Search NASA⌕ Search

SEARCH · Search NASA

Results for “fuel blending”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS2000

Thermophysics Characterization of Kerosene Combustion

A one-formula surrogate fuel formulation and its quasi-global combustion kinetics model are developed to support the design of injectors and thrust chambers of kerosene-fueled rocket engines. This surrogate fuel model depicts a fuel blend that properly represents the general physical and chemical properties of kerosene. The accompanying gaseous-phase thermodynamics of the surrogate fuel is anchored with the heat of formation of kerosene and verified by comparing a series of one-dimensional rocket thrust chamber calculations. The quasi-global combustion kinetics model consists of several global steps for parent fuel decomposition, soot formation, and soot oxidation, and a detailed wet-CO mechanism. The final thermophysics formulations are incorporated with a computational fluid dynamics model for prediction of the combustor efficiency of an uni-element, tri-propellant combustor and the radiation of a kerosene-fueled thruster plume. The model predictions agreed reasonably well with those of the tests.

Wang, Ten-See↗
NASA NTRS2001

Thermophysics Characterization of Kerosene Combustion

A one-formula surrogate fuel formulation and its quasi-global combustion kinetics model are developed to support the design of injectors and thrust chambers of kerosene-fueled rocket engines. This surrogate fuel model depicts a fuel blend that properly represents the general physical and chemical properties of kerosene. The accompanying gaseous-phase thermodynamics of the surrogate fuel is anchored with the heat of formation of kerosene and verified by comparing a series of one-dimensional rocket thrust chamber calculations. The quasi-global combustion kinetics model consists of several global steps for parent fuel decomposition, soot formation, and soot oxidation and a detailed wet-CO mechanism to complete the combustion process. The final thermophysics formulations are incorporated with a computational fluid dynamics model for prediction of the combustion efficiency of an unielement, tripropellant combustor and the radiation of a kerosene-fueled thruster plume. The model predictions agreed reasonably well with those of the tests.

Wang, Ten-See↗
NASA NTRS1999

Initial Observations on the Burning of an Ethanol Droplet in Microgravity

Combustion of liquid ethanol represents an important system both from fundamental and practical points of view, Ethanol is currently being used as an additive to gasoline in order to reduce carbon monoxide and particulate emissions as well as to improve the fuel octane rating. A detailed physical understanding of liquid ethanol combustion is therefore necessary to achieve an optimal performance of such fuel blends in practical conditions. Ethanol is also a relatively simple model compound suitable for investigation of important combustion characteristics typical of more complex fuels. In particular, ethanol has been proposed for studies of sooting behavior during droplet burning. The sooting nature of ethanol has pressure sensitivities similar to that of n-heptane, but shifted to a higher range of pressures (1-3 atm). Additionally, liquid ethanol is miscible with water produced during its combustion forming mixtures with azeotropic behavior, a phenomenon important for understanding multi-component, liquid fuel combustion. In this work, we present initial results obtained in a series of recent space-based experiments and develop a detailed model describing the burning of ethanol droplet in microgravity.

Kazakov, Andrei↗
NASA NTRS1957

Preliminary investigation of the altitude performance of pentaborane and a pentaborane : JP-4 blend in an experimental 9.5-inch-diameter tubular combustor

A preliminary investigation was conducted to determine the altitude performance of pentaborane and a blend fuel of 64.2 percent pentaborane in JP-4 fuel in a tubular combustor of a current production type turbojet engine. A combustor was developed that was 4 inches shorter than standard. It contained a porous wire-cloth liner barrel and dome and an air-atomizing fuel nozzle. Deposits on the liner barrel and dome were virtually nonexistent. The combustion efficiency of 90 to 94 percent for pentaborane and approximately 90 percent for the blend. Outlet temperature profiles were marginal; however, the developed combustor provided lower pressure losses than obtained in conventional combustors.

COMBUSTION - TURBINE ENGINES↗
DOE OSTI2025

Residential Home Decarbonization Using Advanced Micro-CHP

An efficient micro-combined heat and power (CHP) prototype was developed to provide heat and electricity for single-family homes and light commercial buildings. The unit can be installed independently at the point of energy consumption. Consequently, it enables cost-effectively and flexibly matching heat and electrical loads, simplifying distribution and installation processes, and recovering and storing waste heat as hot water. The analyzed results show that the micro-CHP using natural gas as fuel achieves 10.68%–32.80% CO2 reduction in the selected five home applications. The potential effect of H2 on decarbonization of these home was also evaluated, finding that the micro-CHP using a blended fuel with H2 and natural gas can further reduce CO2 emissions. However, the 50% CO2 reduction in the micro-CHP requires at least 70%–90% of H2 in the blend with natural gas. Overall, the micro-CHP technology demonstrates a solid potential to accelerate micro-CHP adoption in residential and light commercial markets, thereby promoting broader micro-CHP acceptance and use in the future for building decarbonization.

Gao, Zhiming [ORNL] (ORCID:0000000271397995)↗
DOE OSTI2023

Simulation of a rapid compression machine for evaluation of ignition chemistry and soot formation using gasoline/ethanol blends

Due to the projected decline of demand for gasoline in light duty engines and the advent of ethanol as a green fuel, the use of gasoline/ethanol blend fuels in heavy duty applications are being investigated as they are projected to have lower cost and lower lifecycle green house gas (GHG) emissions. In heavy duty engines, the primary mode of combustion is mixing controlled combustion where wide range of mixture conditions (equivalence ratio) exist. Soot emissions of these fuels in richer conditions are not well understood. The goal of this research is to evaluate some commercially available soot modeling codes for the particulate matter emissions from gasoline/ethanol fuel blends, especially at fuel rich conditions. A Rapid Compression Machine (RCM) is modeled in a three-dimensional numerical simulation using CONVERGE computational software using a reduced chemical kinetic mechanism with SAGE chemistry solver and a RANS k-ϵturbulence model with a sector model including the creviced piston. The creviced piston is used in the experimental setup to reduce boundary layer effects and to maintain a homogeneous core in the reaction cylinder. Computational fluid dynamics simulations are conducted for different gasoline-ethanol fuel blends from E10 (10% ethanol v/v) to E100. The fuel blend is modeled as a surrogate mixture of toluene, iso-octane, n-heptane for gasoline content, and ethanol. The computational results were validated against experimental results using pressure measurements and laser extinction diagnostics. Different soot models are investigated to evaluate their capability of predicting the sooting tendencies of fuel blends, especially in richer conditions experienced during mixing-controlled combustion. The experimental combustion characteristics such as the ignition delay of different blends of fuel are reasonably well predicted. The Particulate Size Mimic (PSM) model accurately predicts the soot generation characteristics of the different fuels, but the Hiroyasu-NSC model falls short in this regard. For accurate prediction of soot with the PSM model, the thermodynamic conditions during combustion must be accurately modeled. While the current computational modeling tools can produce accurate results for the prediction of particulate matter emissions, there is much work to be done in improving our understanding of the underlying fundamental processes.

Energy & Fuels↗
DOE OSTI2023

Direct Utilization of Pure and Denatured Ethanol in Metal Supported Solid Oxide Fuel Cells

Metal supported solid oxide fuel cells (MS-SOFC) are integrated with internal reforming catalyst for direct utilization of ethanol to generate electricity. MS-SOFCs are operated up to 500 h at 700°C, with water-ethanol blend fuel using high-purity ethanol and denatured ethanol. Performance and durability with denatured ethanol varies dramatically with the composition of the denaturant. Cells operated with three denatured ethanol fuels containing small amount of methanol, isopropanol, and denatonium benzoate demonstrate similar and relative stable performance after stabilization, suggesting that these fuels are fit for MS-SOFC operation. No or minimum carbon deposits are observed on the high entropy alloy-based reforming catalyst layer. Denatured ethanol containing gasoline and toluene leads to fast degradation. Here, MS-SOFCs are promising for direct utilization of denatured ethanol, offering a path to rapid-start, carbon-neutral operation with widely-available fuels.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2025

A theoretical kinetic study of ĊH 3 + ṄH 2 : From electronic structure to NH 3 /CH 4 combustion modelling implications

Carbon–nitrogen interaction reactions play an important role in governing the reactivity of ammonia blended fuels. However, there remains uncertainties regarding their detailed reaction pathways and rate constants, hampering the development of high-fidelity chemical kinetic models. In this study, the kinetics of ĊH 3 + ṄH 2 , a key C–N interaction reaction in ammonia/methane blend combustion have been investigated. The potential energy surface has been explored using the high-level ANL0F method, yielding highly accurate stationary point energies that agree with ATcT values within 0.1 kcal mol –1 . Variable reaction coordinate transition state theory is used to treat the barrierless association and decomposition reaction channels, based on directly sampled radical-radical interaction energies at the CASPT2-F12(2e,2o)/cc-pVTZ-F12 level of theory. The minimum transitional mode numbers of states obtained are then coupled with the RRKM/master equation to calculate temperature- and pressure-dependent rate constants. Our a priori calculations capture available experimental measurements from the literature very well. The calculated rate constants have been incorporated into an NH 3 /CH 4 chemical kinetic model currently under development at the University of Galway. The effect of the updated kinetic data for ĊH 3 + ṄH 2 on model predicted NH 3 /CH 4 fuel reactivity is elucidated.

ab initio↗
DOE OSTI2023

Model predictive control of mixing controlled compression ignition operation for low reactivity fuels

Using gasoline or other low reactivity fuels with a pilot injection or port fuel injection in a compression ignition engine has shown great potential in reducing NOx emissions while keeping high thermal efficiency compared to diesel. However, excessive combustion noise is caused by a high maximum pressure rise rate in the cylinder due to the higher fractions of premixed charge of the low-reactivity fuel. This noise can result in structural damage to engine components and as such, combustion noise limits the range of the operating parameters and makes the control of such engines challenging. In this study, a simulation environment was built up in MATLAB/Simulink leveraging a physics-based zero-dimension combustion model to capture the in-cylinder pressure time traces as well as metrics relevant to thermal efficiency and combustion noise. Here, in order to also facilitate the control of emissions, machine learning models were investigated to capture NOx emissions. A kernel-based extreme learning machine (K-ELM) performed best and had a coefficient of correlation (R-squared) of 0.998. The combustion and NOx emission models are valid for not only conventional gasoline fuel but also oxygenated alternative fuel blends at three different pilot injection strategies. In order to track key combustion metrics while keeping noise and emissions within constraints, a model predictive control (MPC) was applied for a compression ignition engine operating with a range of potential fuels and fuel injection strategies. The MPC is validated under different scenarios, including a load step change, fuel type change, and injection strategy change, with proportional–integral (PI) control as the baseline. The simulation results show that MPC reduces about 26% of ringing intensity in the transient process and 17% at the steady state for E30. Generally, MPC can optimize the overall performance through modifying the main injection timing, pilot fuel mass, and exhaust gas recirculation (EGR) fraction.

42 ENGINEERING↗
DOE OSTI2025

Experimental Measurements of Soot and Soot Precursors of Sustainable Aviation Fuels

Sustainable Aviation Fuels (SAFs) are promising for decarbonizing the challenging-to-electrify aerospace sector and reducing yearly greenhouse gas emissions by thousands of tons. Developing predictive detailed chemical kinetic models for SAF (and traditional) fuel mixtures necessitates a robust experimental database to elucidate the intricate pyrolysis and oxidation chemistry of SAF fuel blend components. Two critical components of SAF surrogate mixtures are iso-dodecane isomers and trans-decalin. This report characterizes the structure of three slightly sooting, laminar, non-premixed, nitrogen-diluted Planar Mixing Layer Flames (PMLFs) fueled by either pure ethylene, ethylene doped with 1500ppm of either 2,2,4,6,6-pentamethyl-heptane or trans-decalin. The flames have the same stoichiometric mixture fraction and total mole fraction of fuels in the fuel stream (X F,F = X C2H4,F + X Dopant,F = 0.26), resulting in approximately the same maximum temperature (T max ≈ 1800 K) to highlight the effect of doping on soot and its gaseous precursors. The PMLF is unconfined and established between adjacent planar jets of the fuel and oxidizer streams surrounded by annular shielding nitrogen. The flow is stabilized by exhausting the hot buoyant flame products through a slot in a downstream plate onto which the cold flow impinges. Importantly, any horizontal cross-section of the PMLF has a self-similar thermochemical structure of a reactive boundary layer that grows at increasing Height Above the Burner (HAB). Therefore, the horizontal cross-sections of a PMLF can be modeled as a One-Dimensional Counterflow Flame (1D-CF) with very low strain rates which are unachievable in traditional CFs and yield a structure that is several millimeters thick. In brief, the PMLF is ideal for performing spatially resolved measurements with minimal effects of the sampling-induced perturbations, to develop and validate detailed chemical kinetic models on time scales of a few tens of milliseconds that are relevant in aviation applications. The horizontal profiles of C0-C18 gaseous species at HAB = 50 mm and soot volume fraction at 25 and 50 mm are measured using capillary sampling followed by GC-MS analyses and Laser Induced Emission Spectroscopy (LIES), respectively. Additionally, the Elastic Laser Light Scattering (E-LLS) coefficient is measured at HAB = 50 mm and 25 mm to determine the strain rates of the 1D-CFs equivalent to the characterized PMLF horizontal cross sections and the profile of the E-LLS equivalent diameter of soot. The comparison of the results in the base PMLF fueled only by ethylene with those in either doped PMLF in which 1500 ppm of ethylene are replaced with 2,2,4,6,6-pentamethyl-heptane or trans-decalin, reveals that the doping increases the mole fraction of several Polycyclic Aromatic Hydrocarbons (PAHs) at both HABs by a factor of approximately 2.5, and the soot volume fraction at both HABs by factors of ~1.5 for 2,2,4,6,6-pentamethyl-heptane and ~1.25 for trans-decalin doping, respectively. Conversely, doping causes a near doubling of the soot equivalent diameter only at HAB = 50 mm, without significant effects at 25 mm. The experimental results partially validate the tested state-of-the-art detailed chemical kinetic model and also point toward the further improvement of its predictive capabilities.

10 SYNTHETIC FUELS↗
DOE OSTI2023

Bioproduction and Evaluation of Renewable Butyl Acetate as a Desirable Bioblendstock for Diesel Fuel

The objective of this project was to develop an integrated bioprocess for efficient butyl acetate (BA) production through strain development using systematic genome engineering and MicroNiche Engineering™ technology (MNE). BA's potential as a bioblendstock for diesel fuel was evaluated through droplet experiments and Mixing Controlled Compression Ignition (MCCI) engine testing. The project aimed to achieve 30 g/L BA production with a yield of 0.4 g/g and a productivity of 0.6 g/L/h. The suitable composition of the blended fuel (BA/biodiesel) would be determined for MCCI engine application.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2024

Numerical investigation of equivalence ratio effects on Flex-Fuel mixing controlled combustion enabled by prechamber ignition

There is interest in adapting renewable and low-carbon intensity fuels to heavy-duty engines to help displace criteria and greenhouse gas emissions associated with diesel combustion. Low-carbon fuels have inherently low cetane numbers and thus pose a significant challenge when considering direct substitution in diesel combustion systems. Use of an actively fueled prechamber as an ignition source to initiate mixing-controlled combustion (PC-MCC) of low-cetane fuels is becoming an attractive combustion mode to alleviate the identified reactivity deficit. This work focuses on the utilization of an active prechamber to facilitate diesel-like combustion of bioethanol-gasoline fuel blends in a heavy-duty engine. Recent results in this emerging technology suggest that ignition quality is uniquely coupled to prechamber equivalence ratio. In this numerical study, the fundamental implications of prechamber equivalence ratio on the ignition performance of direct injected fuels ranging from E10 to E100 are investigated using CONVERGE. Parametric studies of the prechamber operating strategy were assessed at diesel-like conditions to characterize the performance trends relative to a diesel baseline at the same boundary conditions. Simulation results indicate that PC-MCC is flex-fuel capable and achieves diesel-like ignition qualities and combustion processes for all fuels considered under stoichiometric and rich prechamber conditions. To characterize the equivalence ratio trends observed, a novel inflow boundary modeling technique was utilized to prescribe turbulent jets in place of the prechamber where selective speciation of the jet composition was conducted to isolate the ignition contributions of radical and reacting species in lean, stoichiometric, and rich jets. The inflow boundary modeling suggests that excess fuel and combustion intermediates present in jets produced from stratified and fuel-rich prechamber operation promotes higher jet temperatures and as such are superior ignition sources. Relative to a lean prechamber jet, the peak temperature of a reacting jet from a rich prechamber was up to 600 K hotter at fixed distances from the orifice exit. Furthermore, radicals also demonstrated an influence on the ignition process, but the combustion mode was identified to be thermally dominant.

33 ADVANCED PROPULSION SYSTEMS↗
NASA NTRS1980

Experimental evaluation of combustor concepts for burning broad property fuels

A baseline CF6-50 combustor and three advanced combustor designs were evaluated to determine the effects of combustor design on operational characteristics using broad property fuels. Three fuels were used in each test: Jet A, a broad property 13% hydrogen fuel, and a 12% hydrogen fuel blend. Testing was performed in a sector rig at true cruise and simulated takeoff conditions for the CF6-50 engine cycle. The advanced combustors (all double annular, lean dome designs) generally exhibited lower metal temperatures, exhaust emissions, and carbon buildup than the baseline CF6-50 combustor. The sensitivities of emissions and metal temperatures to fuel hydrogen content were also generally lower for the advanced designs. The most promising advanced design used premixing tubes in the main stage. This design was chosen for additional testing in which fuel/air ratio, reference velocity, and fuel flow split were varied.

Kasper, J. M.↗
DOE OSTI2024

Dynamics of hydrogen–ammonia–natural gas lean-premixed high-pressure flames

The influence of fuel composition on self-excited combustion instabilities in a high-pressure combustor operated with ammonia, hydrogen, and natural gas fuels is characterized with high-frequency pressure measurements and imaging of the flame structure. A micromix multi-stage injector with 19 elements is used to introduce the fuel blend premixed with heated air into an optically accessible combustor operated at ~1.1 MPa. As hydrogen is substituted for natural gas, longitudinal thermoacoustic instabilities are observed in the combustor with pressure fluctuation amplitudes as large as 8% of the mean chamber value. In the absence of natural gas, limit-cycle instability magnitude is largely insensitive to ammonia addition. However, fuel compositions with > 20% natural gas result in positive correlation between instability amplitude and ammonia concentration. Spatial distribution of heat release in the combustor evaluated from OH* chemiluminescence imaging reveals axial growth in the regions of heat release fluctuation as hydrogen decreases, thus correlating flame length to instability amplitude. Distinct transitions from the first harmonic of the fundamental longitudinal acoustic mode (~1100 Hz) to the fundamental mode (~550 Hz) are observed with root mean square pressure fluctuations exceeding 7% of the mean chamber value. Here, these cases correspond to hydrogen mole fractions ≤ 50%. Analysis of the phase relationship between pressure fluctuations upstream and downstream of the flame zone indicates acoustic coupling of the injector as a key contributor to instability growth.

03 NATURAL GAS↗
DOE OSTI2020

Comparing Cetane Number Measurement Methods

Cetane number is one of the most important fuel performance metrics for mixing controlled compression-ignition “diesel” engines, quantifying a fuel’s propensity for autoignition when injected into end-of-compression-type temperature and pressure conditions. The historical default and referee method on a Cooperative Fuel Research (CFR) engine configured with indirect fuel injection and variable compression ratio is cetane number (CN) rating. A subject fuel is evaluated against primary reference fuel blends, with heptamethylnonane defining a low-reactivity endpoint of CN = 15 and hexadecane defining a high-reactivity endpoint of CN = 100. While the CN scale covers the range from zero (0) to 100, typical testing is in the range of 30 to 65 CN. Alternatively, several constant-volume combustion chamber (CVCC)-based cetane rating devices have been developed to rate fuels with an equivalent derived cetane number (DCN) or indicated cetane number (ICN). These devices measure ignition delay for fuel injected into a fixed volume of high-temperature and high-pressure air to simulate end-of-compression-type conditions. In this study, a range of novel fuel compounds are evaluated across three CVCC methods: the Ignition Quality Tester (IQT), Fuel Ignition Tester (FIT), and Advanced Fuel Ignition Delay Analyzer (AFIDA). Resulting DCNs and ICNs are compared for fuels within the normal diesel fuel range of reactivity, as well as very high (~100) and very low DCNs/ICNs (~5). Distinct differences between results from various devices are discussed. This is important to consider because some new, high-efficiency advanced compression-ignition (CI) engine combustion strategies operate with more kinetically controlled distributed combustion as opposed to mixing controlled diffusion flames. These advanced combustion strategies may benefit from new fuel chemistries, but current rating methods of CN, DCN, and ICN may not fully describe their performance. In addition, recent evidence suggests ignition delay in modern on-road diesel engines with high-pressure common rail fuel injection systems may no longer directly correlate to traditional CN fuel ratings. Simulated end-of-compression conditions are compared for CN, DCN, and ICN and discussed in the context of modern diesel engines to provide additional insight. Results highlight the potential need for revised and/or multiple fuel test conditions to measure fuel performance for advanced CI strategies.

47 OTHER INSTRUMENTATION↗
NASA NTRS1949

Altitude performance of AN-F-58 fuels in J35-C-3 single combustor

Three fuel blends conforming to AN-F-58 specifications were tested in order to determine the influence of boiling temperatures and aromatic content on altitude performance in single combustor of 4000-pound-thrust turbojet engine. At simulated engine conditions from an altitude of 30,000 to an altitude of 60,000 feet and 85-percent rated engine speed, the three AN-F-58 fuels showed little difference in performance.

COMBUSTION - EFFECT OF ENGINE OPERATING CONDITIONS↗
DOE OSTI2024

Performance Testing of Moving Bed Gasifier Using Biomass and Waste Fuels to Generate Low-Cost Clean Hydrogen

Our need for hydrogen is growing as the world transitions toward a low-carbon future. Hydrogen provides long-term energy storage for grid stability in a solar- and wind-dominated power market and can be used to decarbonize other sectors. One promising process for generating low-cost hydrogen that produces net-negative carbon is to gasify biomass with a mixture of legacy coal wastes, waste plastics, and other wastes with carbon capture. Use of waste fuels lowers costs and diverts waste from landfills. EPRI is leading a project, funded by the U.S. Department of Energy, to conduct performance testing of modular, moving-bed gasification for the generation of low-cost, clean hydrogen from biomass mixed with legacy coal waste, waste plastic, and/or refuse derived fuels. The work scope includes preparation of multiple pellet feedstocks using biomass (both woody biomass and corn stover) with a mixture of legacy coal waste, plastic waste (wire insulation), and refuse-derived fuel (RDF). These pelletized feedstocks are being qualified based on performance testing of selected fuel blend compositions in updraft moving-bed gasifier located in Sardinia, Italy. Testing is being conducted to obtain relevant data to advance the modular design of the moving-bed gasification process, and successfully use these feedstocks to produce a high hydrogen content raw syngas that can be shifted to produce clean hydrogen. Testing results will be used to determine the effects of the various fuels on feedstock development, the resulting products (i.e., syngas compositions, organic condensate production, and ash characteristics), and impacts on gasifier operations.

08 HYDROGEN↗