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At least 145 records · Page 8

Absolute Reactive Oxygen Species Densities in the Effluent of the COST Reference Source and Plasma-generated Atomic Oxygen Density Measurements in Liquid using TALIF

Reactive oxygen species are one of the most important species produced in a plasma. In particular the role of atomic oxygen and the hydroxyl radical OH has attracted many studies ranging from plasma medicine to plasma-driven biocatalysis and water treatment. Atomic oxygen and the hydroxyl radical OH are very reactive and react unselectively with many different substrates. The quantification of atomic oxygen and OH is challenging because of their reactivity and unknown reactions and rate constants.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Hanford Waste Treatment Plant Low Activity Waste Facility Stack Effluent Monitoring: Sampling Probe Location Qualification Evaluation (Rev.1)

The Hanford Tank Waste Treatment and Immobilization Plant Low Activity Waste (LAW) facility stack monitor locations were qualified using scale model stacks to mitigate the risk of discovering that sampling locations do not meet the qualification criteria on the full-scale stacks. As required by the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999 standard, the scale model and its sampling location were geometrically similar to the actual stack and the Reynolds numbers for both the actual and model stacks were >10,000. An additional criterion is that the product of the hydraulic diameter and mean velocity (DV) of the full-scale stack must be between 1/6 DV and 6 DV of the scale model stack tests. Verification tests of the LAW stacks were performed at normal operating conditions. The minimum 1/6 DV value, along with the maximum 6 DV value from the scale model testing, determines the range of stack flow rates for which the full-scale stack may be operated and remain in compliance with the stack verification criterion. For this analysis, the range of qualified flow rates listed is conservatively based on the average DV through 6 DV for LV-S1, LV-S2, and LV-C2, and 1/3 DV to 3 DV for LV-S3. Table S1 lists the operating flow rates along with the conservative lower and upper qualified stack flow rates for each of the LAW facility stacks. For each stack, the operating flow is below the upper qualified stack.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Hanford Waste Treatment Plant LAB Facility Stack Effluent Monitoring: Sampling Probe Location Qualification Evaluation

The Waste Treatment Plant laboratory (LAB) facility stack monitor locations were qualified using scale model stacks to mitigate the risk of identifying that sampling locations do not meet the qualification criteria on the full-scale stack. As required by the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999 standard, the scale model and its sampling location were geometrically similar to the actual stack, and the Reynolds numbers for both the actual and model stacks were >10,000. An additional criterion is that the product of the hydraulic diameter and mean velocity (DV) of the full-scale stack must be between 1/6 DV and 6 DV of the scale model stack tests. Verification tests of the LAB stacks were performed at normal operating conditions. The minimum 1/6 DV value, along with the maximum 6 DV value from the scale model testing, determines the range of conditions for which the full-scale stack may be operated and remain in compliance with the stack verification criterion. A practical range for the full-scale stack qualification uses the average DV through 6 DV from the scale model tests to compute the corresponding flow rates. Table S1 lists the operating flow rates along with the average and maximum qualified stack flow rates for each of the LAB facility stacks. For each stack, the operating flow is below the maximum qualified stack flow, which means that the scale model test results are acceptable for stack qualification. The remaining criteria for the stack verification to be considered valid involve the flow angle and velocity uniformity results. First, the flow angle at the full-scale stack must be ≤20°. Second, the velocity uniformity at the full-scale stack must be ≤20% coefficient of variance (COV). Finally, the velocity uniformity results for the actual and scale model stack tests must agree within 5% COV. These criteria were met through the full-scale stack tests at the LAB facility. Flow angle results were primarily less than 10°, except for the LB-C2 Fan A results, which were an average of 13.7°; all flow angle results were within the ≤20° criterion. The velocity uniformity results for each test condition averaged between 1.5 and 4.1% COV, which were all within the range of the target percent coefficient of variation values from the scale model tests. Based on these stack verification test results, the three LAB filtered exhaust stack sampling locations meet the qualification criteria provided in the ANSI/HPS N13.1-1999 standard for all fan operating configurations. This includes single-fan as well as dual-fan operations for LB-C2, each of the dual-fan operating conditions for LB-S1, and each single-fan operating condition for LB-S2. Further changes to the system configuration or operating conditions that are outside the bounds described in this report may require additional tests or analyses to determine compliance with the standard.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A Brief Review of Technologies for Separating Tritium from the Aqueous Effluent of Reprocessing Plants

The scope of this letter report encompasses a review of technologies applicable to separating tritiated water from light and heavy water with a focus on wastewater arising from the reprocessing of UNF. Reports considering flowsheet options for tritium management are also reviewed. The main objective of this letter report is to support consideration of programmatic opportunities for the Materials Recovery and Waste Form Development (MRWFD) Campaign within the Department of Energy’s Office of Nuclear Energy.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Is Genetic Engineering a Route to Enhance Microalgae-Mediated Bioremediation of Heavy Metal-Containing Effluents?

Contamination of the biosphere by heavy metals has been rising, due to accelerated anthropogenic activities, and is nowadays, a matter of serious global concern. Removal of such inorganic pollutants from aquatic environments via biological processes has earned great popularity, for its cost-effectiveness and high efficiency, compared to conventional physicochemical methods. Among candidate organisms, microalgae offer several competitive advantages; phycoremediation has even been claimed as the next generation of wastewater treatment technologies. Furthermore, integration of microalgae-mediated wastewater treatment and bioenergy production adds favorably to the economic feasibility of the former process—with energy security coming along with environmental sustainability. However, poor biomass productivity under abiotic stress conditions has hindered the large-scale deployment of microalgae. Recent advances encompassing molecular tools for genome editing, together with the advent of multiomics technologies and computational approaches, have permitted the design of tailor-made microalgal cell factories, which encompass multiple beneficial traits, while circumventing those associated with the bioaccumulation of unfavorable chemicals. Previous studies unfolded several routes through which genetic engineering-mediated improvements appear feasible (encompassing sequestration/uptake capacity and specificity for heavy metals); they can be categorized as metal transportation, chelation, or biotransformation, with regulation of metal- and oxidative stress response, as well as cell surface engineering playing a crucial role therein. This review covers the state-of-the-art metal stress mitigation mechanisms prevalent in microalgae, and discusses putative and tested metabolic engineering approaches, aimed at further improvement of those biological processes. Finally, current research gaps and future prospects arising from use of transgenic microalgae for heavy metal phycoremediation are reviewed.

Ranjbar, Saeed (ORCID:0000000256518605)↗

A study to identify and compare airborne systems for in-situ measurements of launch vehicle effluents

An in-situ system for monitoring the concentration of HCl, CO, CO2, and Al2O3 in the cloud of reaction products that form as a result of a launch of solid propellant launch vehicle is studied. A wide array of instrumentation and platforms are reviewed to yield the recommended system. An airborne system suited to monitoring pollution concentrations over urban areas for the purpose of calibrating remote sensors is then selected using a similar methodology to yield the optimal configuration.

Thomas, T. J.↗

Hydrofoil controls outfall effluents in rivers and oceans

System, which consists of vertical semispan hydrofoil anchored in water bed and set at angle of attack with respect to ambient water flow, works by keeping pollutants concentrated within long trailing vortex generated by hydrofoil and either deflecting vortex away from sensitive regions or sweeping it from side to side for rapid dispersion.

Costen, R. C.↗

Portable solar radiometer measures stack-plume effluents

Radiometer features two optical arrangements: easy-to-aline pointing optical system that is boresighted to second radiometric optical system which utilizes four filters to select wavelengths. Four channel device uses Sun as background source and measures attenuation of solar radiation through plume.

Exton, R. J.↗

The effects of solid rocket motor effluents on selected surfaces and solid particle size, distribution, and composition for simulated shuttle booster separation motors

A series of three tests was conducted using solid rocket propellants to determine the effects a solid rocket plume would have on thermal protective surfaces (TPS). The surfaces tested were those which are baselined for the shuttle vehicle. The propellants used were to simulate the separation solid rocket motors (SSRM) that separate the solid rocket boosters (SRB) from the shuttle launch vehicle. Data cover: (1) the optical effects of the plume environment on spacecraft related surfaces, and (2) the solid particle size, distribution, and composition at TPS sample locations.

Jex, D. W.↗

Electrolytic pretreatment unit gaseous effluent conditioning

The electrolytic pretreatment of urine is an advanced process that eliminates the need for handling and storing the highly corrosive chemicals that are normally used in water reclamation systems. The electrolytic pretreatment process also converts the organic materials in urine to gases (N2 and O2) that can be used to replenish those lost to space by leakage, venting, and air lock operations. The electrolytic process is more than a pretreatment, since it decreases the urine solids content by approximately one third, thus reducing the load and eventual solids storage requirements of the urine processing system. The evolved gases from the pretreatment step cannot, however, be returned directly to the atmosphere of a spacecraft without first removing several impurities including hydrogen, chlorine, and certain organic compounds. A treatment concept was developed that would decrease the impurities in the gas stream that emanates from an electrolysis unit to levels sufficiently low to allow the conditioned gas stream to be safely discharged to a spacecraft atmosphere. Two methods were experimentally demonstrated that can accomplish the desired cleanup. The bases of the two methods are, repectively: (1) raw urine scrubbing and (2) silica gel sorption.

Colombo, G. V.↗