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At least 145 records · Page 8

Empirical Acoustic Source Model for Chemical Explosions in Air

Chemical explosions generate pressure disturbances in air that radiate as nonlinear shock waves near the source and transition into acoustic waves with distance. Because low-frequency acoustic waves generally travel large distances without significant loss of energy, they are often used for explosion monitoring and yield estimation. However, quantitative relationships between acoustic energy and explosion yields are required for accurate yield estimation. Here, we develop an empirical acoustic source model for chemical explosions from experimental data. The empirical model returns the acoustic pressure waveform for the detonation of 1 kg of trinitrotoluene, which is conventionally used to represent the explosive release of 4.184 MJ of explosion energy. The full-waveform model can be used to predict acoustic signals for an arbitrary yield of a high-explosive detonation based on the standard scaling law and to estimate acoustic energies in a specific frequency range. We evaluate the accuracy of the acoustic source model independently by estimating the yield of other explosive events that are not included in the model development. Finally, statistical characteristics of the model and their implications for the uncertainty quantification of estimated yields are discussed.

58 GEOSCIENCES↗

Shear-Wave Radiation Patterns from Explosive and Earthquake Sources in Scattering, Heterogeneous Media

Distinguishing whether a seismic event is an earthquake or an explosion is a core problem in explosion monitoring. For simplistic models, earthquakes produce a predictable S-wavefield based on their radiation pattern, while an explosion produces no S-wavefield. However, observations from nuclear tests show that explosions can produce significant S-wave energy on both horizontal components. We perform numerical experiments using SPECFEM to constrain when an S-wavefield generated from an explosion might differ from one produced by an earthquake. We generate the S-wavefield for our explosions by placing the source location within a small region consisting of large velocity heterogeneities. For the 2D cases investigated here, a crucial condition is that the size of the region of heterogeneities must be much smaller (approximately 1/12th) than the minimum wavelength of the wavefield for our simulation setups. We investigate both isotropic heterogeneities and anisotropic heterogeneities. Initial results demonstrate that the heterogeneous region lowers the P/S amplitude ratios of an explosion. The presence of strong anisotropic heterogeneities near the source can also produce an S-wavefield with similar amplitudes to the P-wavefield. Lastly, we show that S-wave polarization angles vary as a function of azimuth and distance for explosive sources in the presence of small-scale heterogeneities.

58 GEOSCIENCES↗

Estimating Explosion Yields Using Moment Tensor Solutions and Seismic Moment

We report seismic moment, a measurable and well-understood quantity of seismic sources, is used to estimate the yield of explosions. Application of such a method in the past, as in the manner of m b -derived yields, has been complicated by the effect of variations in the explosion working point, depth, and secondary source effects (such as spalling and tectonic release) on the observed moment. We start using the full (six-element) moment tensor solution, which can capture the relevant source physics and, at least in theory, better isolate the primary explosion source. The moment-to-yield ratio is then estimated using an explosion source model which, provided with emplacement conditions, can relate the two parameters. We discuss the major sources of uncertainty associated with the method, and calibrate it with chemical and nuclear explosions at the Nevada National Security Site. We then apply the method to published moment tensor solutions for the six declared North Korean nuclear explosions that occurred between 2006 and 2017. The results are mostly consistent with other yield estimates made using a variety of high-frequency methods. This technique is a new approach to estimating explosive yield and simple to implement, as much of the complexity is captured by the source models.

58 GEOSCIENCES↗

Pushing core-collapse supernovae to explosions in spherical symmetry. I. The model and the case of SN 1987A

We report on a method, PUSH, for artificially triggering core-collapse supernova explosions of massive stars in spherical symmetry. We explore basic explosion properties and calibrate PUSH to reproduce SN 1987A observables. Our simulations are based on the GR hydrodynamics code AGILE combined with the neutrino transport scheme isotropic diffusion source approximation for electron neutrinos and advanced spectral leakage for the heavy flavor neutrinos. To trigger explosions in the otherwise non-exploding simulations, the PUSH method increases the energy deposition in the gain region proportionally to the heavy flavor neutrino fluxes. We explore the progenitor range 18–21 M{sub ⊙}. Our studies reveal a distinction between high compactness (HC; compactness parameter ξ{sub 1.75}>0.45) and low compactness (LC; ξ{sub 1.75}<0.45) progenitor models, where LC models tend to explode earlier, with a lower explosion energy, and with a lower remnant mass. HC models are needed to obtain explosion energies around 1 Bethe, as observed for SN 1987A. However, all the models with sufficiently high explosion energy overproduce {sup 56}Ni and fallback is needed to reproduce the observed nucleosynthesis yields. {sup 57–58}Ni yields depend sensitively on the electron fraction and on the location of the mass cut with respect to the shell structure of the progenitor. We identify a progenitor and a suitable set of parameters that fit the explosion properties of SN 1987A assuming 0.1 M{sub ⊙} of fallback. We predict a neutron star with a gravitational mass of 1.50 M{sub ⊙}. We find correlations between explosion properties and the compactness of the progenitor model in the explored mass range. However, a more complete analysis will require exploring of a larger set of progenitors.

79 ASTRONOMY AND ASTROPHYSICS↗

Discrimination of Small Earthquakes and Buried Single-Fired Chemical Explosions at Local Distances (<150 km) in the Western United States from Comparison of Local Magnitude ( M L ) and Coda Duration Magnitude ( M C )

Seismologists distinguish underground nuclear explosions from more commonly occurring earthquakes using moment tensor inversion, high-frequency P/S amplitude ratios, m b :M s comparisons, and P–pP differential travel times. These methods are generally successful for large seismic events (M >3-4) well recorded at regional-to-teleseismic distances (>150 km); however, it is unclear whether they can be modified to work for small events (M <3) well recorded only at local distances (<150 km). Here, we evaluate a recently proposed, local-distance seismic source discriminant—the difference between local magnitude (M L ) and coda duration magnitude (M C )—using seismograms of earthquakes and buried, single-fired chemical explosions recorded in three regions of the western United States. The quantity M L –M C was previously found to be sensitive to source depth, effectively discriminating mine blasts, induced earthquakes, and very shallow tectonic earthquakes from deeper crustal earthquakes. In this study, we report the first evaluation of M L –M C as a depth discriminant using data from buried, single-fired explosions that, unlike the seismic sources studied earlier, are good analogs for underground nuclear explosions. We find that even when using generic, uncalibrated methods of assigning magnitudes, M L –M C separates single-fired explosions and earthquakes. The area under the receiver operating characteristic curve is 0.92 for 19 explosions and 14 earthquakes in Washington, 0.90 for 22 explosions and 90 earthquakes in Wyoming, and 0.99 for three explosions and 149 earthquakes in Nevada. Finally, M L :M C comparisons have the potential to enhance discrimination based on high-frequency P/S amplitudes ratios—which perform less well at local than regional distances—because the two metrics have complementary sensitivities.

58 GEOSCIENCES↗

A Preliminary Explosion Seismic Spectral Model for Saturated/Hard Rock

This short technical report describes a new seismic spectral model for chemical and nuclear explosions in saturated and/or hard rock. Results from the Source Physics Experiments (SPE) indicate that existing explosion spectral models can be poor fits to small and/or over-buried explosions. Here we develop a preliminary improved explosion model to fit both SPE and historic nuclear explosion data. The model is based on revising the Mueller and Murphy (1972) and Denny and Johnson (1991) seismic spectral models. A FORTRAN code was developed to provide the spectral models in SAC format for use in explosion monitoring applications such as detection and yield estimation. This model should be considered preliminary and work is underway to better generalize and expand the model to include explosions in dry porous and/or soft rock media and to better fit explosion S-waves.

58 GEOSCIENCES↗

Final Hazard Classification Request for Not More Than 5 Percent Explosives in Solvent Mixtures

This report requests a non-explosive hazard classification of trace explosives in solution. UN Series 1 and 2 explosive hazard classification tests were performed on a simulated worst-case waste stream of five (5) percent by weight of explosive (CL-20) dissolved in a solvent solution (acetone) for transport and storage. The explosive hazard classification test results reported the sample to be non-explosive and the report provides the necessary data for the Department of Transportation to determine and assign the appropriate hazard class for five (5) percent or less of trace explosive in solvent solutions when being shipped and/or stored. Based on the test results, this report requests that the Department of Transportation assign a hazard class of 3, Desensitized explosive liquid, n.o.s. for this type of substance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Aftershocks of a Chemical Explosion in Granite from the Source Physics Experiment Phase I

The Source Physics Experiment (SPE) is a multiphase experiment to better understand explosion source physics and thereby improve explosion monitoring. The rst phase (Phase I) examined the explosion source in a hard-rock medium and took place in a granite outcrop called the Climax Stock section of the Nevada National Security Site (NNSS). This series of chemical explosions are called the Wet Granite Geology (WGG) events, but are usually referred to simply as the SPE events (i.e., SPE-1, SPE-2, etc.). Event information for the chemical explosions is given in Table 1. The study of explosion aftershocks can aid in understanding of in-situ stresses and be used as a discriminant for earthquakes [Ford and Walter, 2010]. Sweeney and Harben reported no observed aftershocks for SPE-1 and -2, respectively. They calculated a minimum magnitude of observation based on the noise oor of the seismic array and predicted at least one or two events in the week after the events using the hard-rock aftershock model from Ford and Labak. Possible explanations for the null observation ranged from instrumental - poor seismometer coupling, to physical - the shallow depth of burial was unable to access the deep tectonic stress that causes some explosion aftershocks. We extend the analysis of Sweeney and Harben to the largest of the SPE Phase I chemical explosions, SPE-5, which was approximately a 5 tonne TNT-equivalent shot at 76.5 m depth. This event registered as an M L 2 on the University of Nevada, Reno seismic network and should produce a measurable aftershock sequence.

58 GEOSCIENCES↗

LLNL Explosives Anisotropy Research

Lawrence Livermore National Laboratory scientists and engineers led a multi-institutional team in executing a series of high explosives tests that successfully demonstrated fundamental principles of anisotropy, a possible enabler for improved weapon and munition safety. Working under snowy and frigid conditions on Idaho’s Snake River Plain, a 13-member team from LLNL carried out 52 explosives shots over four days in mid-November at the Idaho National Laboratory’s (INL) National Security Test Range (NSTR) to complete the study. The broader anisotropy (ANISO) team included high explosives handlers and volunteers from INL, Los Alamos National Laboratory, Marine Raiders from the Marine Special Operations Command and members of the U.S. Special Operations Command. The purpose of the study was to explore theoretical methods of creating anisotropic explosives — explosives that perform differently depending on the direction the detonation wave moves through the explosive — by engineering certain physical features in the charges and obtaining basic data from testing. The work is part of an overall effort by the Lab to develop anisotropic explosives that could be used in munitions to reduce the severity and lethality of an unintended detonation without sacrificing performance. The data gathered from the study will be used to design and construct follow-on experiments at LLNL’s High Explosives Applications Facility (HEAF) and validate computer models for future anisotropic assemblies.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Totally confined explosive welding

The undesirable by-products of explosive welding are confined and the association noise is reduced by the use of a simple enclosure into which the explosive is placed and in which the explosion occurs. An infrangible enclosure is removably attached to one of the members to be bonded at the point directly opposite the bond area. An explosive is completely confined within the enclosure at a point in close proximity to the member to be bonded and a detonating means is attached to the explosive. The balance of the enclosure, not occupied by explosive, is filled with a shaped material which directs the explosive pressure toward the bond area. A detonator adaptor controls the expansion of the enclosure by the explosive force so that the enclosure at no point experiences a discontinuity in expansion which causes rupture. The use of the technique is practical in the restricted area of a space station.

Bement, L. J.↗

Surface waves generated by shallow underwater explosions

Surface water waves generated by surface and near surface point explosions are calculated. Taking the impulse distribution imparted at the water surface by the explosion as the overriding mechanism for transferring energy of the explosive to surface wave motion, the linearized theory of Kranzer and Keller is used to obtain the wave displacement in the far field. The impulse distribution is obtained by integrating the pressure wave over an appropriate time interval on a horizontal surface just beneath the undisturbed water surface. For surface explosions, a modified form of the similarity method first used by Collins and Holt is used to obtain the flow field. In the case of submerged explosions, the flow field is estimated by making necessary modifications to Sedov's similarity solution to account for the venting that accompanies the interaction of the leading (blast) wave with the ocean surface. Surface waves generated by a charge at six depths of placement (0.15 m, 0.30 m, 0.61 m, 0.91 m, 1.37 m, 3.05 m) are considered in addition to surface explosions. The results seem to support the existence of an upper critical depth phenomenon (of the type already established for chemical explosions) for point (nuclear) explosions.

Falade, A.↗

Explosive Welding of Aluminum, Titanium and Zirconium to Copper Sheet Metal

The main material properties affecting the explosive weldability of a certain metal combination are the yield strength, the ductility, the density and the sonic velocity of the two metals. Successful welding of the metal combination depends mainly on the correct choice of the explosive welding parameters; i.e., the stand off distance, the weight of the explosive charge relative to the weight of the flyer plate and the detonation velocity of the explosive. Based on the measured and the handbook values of the properties of interest, the explosive welding parameters were calculated and the arrangements for the explosive welding of the Al alloy 6061-T6, titanium and zirconium to OFHC copper were determined. The relatively small sheet metal thickness (1/8") and the fact that the thickness of the explosive layer must exceed a certain minimum value were considered during the determination of the explosive welding conditions. The results of the metallographic investigations and the measurements of the shear strength at the interface demonstrate the usefulness of these calculations to minimize the number of experimental trials.

Hegazy, A. A.↗

Explosive assembly and method

An explosive assembly includes a first explosive unit having a first longitudinal end portion having a first mechanical coupling feature, a second explosive unit having a second longitudinal end portion having a second mechanical coupling feature, and a tubular connector having a first end portion mechanically coupled to the first mechanical coupling feature and a second end portion mechanically coupled to the second mechanical coupling feature, such that the first explosive unit, the connector, and the second explosive unit are connected together end-to-end along a common longitudinal axis. Each explosive unit can contain a high explosive material and a detonator, and the connector can comprise a detonation control module electrically coupled to the detonators and configured to detonate the explosive units.

Mace, Jonathan L.↗

A Hydrogen Ignition Mechanism for Explosions in Nuclear Facility Piping Systems

Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein. Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions may occur. Pipe ruptures in nuclear reactor cooling systems were attributed to hydrogen explosions inside pipelines, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents, an ignition source for hydrogen was not clearly demonstrated, but these accidents demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. A new theory to identify an ignition source and explosion cause is presented here, and further research is recommended to fully understand this explosion mechanism.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

2023 Annual Explosives Inventory Completion

The 2023 Lawrence Livermore National Laboratory (LLNL) annual explosives inventory was executed from May 18, 2023 to September 27, 2023 and was verified for accuracy effective September 28, 2023 following the LLNL Explosive Materials Inventory Plan. This year’s annual inventory includes changes incorporated based on the Department of Energy (DOE) Office of Inspector General (OIG) Audit Report DOE-OIG-20-50, The Department of Energy’s Storage and Disposition of Explosives Material at Selected Sites, dated July of 2020. Based on the associated recommendations, explosives at DOE and National Nuclear Safety Administration (NNSA) sites are considered "sensitive personal property" and applicable inventories must comply with 41 CFR 109, Personal Property Management. This regulation adds additional stipulations which require the annual inventory to include accountability of the total site inventory. In addition, the inventory must be performed by personnel other than the property owner, or alternatively must include independent verification. The development of the inventory plan was agreed to by the LLNL Explosives Safety Committee in conjunction with the LLNL Property and Business Division Leader. The LLNL Explosive Materials Inventory Plan was reviewed and approved by the DOE Explosives Safety Committee Chair on May 17, 2023 and by the NNSA Property Management Office on May 25, 2023.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

3D Time-Lapse Electrical Resistivity Imaging of Rock Damage Patterns and Gas Flow Paths Resulting from Two Underground Chemical Explosions

Abstract Rock damage from underground nuclear explosions (UNEs) has a strong influence on sub-surface gas movement and on seismic waveform characteristics, both of which are used to detect UNEs. Although advanced numerical simulation capabilities exist to predict rock damage patterns and corresponding detection signals, those predictions are dependent on (generally) unknown properties of the host rock. For example, the effects of in-situ mechanical heterogeneities on the explosively generated damage/fractures that provide gas flow pathways to the surface are not well understood, due largely to the difficulty in accessing and characterizing the near-source region. In this paper we demonstrate the emerging use of electrical resistivity tomography (ERT) for imaging rock damage and gas flow patterns resulting from two relatively small-scale underground chemical explosions. Pre-explosion ERT and crosshole seismic imaging revealed a natural fracture zone within the test bed. Post-explosion imaging revealed that the damage zone was non-symmetric and was focused primarily within the pre-existing fracture zone, located 10 m above the first explosion and 5 m above the second explosion. Time-lapse ERT imaging of heated air injected into the detonation borehole revealed the primary gas flow paths to be within the upper margin of the same primary damage zone. These results point to the utility of ERT imaging for understanding rock damage and gas flow patterns under experimental conditions, and to the importance of understanding the effects of geologic heterogeneity on UNE detection signals, particularly gas surface breakthrough times.

58 GEOSCIENCES↗

A Window on Surface Explosions: Tartaric Acid on Cu(110)

Autocatalytic reaction mechanisms are observed in a range of important chemical processes including catalysis, radical-mediated explosions, and biosynthesis. Because of their complexity, the microscopic details of autocatalytic reaction mechanisms have been difficult to study on surfaces and heterogeneous catalysts. Autocatalytic decomposition reactions of S,S- and R,R-tartaric acid (TA) adsorbed on Cu(110) offer molecular-level insight into aspects of these processes, which until now, were largely a matter of speculation. The decomposition of TA/Cu(110) is initiated by a slow, irreversible process that forms vacancies in the adsorbed TA layer, followed by a vacancy-mediated, explosive decomposition process that yields CO{sub 2} and small hydrocarbon products. Initiation of the explosive decomposition of TA/Cu(110) has been studied by measurement of the reaction kinetics, time-resolved low energy electron diffraction (LEED), and time-resolved scanning tunneling microscopy (STM). Initiation results in a decrease in the local coverage of TA and a concomitant increase in the areal vacancy concentration. Observations of explosive TA decomposition on the Cu(651)S surface suggest that initiation does not occur at structural defects in the surface, as has been suggested in the past. Once the vacancy concentration reaches a critical value, the explosive, autocatalytic decomposition step dominates the TA decomposition rate. The onset of the explosive decomposition of TA on Cu(110) is accompanied by the extraction of Cu atoms from the surface to form a (±6,7; {-+}2,1) overlayer that is readily observable using LEED and STM. The explosive decomposition step is second-order in vacancy concentration and accelerates with increasing extent of reaction.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

An updated technique to obtain explosive kinetics data on microsecond timescales

There are few techniques available for chemists to obtain time-to-explosion data with known temperature inputs at the early stages of the design and synthesis of new explosives. In the 1960s, a technique was developed to rapidly heat milligram-quantities of confined explosives to ~1000 K on microsecond timescales. Wenograd loaded explosives inside stainless steel hypodermic needles, connected them to a fireset and rapidly discharged a capacitor through the steel. He obtained the temperature by measuring the needle resistance in a Wheatstone bridge arrangement and the time to explosion from a needle rupture. However, owing to the narrow-gauge needles used in the original research, the experiment was only possible with melt-castable explosives; it was never replicated, and modern diagnostics are now available with advances beyond the 1960s. Here, we report the development of the High Explosives Initiation Time (HEIT) test, which utilizes a 250 J pulsed power system to heat the needles. This work extends the Wenograd approach by using optical diagnostics, computational modeling, and advanced techniques to measure needle resistance and needle rupture. Preliminary rate information for pentaerythritol tetranitrate (PETN) will be presented.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗