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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Spatial Engineering Direct Cooperativity between Binding Sites for Uranium Sequestration

Preorganization is a basic design principle used by nature that allows for synergistic pathways to be expressed. Herein, a full account of the conceptual and experimental development from randomly distributed functionalities to a convergent arrangement that facilitates cooperative binding is given, thus conferring exceptional affinity toward the analyte of interest. The resulting material with chelating groups populated adjacently in a spatially locked manner displays up to two orders of magnitude improvement compared to a random and isolated manner using uranium sequestration as a model application. This adsorbent shows exceptional extraction efficiencies, capable of reducing the uranium concentration from 5 ppm to less than 1 ppb within 10 min, even though the system is permeated with high concentrations of competing ions. The efficiency is further supported by its ability to extract uranium from seawater with an uptake capability of 5.01 mg g -1 , placing it among the highest-capacity seawater uranium extraction materials described to date. The concept presented here uncovers a new paradigm in the design of efficient sorbent materials by manipulating the spatial distribution to amplify the cooperation of functions.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1988

Molecular dynamics study of ion capture from water by a model ionophore, tetraprotonated cryptand SC24

The molecular dynamics of chloride capture from water by the tetraprotonated cryptand SC24 has been studied for the cases of 19 distances between the criptand and the chloride. The chloride capture is found to be characterized by a rapid cooperative change in the conformation of the cryptand when the Cl(-) begins to enter the ligand and just as it encounters the energy barrier. The conformational transition is associated with a shift of three N-H bonds from the pure endo orientation, such that they point toward the chloride.

Owenson, Brian↗
NASA NTRS1997

Centrality and collision system dependence of antiproton production from p+A to Au+Au collisions at AGS energies

Antiproton production in heavy ion collisions reflects subtle interplay between initial production and absorption by nucleons. Because the AGS energies (10--20 A(center-dot)GeV/c) are close to the antiproton production threshold, antiproton may be sensitive to cooperative processes such as QGP and hadronic multi-step processes. On the other hand, antiproton has been proposed as a probe of baryon density due to large N(anti N) annihilation cross sections. Cascade models predict the maximum baryon density reaches about 10 times the normal nucleus density in central Au+Au collisions, where the strong antiproton absorption is expected. In this paper, the authors show systematic studies of antiproton production from p+A to Au+Au collisions.

Sako, H.↗
DOE OSTI2023

Highly efficient synthesis of zeolite chabazite using cooperative hydration-mismatched inorganic structure-directing agents

Chabazite (CHA type) zeolite is notoriously difficult to synthesize in the absence of organic structure-directing agents owing to long synthesis times and/or impurity formation. The ability to tailor organic-free syntheses of zeolites is additionally challenging due to the lack of molecular level understanding of zeolite nucleation and growth pathways, particularly the role of inorganic cations. In this study, we reveal that zeolite CHA can be synthesized using six different combinations of inorganic cations, including the first reported seed- and organic-free synthesis without the presence of potassium. We show that lithium, when present in small quantities, is an effective accelerant of CHA crystallization; and that ion pairings can markedly reduce synthesis times and temperatures, while expanding the design space of zeolite CHA formation in comparison to conventional methods utilizing potassium as the sole structure-directing agent. Herein, we posit the effects of cation pairings on zeolite CHA crystallization are related to their hydrated ionic radii. We also emphasize the broader implications for considering the solvated structure and cooperative role of inorganic cations in zeolite synthesis within the context of the reported findings for chabazite.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1977

A shock tube study of line broadening in a temperature range of 6100 to 8300 K

Line widths of the Ca(II) 3968 A and Na(I) 5890 A resonance lines broadened by electric microfields in a plasma were measured. A pressure-driven shock tube was used as the light source. Radiation from the equilibrium region behind the reflected shock wave was studied using a rapid scanning Fabry-Perot interferometer. Electron and argon atom densities of about 8 x 10 to the 16th and 1 x 10 to the 19th/cu cm, respectively, were achieved at the relatively low temperature of around 7500 K by vaporizing a cesium powder that had been added to the shock tube as a solid aerosol in argon gas. The measured line widths were predominantly Stark broadened by the electrons and ions in the plasma, although Doppler, van der Waals, instrument function and optical depth effects had to be taken into account.

Baur, J. F.↗
NASA NTRS2006

Titan Ion Composition at Magnetosphere-Ionosphere Transition Region

Using Cassini Plasma Spectrometer (CAPS) Ion Mass Spectrometer (IMS) ion composition data, we will investigate the compositional changes at the transition region between Saturn's magnetospheric flow and Titan's upper ionosphere. It is this region where scavenging of Titan's upper ionosphere can occur, where it is then dragged away by the magnetospheric flow as cold plasma for Saturn's magnetosphere. This cold plasma may form plumes as originally proposed by (1) during the Voyager 1 epoch. This source of cold plasma may have a unique compositional signature such as methane group ions. Water group ions that are observed in Saturn's outer magnetosphere (2,3) are relatively hot and probably come from the inner magnetosphere where they are born from fast neutrals escaping Enceladus (4) and picked up in the outer magnetosphere as hot plasma (5). This scenario will be complicated by pickup methane ions within Titan's mass loading region, as originally predicted by (6) based on Voyager 1 data and observationally confirmed by (3,7) using CAPS IMS data. But, CH4(+) ions or their fragments can only be produced as pickup ions from Titan's exosphere which can extend beyond the transition region of concern here, while CH5(+) ions can be scavenged from Titan's ionosphere. We will investigate these possibilities.

Sittler, Edward C.↗
NASA NTRS2011

Saturn's Magnetosphere Interaction with Titan for T9 Encounter: 3D Hybrid Modeling and Comparison with CAPS Observations

Global dynamics of ionized and neutral gases in the environment of Titan plays an important role in the interaction of Saturn s magnetosphere with Titan. Several hybrid simulations of this problem have already been done (Brecht et al., 2000; Kallio et al., 2004; Modolo et al., 2007a; Simon et al., 2007a, 2007b; Modolo and Chanteur, 2008). Observational data from CAPS for the T9 encounter (Sittler et al., 2009) indicates an absence of O(+) heavy ions in the upstream that change the models of interaction which were discussed in current publications (Kallio et al., 2004; Modolo et al., 2007a; Simon et al., 2007a, 2007b; Ma et al., 2007; Szego et al., 2007). Further analysis of the CAPS data shows very low density or even an absence of H(+) ions in upstream. In this paper we discuss two models of the interaction of Saturn s magnetosphere with Titan: (A) high density of H(+) ions in the upstream flow (0.1/cu cm), and (B) low density of H(+) ions in the upstream flow (0.02/cu cm). The hybrid model employs a fluid description for electrons and neutrals, whereas a particle approach is used for ions. We also take into account charge-exchange and photoionization processes and solve self-consistently for electric and magnetic fields. The model atmosphere includes exospheric H(+), H(2+), N(2+)and CH(4+) pickup ion production as well as an immobile background ionosphere and a shell distribution for active ionospheric ions (M(sub i)=28 amu). The hybrid model allows us to account for the realistic anisotropic ion velocity distribution that cannot be done in fluid simulations with isotropic temperatures. Our simulation shows an asymmetry of the ion density distribution and the magnetic field, including the formation of Alfven wing-like structures. The results of the ion dynamics in Titan s environment are compared with Cassini T9 encounter data (CAPS).

Lipatov, A. S.↗
DOE OSTI2024

Giant elastocaloric effect at low temperatures in TmVO 4 and implications for cryogenic cooling

Adiabatic decompression of paraquadrupolar materials has significant potential as a cryogenic cooling technology. We focus on TmVO 4 , an archetypal material that undergoes a continuous phase transition to a ferroquadrupole-ordered state at 2.15 K. Above the phase transition, each Tm ion contributes an entropy of k B ln 2 due to the degeneracy of the crystal electric field groundstate. Owing to the large magnetoelastic coupling, which is a prerequisite for a material to undergo a phase transition via the cooperative Jahn–Teller effect, this level splitting, and hence the entropy, can be readily tuned by externally induced strain. Using a dynamic technique in which the strain is rapidly oscillated, we measure the adiabatic elastocaloric response of single-crystal TmVO 4 , and thus experimentally obtain the entropy landscape as a function of strain and temperature. The measurement confirms the suitability of this class of materials for cryogenic cooling applications and provides insight into the dynamic quadrupole strain susceptibility.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2002

Stirring Up an Elastic Fluid: Critical Viscosity of Xenon-2 (CVX-2)

Whipped cream stays in place even when turned upside down. Yet it readily flows through the nozzle of a spray can to reach the dessert plate. This demonstrates the phenomenon of shear thinning that is important to many industrial and physical processes. Paints, film emulsions, and other complex solutions that are highly viscous under normal conditions but become thin and flow easily under shear forces. A simple fluid, such as water, does not exhibit shear thinning under normal conditions. Very close to the liquid-vapor critical point, where the distinction between liquid and vapor disappears, the fluid becomes more complex and is predicted to display shear thinning. At the critical point, xenon atoms interact over long distances in a classical model of cooperative phenomena. Physicists rely on this system to learn how long-range order arises. The Critical Viscosity of Xenon Experiment (CVX-2) will measure the viscous behavior of xenon, a heavy inert gas used in flash lamps and ion rocket engines, at its critical point. Although it does not easily combine with other chemicals, its viscosity at the critical point can be used as a model for a range of fluids. Viscosity originates from the interactions of individual molecules. It is so complicated that, except for the simplest gas, it cannot be calculated accurately from theory. Tests with critical fluids can provide key data, but are limited on Earth because critical fluids are highly compressed by gravity. CVX-2 employs a tiny metal screen vibrating between two electrodes in a bath of critical xenon. The vibrations and how they dampen are used to measure viscosity. CVX flew on STS-85 (1997), where it revealed that, close to the critical point, the xenon is partly elastic: it can 'stretch' as well as flow. For STS-107, the hardware has been enhanced to determine if critical xenon is a shear-thinning fluid.

Berg, Robert F.↗
NASA NTRS1985

Excessive production of electron pairs by soft photons in low multiplicity ion interactions

Three multiply charged primary cosmic ray interactions with carbon nuclei are reported, in which the number of materialized electron pairs within a distance of about 0.3 conversion length is larger than predicted from isospin considerations. These are the most energetic (sigma E gamma 4 TeV) of the low multiplicity ( 15 tracks) events observed in the Japanese-American Cooperative Experiment (JACEE-2) emulsion chamber.

Burnett, T. H.↗
DOE OSTI2023

Sequence-dependent self-assembly of supramolecular nanofibers in periodic dynamic block copolymers

Block copolymers (BCPs) can spontaneously self-assemble into various nanostructured morphologies which enable their diverse applications in selective membranes, polymer electrolytes, and optoelectronics. To expand the range of nanostructures accessible to block copolymers, we designed dynamic block copolymers (DBCPs) that combine the phase separation of traditional block copolymers with the supramolecular self-assembly of periodic dynamic polymers. We demonstrate that DBCPs synthesized with a periodic block sequence self-assemble into high aspect ratio supramolecular nanofibers with well-ordered PEG and PDMS domains, in contrast to those synthesized with a random sequence which do not form nanofibers but have disordered morphologies. The periodicity of the block sequence ensures regular placement of dynamic bonds along the polymer chain, which enables stacking of the hydrogen bonding units into ordered 1D supramolecular nanofibers and delays the onset of terminal flow by up to 60 °C compared to the random block sequence. The hierarchically assembled supramolecular nanofibers display complex mechanical and thermal phase behavior arising from the interplay between phase separation of the dissimilar polymer backbones and supramolecular interactions between dynamic bonds. Despite identical bulk composition, the periodic DBCPs demonstrate ionic conductivity values over two orders of magnitude higher than their random counterparts due to the formation of well-ordered, interconnected, high aspect ratio ion-transporting PEG domains. In conclusion, these results highlight the potential for DBCPs as an emerging material platform to achieve advanced, self-assembled nanostructured morphologies.

36 MATERIALS SCIENCE↗
NASA NTRS1998

Miniature High-Let Radiation Spectrometer for Space and Avionics Applications

This paper reports on the design and characterization of a small, low power, and low weight instrument, a High-LET Radiation Spectrometer (HiLRS), that measures energy deposited by heavy ions in microelectronic devices. The HILRS operates on pulse-height analysis principles and is designed for space and avionics applications. The detector component in the instrument is based on large scale arrays of p-n junctions. In this system, the pulse amplitude from a particle hit is directly proportional to the particle LET. A prototype flight unit has been fabricated and calibrated using several heavy ions with varying LETs and protons with several energies. The unit has been delivered to the Ballistic Missile Defense Organization (BMDO) c/o the Air Force Research Laboratory in Albuquerque, NM, for integration into the military Space Technology Research Vehicle (STRV), a US-UK cooperative mission. Another version of HILRS is being prepared for delivery in April to the Hubble Space Telescope (HST) project, to fly on the HST Orbital Systems Test (HOST) Platform on a shuttle mission.

Stassinopoulos, E. G.↗
NASA NTRS2024

Exploring Earth's Interface with Space: The Scientific Case for a Satellite Mission to the Lower Thermosphere-Ionosphere Transition Region

The ESA-NASA Lower Thermosphere-Ionosphere Science (ENLoTIS) Working Group was formed in May 2022 to cooperatively explore future lower thermosphere-ionosphere (LTI) satellite mission concepts, targeting very low altitudes (100-200 km) with in situ sampling of relevant geophysical parameters associated with the neutral atmosphere, the ionosphere’s plasma, electromagnetic fields, and energetic particles, which, together with modeling, would enable significant advancements in the understanding of neutral-ion interactions and other related science and space weather topics in this critical region of Geospace. The LTI region has been identified as one of considerable interest to both NASA and ESA. Most recently, the Daedalus mission study was carried out under the remit of ESA’s Earth Observation Programmes (EOP) Directorate competitive Earth Explorer 10 pre-feasibility (Phase 0) activities. Furthermore, many NASA studies have also focused on the LTI region, including both directed missions with dipping spacecraft, such as the initial TIMED dual-satellites and the GEC constellation, as well as numerous highly-rated Explorer proposals targeting the LTI. Although the Daedalus mission was not selected, the ESA Advisory Committee on Earth Observation (ACEO) ranked it highly on scientific grounds and encouraged further study activities to mature the concept, exploring potential international collaboration. Subsequent bilateral discussions with NASA’s Science Mission Directorate (SMD) noted that such a concept was in alignment with the 2020 SMD science plan – Science 2020-2024: A Vision for Scientific Excellence – along with other complimentary activities within the NASA Heliophysics Division. Building on NASA’s and ESA’s long history of very successful collaborations, this mutual interest in LTI science led to the establishment of a new inter-agency and cross-discipline science connection, linking the ESA EOP Climate Action, Sustainability and Science Department and the NASA Heliophysics Division. Initial exploratory discussions led to the formation of the ENLoTIS Working Group, which was directed to explore the science case behind a potential joint LTI mission. Members of the ENLoTIS Working Group are listed below, consisting of 7 scientists from ESA Member and Cooperating States and 7 scientists from the United States. The working group held 3 “in person” meetings over the course of 18 months, interspersed with regular virtual meetings on a more frequent basis. This report constitutes their chief findings and recommendations.

thermosphere↗
NASA NTRS1999

Closing Report for NASA Cooperative Agreement NASA-1-242

Reliable estimates of exposures due to ionizing radiations are of paramount importance in achieving human exploration and development of space, and in several technologically important and scientifically significant areas impacting on industrial and public health. For proper assessment of radiation exposures reliable transport codes are needed. An essential input to the transport codes is the information about the interaction of ions and neutrons with the matter. Most of the information about this interaction is put in by nuclear cross section data. In order to obtain an accurate parameterization of cross sections data, theoretical input is indispensable especially for the processes where there is little or no experimental data available. In the grant period reliable data base was developed and a phenomenological model was developed for the total absorption cross sections valid for any charged/uncharged light, medium and heavy collision pairs valid for the entire energy range. It is gratifying to note the success of the model. The cross sections model has been adopted and is in use in NASA cosmic ray detector development projects, the radiation protection and shielding programs and several DoE laboratories and institutions. A list of the publications based on the work done during the grant period is given below and a sample copy of one of the papers is enclosed with this report.

Maung, Khin Maung↗