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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Radiative Forcing of the Lower Stratosphere over the Arctic by Light Absorbing Particles

Light absorbing particles (LAP), such as soot and dust, change the thermodynamic structure of the atmosphere and contribute to regional and global climate change. The lower stratosphere (LS) is particularly sensitive to the presence of LAP since the lifetime of particles in the LS may extend from months to years, in contrast to tropospheric lifetimes of at most a few days. The source of particles in the LS may be aircraft, meteorites or emissions from tropospheric sources. There has been a lack, however, of accurate, quantitative measurements made with sufficiently sensitive instruments. This limits our understanding of the origin and lifetime of aerosols in this region of the atmosphere. Here we present recent measurements in the Arctic UT/LS with a new, highly sensitive instrument that has detected black carbon (BC) mass concentrations of 20-1000 ng m(exp -3) that are 10-1000 times larger than those reported in previous studies and are at least 30 times larger than predicted masses based on fuel consumption by commercial aircraft that fly in these regions. Scattering and absorption of solar and terrestrial radiation by the particles in a layer from 8- 12 Km leads to a negative net forcing of -0.5 W sq m at the top of the atmosphere and 9C of heating in this layer during the average aerosol lifetime at these altitudes. The new measurements suggest that the influence of aircraft emissions have been underestimated or that aircraft may not be the only significant source of light absorbing particles in the UT/LS. The presence of these aerosols can cause local changes in the thermal structure of the lower stratosphere and a subsequent modification of stratosphere/tropopause exchange of gases and particles.

Baumgardner, D.↗

Transient Aircraft Soot Emissions Indicate That Steady-State Measurements Likely Underestimate Real-World, Take-Off Emissions: Time-Varying Aircraft Take-Off Emissions Indices Measured at Los Angeles International Airport

Aircraft engine emissions are unique among mobile pollution sources in that their impacts affect the local air quality near airports as well as upper tropospheric composition and climate over regional-to-hemispheric scales. Furthermore, air travel and its resulting emissions are expected to rebound from the recent COVID-related lows to increase dramatically over the next several decades. Given the multi-decade service lifetime of many commercial aircraft, it is critically important to quantitatively understand the real-world emissions coming from these engines in order to inform environmental assessment and modelling activities. Here, we present a detailed analysis of aircraft emissions during take-off operations at Los Angeles International Airport. The data were collected as part of the NASA Alternative Fuel Effects on Contrails and Cruise Emissions (ACCESS) project in May 2014, and the dataset is publicly available as described by Moore et al. [1]. In particular, we focus on the time-varying nature of the plume concentrations where clear differences in particle size and non-volatile particle fraction are observed during the early portion of the take-off plume relative to the later portion of the plume. We compare the transient emissions indices measured here to engine certification values in the International Civil Aviation Organization (ICAO) Emissions Databank, which suggests that steady-state measurements may underestimate the real-world, non-volatile particle emissions. The implications of this finding for modelling aircraft particle emissions will be discussed.

Richard H. Moore↗

Applications of beam-foil spectroscopy to atomic collisions in solids

Some selected papers presented at the Fourth International Conference on Beam-Foil Spectroscopy, whose results are of particular pertinence to ionic collision phenomena in solids, are reviewed. The topics discussed include solid target effects and means of surmounting them in the measurement of excited projectile ion lifetimes for low-energy heavy element ions; the electron emission accompanying the passage of heavy particles through solid targets; the collision broadening of X rays emitted from 100 keV ions moving in solids; residual K-shell excitation in chlorine ions penetrating carbon; comparison between 40 MeV Si on gaseous SiH4 targets at 300 mtorr and 40 MeV Si on Al; and the emergent surface interaction in beam-foil spectroscopy. A distinct overlap of interests between the sciences of beam-foil spectroscopy and atomic collisions in solids is pointed out.

Sellin, I. A.↗

Compact, variable sources on the sun at 2 centimeter wavelength

VLA observations of compact transient sources on the sun at 2 cm wavelength are presented. These sources have angular sizes of theta of about 5-25 arcsec, brightness temperatures of about 1-3 x 10 to the 5th K, and lifetimes ranging between a few minutes to several hours. The emission originates in regions of diffuse plage and quiet sun, where the photospheric magnetic fields are relatively weak (H of not greater than 100 G). In some cases the 2 cm radiation may be explained as the thermal bremsstrahlung of a dense plasma in the transition region. For other sources, the relatively high circular polarization suggests a nonthermal emission mechanism, such as the gyrosynchrotron radiation of mildly relativistic electron with a power-law spectrum.

Willson, Robert F.↗

Delta XTE Launch Activities and Scrub (Anomaly) at Cape Canaveral Air Station Complex 17

This NASA Kennedy Space Center video presents launch activities of the Delta X-ray Timing Explorer and scrub aboard a McDonnell Douglas Delta II rocket from Complex 17. The primary objective of the Delta XTE is to study time variability and broadband spectral phenomena in the X-ray emission from astronomical sources. XTE is designed for a required lifetime of two years with a goal of five years and will be inserted into a low-Earth circular orbit at an altitude of 600 km. The launch was postponed due to unfavorable wind conditions aloft.

Source record↗

Biomass Burning and the Production of Greenhouse Gases

Biomass burning is a source of greenhouse gases, carbon dioxide, methane, and nitrous oxide. In addition, biomass burning is a source of chemically active gases, including carbon monoxide, nonmethane hydrocarbons, and nitric oxide. These gases, along with methane, lead to the chemical production of tropospheric ozone (another greenhouse gas) as well as control the concentration of the hydroxyl radical, which regulates the lifetime of almost every atmospheric gas. Following biomass burning, biogenic emissions of nitrous oxide, nitric oxide, and methane are significantly enhanced. It is hypothesized that enhanced postburn biogenic emissions of these gases are related to fire-induced changes in soil chemistry and/or microbial ecology. Biomass burning, once believed to be a tropical phenomenon, has been demonstrated by satellite imagery to also be a regular feature of the world's boreal forests. One example of biomass burning is the extensive 1987 fire that destroyed more than 12 million acres of boreal forest in the People's Republic of China and across its border in the Soviet Union. Recent estimates indicate that almost all biomass burning is human-initiated and that it is increasing with time. With the formation of greenhouse and chemically active gases as direct combustion products and a longer-term enhancement of biogenic emissions of gases, biomass burning may be a significant driver for global change.

Levine, Joel S.↗

Studies for the Loss of Atomic and Molecular Species from Io

Continued effort is reported to improve the emission rates of various emission lines for atomic oxygen and sulfur. Atomic hydrogen has been included as a new species in the neutral cloud model. The pertinent lifetime processes for hydrogen in the plasma torus and the relevant excitation processes for H Lyman-alpha emission in Io's atmosphere are discussed.

Smyth, William H.↗

Measurement of Metastable Lifetimes of Highly-Charged Ions

The present work is part of a series of measurements of metastable lifetimes of highly-charged ions (HCIs) which contribute to optical absorption, emission and energy balance in the Interstellar Medium (ISM), stellar atmospheres, etc. Measurements were carried out using the 14-GHz electron cyclotron resonance ion source (ECRIS) at the JPL HCI facility. The ECR provides useful currents of charge states such as C(sup(1-6)+), Mg(sup(1-6)+) and Fe(sup(1-17)+). In this work the HCI beam is focused into a Kingdon electrostatic ion trap for measuring lifetimes via optical decays.

Smith, Steven J.↗

Modeling and Evaluation of the Global Sea-Salt Aerosol Distribution: Sensitivity to Emission Schemes and Resolution Effects at Coastal/Orographic Sites

One of the major sources of uncertainty in model estimates of the global sea-salt aerosol distribution is the emission parameterization. We evaluate a new sea-salt aerosol life cycle module coupled to the online multi-scale chemical transport model NMMB/BSC-CTM. We compare 5 year global simulations using five state-of-the-art sea-salt open-ocean emission schemes with monthly averaged coarse aerosol optical depth (AOD) from selected AERONET sun photometers, surface concentration measurements from the University of Miami's Ocean Aerosol Network, and measurements from two NOAA/PMEL cruises (AEROINDOEX and ACE1). Model results are highly sensitive to the introduction of sea-surface-temperature (SST)-dependent emissions and to the accounting of spume particles production. Emission ranges from 3888 teragrams per year to 8114 teragrams per year, lifetime varies between 7.3 hours and 11.3 hours, and the average column mass load is between 5.0 teragrams and 7.2 teragrams. Coarse AOD is reproduced with an overall correlation of around 0.5 and with normalized biases ranging from +8.8 percent to +38.8 percent. Surface concentration is simulated with normalized biases ranging from minus 9.5 percent to plus 28 percent and the overall correlation is around 0.5. Our results indicate that SST-dependent emission schemes improve the overall model performance in reproducing surface concentrations. On the other hand, they lead to an overestimation of the coarse AOD at tropical latitudes, although it may be affected by uncertainties in the comparison due to the use of all-sky model AOD, the treatment of water uptake, deposition and optical properties in the model and/or an inaccurate size distribution at emission.

Bias↗

Effect of Nitrogen Gas on the Lifetime of Carbon Nanotube Field Emitters for Electron-Impact Ionization Mass Spectrometry

The lifetime of a patterned carbon nanotube film is evaluated for use as the cold cathode field emission ionization source of a miniaturized mass spectrometer. Emitted current is measured as a function of time for varying partial pressures of nitrogen gas to explore the robustness and lifetime of carbon nanotube cathodes near the expected operational voltages (70-100 eV) for efficient ionization in mass spectrometry. As expected, cathode lifetime scales inversely with partial pressure of nitrogen. Results are presented within the context of previous carbon nanotube investigations, and implications for planetary science mass spectrometry applications are discussed.

Getty, Stephanie A.↗

Atmospheric sulfur hexafluoride - Sources, sinks and greenhouse warming

An estimate is obtained of worldwide production of SF6, from which a global emission rate is derived and extrapolated for the next 20 years. The atmospheric lifetime of SF6 is then estimated based on a known mechanism (e.g., photolysis and atmospheric oxidation) and/or on the mass balance method. Finally, the radiative forcing of SF6 is calculated based on recent laboratory IR absorption data, and the expected warming over the time period 1950-2010 is computed for several emission scenarios. Calculations showed that SF6 is 3 times more effective as a greenhouse gas compared to CFC 11 on a per-molecule basis. However, based on projected emission scenarios, the expected warming from SF6 through 2010 is small (0.004 C), compared to the warming from CO2 and other trace gases (0.8 C).

Ko, Malcolm K. W.↗

X-ray imaging - Supernova remnants

Consideration is given to imaging observations of supernova remnants (SNRs) obtained during the first year of the Einstein Observatory's operation. Inferences are drawn regarding models for stellar explosions, remnant evolution, neutron star formation and the interstellar medium. Because the X-ray emission traces the expanding shock boundary and dominates the radiative energy losses of an SNR over much of its lifetime, it can provide data on the possible collapsed remnants of the explosion, such as neutron stars and/or black holes. X-ray emission also allows a supernova shock to be used as a probe of interstellar medium structure. The imaging instrument aboard the Einstein satellite has been used to observe over 30 known Galactic remnants, and a similar number of objects in other galaxies, in the 0.15-4.5 keV band.

Helfand, D. J.↗

Does the Blazar Gamma-ray Spectrum Harden with Increasing Flux? - Analysis of Nine Years of EGRET Data

The Energetic Gamma Ray Experiment Telescope (EGRET) on the Compton Gamma Ray Observatory (CGRO) discovered gamma-ray emission from more than 67 blazars during its nine-year lifetime. We conducted an exhaustive search of the EGRET archives and selected all the blazars that were observed multiple times and were bright enough to enable a spectral analysis using standard powerlaw models. The sample consists of 18 flat-spectrum radio quasars (FSRQs), 6 low-frequency-peaked BL Lacs (LBLs) and 2 high-frequency-peaked BL Lacs (HBLs). We do not detect any clear pattern in'the variation of spectral index with flux. Some of the blazars do not show any statistical evidence for spectral variability. The spectrum hardens with increasing flux in a few cases. There is also evidence for a flux-hardness anticorrelation at lo\v fluxes in five blazars. The well observed blazars (3C 279,3C 273, PKS 0528-i-134, PKS 1622-297, PKS 0208- 512) do not show any overall trend in the long-term spectral dependence on flux, but the sample shows a mixture of hard and soft states. We observed spectral hysteresis at weekly timescales in all the three FSRQs for which data from flares lasting for 3 approx. 4 weeks were available. All three sources show a counterclockwise rotation despite the widely different flux profiles. Hysteresis in the spectral index vs. flux space has never been observed in FSRQs in gamma-rays at weekly timescales. itre analyze the observed spectral behavior in the context of various inverse-Compton mechanisms believed to be responsible for emission in the EGRET energy range. Our analysis uses the EGRET skymaps that were regenerated to include the changes in performance during the mission.

Nandikotkur, Giridhar↗

Atmospheric trends in methylchloroform and the global average for the hydroxyl radical

ALE-GAGE (Atmospheric Lifetime Experiment-Global Atmospheric Gases Experiment) data obtained over the seven-year period from July 1978 to June 1985 are presented and interpreted. The data, combined with knowledge of industrial emissions, are used in an optimal estimation inversion scheme to deduce a globally average methylchloroform atmospheric lifetime of 6.3(+ 1.2, - 0.9) years (1 sigma uncertainty) and a globally averaged tropospheric hydroxyl radical concentration of (7.7 + or - 1.4) x 10 to the 5th radicals/cu cm (1 sigma uncertainty). These results provide the most accurate estimates yet of the trends and lifetime of methylchloroform and of the global average for tropospheric hydroxyl radical levels.

Prinn, R.↗

Radiative lifetimes of the CN (A 2 Pi i) electronic state

Radiative lifetimes have been measured for CN (A 2 Pi i v-prime = 2...7). Ground-state radicals formed in the 193 nm photolysis of C2N2 and ClCN were excited to A 2 Pi i v-prime = 2...7 vibrational levels. The decay was monitored by following the fluorescence. Cascading effects were eliminated by working at low pressures and monitoring emission from a single vibrational band. Quenching rates and zero-pressure radiative lifetimes were obtained from Stern-Volmer plots. The lifetimes are significantly lower than previous measurements and theoretical calculations for vibrational states v-prime over 2.

Lu, Richang↗

The atmospheric lifetime experiment. I - Introduction, instrumentation, and overview

The Atmospheric Lifetime Experiment is designed to determine accurately the atmospheric concentrations of the four halocarbons CFCl3, CF2Cl2, CCl4, and CH3CCl3, and also of N2O with emphasis on measurement of their long-term trends in the atmosphere. Comparison of these concentrations and trends for the four halocarbons with estimates of their industrial emission rates then enables calculations of their global circulation rates and globally averaged atmospheric lifetimes. The experiment utilizes automated dual-column electron-capture gas chromatographs which sample the background air about 4 times daily at the following globally distributed sites: Adrigole, Ireland, Cape Meares, Oregon; Ragged Point, Barbados; Point Matatula, American Samoa, and Cape Grim, Tasmania. The climatology of these 'clean air' sites and their ability to describe the global air mass are reviewed. The instrumentation and methods for data acquisition and processing are then described. An overview of the data obtained and the trends derived during the 3-year period from July 1978 through June 1981 for each of the five species being measured is presented.

Prinn, R. G.↗

CO/d-3 Delta sub i to X-1 Sigma +/ fluorescence from photodissociation of CO2 by 923 A photons

Measurements of vacuum ultraviolet fluorescence from the photodissociation of CO2 by photons from a N IV line emission source at a wavelength of 923 A have revealed a second CO band system in addition to the expected emission bands. Spectra with time resolution were obtained and the fluorescence lifetime and the dependence of fluorescence intensity on CO2 pressure were measured. An analysis of this data has permitted the second band system to be identified as originating from CO(d-3 Delta sub i to X-1 Sigma +) transitions.

Phillips, E.↗