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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Development of a SPARK Training Dataset

In its first five years, the National Nuclear Security Administration’s (NNSA) Next Generation Safeguards Initiative (NGSI) sponsored more than 400 undergraduate, graduate, and post-doctoral students in internships and research positions (Wyse 2012). In the past seven years, the NGSI program has, and continues to produce a large body of scientific, technical, and policy work in targeted core safeguards capabilities and human capital development activities. Not only does the NGSI program carry out activities across multiple disciplines, but also across all U.S. Department of Energy (DOE)/NNSA locations in the United States. However, products are not readily shared among disciplines and across locations, nor are they archived in a comprehensive library. Rather, knowledge of NGSI-produced literature is localized to the researchers, clients, and internal laboratory/facility publication systems such as the Electronic Records and Information Capture Architecture (ERICA) at the Pacific Northwest National Laboratory (PNNL). There is also no incorporated way of analyzing existing NGSI literature to determine whether the larger NGSI program is achieving its core safeguards capabilities and activities. A complete library of NGSI literature could prove beneficial to a cohesive, sustainable, and more economical NGSI program. The Safeguards Platform for Automated Retrieval of Knowledge (SPARK) has been developed to be a knowledge storage, retrieval, and analysis capability to capture safeguards knowledge to exist beyond the lifespan of NGSI. During the development process, it was necessary to build a SPARK training dataset (a corpus of documents) for initial entry into the system and for demonstration purposes. We manipulated these data to gain new information about the breadth of NGSI publications, and they evaluated the science-policy interface at PNNL as a practical demonstration of SPARK’s intended analysis capability. The analysis demonstration sought to answer the question, “Who leads research and development at PNNL, scientists or policy researchers?” The analysis was inconclusive as to whether policy researchers or scientists are primary drivers for research at PNNL. However, the dataset development and analysis activity did demonstrate the utility and usability of the SPARK dataset. After the initiation of the NGSI program there is a clear increase in the number of publications of safeguards products. Employing the natural language analysis tool IN SPIRE™ showed the presence of vocation- and topic-specific vernacular within NGSI sub-topics. The methodology developed to define the scope of the dataset was useful in describing safeguards applications, but may be applicable for research on other topics beyond safeguards. The analysis emphasized the need for an expanded dataset to fully understand the scope of safeguards publications and research both nationally and internationally. As the SPARK dataset grows to include publications outside PNNL, topics crosscutting disciplines and DOE/NNSA locations should become more apparent. NGSI was established in 2008 to cultivate the next generation of safeguards professionals and support the development of core safeguards capabilities (NNSA 2012). Now a robust system to preserve and share institutional memory such as SPARK is needed to inspire and equip the next generation of safeguards experts, technologies, and policies.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Circular Perspective for Utilization of Industrial Wastewaters via Phytoremediation

Wastewater generated in municipal rendering facilities requires multi-step treatment, but it may also serve as a source of nutrients and water and thus may be valorized before or instead of the necessary wastewater treatment operations. In this work, wastewaters from a composting plant were utilized to support the growth of Miscanthus x giganteus, known as both a remediation plant and an energy biomass source. A pot experiment was established to compare the effects of different wastewater doses (0, 50, 100, and 200 mL per pot per week) on the miscanthus biomass yield, phytoextraction of heavy metals, biomass heat of combustion, and plant condition. The increase in the wastewater dose resulted in increases in both biomass yield (from about 44 to 139%) and biomass heat of combustion (from 7 to 17%) when compared to the control sample, with no adverse effects on plant physiological parameters. The highest concentrations of metals were found in miscanthus grown with the highest dose of wastewaters. It was found that higher wastewater dose correlates to both higher phytoextraction and phytorecovery of metals from plant substrate and wastewaters. The highest metal uptake was identified for Fe (431 mg·pot −1 ), followed by Al, Zn, Mn, Cu, Ni, Cr. The lowest metal uptake was noted for Pb, Co and Cd (0.88, 0.11, and 0.95 mg·pot −1 , respectively). The results indicate that miscanthus can be recommended for industrial wastewater treatment. In addition, due to high absorption efficiency of the substrate components, miscanthus can be used as a remediation tool, e.g., for the ecological stabilization of remediation of metal-polluted soils, especially in municipal facilities like rendering plants. This presents a circular perspective for the valorization of post-fermentation wastewaters with subsequent growth of energy crops, with other potential benefits for the environment, such as soil treatment, absorption of CO 2 , and air purification.

Miscanthus x giganteus↗

Control center operations at the Goddard Space Flight Center

Information is given in viewgraph form on control center operations at the Goddard Space Flight Center. Information is given on multi-mission, dedicated and attached payload support; the mission operations environment; technical challenges; Hubble Space Telescope (HST) science planning interface; operations engineering life cycle; Special Analysis of Maneuverable Satellites (SAMS) operations; and user interface applications.

Connerton, Robert M.↗

Microgravity Emissions Laboratory Facility and Testing Results

The goal of this presentation is to provide information about the testing support for simulation and verification of the Space Station microgravity: environment component and rack surveys for ISS; essential for ground SEA/FEM analytical correlation; and essential to predicting interface and science levels on orbit.

McNelis, Anne↗

An Infrared Telescope for Planet Detection and General Astrophysics

NASA plans to launch a Terrestrial Planet Finder (TPF) mission in 2014 to detect and characterize Earth-like planets around nearby stars, perform comparative planetology studies, and obtain general astrophysics observations. During our recently completed a TPF Mission Architecture study for NASA/JPL we developed the conceptual design for a 28-meter telescope with an IR Coronagraph that meets these mission objectives. This telescope and the technology it embodies are directly applicable to future Far-IR and Submillimeter space missions. The detection of a 30th magnitude planet located within 50 milli-arc-seconds of a 5th (Visual) magnitude star is an exceptionally challenging objective. Observations in the thermal infrared (7-17 microns) are somewhat easier since the planet is "only" 15(sup m) fainter than the star at these wavelengths, but many severe challenges must still be overcome. These challenges include: 1. Designing a coronagraph for star:planet separations less than or equal to lambda/D. 2. Developing the deployment scheme for a 28m space telescope that can fit in an existing launch vehicle payload fairing. 3. Generating configuration layouts for the IR telescope, coronagraph, spacecraft bus, sunshade, solar array, and high-gain antenna. 4. Providing: Structural stability to within 10 microns to support the optics. Thermal control to achieve the necessary structural stability, as well as providing a stable (approx. 30K) thermal environment for the optics. Dynamics isolation from potential jitter sources. 5. Minimizing launch mass to provide the maximum payload for the science mission Interfacing to an EELV Heavy launch vehicle, including acoustic and stress loads for the launch environment. 6. Identifying the key technologies (which can be developed by 2009) that will enable TPF mission to be performed. 7. Generating a manufacturing plan that will permit TPF to be developed at a reasonable cost and schedule. Many of these design challenges result in inherently conflicting requirements on the design of TPF. Drawing on our experience with large space telescopes such as the Chandra X-ray Observatory and the Next Generation Space Telescope, we have created a conceptual design for TPF that successfully meets these challenging requirements. This paper describes our solution to these challenges.

Lillie, C. F.↗

Increasing the Uptake of Ecological Model Results in Policy Decisions to Improve Biodiversity Outcomes

Models help decision-makers anticipate the consequences of policies for ecosystems and people; for instance, improving our ability to represent interactions between human activities and ecological systems is essential to identify pathways to meet the 2030 Sustainable Development Goals. However, use of modeling outputs in decision-making remains uncommon. We share insights from a multidisciplinary National Socio-Environmental Synthesis Center working group on technical, communication, and process-related factors that facilitate or hamper uptake of model results. We emphasize that it is not simply technical model improvements, but active and iterative stakeholder involvement that can lead to more impactful outcomes. In particular, trust- and relationship-building with decision-makers are key for knowledge-based decision making. In this respect, nurturing knowledge exchange on the interpersonal (e.g., through participatory processes), and institutional level (e.g., through science-policy interfaces across scales), represent promising approaches. To this end, we offer a generalized approach for linking modeling and decision-making.

Biodiversity-ecosystem function relationships↗

The Chemistry, Formation and Passivation of Solid-Electrolyte Interphase (SEI) from FSI- Breakdown at Li-metal Potential

LiFSI-based liquid electrolytes are promising for realizing high Coulombic efficiency (CE) and long cycle life of next-generation high-energy Li metal battery. Nevertheless, the fundamentals of both the chemistry and formation of solid-electrolyte interphase (SEI) in these electrolytes have remained elusive. Herein, we extensively combine electrochemistry and X-ray photoelectron spectroscopy (XPS) to illustrate the reaction pathways of electrolyte decomposition, especially FSI- breakdown, as well as the dissolution trend of various inorganic SEI components. The SEI-forming reactions at Cu/electrolyte interface manifest a potential (E) dependence, driven by direct electron-transfer (ET) and Li underpotential-deposition (Li UPD) at high and low E regions, respectively. By closely correlating the XPS data obtained with and without solvent washing, we demonstrate that not all the products derived from SEI reactions are incorporated into forming a passivating surface layer, with a notable portion dissolving into liquid electrolyte instead. Importantly, high-CE electrolyte dictated by the chemical identity of solvent, is found to exhibit minimized interfacial reactivity of SEI formation enabling more effective interphasial passivation, via preferential integration of passivating ingredients such as LiF. Overall, this work formulates a systematic understating of bridging the SEI chemistry, formation and passivation while identifying key characteristics of high-performance electrolyte for guiding future design.

Bao, Zhenan [SLAC National Accelerator Laboratory ↗

Reusable Rack Interface Controller Common Software for Various Science Research Racks on the International Space Station

The purpose of the EXPRESS (Expedite the PRocessing of Experiments to Space Station) rack project is to provide a set of predefined interfaces for scientific payloads which allow rapid integration into a payload rack on International Space Station (ISS). VxWorks' was selected as the operating system for the rack and payload resource controller, primarily based on the proliferation of VME (Versa Module Eurocard) products. These products provide needed flexibility for future hardware upgrades to meet everchanging science research rack configuration requirements. On the International Space Station, there are multiple science research rack configurations, including: 1) Human Research Facility (HRF); 2) EXPRESS ARIS (Active Rack Isolation System); 3) WORF (Window Observational Research Facility); and 4) HHR (Habitat Holding Rack). The RIC (Rack Interface Controller) connects payloads to the ISS bus architecture for data transfer between the payload and ground control. The RIC is a general purpose embedded computer which supports multiple communication protocols, including fiber optic communication buses, Ethernet buses, EIA-422, Mil-Std-1553 buses, SMPTE (Society Motion Picture Television Engineers)-170M video, and audio interfaces to payloads and the ISS. As a cost saving and software reliability strategy, the Boeing Payload Software Organization developed reusable common software where appropriate. These reusable modules included a set of low-level driver software interfaces to 1553B. RS232, RS422, Ethernet buses, HRDL (High Rate Data Link), video switch functionality, telemetry processing, and executive software hosted on the FUC computer. These drivers formed the basis for software development of the HRF, EXPRESS, EXPRESS ARIS, WORF, and HHR RIC executable modules. The reusable RIC common software has provided extensive benefits, including: 1) Significant reduction in development flow time; 2) Minimal rework and maintenance; 3) Improved reliability; and 4) Overall reduction in software life cycle cost. Due to the limited number of crew hours available on ISS for science research, operational efficiency is a critical customer concern. The current method of upgrading RIC software is a time consuming process; thus, an improved methodology for uploading RIC software is currently under evaluation.

Lu, George C.↗

Impact of the retained heat shield concept on science instruments

Associated interface problems between the mass spectrometer and the actual probe design are considered along with the problem of producing a clean sample to the gas detection instrument. Of particular interest is the penetration of the heat shield by the mass spectrometer sampling tube, because it must be demonstrated that the sampling tube can penetrate the heat shield and that the mass spectrometer can be supplied with a contaminant-free gas sample, free of contaminants from out-gassing of the heat shield.

Kessler, W. C.↗

Next Generation Space Telescope Integrated Science Module Data System

The Data system for the Next Generation Space Telescope (NGST) Integrated Science Module (ISIM) is the primary data interface between the spacecraft, telescope, and science instrument systems. This poster includes block diagrams of the ISIM data system and its components derived during the pre-phase A Yardstick feasibility study. The poster details the hardware and software components used to acquire and process science data for the Yardstick instrument compliment, and depicts the baseline external interfaces to science instruments and other systems. This baseline data system is a fully redundant, high performance computing system. Each redundant computer contains three 150 MHz power PC processors. All processors execute a commercially available real time multi-tasking operating system supporting, preemptive multi-tasking, file management and network interfaces. These six processors in the system are networked together. The spacecraft interface baseline is an extension of the network, which links the six processors. The final selection for Processor busses, processor chips, network interfaces, and high-speed data interfaces will be made during mid 2002.

Schnurr, Richard G.↗

Leadership at Interfaces: Capitalizing on the "Gaps" in Science, Technology and Education [Slides]

Leadership in the scientific enterprise is most commonly exemplified by those who commandeer major discoveries and critical breakthroughs that expand boundaries, naturally underpinning a competitive spirit among peers in the field. However, many other leadership opportunities exist at the interfaces of such boundaries - as well as at the interfaces of scientific disciplines, classes of professions and across generations - and may enable alternative guiding philosophies that are intrinsically less prone to competition and saturation, and perhaps appreciation. This presentation features a personal reflection of scientific and leadership philosophies that were intentionally manifested at, and by, irreplaceable interfaces of human creativity. Reaction engineering, an increasingly vanishing discipline within chemical engineering, is emphasized as a manifestation of interfacial leadership and serves as a vehicle to trace pivotal career moments in both the speaker's scientific discoveries and in his relational values within human enterprises.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantum-Classical Science for the Plasma-Material Interface in NSTXU (Final Technical Report)

Plasma facing surfaces (PFS) have a profound influence on plasma performance and choice of material for PFSs is a burning issue for tokamak reactors. Using lithium wall conditioning in NSTX has resulted in a beneficial influence on plasma behavior including control of hydrogen recycling and improvements in energy confinement, longer confinement times, edge density control, and the elimination of Edge Localized Modes. A major challenge for the NSTX-U (increased power flux, increased campaign time) as well as for other magnetic fusion devices is to extend high-performance plasmas for very long durations, and to integrate this high performance with plasma facing components (PFCs) that can withstand very high heat and particle fluxes while maintaining structural integrity with minimal retention of fusion fuel. This project directly contributed to filling up the knowledge gaps and data for the dynamics of the plasma-facing interfaces in the NSTX-U at nano and nano-to-micro scales. This was achieved by both deciphering the poorly understood nanoscale phenomenology of plasma-surface interactions and providing the connection and comparison with the experiments which provide understanding at the mesoscopic scales. We modelled the dynamic response and evolution of a mixed material surfaces (D, Li, C, B, O) to bombardment by plasma particles, and investigated microstructure changes, erosion, surface chemistry, deuterium implantation and permeation. The main objectives of the project are i) a comparison of Li and B effects when deposited on carbon, and ii) the role of oxygen and other impurities (e.g. carbon, boron) in the lithium performance. In addition to predicting and understanding the phenomenology of the processes, the project achieved deliverables on the i) plasma induced erosion rates of PFCs (outer wall, divertor, etc.), including chemical and physical sputtering yields at various temperatures (300-700K), ii) deuterium uptake/recycling rates, and iii) accurate probability rates for the processes and reactions in i-ii which were used to understand the experimental results of the J.P. Allain and B. Koel NSTX-U projects. Lithium was a distinctive focus of the project. It easily charges in contact with other fusion material atoms, giving partially or fully its external electron cloud to other atoms in its vicinity and polarizing the mixed material. Our research strategy used experimentally validated multiscale theory applied to the large, multicomponent material surface systems. With the use of US supercomputing facilities we simulated evolution of atomic charges, chemistry, retention of deuterium, sputtering and morphology by introducing the corrections to the classical molecular dynamics, like are electronegativity equalization method (EEM) and quantum-classical molecular dynamics (QCMD). The goal was to understand and quantify the dynamics of the creation and evolution of the plasma-material interface under irradiation by atoms and molecules at boronized carbon, lithiated carbon, and boronized-lithiated carbon for both solid and self-healing liquid-metal divertor.

36 MATERIALS SCIENCE↗

Science sequence design

The activities of the following members of the Navigation Team are recorded: the Science Sequence Design Group, responsible for preparing the final science sequence designs; the Advanced Sequence Planning Group, responsible for sequence planning; and the Science Recommendation Team (SRT) representatives, responsible for conducting the necessary sequence design interfaces with the teams during the mission. The interface task included science support in both advance planning and daily operations. Science sequences designed during the mission are also discussed.

Koskela, P. E.↗

The NPOESS Preparatory Project (NPP) Science Data Segment (SDS) Data Depository and Distribution Element (SD3E) System Architecture

The National Polar-orbiting Operational Environmental Satellite System (NPOESS), the U.S. Government's future low-Earth orbiting satellite system, will monitor global weather and environmental conditions. Serving as a risk reduction for NPOESS, the NPOESS Preparatory Project (NPP) will provide remotely sensed atmospheric, land, ocean, ozone, and sounder data that will serve the meteorological and global climate change scientific communities. The National Aeronautics and Space Administration (NASA) NPP Science Data Segment's (SDS) primary role is to independently assess the quality of the NPP science and environmental data records for their ability to support climate research. The SDS is composed of nine elements; an input element that receives data from the operational agencies and acts as a buffer, a calibration analysis element, five elements devoted to measurement based quality assessment, an element used to test algorithmic improvements, and an element that provides overall science direction. Each element requires a set of sensor specific science data products for their evaluation. There are four NPP sensors that will be flown on the NPP observatory. They are the Visible Infrared Imagining Radiometer Suite (VIIRS), the Advanced Technology Microwave Sounder (ATMS), the Cross-Track Infrared Sounder (CrIS), and the Ozone Mapper/Profiler Suite (OMPS). It is estimated that these four sensors combined will make daily data requests for approximately six terabytes of NPP science products from the operational data providers. As a result, issues associated with duplicate data requests, data transfers of large volumes of diverse products, and data transfer failures raised concerns with respect to the network traffic and bandwidth consumption. Therefore, a central data broker system for receiving and buffering data requests and data products for the SDS was developed. The data element for this system is called the SDS Data Depository and Distribution Element (SD3E). It supports science mission data assessment by assuring the timely and validated acquisition and subsequent transfer of the NPP Science Mission data to the SDS Elements and NPP Science Team. The six science elements that interface with the SD3E span across the NASA Goddard Space Flight Center (GSFC), the NASA Jet Propulsion Laboratory (JPL), and the University of Wisconsin. As the primary communication vehicle for the science elements and science team, the SD3E has an interface to the operational data providers: National Environment Satellite, Data, and Information Service (NESDIS) Interface Data Processing System (IDPS) and the National Oceanic Atmospheric Administration's (NOAA) Comprehensive Large Array-data Stewardship system (CLASS) Archive Data System (ADS), that are responsible for product generation and archive and distribution respectively. The SD3E is designed to be a semi-customizable and semi-automated system. This system is designed to provide flexibility and ease of use for the science users in accessing the latest data products by creating a rolling data cache that temporarily stores the products locally before transferring the data to the SDS Measurement based elements for the land, ocean, atmosphere, sounder, and ozone. This paper describes the design and architecture of one of the nine SDS elements, the SD3E, and how this system has provided a mechanism for efficient data exchange, how it has helped in alleviating some of the network traffic and usage, and how it has contributed to reducing operational costs.

Ho, Evelyn L.↗

Cryo Testing of tbe James Webb Space Telescope's Integrated Science Instrument Module

The Integrated Science Instrument Module (ISIM) of the James Webb Space Telescope will be integrated and tested at the Environmental Test Facilities at Goddard Space Flight Center (GSFC). The cryogenic thermal vacuum testing of the ISIM will be the most difficult and problematic portion of the GSFC Integration and Test flow. The test is to validate the coupled interface of the science instruments and the ISIM structure and to sufficiently stress that interface while validating image quality of the science instruments. The instruments and the structure are not made from the same materials and have different CTE. Test objectives and verification rationale are currently being evaluated in Phase B of the project plan. The test program will encounter engineering challenges and limitations, which are derived by cost and technology many of which can be mitigated by facility upgrades, creative GSE, and thorough forethought. The cryogenic testing of the ISIM will involve a number of risks such as the implementation of unique metrology techniques, mechanical, electrical and optical simulators housed within the cryogenic vacuum environment. These potential risks are investigated and possible solutions are proposed.

VanCampen, Julie↗

Capturing the swelling of solid-electrolyte interphase in lithium metal batteries

Although liquid-solid interfaces are foundational in broad areas of science, characterizing this delicate interface remains inherently difficult because of shortcomings in existing tools to access liquid and solid phases simultaneously at the nanoscale. This leads to substantial gaps in our understanding of the structure and chemistry of key interfaces in battery systems. We adopt and modify a thin film vitrification method to preserve the sensitive yet critical interfaces in batteries at native liquid electrolyte environments to enable cryo–electron microscopy and spectroscopy. We report substantial swelling of the solid-electrolyte interphase (SEI) on lithium metal anode in various electrolytes. Here, the swelling behavior is dependent on electrolyte chemistry and is highly correlated to battery performance. Higher degrees of SEI swelling tend to exhibit poor electrochemical cycling.

25 ENERGY STORAGE↗

Effect of ultrasonic loading on current in Mo/n-n{sup +}-Si with Schottky barriers

The results obtained in experimental studies of the operation of silicon Schottky diodes subjected to ultrasonic loading (oscillations frequency of 9.6 MHz; intensity of longitudinal waves as high as 0.7 W/cm{sup 2}) are reported. A reversible acoustically induced decrease in the Schottky barrier height (to 0.13 V) and an increase in the saturation and reverse current (by as much as 60%) are observed. It is shown that ultrasound does not affect the ideality factor of the diodes and the tunneling component of the reverse current. The process of electron transport is considered within the context of the model of an inhomogeneous Schottky barrier; it is shown that the observed effects can be related to the acoustically induced ionization of defects, which are located at the metal-semiconductor interface.

36 MATERIALS SCIENCE↗