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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1975

Chemistry of agglutinate fractions in lunar soils

Agglutinates are aggregates of crystalline grains and lithic fragments bonded together by glass. It is thought that glassy agglutinates are formed at the upper surface of the lunar regolith by impact-related melting and welding of soil particles, in response to meteoroid and micrometeoroid bombardment. A description is presented of an investigation in which bulk soils were separated into 'agglutinate' and 'nonagglutinate' fractions. The obtained fractions were analyzed for major, minor, and trace elements. The obtained chemical data for agglutinate and nonagglutinate fractions of lunar soils indicate that agglutinitic glass is enriched in mafic and most lithophile elements relative to the bulk soils. A model involving preferential melting and assimilation of mesostasis material and mafic soil components is proposed to account for the observed chemical data. It is suggested that glassy agglutinates may form more readily in mafic soils than in more feldspathic ones. Such selectivity should be most effective between mare and highland soils, but may possibly operate on a more local scale.

Rhodes, J. M.↗
NASA NTRS1978

Microcrater and solar-flare track maturation of the lunar regolith

The microcrater, pancake and cosmic ray track record in the 100-200 microns feldspar fraction of a variety of surface soils and Apollo and Luna 16-24 cores have been studied. In Luna 24, a study of the glassy agglutinates plus breccias in 9 levels revealed this core was deposited as discrete layers, most of which are immature. Luna 16 and 20 cores were found respectively mature and immature. Glassy agglutinates and impact microcraters, absent to rare in immature soils such as 12033 and 14141, are present in similar abundances on crystals from submature to mature soils. In submature and mature soils, pancakes are present on 60 to 100 percent of crystals and craters on 50 to 70 percent. Microcrater, track and solar wind gas data suggest feldspar crystals in the size range considered reach an equilibrium maturity grade faster than bulk soils. This is interpreted as due to the limited lifetime of these crystals in the lunar regolith.

Poupeau, G.↗
NASA NTRS1979

Laboratory simulation of infrared astrophysical features

Laboratory infrared emission and absorption spectra have been taken of terrestrial silicates, meteorites, and lunar soils in the form of micrometer and submicrometer grains. The emission spectra were taken in a way that imitates telescopic observations. The purpose was to see which materials best simulate the 10-micron astrophysical feature. The emission spectra of dunite, fayalite, and Allende give a good fit to the 10-micron broadband emission feature of comets Bennett and Kohoutek. A study of the effect of grain size on the presence of the 10-micron emission feature of dunite shows that for particles larger than 37 microns no feature is seen. The emission spectrum of the Murray meteorite, a Type 2 carbonaceous chrondrite, is quite similar to the intermediate-resolution spectrum of comet Kohoutek in the 10-micron region. Hydrous silicates or amorphous magnesium silicates in combination with high-temperature condensates, such as olivine or anorthite, would yield spectra that match the intermediate-resolution spectrum of comet Kohoutek in the 10-micron region. Glassy olivine and glassy anorthite in approximately equal proportions would also give a spectrum that is a good fit to the cometary 10-micron feature.

Rose, L. A.↗
NASA NTRS1980

Flow behavior of droplet chondrules in the Manych /L-3/ chondrite

The Manych (L-3) chondrite contains chondrules that have radically different thermal histories. The high-SiO2 composition cooled at about 1 K/min to a glassy state or more slowly to form a variety of fractions of crystals. The low-SiO2 composition cooled at about 3000 K/min to form a glassy coating or much more slowly to form microporphyry. The extreme range of cooling rates displayed by objects in the Manych chondrite is difficult to reconcile with a model involving droplet condensation at low pressure which provides a uniform temperature, a uniform cooling rate, and an ambient that is not necessarily cold. The experimental results presented here are interpreted to mean that the origin of the chondrules is likely a result of impact melting because of the range of cooling histories represented in the chondrite.

Klein, L. C.↗
NASA NTRS1982

Electron microscopy of carbonaceous matter in Allende acid residues

On the basis of characteristic diffuse ring diffraction patterns, much of the carbonaceous matter in a large suite of Allende acid residues has been identified as a variety of turbostratic carbon. Crystallites of this phase contain randomly stacked sp(2) hybridized carbon layers and diffraction patterns resemble those from carbon black and glassy carbon. Carbynes are probably absent, and are certainly restricted to less than 0.5% of these acid residues. The work of Ott et al. (1981) provides a basis for the possibility that turbostratic carbon is a carrier of noble gases, but an additional component - amorphous carbon - may be necessary to explain the high release temperatures of noble gases as well as the glassy character of many of the carbonaceous particles. Carbynes are considered to be questionable as important carriers of noble gases in the Allende acid residues.

Lumpkin, G. R.↗
NASA NTRS1982

Spheres of the metallic glass Au55 Pb22.5 Sb22.5 and their surface characteristics

Spheres of the metallic glass Au55 Pb22.5 Sb22.5 have been formed up to a size of approximately 1.5 mm in diameter. X-ray diffraction was used to establish the glassy nature of the samples and to provide evidence of two phase-separated glass regions. Scanning electron microscopy provided a direct visual observation of the two-phase amorphous network on the surface of the sphere. The physical dimensions of the phase-separated regions were observed to be cooling-rate sensitive. Energy dispersive spectroscopy indicated that the compositions of these two glassy phases were Au-rich and Pb-rich, respectively, confirming the results of Kim and Johnson (1981). In addition, the spheres exhibited an unusual surface smoothness of better than + or - 250 A

Lee, M. C.↗
NASA NTRS1982

The mechanisms of fine particle generation and electrification during Mount St. Helens volcanic eruption

Microscopical investigation of volcanic ash collected from ground stations during Mount St. Helens eruptions reveal a distinctive bimodel size distribution with high concentrations of particle ranges at (1) 200-100 microns and (2) 20-0.1 microns. Close examination of individual particles shows that most larger ones are solidified magma particles of porous pumice with numerous gas bubbles in the interior and the smaller ones are all glassy fragments without any detectable gas bubbles. Elemental analysis demonstrates that the fine fragments all have a composition similar to that of the larger pumice particles. Laboratory experiments suggest that the formation of the fine fragments is by bursting of glassy bubbles from a partially solidified surface of a crystallizing molten magma particle. The production of gas bubbles is due to the release of absorbed gases in molten magma particles when solubility decreases during phase transition. Diffusion cloud chamber experiments strongly indicate that sub-micron volcanic fragments are highly hygroscopic and extremely active as cloud condensation nuclei. Ice crystals also are evidently formed on those fragments in a supercooled (-20 C) cloud chamber. It has been reported that charge generation from ocean volcanic eruptions is due to contact of molten lava with sea water. This seems to be insufficient to explain the observed rapid and intense lightning activities over Mount St. Helens eruptions. Therefore, a hypothesis is presented here that highly electrically charged fine solid fragments are ejected by bursting of gas bubbles from the surface of a crystallizing molten magma particles.

Cheng, R. J.↗
NASA NTRS1982

Effect of Y2O3 and Al2O3 on the oxidation resistance of Si3N4

Oxidation of cold-pressed and sintered Si3N4 containing 15 wt% Y2O3 and 2, 4, 6, and 8% Al2O3 is observed at temperatures as low as 1000 C with IR reflection spectroscopy. Concentrations of Al2O3 in excess of 4% greatly retard the rate of oxidation and alter the mechanism of surface attack by promoting formation of a glassy layer on the surface containing mixed oxynitride bonds. The glassy layer retards heterogeneous attack and reduces the effect of an oxidation transition temperature between 1000 and 1100 C for these materials.

Hench, L. L.↗
NASA NTRS1984

Microanalytical study of some cosmic dust discovered in sea-floor sediments in China

The study of cosmic dust can provide useful data in the investigation of the origin of the Earth and the evolution of celestial bodies. Three types of cosmic dust (ferriginous, siliceous, and glassy) were discovered in the seafloor sediments near China. Their chemical composition and microstructure were examined by X-ray diffraction, fractography, and electron microscopy. The major mineral in an iron-containing cosmic dust is magnetite. The silicate spheres contain sundry metals and metal oxides. Glassy microtektites are similar in composition to tektites, and are found in all the major meteorite areas worldwide.

Shijie, Z.↗
NASA NTRS1984

The potential for bulk undercooling as an industrial process

The main focus is on solidification occurring in highly supercooled melts. Solidification rates in such melts are extremely high, an attractive feature from a commercial standpoint. Thus, the reported growth velocities for pure Ni and Co dendrites at a supercooling of 175 K are in excess of 180 km/hr. Rapidly quenched crystalline alloys produced by various atomization processes (e.g., centrifugal atomization or inert gas atomization) or melt spinning are examples of solidification processes, currently being intensively explored commercially, wherein extremely high solidification rates are achieved. Estimated dendrite tip growth rates are about 2 km/hr in a binary Al-4.5 wt % alloy, with a heat transfer coefficient of 6.4x10 sub 5 w/sq cm K or 15 cal/cu cm sK. In the limit, when the solidification rate exceeds a critical value, a glassy microstructure is obtained even in highly alloyed melts, which under normal conditions would solidity to form one or more crystalline phases. Glassy metals, also called metallic glasses, are candidate materials for distribution transformers because of their very low energy losses and are also being used in brazing and soldering applications.

Laxmanan, V.↗
NASA NTRS1986

Effect of annealing history on free volume in thermoplastics

Two different types of thermoplastic glassy polymers have been investigated for the effects of thermal annealing on their free volumes. It has been observed that free volumes in glassy polymers decrease asymptotically to a steady level after about four thermal anneals lasting for 24 hours at a temperature about 50 C below their glass transition temperatures. These results indicate that composites incorporating properly annealed thermoplastic matrices may not experience any additional internal stresses due to subsequent thermal excursions experienced while in service.

Singh, J. J.↗
NASA NTRS1988

The high temperature creep deformation of Si3N4-6Y2O3-2Al2O3

The creep properties of silicon nitride containing 6 wt percent yttria and 2 wt percent alumina have been determined in the temperature range 1573 to 1673 K. The stress exponent, n, in the equation epsilon dot varies as sigma sup n, was determined to be 2.00 + or - 0.15 and the true activation energy was found to be 692 + or - 25 kJ/mol. Transmission electron microscopy studies showed that deformation occurred in the grain boundary glassy phase accompanied by microcrack formation and cavitation. The steady state creep results are consistent with a diffusion controlled creep mechanism involving nitrogen diffusion through the grain boundary glassy phase.

Todd, J. A.↗
NASA NTRS1988

On the siting of gases shock-emplaced from internal cavities in basalt

Laboratory experiments were carried out on shock-emplaced gases from Servilleta basalt samples that contained gas-filled cavities to answer the following questions: (1) what is the role of shock melting in trapping gases; (2) how are the glassy pockets that contain trapped gases formed; and (3) are the gases trapped in laboratory shocked basalts sited similarly to, and emplaced with the same efficiency as, the gases in the EETA 79001 shergottite? Noble gases were extracted by stepped combustion and crushing followed by shock at 40 GPa, and were analyzed for abundances. Results obtained indicate that noble gases trapped from internal cavities of shock-exposed basalt are associated with glass and are sited predominantly in microvesicles, with a significant fraction of the gases released by crushing. The presence of gas-filled cavities prior to shock results in substantially greater shock effects locally. Thus, glassy pockets similar to those seen in EETA 79001 can be produced in situ within a matrix shocked to only moderate pressures. However, the siting of the gases points to a more complex scenario.

Wiens, R. C.↗
NASA NTRS1989

The high temperature creep deformation of Si3N4-6Y2O3-2Al2O3

The creep properties of silicon nitride containing 6 wt percent yttria and 2 wt percent alumina have been determined in the temperature range 1573 to 1673 K. The stress exponent, n, in the equation epsilon dot varies as sigma sup n, was determined to be 2.00 + or - 0.15 and the true activation energy was found to be 692 + or - 25 kJ/mol. Transmission electron microscopy studies showed that deformation occurred in the grain boundary glassy phase accompanied by microcrack formation and cavitation. The steady state creep results are consistent with a diffusion controlled creep mechanism involving nitrogen diffusion through the grain boundary glassy phase.

Todd, J. A.↗
NASA NTRS1990

Catalytic carbide formation at aluminium-carbon interfaces

X-ray photoelectron spectroscopy investigations of the reaction of several monolayer-thick films of aluminum with glassy carbon substrates are presented. The influence of molecular oxygen and water vapor on the rate of reaction is examined. It is concluded that water vapor catalyzed the formation of aluminum carbide from aluminum and carbon by forming active sites which weakened carbon-carbon bonds at the glassy carbon surface, thus assisting their cleavage. The rate of carbide formation for undosed and molecular oxygen-dosed examples was less as neither metallic aluminum nor oxygen-formed alumina could bond to the carbon atom with sufficient strength to dissociate it quickly.

Maruyama, B.↗
NASA NTRS1992

Coeval Ar-40/Ar-39 ages of 65.0 million years ago from Chicxulub crater melt rock and Cretaceous-Tertiary boundary tektites

Ar-40/Ar-39 dating of drill-core samples of a glassy melt rock recovered from beneath a massive impact breccia contained with the 180-kilometer subsurface Chicxulub crater yields well-behaved incremental heating spectra with a mean plateau age of 64.98 +/- 0.05 million years ago (Ma). The glassy melt rock of andesitic composition was obtained from core 9 (1390 to 1393 meters) in the Chicxulub 1 well. The age of the melt rock is virtually indistinguishable from Ar-40/Ar-39 ages obtained on tektite glass from Beloc, Haiti, and Arroyo el Mimbral, northeastern Mexico, of 65.01 +/- 0.08 Ma (mean plateau age for Beloc) and 65.07 +/- 0.10 Ma (mean total fusion age for both sites). The Ar-40/Ar-39 ages, in conjunction with geochemical and petrological similarities, strengthen the suggestion that the Chicxulub structure is the source for the Haitian and Mexican tektites and is a viable candidate for the Cretaceous-Tertiary boundary impact site.

Swisher, Carl C., III↗
NASA NTRS1993

High temperature polymer from maleimide-acetylene terminated monomers

Thermally stable, glassy polymeric materials were prepared from maleimide-acetylene terminated monomeric materials by several methods. The monomers were heated to self-polymerize. The A-B structure of the monomer allowed it to polymerize with either bismaleimide monomers/oligomers or bis-acetylene monomers/oligomers. Copolymerization can also take place by mixing bismaleimide and bisacetylene monomers/oligomers with the maleimide-acetylene terminated monomers to yield homogenous glassy polymers.

Gerber, Margaret K.↗
NASA NTRS1993

Thermal processing of omicron-terphenyl - A Raman study

Raman spectra from omicron-terphenyl sealed in glass capillary tubes were acquired over temperatures ranging from 233 to 343 K. Over this temperature range, omicron-terphenyl can exist in the solid-crystalline, molten, supercooled-liquid, and amorphous-glassy states. Representative structure-sensitive spectra are presented along with a qualitative description. The lattice spectral feature occurring at a Raman shift of 123/cm displays abrupt changes in profile and intensity as melting and glass transition occur. The intensity ratio of the C-C stretching 996/cm line and C-H stretching line at 1008/cm displays a change related to the transformation of the ordered-crystalline phase to the disordered-liquid or glassy state. At a Raman shift of 1162/cm the solid-crystalline state shows a splitting due to the effect of the crystal field. The possibility of using these structure-sensitive Raman characteristics for in situ diagnostics during materials processing is discussed.

Biswas, A.↗