omega R(sub O)/c)(exp 2) by the impedance of free space Z approx eq 4 pi/c; the resulting polar cap current density is close to $n {GJ} c$ where $n_{GJ}$ is the Goldreich-Julian (GJ) charge density. This argument suggests that even at current densities close to the GJ one, pulsar magnetospheres have a significant component of electric field $E_{parallel}$, parallel to the magnetic field, a condition necessary for particle acceleration and the production of radiation. We present the magnetic and electric field structures as well as the currents, charge densities, spin down rates and potential drops along the magnetic field lines of pulsar magnetospheres which do not obey the ideal MHD condition $E cdot B = 0$. By relating the current density along the poloidal field lines to the parallel electric field via a kind of Ohm's law $J = sigma E_{parallel}$ we study the structure of these magnetospheres as a function of the conductivity $sigma$. We find that for $sigma gg OmegaS the solution tends to the (ideal) Force-Free one and to the Vacuum one for $sigma 11 OmegaS. Finally, we present dissipative magnetospheric solutions with spatially variable $sigma$ that supports various microphysical properties and are compatible with the observations.

Kazanas, Z.↗
NASA NTRS1987

A laboratory investigation of potential double layers

In a triple plasma device, the injection of electron current from the source chamber to the target chamber causes the formation of a potential double layer. At a low current density, the space charge of the injected current produces a virtual cathode-type potential double layer. This double layer is stable, and various wave instabilities are observed to associate with this double layer. As the current density is increased, the double layer becomes unstable, and a moving double layer results. As the current density is increased further, the enhanced ionization causes the neutralization of the space charge of the electron beam, and the beam plasma discharge is ignited.

Leung, Philip↗
NASA NTRS1987

A laboratory investigation of potential double layers

In a triple plasma device, the injection of electron current from the source chamber to the target chamber causes the formation of a potential double layer. At a low current density, the space charge of the injected current produces a virtual cathode-type potential double layer. This double layer is stable and various wave instabilities are observed to associate with this double layer. As the current density is increased, the double layer becomes unstable and a moving double layer results. As the current density is increased further, the enhanced ionization causes the neutralization of the space charge of the electron beam and the 'beam plasma discharge' is ignited.

Leung, Philip↗
NASA NTRS1983

The molten carbonate carbon dioxide concentrator - Cathode performance at high CO2 utilization

An experimental study of the cathode performance of the molten carbonate carbon dioxide concentrator (MCCDC) at typical gas concentrations is reported, and the behavior is described in terms of standard electrochemical kinetic analysis. Theoretical aspects of the MCCDC are discussed, including the current-generating processes, the overpotential, and the reaction kinetics. A final working equation is derived, and the electrochemical cell is described. The parameters determined by the experiments include cathode overpotentials and removal and current efficiency as a function of current density, as well as carbon dioxide removal rate as a function of flow rate. The results are compared with data for other cells; the agreement with data for the molten carbonate fuel cell suggests that the major difference between the two cells is in the wetting characteristics. The MCCDC achieves high removal efficiencies at high current efficiencies. The lowest current efficiency recorded was 80 percent, and at most current densities, current efficiencies were above 100 percent.

Weaver, J. L.↗
DOE OSTI2024

A Novel Spinel High-Entropy Oxide (Cr0.2Mn0.2Co0.2Ni0.2Zn0.2)3O4 as Anode Material for Lithium-Ion Batteries

In this study, we synthesized spinel high-entropy oxide (HEO) (Cr0.2Mn0.2Co0.2Ni0.2Zn0.2)3O4 nanoparticles by a simple solution combustion method. These particles were investigated for their performance as anodes in lithium-ion batteries. The reversible capacity is 132 mAh·g−1 after 100 cycles at a current density of 100 mA·g−1, 107 mAh·g−1 after 1000 cycles at a current density of 1 A g−1, and 96 mAh·g−1 rate capacity at a high current density of 2 A g−1. The outstanding cycle stability under high current densities and remarkable rate performance can be attributed to the stable structure originating from the high entropy of the material.

25 ENERGY STORAGE↗
NASA NTRS1962

Estimation of Critical Temperature for Surface Ion Currents from Electron Emission Data

A method of calculating a relation for the critical surface temperature for ion current emission is presented. The method is based on the S-shaped electron emission curves for surfaces in the presence of ionizable vapors and upon the assumptions of thermodynamic equilibrium involved in the Saha-Langmuir relation. A comparison of the critical temperatures so calculated with the relation obtained from actual ion emission data on the cesium-tungsten system shows good agreement over a wide current density range. Critical temperatures for cesium ion current densities of 0.21 and 1.9 amperes per square centimeter calculated by this method are presented for surfaces of rhenium, molybdenum, tantalum, and niobium. Tentative relations of the form log j equals A (sub p) plus (B (sub p) over T) are presented for these same systems, where j is the ion current density, A (sub p) and B (sub p) are constants, and T is the temperature.

ELECTRON EMISSION↗
NASA NTRS1992

The coalescence instability in collisionless plasmas

The process whereby magnetic island structures tend to merge into larger units is known as magnetic island coalescence. This coalescence process is investigated for the case of a collisionless plasma by means of 2D particle simulations. The pairwise merging of a preformed island chain leads to a gentle redistribution of the density and current density profiles. The nonlinear evolution of the collisionless tearing instability in a long system is found to lead to a much more violent coalescence process resulting in the formation of a vacuum X region. This stage is characterized by enhanced growth rates for the long-wavelength modes that exceed the maximum linear tearing growth rate, super-Alfvenic flows away from the reconnection X line, substantial bulk heating in the parallel direction, and the formation of energetic particle tails in the direction of the inductive electric field.

Pritchett, P. L.↗
NASA NTRS1995

Line-of-sight magnetic flux imbalances caused by electric currents

Several physical and observational effects contribute to the significant imbalances of magnetic flux that are often observed in active regions. We consider an effect not previously treated: the influence of electric currents in the photosphere. Electric currents can cause a line-of-sight flux imbalance because of the directionality of the magnetic field they produce. Currents associated with magnetic flux tubes produce larger imbalances than do smoothly-varying distributions of flux and current. We estimate the magnitude of this effect for current densities, total currents, and magnetic geometry consistent with observations. The expected imbalances lie approximately in the range 0-15%, depending on the character of the current-carying fields and the angle from which they are viewed. Observationally, current-induced flux imbalances could be indicated by a statistical dependence of the imbalance on angular distance from disk center. A general study of magnetic flux balance in active regions is needed to determine the relative importance of other- probably larger- effects such as dilute flux (too weak to measure or rendered invisible by radiative transfer effects), merging with weak background fields, and long-range connections between active regions.

Gary, G. Allen↗
NASA NTRS2007

Process for High-Rate Fabrication of Alumina Nanotemplates

An anodizing process, at an early stage of development at the time of reporting the information for this article, has shown promise as a means of fabricating alumina nanotemplates integrated with silicon wafers. Alumina nanotemplates are basically layers of alumina, typically several microns thick, in which are formed approximately regular hexagonal arrays of holes having typical diameters of the order of 10 to 100 nm. Interest in alumina nanotemplates has grown in recent years because they have been found to be useful as templates in the fabrication of nanoscale magnetic, electronic, optoelectronic, and other devices. The present anodizing process is attractive for the fabrication of alumina nanotemplates integrated with silicon wafers in two respects: (1) the process involves self-ordering of the holes; that is, the holes as formed by the process are spontaneously arranged in approximately regular hexagonal arrays; and (2) the rates of growth (that is, elongation) of the holes are high enough to make the process compatible with other processes used in the mass production of integrated circuits. In preparation for fabrication of alumina nanotemplates in this process, one first uses electron-beam evaporation to deposit thin films of titanium, followed by thin films of aluminum, on silicon wafers. Then the alumina nanotemplates are formed by anodizing the aluminum layers, as described below. In experiments in which the process was partially developed, the titanium films were 200 A thick and the aluminum films were 5 m thick. The aluminum films were oxidized to alumina, and the arrays of holes were formed by anodizing the aluminum in aqueous solutions of sulfuric and/or oxalic acid at room temperature (see figure). The diameters, spacings, and rates of growth of the holes were found to depend, variously, on the composition of the anodizing solution, the applied current, or the applied potential, as follows: In galvanostatically controlled anodizing, regardless of the chemical composition of the solution, relatively high current densities (50 to 100 mA/cm2) resulted in arrays of holes that were more nearly regular than were those formed at lower current densities. . The rates of elongation of the holes were found to depend linearly on the applied current density: the observed factor of proportionality was 1.2 (m/h)/(mA/cm2). For a given fixed current density and room temperature, the hole diameters were found to depend mainly on the chemical compositions of the anodizing solutions. The holes produced in sulfuric acid solutions were smaller than those produced in oxalic acid solutions. The arrays of holes produced in sulfuric acid were more ordered than were those produced in oxalic acid. . The breakdown voltage was found to decrease logarithmically with increasing concentration of sulfuric acid. The breakdown voltage was also found to decrease with temperature and to be accompanied by a decrease in hole diameter. The hole diameter was found to vary linearly with applied potential, with a slope of 2.1 nm/V. This slope differs from slopes (2.2 and 2.77 nm/V) reported for similar prior measurements on nanotemplates made from bulk aluminum. The differences among these slopes may be attributable to differences among impurities and defects in bulk and electron-beam-evaporated aluminum specimens.

Myung, Nosang↗
DOE OSTI2025

Role of the junction voltage on the overflow current in light-emitting diodes

Quantum-well (QW)-based light emitters, such as light-emitting diodes (LEDs) and lasers, of various semiconductor materials experience a reduction in their efficiency when operating at higher temperatures, a phenomenon referred to as “thermal droop.” Among the various claims on the origins of thermal droop, an increased overflow current with increasing temperatures is a common contender. Since overflow of carriers can only occur when the junction voltage 𝑉 Junction approaches the built-in voltage 𝑉 BI of any diodes, we develop a simple method relating the difference between 𝑉 Junction and 𝑉 BI to approximate the upper limit of overflow occurring in QW-based light-emitting diodes. The measured difference between 𝑉 Junction and 𝑉 BI of state-of-the-art commercial blue and green In⁢Ga⁢N-based LEDs at temperatures up to ∼450 K suggests negligible overflow. To further experimentally verify the absence of overflow, we perform temperature-dependent electron emission spectroscopy on the same commercial blue and green LEDs and find no evidence of thermally enhanced overflow carriers up to ∼450 K. In agreement with our claims that 𝑉 Junction must approach 𝑉 BI for overflow to occur, two-dimensional temperature-dependent electrical simulations of violet, blue, and green LEDs including alloy disorder and V-defects demonstrate that overflow can be significant in violet LEDs, where the small band offset between the In⁢Ga⁢N QW and Ga⁢N cladding layers due to the larger QW bandgap requires larger 𝑉 Junction to reach standard operating current densities, thereby approaching 𝑉 BI . By contrast, simulations indicate that overflow is negligible in blue and green LEDs, whose smaller QW bandgaps result in smaller quasi-Fermi levels difference to reach significant carrier injection, resulting in a 𝑉 Junction much smaller than 𝑉 BI up to large operating current densities. Considering that overflow is negligible in blue and longer-wavelength LEDs, and our observations of the large thermal droop occurring at low current densities, where Shockley-Read-Hall (SRH) recombination dominates, we conclude that thermally enhanced SRH processes are the most significant contributor to thermal droop. Finally, we also simulate the carrier densities in the different QWs of a multiple-QW LED and observe a reduction in the total carrier density at a given operating current density, which results in a decrease in the total Auger-Meitner current of the LED from just the thermally enhanced carrier redistribution among QWs without taking any possible additional temperature dependence of their recombination coefficients. Taking all this into account, minimizing thermal droop effects in LEDs can be achieved by a reduction in defect density, using wider band gap p-n junction-defining cladding layers, and operating at higher currents.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1995

Reduction, analysis, and properties of electric current systems in solar active regions

The specific attraction and, in large part, the significance of solar magnetograms lie in the fact that they give the most important data on the electric currents and the nonpotentiality of active regions. Using the vector magnetograms from the Marshall Space Flight Center (MSFC), we employ a unique technique in the area of data analysis for resolving the 180 deg ambiguity in order to calculate the spatial structure of the vertical electric current density. The 180 deg ambiguity is resolved by applying concepts from the nonlinear multivariable optimization theory. The technique is shown to be of particular importance in very nonpotential active regions. The characterization of the vertical electric current density for a set of vector magnetograms using this method then gives the spatial scale, locations, and magnitude of these current systems. The method, which employs an intermediate parametric function which covers the magnetogram and which defines the local `preferred' direction, minimizes a specific functional of the observed transverse magnetic field. The specific functional that is successful is the integral of the square of the vertical current density. We find that the vertical electric current densities have common characteristics for the extended bipolar (beta) (gamma) (delta)-regions studied. The largest current systems have j(sub z)'s which maximizes around 30 mA/sq m and have a linear decreasing distribution to a diameter of 30 Mn.

Gary, G. Allen↗
NASA NTRS1995

Reduction, Analysis, and Properties of Electric Current Systems in Solar Active Regions

The specific attraction and, in large part, the significance of solar vector magnetograms lie in the fact that they give the most important data on the electric currents and the nonpotentiality of active regions. Using the vector magnetograms from the Marshall Space Flight Center (MSFC), we employ a unique technique in the area of data analysis for resolving the 180 degree ambiguity in order to calculate the spatial structure of the vertical electric current density. The 180 degree ambiguity is resolved by applying concepts from the nonlinear multivariable optimization theory. The technique is shown to be of particular importance in very nonpotential active regions. The characterization of the vertical electric current density for a set of vector magnetograms using this method then gives the spatial scale, locations, and magnitude of these current systems. The method, which employs an intermediate parametric function which covers the magnetogram and which defines the local "preferred" direction, minimizes a specific functional of the observed transverse magnetic field. The specific functional that is successful is the integral of the square of the vertical current density. We find that the vertical electric current densities have common characteristics for the extended bipolar beta gamma delta-regions studied. The largest current systems have j(sub z)'s which maximizes around 30 mA per square meter and have a linear decreasing distribution to a diameter of 30 Mm.

Gary, G. Allen↗
NASA NTRS1986

Calculations of electric currents in Europa

Electrical currents should flow in the Galilean satellite, Europa, because it is located in Jupiter's corotating magnetosphere. The possible magnitudes of these currents are calculated by assuming that Europa is a differentiated body consisting of an outer H2O layer and a silicate core. Two types of models are considered here: one in which the water is completely frozen and a second in which there is an intermediate liquid layer. For the transverse electric mode (eddy currents), the calculated current density in a liquid layer is approximately 10 to the -5/Am. For the transverse magnetic mode (unipolar generator), the calculated current density in the liquid is severely constrained by the ice layer to a range of only 10 to the -10 to -11th power/ Am, for a total H2O thickness of 100 km, provided that neither layer is less than 4 km thick. The current density is less for a completely frozen H2O layer. If transient cracks were to appear in the ice layer, thereby exposing liquid, the calculated current density could rise to a range of 10 to the -6 to 10 to the -5/Am, depending on layer thicknesses, which would require an exposed area of 10 to the -9 to 10 to the -8 of the Europa surface. The corresponding total current of 2.3x10 to the 5th power A could in 1 yr. electrolyze 7x10 to the 5th power kg of water (and more if the cells were in series), and thereby store up to 10 the 8th power J of energy, but it is not clear how electrolysis can take place in the absence of suitable electrodes. Electrical heating would be significant only if the ice-layer thickness were on the order of 1 m, such as might occur if an exposed liquid surface were to freeze over; the heating under this condition could hinder the thickening of the ice layer.

Colburn, D. S.↗