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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Hyperspectral Light Sheet Raman Imaging of Leaf Metabolism (Final Report)

This final technical report details the accomplishment and findings of a project that developed technology related to imaging metabolic processes in plants. The report gives technical details of the design, construction and characterization of a Raman microscope system capable of identifying chemical species using the wavelength shifts of scattered excitation light. Some of the unique aspects of the design include: use of a Bessel beam excitation source, which allow long excitation lines that are resistant to scattering in complex media such as plants; excitation at 785 nm to avoid fluorescence emission that can occur in photosynthetic organisms; and a flat optical design that makes construction and alignment significantly simpler. This project also used stable isotope labeling to look at photorespiratory flux in the leaves of three different types of plants that have different photosynthesis pathways. Gas chromatography–mass spectrometry was used to look at which metabolites and amino acids had altered oxygen, carbon and hydrogen uptake under various conditions of environmental oxygen. This generated a rich data set that is being further analyzed to understand metabolic pathways in plants. This project also used the natural fluorescence in sorghum and rice to conduct an extensive experiment across different developmental stages. Spectral differences were identified at most of the developmental stages and these can be attributed to differential pigment and pigment-protein complexes present in different relative abundances as the plant develops.

09 BIOMASS FUELS↗

Accuracy of Vaisala RS41 and RS92 Upper Tropospheric Humidity Compared to Satellite Hyperspectral Infrared Measurements

Radiosondes are important for calibrating satellite sensors and assessing sounding retrievals. Vaisala RS41 radiosondes have mostly replaced RS92 in the Global Climate Observing System (GCOS) Reference Upper Air Network (GRUAN) and the conventional network. This study assesses RS41 and RS92 upper tropospheric humidity (UTH) accuracy by comparing with Infrared Atmospheric Sounding Interferometer (IASI) upper tropospheric water vapor absorption spectrum measurements. Using single RS41 and RS92 soundings at three GRUAN and DOE Atmospheric Radiation Measurement (ARM) sites and dual RS92/RS41 launches at three additional GRUAN sites, collocated with cloud-free IASI radiances (OBS), we compute Line-by-Line Radiative Transfer Model radiances for radiosonde profiles (CAL). We analyze OBS-CAL differences from 2015 to 2020, for daytime, nighttime, and dusk/dawn separately if data is available, for standard (STD) RS92 and RS41 processing, and RS92 GRUAN Data Processing (GDP; RS41 GDP is in development). We find that daytime RS41 (even without GDP) has ~1% smaller UTH errors than GDP RS92. RS41 may still have a dry bias of 1–1.5% for both daytime and nighttime, and a similar error for nighttime RS92 GDP, while standard RS92 may have a dry bias of 3–4%. These sonde humidity biases are probably upper limits since “cloud-free” scenes could still be cloud contaminated. Radiances computed from European Centre for Medium-Range Weather Forecasts (ECMWF) analyses match better than radiosondes with IASI measurements, perhaps because ECMWF assimilates IASI measurements. Relative differences between RS41 STD and RS92 GDP, or between radiosondes and ECMWF humidity profiles obtained from the radiance analysis, are consistent with their differences obtained directly from the RH measurements.

54 ENVIRONMENTAL SCIENCES↗

Using Downwelling Far- and Thermal-Infrared Hyperspectral Radiance for Cloud Phase Classification in the Antarctic

The cloud phase is one of the most important parameters of clouds. In this paper, we propose a method for cloud phase classification that synergistically utilizes the far- and thermal-infrared bands based on the Atmospheric Emitted Radiance Interferometer (AERI) at the Atmospheric Radiation Measurement West Antarctic Radiation Experiment (AWARE) observatory in 2016. The possible features in the far- and thermal-infrared bands are analyzed based on the differences in the simulated cloud brightness temperature (BT) spectra with different cloud phases. Using the support vector machine (SVM) algorithm, four features are determined to identify the cloud phase, which include the BT at 900 cm -1 , the slope of the fitted function of BT in the 900–1000 cm -1 interval, the BT difference (BTD) between 512 cm -1 and 726 cm -1 , and the BTD between 550 cm -1 and 726 cm -1 . Here, the performance of the proposed method is evaluated with Shupe’s and Turner’s method. The monthly average accuracy of the proposed method, the method without the two far-infrared features, and Turner’s method are about 76%, 36%, and 49%, respectively, which infer the good performance of the proposed method and also indicate that the far-infrared band features can effectively enhance cloud phase classification. It is notable that, compared to Shupe’s method, the accuracy for the proposed method is only 61% during the Antarctic summer, which results from the definitions of cloud phase and radiative effect. In addition, the accuracy is only 44% for Turner’s method in seasons with a low frequency of mixed clouds due to the significant effect of water vapor.

54 ENVIRONMENTAL SCIENCES↗