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At least 145 records · Page 8

Flammability of Epoxy Resins Containing Phosphorus

As part of a program to develop fire-resistant exterior composite structures for future subsonic commercial and general aviation aircraft, flame-retardant epoxy resins are under investigation. Epoxies and their curing agents (aromatic diamines) containing phosphorus were synthesized and used to prepare epoxy formulations. Phosphorus was incorporated within the backbone of the epoxy resin and not used as an additive. The resulting cured neat epoxy formulations were characterized by thermogravimetric analysis, propane torch test, elemental analysis, microscale combustion calorimetry, and fire calorimetry. Several formulations showed excellent flame retardation with phosphorous contents as low as 1.5% by weight. The fracture toughness and compressive strength of several cured formulations showed no detrimental effect due to phosphorus content. The chemistry and properties of these new epoxy formulations are discussed.

Flammability studies↗

Effects of Atmospheric Environment on Flammability of Fabrics and Carbonaceous Solids

In this chapter and in the others to follow, an attempt will be made to outline empirical studies which shed some light on the effects of internal atmospheric conditions on the fire hazard in space cabins. The results of these experiments will be interpreted, whenever possible, in light of the theoretical considerations outlined in Chapter 1.

Roth, Emanuel M.↗

Flammability testing conducted in support of Apollo 13

In support of the Apollo 13 investigation of the oxygen tank failure, flame propagation rates were determined for Teflon insulation in cryogenic and ambient temperature oxygen for upward, downward, and zero g burns. The propagation rates depended heavily on configuration and varied from 4.8 to 10.9 cm/sec for upward one g burns to 0.48 cm/sec for zero g burns. In addition to the flame propagation rates, tests were conducted to determine if Teflon burning in cryogenic oxygen could ignite metals (promoted ignition) with which it came in contact. Tests conducted on various metal alloys used in the oxygen tank indicated that most of the alloys could be ignited by burning Teflon in certain configurations. After the propagation rates and promoted metal ignitions had been evaluated, a test was conducted on a quantity gauge and wire harness used in the oxygen tank to determine if flame propagation to the tank wall was possible. Propagation of the wire bundle after ignition resulted in a catastrophic failure of the test vessel in the area of the quantity gauge.

Leger, L. J.↗

Flammability control for electrical cables and connectors

Technique of covering fire-hazardous sections of electrical wiring with fireproof materials prevents fires from spreading in oxygen-enriched atmospheres and eliminates use of heavy metal enclosures. Materials used to cover potting on connectors and ground terminals are made from Teflon-coated Beta cloth and Fluorel, a nonflammable fully-saturated polymer.

Wick, W. O.↗

Non-flammable elastomeric fiber from a fluorinated elastomer and containing an halogenated flame retardant

Flame retardant elastomeric compositions are described comprised of either spandex type polyurethane having incorporated into the polymer chain halogen containing polyols, conventional spandex type polyurethanes in physical admixture with flame retardant additives, or fluoroelastomeric resins in physical admixture with flame retardant additives. Methods are described for preparing fibers of the flame retardant elastomeric materials and articles of manufacture comprised of the flame retardant clastomeric materials and non elastic materials such as polybenzimidazoles, fiberglass, nylons, etc.

Howarth, J. T.↗

The 737 aircraft flammability testing

The FAA requested approximately 20 component and full-scale tests in a 737 fuselage to provide validation data or indicate changes that need to be made to a fire math model (Dayton Aircraft Cabin Fire Model) developed for the FAA. Some preliminary tests were conducted to evaluate the adequacy of planned instrumentation. The objectives of the program were met in that it was verified that propagation of a fire could be determined from the sequential response of thermocouples located on a test specimen(such as a seat), and continuous weighing of the specimen during the test was accomplished. Two differenct techniques for measuring smoke density were found to be comparable.

Bricker, R. W.↗

Airport flammability, full scale fire tests

The primary objectives of the fire tests are: (1) conduct full scale test with 737 fuselages by the end of 1980; (2) demonstrate evacuation time increase to five minutes minimum; (3) show that exterior fire will not penetrate an intact cabin for five minutes; (4) show that closed cabin will not have excess smoke or temperatures above 400 F; and (5) demonstrate that fire in cabin opening will not propagate throughout cabin. The test program has three phases. A test schedule and status of required materials are presented.

Bricker, R. W.↗

Non-flammable polyimide materials for commercial application

Thermally-stable, fire-resistant polyimide foams developed for use as fire protection in aircraft, spacecraft and ground applications are presented. Polyimide precursors, synthesized by the reaction of 3, 3', 4, 4'-benzophenone tetracarboxylic acid dianhydride with a mixture of two diamines, can be processed into foams by indirect or direct heating techniques. Flexible resilient foams and thermal acoustical foams produced by the microwave heating of polyimide precursors are shown to conform to requirements for aircraft seating foams and thermal and acoustical insulation materials, respectively. Rigid polyimide foams reinforced by carbon mat, chopped carbon mat and chopped glass strand fillers and prepared by the microwave heating of a continuous mat, followed by its compression, or by filling a honeycomb structure with low density foam, are found to exhibit outstanding fire resistance and have mechanical properties approaching those desired for structural materials.

Gagliani, J.↗