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At least 145 records · Page 8

Determination of collisional linewidths and shifts by a convolution method

A technique is described for fitting collisional linewidths and shifts from experimental spectral data. The method involves convoluting a low-pressure reference spectrum with a Lorentz shape function and comparing the convoluted spectrum with higher pressure spectra. Several experimental examples are given. One advantage of the method is that no extra information is needed about the instrument response function or spectral modulation. In addition, the method is shown to be relatively insensitive to the presence of reflections in the sample cell.

Pickett, H. M.↗

The spectrum of N2O between 800 and 5200 cm(-1)

An atlas of N2O lines between 800 and 5200/cm obtained from low-pressure, long-path-length samples at 296K is presented. Many of the line centers were marked and their positions were tabulated. The peak absorptances of the weaker lines in the atlas are similar to those expected in an extreme path through the atmosphere.

Hawkins, R. L.↗

Possible influence of solar rotation on tropospheric circulation

A large-scale structure observed in the photospheric magnetic field is carried out into the heliosphere by the solar wind. At Earth the resulting interplanetary magnetic field has polarity away from the Sun for several consecutive days followed by an abrupt reversal and several days with field polarity toward the Sun. Low-pressure troughs near the Gulf of Alaska appear to have significantly larger area when the interplanetary field is away from the Sun than when it is toward the Sun. This relation persisted during most of the winters of 1951 to 1973. Surface pressures around the Gulf of Alaska during some winters were in anti-phase for interplanetary field toward and away from the Sun. During the two days after a polarity reversal, the accuracy of the best weather forecasts for the continental United States appears to be significantly lower than at other times. Polarity reversals that are accompanied by energetic interplanetary conditions appear to be associated with a larger decrease in the area of the low pressure troughs.

Wilcox, J. M.↗

Si-rich Fe-Ni grains in highly unequilibrated chondrites

Consideration is given to the Si contents of Fe-Ni grains in highly unequilibrated chondrites, which have undergone little metamorphosis and thus best preserve the record of processes in the solar nebula. Electron microprobe determinations of silicon content in grains of the Bishunpur chondrite are presented for the six Si-bearing Fe-Ni grains for which data could be obtained, five of which were found to be embedded in olivine chondrules. In addition, all grains are found to be Cr-rich, with Cr increased in concentration towards the grain edge, and to be encased in FeS shells which evidently preserved the Si that entered the FeNi at higher temperatures. A mechanism for the production of Si-bearing metal during the condensation of the cooling solar nebula is proposed which considers the metal to have condensed heterogeneously while the mafic silicates condensed homogeneously with amounts of required undercooling in the low-pressure regions where ordinary and carbonaceous chondrites formed, resulting in Si mole fractions of 0.003 at nebular pressures less than 0.000001 atm.

Rambaldi, E. R.↗

NASA's activities in the conservation of strategic aerospace materials

The United States imports 50-100 percent of certain metals critical to the aerospace industry, namely, cobalt, columbium, chromium, and tantalum. In an effort to reduce this dependence on foreign sources, NASA is planning a program called Conservation of Strategic Aerospace Materials (COSAM), which will provide technology minimizing strategic metal content in the components of aerospace structures such as aircraft engines. With a proposed starting date of October 1981, the program will consist of strategic element substitution, process technology development, and alternate materials research. NASA's two-fold pre-COSAM studies center on, first, substitution research involving nickel-base and cobalt-base superalloys (Waspaloy, Udimet-700, MAE-M247, Rene 150, HA-188) used in turbine disks, low-pressure blades, turbine blades, and combustors; and, second, alternate materials research devoted initially to investigating possible structural applications of the intermetallic alloys nickel aluminide and iron aluminide.

Stephens, J. R.↗

Temperature dependence of the reaction O/3P/ + OH/2 Pi/ yields O2 + H

Measurements of the absolute rate and temperature dependence of the rate constant for the reaction of ground state atomic oxygen with hydroxyl radicals to yield molecular oxygen and hydrogen atoms over the temperature range 211-499 K are presented. The reaction was monitored in a low-pressure discharge flow resonance fluorescence apparatus under pseudo-first-order conditions in which the oxygen concentration was greater than the hydroxyl concentration. An expression for the temperature dependence of the rate constant is derived from a least-squares fit to the observed bimolecular rate constants, which were found to range from 3.21 to 2.77 x 10 to the -11th cu cm/molecule per sec for temperatures from 211 to 499 K, indicative of a slight negative temperature dependence. Results are compared with those of previous workers, and the significance of the lower value of the rate constant obtained in the present study to models of HO(x) in the upper stratosphere is indicated.

Lewis, R. S.↗

Water ice polymorphs and their significance on planetary surfaces

Impacts into an icy surface could produce significant amounts of high pressure forms of water ice. Due to the relatively low ambient surface temperatures on satellites in the outer solar system and the modest temperature rises accompanying the impact pressures required for water ice metamorphism, high-pressure polymorphs will be created by and may remain after large cratering events. If so, those high-pressure ices should be ubiquitous. Low-pressure cubic ice may be abundant as well. Impacts into an icy regolith may both produce high-pressure polymorphs from ice I and destroy high-pressure polymorphs already present. The result will be an (unknown) equilibrium concentration of high pressure polymorphs in the regolith. Polymorphs may be detectable and mappable by reflection spectroscopy at vacuum ultraviolet and mid-infrared wavelengths.

Gaffney, E. S.↗

Classification, experimental petrology and possible volcanic histories of the Apollo 11 high-K basalts

The Apollo 11 high-K basalt samples are classified into three textural categories: vitrophyric, anti-insertal, and antiophitic. Low-pressure phase equilibrium experiments and cooling rate studies were performed on a synthetic analog of 10085, 832. The dynamic crystallization experiments were designed to study textural development with: (1) a variable cooling rate from a constant initial temperature above the liquidus, and (2) cooling at a constant rate from variable initial temperatures below the liquidus. These experiments show that a variety of cooling rates initiated from temperatures both below and above the liquidus can produce all the observed textures. The results are consistent with the interpretation that all of the high-K basalt samples were derived from a single lava flow or lava lake.

Grove, T. L.↗

Nonmetallic Material Compatibility with Liquid Fluorine

Static tests were made on the compatibility of liquid fluorine with several nonmetallic materials at -3200 F and at pressures of 0 and 1500 pounds per square inch gage. The results are compared with those from previous work with gaseous fluorine at the same pressures, but at atmospheric temperature. In general, although environmental effects were not always consistent, reactivity was least with the low-temperature, low-pressure liquid fluorine. Reactivity was greatest with the warm, high-pressure gaseous fluorine. None of the liquids and greases tested was found to be entirely suitable for use in fluorine systems. Polytrifluorochloroethylene and N-43, the formula for which is (C4F9)3N, did not react with liquid fluorine at atmospheric pressure or 1500 pounds per square inch gage under static conditions, but they did react when injected into liquid fluorine at 1500 pounds per square inch gage; they also reacted with gaseous fluorine at 1500 pounds per square inch gage. While water did not react with liquid fluorine at 1500 pounds per square inch gage, it is known to react violently with fluorine under other conditions. The pipe-thread lubricant Q-Seal did not react with liquid fluorine, but did react with gaseous fluorine at 1500 pounds per square inch gage. Of the solids, ruby (Al2O3) and Teflon did not react under the test conditions. The results show that the compatibility of fluorine with nonmetals depends on the state of the fluorine and the system design.

Price, Harold G , Jr↗

Experimental investigation of the physical properties of medium and heavy oils, their vaporization and use in explosion engines. Part I

While little has been accomplished in obtaining an abundant supply of light oils from coal and heavy oils, progress has been made on engine design to make use of the heavier oils. Progress has been made in two different directions which are outlined in this paper: the group of engines with medium and high-pressure carburetion in the cylinder; and the group of engines with low-pressure carburetion of the heavy oils before reaching the cylinder.

OILS↗

Stability of Castering Wheels for Aircraft Landing Gears

A theoretical study was made of the shimmy of castering wheels. The theory is based on the discovery of a phenomenon called kinematic shimmy. Experimental checks, use being made of a model having low-pressure tires, are reported and the applicability of the results to full scale is discussed. Theoretical methods of estimating the spindle viscous damping and the spindle solid friction necessary to avoid shimmy are given. A new method of avoiding shimmy -- lateral freedom -- is introduced.

Kantrowitz, Arthur↗

Aerodynamic Forces and Loadings on Symmetrical Circular-Arc Airfoils with Plain Leading-Edge and Plain Trailing-Edge Flaps

An investigation has been made in the Langley two-dimensional low-turbulence tunnel and in the Langley two-dimensional low-pressure tunnel of 6- and 10-percent-thick symmetrical circular-arc airfoil sections at low Mach numbers and several Reynolds numbers. The airfoils were equipped with 0.15-chord plain leading-edge flaps and 0.20-chord plan trailing-edge flaps. The section lift and pitching-moment characteristics were determined for both airfoils with the flaps deflected individually and in combination. The section drag characteristics were obtained for the 6-percent-thick airfoil with the flaps partly deflected as low-drag-control flaps and for airfoils with the flaps neutral. Surface pressures were measured on the 6-percent-thick airfoil section with the flaps deflected either individually or in appropriate combination to furnish flap load and hinge-moment data applicable to the structural design of the airfoil. A generalized method is developed that permits the determination of the chordwise pressure distribution over sharp-edge airfoils with plain leading-edge flaps and plain trailing-edge flaps of arbitrary size and deflection.

Cahill, Jones F↗

Effect of viscosity in speed measurements with double-throat Venturi tubes

In order to clarify the viscosity effect some experiments were made in the Gottigen low-pressure tunnel with the Bruhn double-throat Venturi tube. This type of tunnel makes it possible to vary the pressure and thereby the density within wide limits and consequently, to examine the viscosity effect. This, however, did not impair the results because pressure and temperature were determined at different periods.

Peters, H↗

Review of Aircraft Altitude Errors Due to Static-Pressure Source and Description of Nose-Boom Installations for Aerodynamic Compensation of Error

A brief review of airplane altitude errors due to typical pressure installations at the fuselage nose, the wing tip, and the vertical fins is presented. A static-pressure tube designed to compensate for the position errors of fuselage-nose installations in the subsonic speed range is described. This type of tube has an ogival nose shape with the static-pressure orifices located in the low-pressure region near the tip. The results of wind-tunnel tests of these compensated tubes at two distances ahead of a model of an aircraft showed the position errors to be compensated to within 1/2 percent of the static pressure through a Mach number range up to about 1.0. This accuracy of sensing free-stream static pressure was extended up to a Mach number of about 1.15 by use of an orifice arrangement for producing approximate free-stream pressures at supersonic speeds and induced pressures for compensation of error at subsonic speeds.

Gracey, William↗

Tire-to-Surface Friction Especially Under Wet Conditions

The results of measurements of the maximum friction available in braking on various runway surfaces under various conditions is shown for a C-123B airplane and comparisons of measurements with a tire-friction cart on the same runways are made. The.results of studies of wet-surface friction made with a 12-inch-diameter low-pressure tire on a tire-friction treadmill, with an automobile tire on the tire-friction cart, and with a 44 x 13 extra-high-pressure type VII aircraft tire at the Langley landing-loads track are compared. Preliminary results of tests on the tire-friction treadmill under wet-surface conditions to determine the effect of the wiping action of the front wheel of a tandem-wheel arrangement on the friction available in braking for the rear wheel are given.

Sawyer, Richard H.↗

Alignment Charts for Transport Properties Viscosity, Thermal Conductivity, and Diffusion Coefficients for Nonpolar Gases and Gas Mixtures at Low Density

Alignment charts (nomographs) designed to permit rapid calculations of the low-pressure transport properties of nonpolar gases and gas mixtures are presented. Calculations for pure gases are based on the rigorous kinetic theory of gases as applied to a realistic intermolecular force law. Mixture viscosities and conductivities are calculated from good approximations derived from rigorous theory. The properties are calculable with a precision of 2 percent or better. Accuracy depends on how well the constants characterizing the Intermolecular force law are known; if constants are derived from experimental data, results should be accurate to 5 percent or better. Force constants are tabulated for 65 gases.

Brokaw, Richard S.↗

Stability of Castering Wheels for Aircraft Landing Gears, Special Report

In many installations of castering rubber-tired wheels there is a tendency for the wheel to oscillate violently about the spindle axis. This phenomenon, popularly called 'shimmy,' has occurred in some airplane tail wheels and has been corrected in two ways: first by the application of friction in the spindles of the tail wheels; and, second, by locking the wheels while taxiing at high speeds. Shimmy is common with the large wheels used as nose wheels in tricycle landing gears and, since it is impossible to lock the wheels, friction in the nose-wheel spindle has been the sole means of correction. Because the nose wheel is larger than the conventional tail wheel and usually carries a greater load, the larger amounts of spindle friction necessary to prevent shimmy are objectionable. the present paper presents a theoretical and experimental study of the problem of the stability of castering wheels for airplane landing gears. On the basis of simplified assumptions induced from experimental observations, a theoretical study has been made of the shimmy of castering wheels. The theory is based on the discovery of a phenomenon called 'kinematic shimmy' and is compared quantitatively with the results of model experiments. Experimental checks, using a model having low-pressure tires, are reported and the applicability of the results to full scale is discussed. Theoretical methods of estimating the spindle viscous damping and spindle solid friction necessary to avoid shimmy - lateral freedom - is introduced.

Kantrowitz, Arthur↗

Atmospheric Photochemistry

The upper atmosphere offers a vast photochemical laboratory free from solid surfaces, so all reactions take place in the gaseous phase. At 30 km altitude the pressure has fallen to about one-hundredth of that at ground level, and we shall, rather arbitrarily, regard the upper atmosphere as beginning at that height. By a little less than 100 km the pressure has fallen to 10(exp -3) mm Hg and is decreasing by a power of ten for every 15 km increase in altitude. Essentially we are concerned then with the photochemistry of a nitrogen-oxygen mixture under low-pressure conditions in which photo-ionization, as well as photodissociation, plays an important part. Account must also be taken of the presence of rare constituents, such as water vapour and its decomposition products, including particularly hydroxyl, oxides of carbon, methane and, strangely enough, sodium, lithium and calcium. Many curious and unfamiliar reactions occur in the upper atmosphere. Some of them are luminescent, causing the atmosphere to emit a dim light called the airglow. Others, between gaseous ions and neutral molecules, are almost a complete mystery at this time. Similar interesting phenomena must occur in other planetary atmospheres, and they might be predicted if sufficient chemical information were available.

Massey, Harrie↗