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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Mars - The role of the regolith in volatile storage and atmospheric evolution

Earth-based observations of the optical properties of Mars, laboratory alteration experiments, Mariner 9 data, and Viking lander observations are reviewed which indicate the existence of hydrated minerals on the Martian surface. The problem of estimating the total inventory of H2O, CO2, and other volatiles that may be stored in the Martian regolith is discussed, and morphological evidence is cited which supports the possible occurrence of hard-frozen permafrost in some areas on Mars. Physical adsorption of CO2 in the Martian regolith is considered, buffering of atmospheric pressure by regolith-atmosphere reequilibration is examined, and the problem of the exceedingly low inventory of Ar-36 in the Martian atmosphere is investigated. The possibility is considered that earth's degassing history may have had a larger component of long-diffusion-path degassing from a large hot body while the Martian surface inventory may have received a proportionately greater contribution from volatization of accreting particles.

Fanale, F. P.↗
DOE OSTI2026

First-Principles Insights into Proton-Coupled Electron Transfer versus Hydrogen Evolution Reaction Selectivity from a Base-Appended Cobaltocene Mediator

Performing selective proton-coupled electron transfer (PCET) to substrates such as N 2 , CO 2 , and unsaturated organic molecules under electrochemical conditions requires the suppression of the competing hydrogen evolution reaction (HER). To address this challenge, our laboratory previously demonstrated a PCET mediator strategy using a dimethylaniline-appended cobaltocene complex, [(CpCoCp NMe2 )H] + , which performs selective reductive chemistry while suppressing the HER. However, the origin of the suppressed, yet still observable, HER has not been thoroughly established. In this work, we perform density functional theory (DFT) calculations to elucidate the HER mechanism involving this redox mediator and to provide atomistic insights into the bifurcation between the PCET and HER pathways. We find that protonation of the aniline moiety to form [CpCoCp NMe2H ] + is more favorable, both kinetically and thermodynamically, than formation of the ring-protonated species [(CpCo(Cp-H) NMe2 )] + . Furthermore, PCET to acetophenone is energetically more favorable via [CpCoCp NMe2H ] + than via [(CpCo(Cp-H) NMe2 )] +1/0 . In contrast, the most favorable HER pathway involves the ring-protonated Co(I) species. These results offer mechanistic insights into HER versus PCET bifurcation and establish guiding principles for designing PCET mediators for selective electroreductive transformations.

evolution reactions↗
NASA NTRS1974

Natural evidence for chemical and early biological evolution

Oparin (1924) and Haldane (1929) have independently hypothesized that life arose under reducing conditions through an evolutionary sequence of events involving increasingly complex organic substances. The natural evidence for this hypothesis of chemical evolution is considered, giving particular attention to tangible samples which have been chemically analyzed in earth-bound laboratories. It is found that meteorites provide naturally occurring evidence in support of chemical evolution, but not of biological evolution. Studies on the early Precambrian Swaziland Sequence and the Bulawayan System of southern Africa provide evidence for very early biological evolution.

Kvenvolden, K. A.↗
NASA NTRS1998

Evolution of Interstellar Grains

During the past two decades observations combined with laboratory simulations, have revolutionized our understanding of interstellar ice and dust, the raw materials from which planets, comets and stars form. Most interstellar material is concentrated in large molecular clouds where simple molecules are formed by dust-grain and gas-phase reactions. Gaseous species striking the cold (10K) dust stick, forming an icy grain mantle. This accretion, coupled with UV photolysis, produces a complex chemical mixture containing volatile, non-volatile, and isotopically fractionated species. Ices in molecular clouds contain the very simple molecules H2O, CH3OH, CO, CO2, H2, and perhaps some NH3 and H2CO, as well as more complex species. The evidence for these compounds, as well as carbon-rich materials, will be reviewed and the possible connections with comets and meteorites will be presented in the first part of the talk . The second part of the presentation will focus on interstellar/precometary ice photochemical evolution and the species likely to be found in comets. The chemical composition and photochemical evolution of realistic interstellar/pre-cometary ice analogs will be discussed. Ultraviolet photolysis of these ices produces H2, H2CO, CO2, CO, CH4, HCO, and more complex molecules. When ices representative of interstellar grains and comets are exposed to UV radiation at low temperature a series of moderately complex organic molecules are formed in the ice including: CH3CH2OH (ethanol), HC(=O)NH2 (formamide), CH3C(=O)NH2 (acetamide), and R-C=N (nitriles). Several of these are already known to be in the interstellar medium, and their presence indicates the importance of grain processing. After warming to room temperature an organic residue remains. This is composed primarily of hexamethylenetetramine (HMT, C6H12N4), with lesser amounts of polyoxymethylene-related species (POMs), amides, and ketones. This is in sharp contrast to the organic residues produced by irradiating unrealistic interstellar ice analogs or thermally promoted polymerization-type reactions in unirradiated realistic ice mixtures.

Allamandola, Lou J.↗
NASA NTRS1985

Images in the rocket ultraviolet - The initial helium abundance and distance modulus of the globular cluster M5 from photometry of horizontal-branch stars

A natural laboratory for the study of postmain-sequence evolution of low-mass (less than one solar mass) metal-poor stars is provided by globular clusters. These clusters are, therefore, a critical aid for developing an understanding of advanced stages of stellar evolution and of the chemical evolution of the Galaxy. Bohlin et al. (1983) have described a study of the postasymptotic branch star near the center of M5. The present investigation is concerned with the fainter horizontal-branch stars. The observations were made with the aid of a rocket-borne 38 cm f/9.0 Ritchey-Chretien telescope. Attention is given to payload and flight data, preflight bandpass calibration, the reduction of flight data, star selection, position measurement, photometry, the minimum observed horizontal-branch mass and inferences on mass loss, and individual UV-bright stars.

Bohlin, R. C.↗
NASA NTRS2017

Interplanetary Coronal Mass Ejection Observed at STEREO-A, Mars, Comet 67P/Churyumov-Gerasimenko, Saturn,and New Horizons En Route to Pluto: Comparison of Its Forbush Decreases at 1.4, 3.1, and 9.9 AU

We discuss observations of the journey throughout the Solar System of a large interplanetary coronal mass ejection (ICME) that was ejected at the Sun on 14 October 2014. The ICME hit Mars on 17 October, as observed by the Mars Express, Mars Atmosphere and Volatile EvolutioN Mission (MAVEN), Mars Odyssey, and Mars Science Laboratory (MSL) missions, 44 h before the encounter of the planet with the Siding-Spring comet, for which the space weather context is provided. It reached comet 67P/Churyumov-Gerasimenko, which was perfectly aligned with the Sun and Mars at 3.1 AU, as observed by Rosetta on 22 October. The ICME was also detected by STEREO-A on 16 October at 1 AU, and by Cassini in the solar wind around Saturn on the 12 November at 9.9 AU. Fortuitously, the New Horizons spacecraft was also aligned with the direction of the ICME at 31.6 AU. We investigate whether this ICME has a nonambiguous signature at New Horizons. A potential detection of this ICME by Voyager 2 at 110-111 AU is also discussed. The multispacecraft observations allow the derivation of certain properties of the ICME, such as its large angular extension of at least 116deg, its speed as a function of distance, and its magnetic field structure at four locations from 1 to 10 AU. Observations of the speed data allow two different solar wind propagation models to be validated. Finally, we compare the Forbush decreases (transient decreases followed by gradual recoveries in the galactic cosmic ray intensity) due to the passage of this ICME at Mars, comet 67P, and Saturn.

Witasse, O.↗
NASA NTRS2021

TESS-Keck Survey. V. Twin Sub-Neptunes Transiting the Nearby G Star HD 63935

We present the discovery of two nearly identically sized sub-Neptune transiting planets orbiting HD 63935, abright(V=8.6 mag), Sun-like(Teff=5560 K)star at 49 pc. TESS identified thefirst planet, HD 63935 b(TOI-509.01), in Sectors 7 and 34. We identified the second signal(HD 63935 c)in Keck High Resolution EchelleSpectrometer and Lick Automated Planet Finder radial velocity data as part of our follow-up campaign. It wassubsequently confirmed with TESS photometry in Sector 34 as TOI-509.02. Our analysis of the photometric andradial velocity data yielded a robust detection of both planets with periods of 9.0600±0.007 and 21.40±0.0019days, radii of 2.99±0.14 and 2.90±0.13R⊕, and masses of 10.8±1.8 and 11.1±2.4M⊕. We calculated densities for planets b and c consistent with a few percent of the planet mass in hydrogen/helium envelopes. Wealso describe our survey’s efforts to choose the best targets for James Webb Space Telescope atmospheric follow-up. These efforts suggest that HD 63935 b has the most clearly visible atmosphere of its class. It is the best targetfor transmission spectroscopy(ranked by the transmission spectroscopy metric, a proxy for atmosphericobservability)in the so far uncharacterized parameter space comprising sub-Neptune-sized(2.6R⊕<Rp<4R⊕),moderately irradiated(100F⊕<Fp<1000F⊕)planets around G stars. Planet c is also a viable target fortransmission spectroscopy, and given the indistinguishable masses and radii of the two planets, the system servesas a natural laboratory for examining the processes that shape the evolution of sub-Neptune planets.

Nicholas Scarsdale↗
NASA NTRS2017

LCRD Update and Path to Optical Relay Operations

Speaker and Presenter at the Lincoln Laboratory Communications Workshop on May 23, 2017 at the Massachusetts Institute of Technology Lincoln Laboratory in Lexington, MA. This presentation discusses a concept for an evolution of NASAs optical communications near-Earth relay architecture. NASA's Laser Communications Relay Demonstration (LCRD) is a joint project between NASAs Goddard Space Flight Center (GSFC), the Jet Propulsion Laboratory California Institute of Technology (JPL), and the Massachusetts Institute of Technology Lincoln Laboratory (MIT LL). LCRD will provide a minimum of two years of high data rate optical communications service experiments in geosynchronous orbit (GEO) following launch in 2019. This presentation will provide an update of the LCRD mission status and planned capabilities and experiments, followed by a discussion of the path from LCRD to operational network capabilities.

Space Communications↗
DOE OSTI2025

Final report on assessment of molten salt corrosion testing of unirradiated and ion irradiated advanced manufactured high entropy alloys

Generation IV reactors and future fusion reactor designs have led to more demanding materials performance requirements due to their increased operating temperatures, corrosive coolants, and increased radiation doses compared to the current light-water reactor fleet. Among the innovative nuclear technologies under development, molten salt reactors stand out for their potential to offer superior fuel utilization, intrinsic safety characteristics, and economic viability. Of the proposed Generation IV designs, the gas fast reactor operates at 450 to 850°C and the molten salt reactor operates at 565 to 850°C, with the molten salt reactor design needing molten salt corrosion resistant materials [1, 2]. These increased temperatures and more extreme corrosion environments necessitate higher material performance, such as creep strength, radiation-tolerant microstructures, corrosion resistance, and high-temperature tensile properties. Hastelloy-N, a nickel-based alloy with additions of molybdenum and chromium, has been successfully employed to contain molten fluoride salt at temperatures up to 705°C. However, Hastelloy-N becomes embrittled upon neutron irradiation, primarily due to the accumulation of helium produced by (n,a) transmutation reactions. Furthermore, the corrosive nature of molten fluoride and chloride salts presents a formidable challenge, as these salts can react with and dissolve alloying elements such as Cr, Mo, and Fe, leading to selective leaching, loss of protective oxide layers, and accelerated degradation. High entropy alloys (HEAs) and refractory high entropy alloys (RHEAs) have emerged as a prominent area of interest, due to their ability to achieve tailored chemical compositions for specific applications. Unlike conventional alloys, HEAs are characterized by having multiple principal elements in equimolar or near equimolar ratios, leading to an unconventional alloying strategy [3]. This alloying strategy is believed to promote unique properties, such as single-phase stabilization of chemically compatible elements, lattice distortion effects due to atomic radius differences, and proposed sluggish diffusion effects. For extreme-environment applications, RHEAs have garnered much research interest because of the possibility of creating relatively ductile materials that can operate in extremely high-temperature environments, beyond the operating temperatures where other Ni-based superalloys begin to lose strength [4-6]. Idaho National Laboratory (INL) initiated a joint international effort with the Czech Republic to explore the feasibility of manufacturing HEAs for high-temperature nuclear applications using advanced manufacturing. This effort was funded at INL by the United States Department of Energy's Office of Nuclear Energy under the Advanced Reactor Technologies and Advanced Materials and Manufacturing Technologies (AMMT) Program. The HEAs were specifically designed for the corrosive and irradiation environments experienced in gas-cooled fast reactors, molten salt reactors, and fusion power. These alloys have been manufactured by multiple processes to determine the impact of manufacturing processes on the performance of the alloys in corrosive and irradiation environments. Preliminary molten salt corrosion testing showed that equimolar MoNbTiV and MoNbTi alloys exhibit exceptional performance, with arc-melted variants demonstrating only minimal degradation after 1000 hours of exposure to molten chloride salt at 700°C. Conversely, Nb2TiVZr2 showed significant molten salt corrosion susceptibility and microstructural instability during high-temperature molten salt exposures, and was, therefore deemed unfit for molten salt reactor applications. The MoNbTiV, MoNbTi, and Nb2TiVZr2 alloys were further evaluated through ion irradiation experiments conducted at the Michigan Ion Beam Laboratory at the University of Michigan. The microstructural stability and the evolution of irradiation-induced defects were characterized to assess the irradiation resistance of each of these alloys.

36 - MATERIALS SCIENCE↗
NASA NTRSDate not supplied

Spectrally Resolving High Redshift Dual AGNs with the Line Emission Mapper

The Line Emission Mapper (LEM) is an X-ray Probe-class Mission concept which combines 1-2 eV spectral resolution in the soft X-ray band (0.2-2 keV) with an effective area of ~2600 cm^2 at 1 keV, and 10’’ HPD over a large 30'x30' field of view. The mission will directly address the Astro2020 Decadal Report’s Priority Area of Unveiling the Drivers of Galaxy Growth through the study of merging galaxies, which offer one of the most dramatic channels for galaxy growth and evolution and can potentially trigger both star formation and supermassive black hole (SMBH) growth. Dual and binary AGNs in late-stage mergers are predicted to be a critical stage of merger-induced SMBH growth and coincide with the most transformative period for the host galaxies. Thus, dual and binary AGNs represent ideal laboratories for studying examples of SMBH-galaxy co-evolution. Recent discoveries of dual AGNs at redshifts of z~>2 have been made via optical observations, but such dual AGNs are inaccessible to current X-ray observatories due to a lack of instrumental capabilities, including sensitivity, spectral and spatial resolution. LEM will be uniquely suited to study AGNs at z > 3, where the intrinsic X-ray power law continuum and Iron K alpha emission line - a nearly ubiquitous signpost for AGN accretion – are redshifted into the LEM bandpass. In this poster, we present a simulation-based study on LEM’s ability to discern dual, binary, and/or clustered AGNs at high redshift. We demonstrate the unique capabilities of LEM to spectrally resolve Iron K-alpha lines emitted by distinct AGNs with sufficient line-of-sight velocity differences, even in cases of convolved point sources. Using a suite of simulations probing a range of velocity differences, line strengths, and column densities, we demonstrate LEM’s ability to constrain the spectral properties of dual AGNs at z>3 for a variety of physically realistic pairings. LEM will uniquely provide crucial constraints on dual AGN environments and activity as a function of redshift and will complement optical and infrared observations from upcoming Extremely Large Telescopes.

Ryan W Pfeifle↗
NASA NTRS1981

Copolyamino acid fractionation and protobiochemistry

Investigation of the origins of living things by the uniquely appropriate method of successive approximation in attempted retracement of steps in molecular evolution has yielded: a comprehensive theoretical flowsheet from archaic inanimate matter to an infrastructured, microscopic, protoreproductive, protometabolic protocell; a laboratory model of the same; and an explanatory assessment of the natural variation component of Darwinian evolution. For each of these, the significance is dependent upon awareness of the intrinsic tendency of amino acids, in mixed sets, to order themselves. Without such awareness, it is believed these vistas would have been delayed for decades. Selfordering would have in turn been difficult to recognize and support were it not for the chromatographic developments in fractionation of copolyamino acids.

Fox, S. W.↗
NASA NTRS2011

Stress-Driven Selection of Novel Phenotypes

A process has been developed that can confer novel properties, such as metal resistance, to a host bacterium. This same process can also be used to produce RNAs and peptides that have novel properties, such as the ability to bind particular compounds. It is inherent in the method that the peptide or RNA will behave as expected in the target organism. Plasmid-born mini-gene libraries coding for either a population of combinatorial peptides or stable, artificial RNAs carrying random inserts are produced. These libraries, which have no bias towards any biological function, are used to transform the organism of interest and to serve as an initial source of genetic variation for stress-driven evolution. The transformed bacteria are propagated under selective pressure in order to obtain variants with the desired properties. The process is highly distinct from in vitro methods because the variants are selected in the context of the cell while it is experiencing stress. Hence, the selected peptide or RNA will, by definition, work as expected in the target cell as the cell adapts to its presence during the selection process. Once the novel gene, which produces the sought phenotype, is obtained, it can be transferred to the main genome to increase the genetic stability in the organism. Alternatively, the cell line can be used to produce novel RNAs or peptides with selectable properties in large quantity for separate purposes. The system allows for easy, large-scale purification of the RNAs or peptide products. The process has been reduced to practice by imposing sub-inhibitory concentrations of NiCl2 on cells of the bacterium Escherichia coli that were transformed separately with the peptide library and RNA library. The evolved resistant clones were isolated, and sequences of the selected mini-gene variants were established. Clones resistant to NiCl2 were found to carry identical plasmid variants with a functional mini-gene that specifically conferred significant nickel tolerance on the host cells. Sequencing of the selected mini-gene revealed a propensity of the encoded peptide to bind transient metal ions. Expression of the mini-gene markedly improved growth parameters of the evolved clones at sub-inhibitory concentrations of NiCl2 while being slightly detrimental in the absence of stress. Similar results have been obtained with the RNA libraries. Overall, the results demonstrate a very natural outcome of the selection experiments in which the mini-genes were expected to be either successfully integrated into bacterial genetic networks, or rejected depending upon their effect on host fitness. This described approach can be useful as a laboratory model to study the dynamics of bacterial adaptive evolution on the molecular level. It can also provide a strategy for screening expressed DNA libraries in search of novel genes with desirable properties.

Fox, George E.↗
NASA NTRS2012

Designing Mission Operations for the Gravity Recovery and Interior Laboratory Mission

NASA's Gravity Recovery and Interior Laboratory (GRAIL) mission, to understand the internal structure and thermal evolution of the Moon, offered unique challenges to mission operations. From launch through end of mission, the twin GRAIL orbiters had to be operated in parallel. The journey to the Moon and into the low science orbit involved numerous maneuvers, planned on tight timelines, to ultimately place the orbiters into the required formation-flying configuration necessary. The baseline GRAIL mission is short, only 9 months in duration, but progressed quickly through seven very unique mission phases. Compressed into this short mission timeline, operations activities and maneuvers for both orbiters had to be planned and coordinated carefully. To prepare for these challenges, development of the GRAIL Mission Operations System began in 2008. Based on high heritage multi-mission operations developed by NASA's Jet Propulsion Laboratory and Lockheed Martin, the GRAIL mission operations system was adapted to meet the unique challenges posed by the GRAIL mission design. This paper describes GRAIL's system engineering development process for defining GRAIL's operations scenarios and generating requirements, tracing the evolution from operations concept through final design, implementation, and validation.

MOS↗
NASA NTRS1986

Experimental study of the influence of wind on Benjamin-Feir sideband instability

A laboratory investigation of the influence of wind on the evolution of mechanically generated regular (m.g.r.) waves is reported. Surface elevation measurements were made at four fetches for steep (0.1 less than ak(bar) less than 0.2, 2 Hz) m.g.r. waves, moderate (15 less than u(asterisk) less than 25 cm/s, 3-6 Hz) wind waves, and combinations of the m.g.r. and wind waves. The m.g.r. wave spectra exhibit Benjamin-Feir sidebands that grow exponentially with fetch and whose growth rate increases as the initial wave steepness increases. As fetch increases for the wind cases, total energy increases and the frequency of the spectral maximum downshifts, but no spectral lines representing Benjamin-Feir sidebands were detected even though the wave steepness and fetch were similar to the m.g.r. waves whose spectra displayed sidebands. As wind speed increased over the m.g.r. waves, sideband magnitude, sideband growth rate, and low-frequency perturbation components associated with the instability mechanism were reduced.

Bliven, L. F.↗
NASA NTRS1993

The evolving trend in spacecraft health analysis

The Space Flight Operations Center inaugurated the concept of a central data repository for spacecraft data and the distribution of computing power to the end users for that data's analysis at the Jet Propulsion Laboratory. The Advanced Multimission Operations System is continuing the evolution of this concept as new technologies emerge. Constant improvements in data management tools, data visualization, and hardware lead to ever expanding ideas for improving the analysis of spacecraft health in an era of budget constrained mission operations systems. The foundation of this evolution, its history, and its current plans will be discussed.

Kirkpatrick, Russell L.↗
NASA NTRS1995

Development of Doppler Global Velocimetry as a Flow Diagnostics Tool

The development of Doppler global velocimetry is described from its inception to its use as a flow diagnostics tool. Its evolution is traced from an elementary one-component laboratory prototype, to a full three-component configuration operating in a wind tunnel at focal distances exceeding 15 m. As part of the developmental process, several wind tunnel flow field investigations were conducted. These included supersonic flow measurements about an oblique shock, subsonic and supersonic measurements of the vortex flow above a delta wing, and three-component measurements of a high-speed jet.

Meyers, James F.↗