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NASA NTRS1987

Observations of absorption lines from highly ionized atoms

In the ultraviolet spectra of hot stars, absorption lines can be seen from highly ionized species in the interstellar medium. Observations of these features which have been very influential in revising the perception of the medium's various physical states, are discussed. The pervasiveness of O 6 absorption lines, coupled with complementary observations of a diffuse background in soft X-rays and EUV radiation, shows that there is an extensive network of low density gas (n approx. few x 0.001/cu cm) existing at coronal temperatures log T = 5.3 or 6.3. Shocks created by supernova explosions or mass loss from early-type stars can propagate freely through space and eventually transfer a large amount of energy to the medium. To create the coronal temperatures, the shocks must have velocities in excess of 150 km/sec; shocks at somewhat lower velocity (v = 100 km/sec) can be directly observed in the lines of Si3. Observations of other lines in the ultraviolet, such as Si 4V and C 5, may highlight the widespread presence of energetic UV radiation from very hot, dwarf stars. More advanced techniques in visible and X-ray astronomical spectroscopy may open up for inspection selected lines from atoms in much higher stages of ionization.

Jenkins, Edward B.↗

NASA NTRS2006

Recent Selected Ion Flow Tube (SIFT) Studies Concerning the Formation of Amino Acids in the Gas Phase

Recently the simplest amino acid, glycine, has been detected in interstellar clouds, ISC, although this has since been contested. In order to substantiate either of these claims, plausible routes to amino acids need to be investigated. For gas phase synthesis, the SIFT technique has been employed to study simple amino acids via ion-molecule reactions of several ions of interstellar interest with methylamine, ethylamine, formic acid, acetic acid, and methyl formate. Carboxylic acid type ions were considered in the reactions involving the amines. In reactions where the carboxylic acid and methyl formate neutrals were studied, the reactant ions were primarily amine ion fragments. It was observed that the amines and acids preferentially fragment or accept a proton whenever energetically possible. NH3(+), however, uniquely reacted with the neutrals via atom abstraction to form NH4(+). These studies yielded a body of data relevant to astrochemistry, supplementing the available literature. However, the search for gas phase routes to amino acids using conventional molecules has been frustrated. Our most recent research investigates the fragmentation patterns of several amino acids and several possible routes have been suggested for future study.

Jackson, Douglas M.↗

NASA NTRS1973

Interstellar Na I, K I, Ca II, and CH/+/ line profiles toward zeta Ophiuchi.

Comparison of interferometric, photoelectric scans of interstellar absorption-line profiles of Na I, K I, Ca II, and CH(+) toward zeta Ophiuchi. Near a heliocentric velocity of -15 km/sec, there is a strong composite feature showing four components. The atomic and molecular absorption lines do not arise in a common volume of gas but rather in essentially different clouds whose atomic abundances and/or ionization balances vary substantially.

Hobbs, L. M.↗

NASA NTRS1992

Galactic worms. I - Catalog of worm candidates

A catalog of candidates for the Galactic worms that are possibly the walls surrounding the superbubbles is compiled; 118 isolated structures that appear both in H I and in IR (60 and 100 microns). Fifty-two are possibly associated with H II regions. It is found that the 100-micron emissivity increases systematically toward the Galactic interior, which is consistent with the increase of the general interstellar radiation field. The 100-micron emissivity of the structures associated with the H II regions is larger than that of the structures without associated H II regions. The 60-100-micron ratio is large, 0.28 +/- 0.03, which may indicate that the grains associated with the atomic gas have a relatively large population of small grains. Thirty-five structures appear in the 408-MHz continuum. The IR and the radio continuum properties suggest that the 408-MHz continuum emission in those structures is very likely thermal. The implications of these results on the ionization of gas far from the Galactic plane are discussed.

Koo, Bon-Chul↗

NASA NTRS1995

Determining large-scale heliospheric structure using ultraviolet resonance line observations

Currently the Pioneer 10 and Voyager 1 and 2 spacecraft are beyond the orbit of Pluto, traveling outward from the Sun. Each is capable of detecting ultraviolet radiation resonantly scattered from hydrogen and helium atoms in the heliosphere and local interstellar medium. These observations are particularly well suited for the investigation of the large-scale heliospheric H and He distributions because the Voyager spacecraft are heading upstream, into the direction of local interstellar flow, whereas Pioneer 10 is heading downstream. Observations of the brightest resonance line, H Lyman-alpha, reveals that beyond about 20 AU from the Sun, upstream intensities decrease less quickly as a function of solar distance than downstream intensities. This implies that the heliospheric H distributions in the upstream and downstream directions are significantly different. Heliospheric H atoms originate in the local interstellar flow, and must penetrate through the heliospheric interface, where they are subject to charge exchange collisions with solar wind and interstellar protons. Models indicate that this process is probably responsible for the upstream/downstream difference in H Lyman-alpha. In addition, a recent spectroscopic determination of the H atom velocity distribution in the inner heliosphere implies a significant deceleration in the bulk flow speed of the heliospheric hydrogen gas relative to the helium flow, an effect that is also likely due to H-p charge exchange occurring in the upstream heliospheric interface region. In this presentation, recent heliospheric resonance line observations and their interpretations will be reviewed, focusing on their sensitivity to large-scale heliospheric structure.

Hall, Doyle T.↗

NASA NTRS1975

Copernicus observations of interstellar absorption at Lyman alpha

Column densities NH of atomic hydrogen have been derived for 40 OB stars from spectral scans at Lyman alpha obtained by the Copernicus (OAO-3) satellite. The stars are all between 60 and 1100 pc away with a range of mean densities n sub H of 0.01 to 2.5 atoms cm-3. The gas to color-excess ratio in clouds varies from 1 to 3 times the mean outside of clouds. The presence of molecular hydrogen correlates with E(B-V), but the best tracer for H2 is atomic hydrogen. The mean density of the gas for all 40 stars is much smaller than the mean of 0.7 atoms cm-3 obtained from 21-cm observations, because the brightest stars with less than average amounts of matter in the line of sight were selected for observation.

Bohlin, R. C.↗

NASA NTRS1992

The interstellar gas experiment

The Interstellar Gas Experiment (IGE) exposed thin metallic foils to collect neutral interstellar gas particles. These particles penetrate the solar system due to their motion relative to the sun. Thus, it is possible to entrap them in the collecting foils along with precipitating magnetospheric and perhaps some ambient atmospheric particles. For the entire duration of the Long Duration Exposure Facility (LDEF) mission, seven of these foils collected particles arriving from seven different directions as seen from the spacecraft. In the mass spectroscopic analysis of the noble gas component of these particles, we have detected the isotopes of He-3, He-4, Ne-20, and Ne-22. In the foil analyses carried out so far, we find a distribution of particle arrival directions which shows that a significant part of the trapped particles are indeed interstellar atoms. The analysis needed to subtract the competing fluxes of magnetospheric and atmospheric particles is still in progress.

Lind, D. L.↗

NASA NTRS1993

Experimental technique to investigate the interstellar gas - Preliminary analysis

The Interstellar Gas Experiment (IGE) exposed thin metallic foils to collect neutral interstellar gas particles. These particles penetrate the solar system due to their motion relative to the sun. Thus, it was possible to entrap them in the collecting foils along with precipitating magnetospheric and perhaps some ambient atmospheric particles. For the entire duration of the Long Duration Exposure Facility mission, seven of these foils collected particles arriving from seven different directions as seen from the spacecraft. In the mass spectrometric analysis of the noble gas component of these particles, we have detected the isotopes of He-3, He-4, Ne-20, and Ne-22. In the foil analyses carried out so far, we find a distribution of particle arrival directions which shows that a significant part of the trapped particles are indeed interstellar atoms. The analysis needed to subtract the competing fluxes of magnetospheric and atmospheric particles is still in progress.

Lind, D. L.↗

NASA NTRS2003

The Evolution of Interstellar Gas: Massive Stars and the Dispersal of Neutral Material

We studied the effects of newly formed O and B stars on their surrounding interstellar material through a combination of observations and theoretical modeling. The observational data came from measurements of absorption seen in the spectra of background, newly formed stars. Particular attention was given to stellar radiation which converts molecular to atomic material. Laboratory data on absorption cross sections relevant to the analysis and interpretation of carbon monoxide formed part of the effort. The grant supported Postdoctoral Fellows, Drs. Min Yan and Yaron Sheffer, and a laboratory technician. Though the students themselves were not supported. one M.S. Thesis and two Ph.D. dissertations from the University of Toledo were based on the research done under the grant. The research accomplished under this grant led directly to other funded programs. An observing proposal to study the chemistry of diffuse molecular clouds in the Large and Small Magellanic Clouds with ESO s Very Large Telescope was another example of a successful outcome of my LTSA program.

Federman, Steven R.↗

NASA NTRS1985

The effect of a weak shock on interstellar gas toward the Rho Ophiuchi cloud

The effect of a low-velocity shock on depletion in interstellar clouds is studied. High-resolution Copernicus observations of interstellar absorption lines toward four stars in the Rho Ophiuchi cloud complex were used to measure differential depletion in interstellar clouds separated by velocities of 10-15 km/s. Optical observations of CH and CH(+) were used as indicators of shock strength and direction of propagation. Observations indicate the presence of a shock with velocity about 10 km/s expanding away from the sun into the Rho Oph cloud. The existence of this shock is supported by the other observations quoted in the literature. Two distinct regions in the lines of sight have been found. A low-density, less depleted, predominantly atomic region is associated with preshock gas, while postshock gas accounts for a predominantly molecular, more highly depleted region. Apparently a weak shock, has the effect of enhancing grain formation or grain growth as a result of increased density in the postshock gas. It is possible for grain growth by accretion to occur in the shocked gas on time scales short compared with the cloud-crossing time of the shock.

Meyers, K. A.↗

NASA NTRS1995

The life cycle of the Interstellar Medium in other galaxies

Gas in spiral galaxies cycles between the diffuse and dense phases as clouds collapse, form stars and are dispersed back into the ISM. Far infrared observations of continuum emission from interstellar dust and line emission from interstellar gas have revealed a wealth of information on the state of the ISM in galaxies of different morphological types. The analysis of these observations gives us information about the processes of star formation and about the evolution of the ISM. Star formation rates vary widely from galaxy to galaxy, with the rates in starburst galaxies being 10 - 100 times those in quiescent spiral galaxies. Far infrared spectroscopy of star-forming galaxies shows that the interstellar pressure increases with star formation rate. The structure of the interstellar medium in starburst galaxies is quite different from that of quiescent galaxies - much of the mass and volume are in HII regions and photodissociation regions. The size distribution of dust grains seems to depend on environment; small grains are abundant in the diffuse interstellar medium but not in dense molecular star forming regions. Quiescent spiral and elliptical galaxies contain a significant population of small grains, but starburst galaxies do not. Dwarf irregular galaxies also seem to contain few small grains; this may be the result of the higher UV flux in these galaxies. The star forming regions in dwarf irregulars also have a higher ratio of atomic to molecular gas than do those in the Galaxy. These results show that the ISM in galaxies of different morphological types reaches different equilibria, resulting in different modes of star formation and global galaxy evolution.

Knapp, G. R.↗

NASA NTRS1973

Solar wind heating beyond 1 AU

The effect of an interplanetary atomic hydrogen gas on solar wind proton, electron and alpha-particle temperatures beyond 1 AU is considered. It is shown that the proton temperature (and probably also the alpha-particle temperature) reaches a minimum between 2 AU and 4 AU, depending on values chosen for solar wind and interstellar gas parameters. Heating of the electron gas depends primarily on the thermal coupling of the protons and electrons. For strong coupling, the electron temperature reaches a minimum between 4 AU and 8 AU, but for weak coupling (Coulomb collisions only), the electron temperature continues to decrease throughout the inner solar system. A spacecraft travelling to Jupiter should be able to observe the heating effect of the solar wind-interplanetary hydrogen interaction, and from such observations it may be possible of infer some properties of the interstellar neutral gas.

Holzer, T. E.↗

NASA NTRS1981

Radio observations of molecules in the interstellar gas

Since 1968, radio astronomy has made it possible to identify nearly 50 molecules in the dense concentrations of the interstellar gas now generally termed molecular clouds. Most interstellar molecules are familiar stable compounds. However, one-fifth of the discovered species are ions, radicals, and acetylenic carbon chains so reactive in the laboratory that before being detected in space they had rarely been observed or were entirely unknown. The heavy atom backbone of the known interstellar molecules is a linear chain of C, N, O, or S. Si is found in two diatomic molecules. Rings and branched chains are missing. The most readily observed spectral lines of most interstellar molecules correspond to rotational transitions at millimeter wavelengths. These are generally excited by H2 collisions. A number of rare isotopic species are observed in interstellar molecules. Isotopic ratios differing from those on Earth exist, and can in almost all cases be attributed to stellar nucleosynthesis since the formation of the solar system.

Thaddeus, P.↗

NASA NTRS1994

A weak diffuse interstellar band in the far-ultraviolet spectrum of zeta Ophiuchi?

Goddard High Resolution Spectrograph (GHRS) observations at 3.5 km/s resolution reveal several new weak unidentified interstellar absorption lines in the ultraviolet spectrum of zeta Ophiuchi. The unidentified line at 1369.13 A has the appearance and characteristics of a weak diffuse interstellar band (DIB). The line has a smooth profile similar to many optical diffuse interstellar bands (i.e., a shallow asymmetric profile), it is clearly broader than identified interstellar lines near it in wavelength, and its full width at half maximum in ergs is comparable to the widths of the weak optical DIBs. The asymmetric profile cannot be attributed to blended absorption from diffuse clouds at different velocities; at this resolution the two principal cloud complexes on the sight line at heliocentric velocities of -27 and -15 km/s are clearly separated. We compare this unidentified absorption feature to identified interstellar atomic and molecular absorption lines and optical DIBs observed on the zeta Oph and xi Per sight lines, and we conclude that it is reasonable to suggest that this absorption feature might be a DIB. This is not a unique interpretation however; the unidentified line could alternatively be due to gas in the zeta Oph H II region or a blend of unknown neutral atomic or molecular absorption lines.

Tripp, Todd M.↗

NASA NTRS2012

Chemical and Hydrodynamical Models of Cometary Comae

Multi-fluid modelling of the outflowing gases which sublimate from cometary nuclei as they approach the Sun is necessary for understanding the important physical and chemical processes occurring in this complex plasma. Coma chemistry models can be employed to interpret observational data and to ultimately determine chemical composition and structure of the nuclear ices and dust. We describe a combined chemical and hydrodynamical model [1] in which differential equations for the chemical abundances and the energy balance are solved as a function of distance from the cometary nucleus. The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of 1P/Halley. The anions O(-), OH(-), C(-), CH(-) and CN(-) have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu [2]. Organic molecular anions such as C4H(-) and C6H(-) are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas-phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been fully explored. We present details of new models for the chemistry of cometary comae that include atomic and molecular anions and calculate the impact of these anions on the coma physics and chemistry af the coma.

Charnley, Steven↗

NASA NTRS2012

Models for Cometary Comae Containing Negative Ions

The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of IP/Halley. The anions O(-), OH(-), C(-), CH(-) and CN(-) have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu [I]. Organic molecular anions such as C4H(-) and C6H(-) are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been fully explored. We present details of our new models for the chemistry of cometary comae that include atomic and molecular anions. We calculate the impact of these anions on the charge balance and examine their importance for cometary coma chemistry.

Cordiner, M. A.↗

NASA NTRS1990

Optical coronal emission lines from equilibrium and cooling plasmas

A calculation has been made of the emission from gas at temperature of about 10 to the 6th K due to optical coronal lines that result from fine structure transitions within the ground states of highly ionized atoms. These lines include the Forbidden Fe X 6374-A line, the Forbidden Fe XIV 5303-A line, and many other lines from stages of ionization of S, Ca, Fe, and Ni. The calculations are valid in the limit of very low density, and apply to the diffuse gas found in supernova remnants, the interstellar medium in galaxies, and intergalactic gas. It is found that the amount of optical coronal emission produced by a given amount of cooling gas is largely unaffected by changes in element abundances (provided the proportions of heavy elements remain the same).

Graney, Christopher M.↗

NASA NTRS1998

The Anatomy of the Perseus Spiral Arm: 12 CO and IRAS Imaging Observations of the W3-W4-W5 Cloud Complex

Panoramic images of 12CO J = 1-0 and thermal dust emissions from the W3-W4-W5 region of the outer Galaxy are presented. These data and recently published H I 21 cm line emission images provide an approximate 1' resolution perspective to the dynamics and thermal energy content of the interstellar gas and dust components contained within a 9 deg. arc of the Perseus spiral arm. We tabulate the molecular properties of 1560 clouds identified as closed surfaces within the l-b-v CO data cube at a threshold of 0.9 K T* (sub R). Relative surface densities of the molecular (28:1) and atomic (2.5:1) gas components determined within the arm and interarm velocity intervals demonstrate that the gas component that enters the spiral arm is predominantly atomic. Molecular clouds must necessarily condense from the compressed atomic material that enters the spiral arm and are likely short lived within the interarm regions. From the distribution of centroid velocities of clouds, we determine a random cloud-to-cloud velocity dispersion of 4 km s (exp. -1) over the width of the spiral arm but find no clear evidence within the molecular gas for streaming motions induced by the spiral potential. The far-infrared images are analyzed with the CO J = 1-0 and H I 21 cm line emission. The enhanced UV (Ultraviolet) radiation field from members of the Cas OB6 association and embedded newborn stars provide a significant source of heating to the extended dust component within the Perseus arm relative to the quiescent cirrus regions. Much of the measured far-infrared flux (69% at 60 micrometers and 47% at 100 micrometers) originates from regions associated with star formation rather than the extended, infrared cirrus component.

Heyer, Mark H.↗