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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

Evidence for a Heterogeneous Distribution of Water in the Martian Interior

The abundance and distribution of H2O within the terrestrial planets, as well as its timing of delivery, is a topic of vital importance for understanding the chemical and physical evolution of planets and their potential for hosting habitable environments. Analysis of planetary materials from Mars, the Moon, and the eucrite parent body (i.e., asteroid 4Vesta) have confirmed the presence of H2O within their interiors. Moreover, H and N isotopic data from these planetary materials suggests H2O was delivered to the inner solar system very early from a common source, similar in composition to the carbonaceous chondrites. Despite the ubiquity of H2O in the inner Solar System, the only destination with any prospects for past or present habitable environments at this time, outside of the Earth, is Mars. Although the presence of H2O within the martian interior has been confirmed, very little is known regarding its abundance and distribution within the martian interior and how the martian water inventory has changed over time. By combining new analyses of martian apatites within a large number of martian meteorite types with previously published volatile data and recently determined mineral-melt partition coefficients for apatite, we report new insights into the abundance and distribution of volatiles in the martian crust and mantle. Using the subset of samples that did not exhibit crustal contamination, we determined that the enriched shergottite mantle source has 36-73 ppm H2O and the depleted shergottite mantle source has 14-23 ppm H2O. This result is consistent with other observed geochemical differences between enriched and depleted shergottites and supports the idea that there are at least two geochemically distinct reservoirs in the martian mantle. We also estimated the H2O content of the martian crust using the revised mantle H2O abundances and known crust-mantle distributions of incompatible lithophile elements. We determined that the bulk martian crust has approximately 1400 ppm H2O, which is likely distributed toward the martian surface. This crustal water abundance would equate to a global equivalent layer (GEL) of water at a depth of-229 m, which can account for at least some of the surface features on Mars attributed to flowing water and may be sufficient to support the past presence of a shallow sea on Mars' surface.

McCubbin, Francis↗
NASA NTRS1992

Geological and geophysical field investigations from a lunar base at Mare Smythii

Mare Smythii, located on the equator and east limb of the Moon, has a great variety of scientific and economic uses as the site for a permanent lunar base. Here a complex could be established that would combine the advantages of a nearside base (for ease of communications with Earth and normal operations) with those of a farside base (for shielding a radio astronomical observatory from the electromagnetic noise of Earth). The Mare Smythii region displays virtually the entire known range of geological processes and materials found on the Moon; from this site, a series of field traverses and investigations could be conducted that would provide data on and answers to fundamental questions in lunar geoscience. This endowment of geological materials also makes the Smythii region attractive for the mining of resources for use both on the Moon and in Earth-Moon space. We suggest that the main base complex be located at 0, 90 deg E, within the mare basalts of the Smythii basin; two additional outposts would be required, one at 0, 81 deg E to maintain constant communications with Earth, and and the other, at 0, 101 deg E on the lunar farside, to serve as a radio astronomical observatory. The bulk of lunar surface activities could be conducted by robotic teleoperations under the direct control of the human inhabitants of the base.

Spudis, Paul D.↗
NASA NTRS1992

Resources for a lunar base: Rocks, minerals, and soil of the Moon

The rocks and minerals of the Moon will be included among the raw materials used to construct a lunar base. The lunar regolith, the fragmental material present on the surface of the Moon, is composed mostly of disaggregated rocks and minerals, but also includes glassy fragments fused together by meteorite impacts. The finer fraction of the regolith (i.e., less than 1 cm) is informally referred to as soil. The soil is probably the most important portion of the regolith for use at a lunar base. For example, soil can be used as insulation against cosmic rays, for lunar ceramics and abodes, or for growing plants. The soil contains abundant solar-wind-implanted elements as well as various minerals, particularly oxide phases, that are of potential economic importance. For example, these components of the soil are sources of oxygen and hydrogen for rocket fuel, helium for nuclear energy, and metals such as Fe, Al, Si, and Ti.

Taylor, Lawrence A.↗
NASA NTRS2005

The Core of the Moon - Molten or Solid?

While several studies beginning in the Apollo era and continuing up to the present have tried to detect the lunar core, either geochemically, geophysically or geologically [e.g. 1, 2, 3, 4], it has so far proven somewhat elusive. The unambiguous detection of the lunar core is of prime importance as it holds the potential of distinguishing between the various theories for the formation of the Moon. The theory which currently enjoys the greatest success is the giant impact model, which has the Moon forming about 4.5 Gyr ago from the debris produced when a Mars sized proto planet collided with the proto Earth [e.g. 5, 6]. Simulations reveal that the material from which the Moon is made up contains very little iron and consequently a lunar core, if it exists, should be small.

Khan, A.↗
NASA NTRS2017

Enhanced Gravity Tractor Derived from the Asteroid Redirect Mission for Deflecting Hypothetical Asteroid 2017 PDC

The Asteroid Redirect Mission (ARM) concept would robotically visit a hazardous-size near-Earth asteroid (NEA) with a rendezvous spacecraft, collect a multi-ton boulder and regolith samples from its surface, demonstrate an innovative planetary defense technique known as the Enhanced Gravity Tractor (EGT), and return the asteroidal material to a stable orbit around the Moon, allowing astronauts to explore the returned material in the mid-2020s. Launch of the robotic vehicle to rendezvous with the ARM reference target, NEA (341843) 2008 EV5, would occur in late 2021 [1,2]. The robotic segment of the ARM concept uses a 40 kW Solar Electric Propulsion (SEP) system with a specific impulse (Isp) of 2600 s, and would provide the first ever demonstration of the EGT technique on a hazardous-size asteroid and validate one method of collecting mass in-situ. The power, propellant, and thrust capability of the ARM robotic spacecraft can be scaled from a 40 kW system to 150 kW and 300 kW, which represent a likely future power level progression. The gravity tractor technique uses the gravitational attraction of a station-keeping spacecraft with the asteroid to provide a velocity change and gradually alter the trajectory of the asteroid. EGT utilizes a spacecraft with a high-efficiency propulsion system, such as Solar Electric Propulsion (SEP), along with mass collected in-situ to augment the mass of the spacecraft, thereby increasing the gravitational force between the objects [3]. As long as the spacecraft has sufficient thrust and propellant capability, the EGT force is only limited by the amount of in-situ mass collected and can be increased several orders of magnitude compared to the traditional gravity tractor technique in which only the spacecraft mass is used to generate the gravitational attraction force. This increase in available force greatly reduces the required deflection time. The collected material can be a single boulder, multiple boulders, regolith, or a combination of different material types using a variety of collection techniques. The EGT concept assumes that the ability to efficiently collect asteroid mass in-situ from a wide variety of asteroid types and environments is a future capability that will be developed and perfected in the future by the asteroid mining community. Additionally, it is anticipated that the mass collection would likely be performed by a single or multiple separable spacecraft to allow the SEP spacecraft to operate at safe distance from the asteroid.

Mazanek, Daniel D.↗
NASA NTRS2010

Direct Electrolysis of Molten Lunar Regolith for the Production of Oxygen and Metals on the Moon

When considering the construction of a lunar base, the high cost ($ 100,000 a kilogram) of transporting materials to the surface of the moon is a significant barrier. Therefore in-situ resource utilization will be a key component of any lunar mission. Oxygen gas is a key resource, abundant on earth and absent on the moon. If oxygen could be produced on the moon, this provides a dual benefit. Not only does it no longer need to be transported to the surface for breathing purposes; it can also be used as a fuel oxidizer to support transportation of crew and other materials more cheaply between the surface of the moon, and lower earth orbit (approximately $20,000/kg). To this end a stable, robust (lightly manned) system is required to produce oxygen from lunar resources. Herein, we investigate the feasibility of producing oxygen, which makes up almost half of the weight of the moon by direct electrolysis of the molten lunar regolith thus achieving the generation of usable oxygen gas while producing primarily iron and silicon at the cathode from the tightly bound oxides. The silicate mixture (with compositions and mechanical properties corresponding to that of lunar regolith) is melted at temperatures near 1600 C. With an inert anode and suitable cathode, direct electrolysis (no supporting electrolyte) of the molten silicate is carried out, resulting in production of molten metallic products at the cathode and oxygen gas at the anode. The effect of anode material, sweep rate, and electrolyte composition on the electrochemical behavior was investigated and implications for scale-up are considered. The activity and stability of the candidate anode materials as well as the effect of the electrolyte composition were determined. Additionally, ex-situ capture and analysis of the anode gas to calculate the current efficiency under different voltages, currents and melt chemistries was carried out.

Sirk, Aislinn H. C.↗
NASA NTRS1976

The asymmetric distribution of lunar maria and the earth's gravity

The paper investigates the hypothesis that the asymmetry of the moon with respect to the distribution of maria, reflected in that the surface area of the moon covered by mare material is far greater on the earth-facing side than on the far side, is due to the action of the earth's gravity at a time when the moon was less distant from the earth than today. Such conditions would lead to gravitationally favored areas on the moon such that mare basalt magmas might erupt preferentially on the front side of the moon. Gravitational asymmetry is also discussed in terms of its effect on the shape of the moon, its center of mass, its moments of inertia, and the time scale for the evolution of its orbit.

Hartung, J. B.↗
NASA NTRS1979

Scaling and the start-up phase of space industrialization

By terrestrial standards very little mass is needed to construct the space portion of a 10,000 megawatt (10 GW) power system. Use of lunar materials makes it reasonable to consider alternatives to silicon solar cells for conversion of sunlight to electricity and thereby avoid present major problems associated with solar cell production. Machinery needed on the moon to excavate lunar materials and deliver them to a transport system, to beneficiate lunar materials, to produce glasses and ceramics from lunar materials and to chemically process lunar materials into their major oxides and elements are minor mass fractions of the total mass of equipment needed in space to produce an SPS. In addition the processing equipment can throughput several hundred times their own mass each year with very little requirement for makeup mass from earth.

Criswell, D. R.↗
NASA NTRS1992

Evidence for magma oceans on asteroids, the moon, and Earth

There are sound theoretical reasons to suspect that the terrestrial planets melted when they formed. For Earth, the reasons stem largely from the hypothesis that the moon formed as a result of the impact of a Mars-sized planetesimal with the still accreting Earth. Such a monumental event would have led to widespread heating of the Earth and the materials from which the moon was made. In addition, formation of a dense atmosphere on the Earth (and possibly the Moon) would have led to retention of accretional heat and, thus, widespread melting. In other words, contemporary theory suggests that the primitive Moon and terrestrial planets had magma oceans.

Taylor, G. Jeffrey↗
NASA NTRS1992

Water and cheese from the lunar desert: Abundances and accessibility of H, C, and N on the Moon

The Moon has been underrated as a source of H, N, C, and other elements essential to support life and to provide fuel for rockets. There is enough of these elements in each cubic meter of typical lunar soil to provide a substantial lunch for two, if converted to edible forms. The average amount of C per square meter of the lunar surface to a depth of 2 m is some 35 percent of the average amount per square meter tied up in living organisms on Earth. The water equivalent of H in the upper 2 m of the regolith averages at least 1.3 million liters per square kilometer. Mining of H from a small fraction of the regolith would provide all the rocket fuel needed for thousands of years. These elements can be removed from the soil by heating it to high temperature. Some favor the unproven resources of Phobos, Deimos, or near-Earth asteroids instead of the Moon as a source of extraterrestrial material for use in space, or Mars over the Moon as a site for habitation, partly on the basis that the chemical elements needed for life support and propellant are readily abundant on those bodies, but not on the Moon. Well, the Moon is not as barren of H, C, and N as is commonly perceived. In fact, the elements needed for life support and for rocket fuel are plentiful there, although the ore grades are low. Furthermore, the proximity of the Moon and consequent lower cost of transportation and shorter trip and communication times favor that body as the logical site for early acquisition of resources and extraterrestrial living.

Haskin, L. A.↗
NASA NTRS1992

The meteoritic contribution to dust and aerosols in the atmosphere of Mars

The continuous, planet-wide accretion of meteoritic material onto the Earth and Moon has been established by stratospheric sampling on Earth and chemical abundance analysis of the lunar soils. Meteoritic material must contribute in a similar manner to the atmospheres of all the planets and moons of the inner solar system. Although meteorites that survive planetary entry unmelted are the primary contributors, secondary contributions come from: (1) recondensed vapor in meteorite trails; and (2) fragmentation debris from low density meteoroids. These three contributions provide a constant planet-wide source of atmospheric particulates on Mars. In the size range greater than 1 micro-m in diameter micrometeorites which survive atmospheric entry unmelted are the major contributor, accounting for about 8.6 x 10(exp 6) kg/year of material. For particles less than 1 micro-m in diameter the majority of the mass is likely to come from recondensed meteoric vapor, which could account for approx. 2 x 10(exp 6) kg/year.

Flynn, G. J.↗
NASA NTRS1990

Ilmenite beneficiation and high-precision analyses of extraterrestrial material

During the past year, work on characterizing lunar material that has the potential of becoming ilmenite lunar ore was performed. The important aspects of any such material are that it has abundant ilmenite and that the ilmenite be easily separated. The final result sought is a pure (greater than 99 percent ilmenite) concentrate that will be used as feed for the ilmenite reduction process. There are two types of starting material available on the moon. Solid rock (basalt or anorthosite) and regolith. Extensive literature reviews of ilmenite separation experiments were performed, and simulants (meteorites) were separated. It was concluded that, because of the large amounts of agglomerates, regolith may not be the best starting material for ilmenite beneficiation and that either basalts or anorthosites may be better. This is because no matter how finely the regolith is ground, it would not be possible to efficiently separate all the ilmenite. This hypotheses, however, needs to be tested with lunar material.

Ruiz, J.↗
NASA NTRS2011

Composition of LHB Comets and Their Influence on the Early Earth Atmosphere Composition

Two main processes were responsible for the composition of this atmosphere: chemical evolution of the volatile fraction of the accretion material forming the planet and the delivery of gasses to the planetary surface by impactors during the late heavy bombardment (LHB). The amount and composition of the volatile fraction influences the outgassing of the Earth mantle during the last planetary formation period. A very weakened form of outgassing activity can still be observed today by examining the composition of volcanic gasses. An enlightenment of the second process is based on the sparse records of the LHB impactors resulting from the composition of meteorites, observed cometary comas, and the impact material found on the Moon. However, for an assessment of the influence of the outgassing on the one hand and the LHB event on the other, one has to supplement the observations with numerical simulations of the formation of volatiles and their incorporation into the accretion material which is the precursors of planetary matter, comets and asteroids. These simulations are performed with a combined hydrodynamic-chemical model of the solar nebula (SN). We calculate the chemical composition of the gas and dust phase of the SN. From these data, we draw conclusions on the upper limits of the water content and the amount of carbon and nitrogen rich volatiles incorporated later into the accretion material. Knowing these limits we determine the portion of major gas compounds delivered during the LHB and compare it with the related quantities of the outgassed species.

Tornow, C.↗
DOE OSTI2025

Enhancing Cycle Life in Superoxide‐Based Na–O 2 Batteries by Reducing Interface Reactivity

Abstract Sodium–oxygen (Na–O 2 ) batteries are considered a promising energy storage alternative to current state‐of‐the‐art technologies owing to their high theoretical energy density, along with the natural abundance and low price of Na metal. The chemistry of these batteries depends on sodium superoxide (NaO 2 ) or peroxide (Na 2 O 2 ) being formed/decomposed. Most Na–O 2 batteries form NaO 2 , but reversibility is usually quite limited due to side reactions at interfaces. By using new materials, including a highly active catalyst based on vanadium phosphide (VP) nanoparticles, an ether/ionic liquid‐based electrolyte, and an effective sodium bromide (NaBr) anode protection layer, the sources of interface reactivity can be reduced to achieve a Na–O 2 battery cell that is rechargeable for 1070 cycles with a high energy efficiency of more than 83%. Density functional theory calculations, along with experimental characterization confirm the three factors leading to the long cycle life, including the effectiveness of the NaBr protective layer on the anode, a tetraglyme/EMIM‐BF 4 based electrolyte that prevents oxidation of the VP cathode catalyst surface, and the EMIM‐BF 4 ionic liquid aiding in avoiding electrolyte decomposition on NaO 2 .

Azaribeni, Adel [Department of Chemical and Biolog↗
NASA NTRS2002

Technology for Solar Array Production on the Moon

Silicon, aluminum, and glass are the primary raw materials that will be required for production of solar arrays on the moon. A process sequence is proposed for producing these materials from lunar regolith is proposed, consisting of separating the required materials from lunar rock with fluorine. Fluorosilane produced by this process is reduced to silicon; the fluorine salts are reduced to metals by reaction with metallic potassium. Fluorine is recovered from residual MgF and CaF2 by reaction with K2O. Aluminum, calcium oxide, and magnesium oxide are recovered to manufacture structural materials and glass.

Landis, Geoffrey A.↗
NASA NTRS2010

Plasma IMS Composition Measurements for Europa and Ganymede

NASA and ESA are planning the joint Europa Jupiter System Mission (EJSM) to the Jupiter system with specific emphasis to Europa and Ganymede, respectively. The Japanese Space Agency is also planning an orbiter mission to explore Jupiter's magnetosphere and the Galilean satellites. For NASA's Jupiter Europa Orbiter (JEO) we are developing the 3D Ion Mass Spectrometer (IMS) with two main goals which can also be applied to the other Galilean moons, 1) measure the plasma interaction between Europa and Jupiter's magnetosphere and 2) infer the 4n surface composition to trace elemental [1] and significant isotopic levels. The first goal supports the magnetometer (MAG) measurements, primarily directed at detection of Europa's sub-surface ocean, while the second gives information about transfer of material between the Galilean moons, and between the moon surfaces and subsurface layers putatively including oceans. The measurement of the interactions for all the Galilean moons can be used to trace the in situ ion measurements of pickup ions back to either Europa's or Ganymede's surface from the respectively orbiting spacecraft. The IMS instrument, being developed under NASA's Astrobiology Instrument Development Program, would maximally achieve plasma measurement requirements for JEO and EJSM while moving forward our knowledge of Jupiter system composition and source processes to far higher levels than previously envisaged.

Sittler, E.↗
NASA NTRS2010

Performance Testing of Molten Regolith Electrolysis with Transfer of Molten Material for the Production of Oxygen and Metals on the Moon

Previously, we have demonstrated the production of oxygen by electrolysis of molten regolith simulants at temperatures near 1600 C. Using an inert anode and suitable cathode, direct electrolysis (no supporting electrolyte) of the molten silicate is carried out, resulting in the production of molten metallic products at the cathode and oxygen gas at the anode. Initial direct measurements of current efficiency have confirmed that the process offer potential advantages of high oxygen production rates in a smaller footprint facility landed on the moon, with a minimum of consumables brought from Earth. We now report the results of a scale-up effort toward the goal of achieving production rates equivalent to 1 metric ton O2/year, a benchmark established for the support of a lunar base. We previously reported on the electrochemical behavior of the molten electrolyte as dependent on anode material, sweep rate and electrolyte composition in batches of 20-200g and at currents of less than 0.5 A. In this paper, we present the results of experiments performed at currents up to 10 Amperes) and in larger volumes of regolith simulant (500 g - 1 kg) for longer durations of electrolysis. The technical development of critical design components is described, including: inert anodes capable of passing continuous currents of several Amperes, container materials selection, direct gas analysis capability to determine the gas components co-evolving with oxygen. To allow a continuous process, a system has been designed and tested to enable the withdrawal of cathodically-reduced molten metals and spent molten oxide electrolyte. The performance of the withdrawal system is presented and critiqued. The design of the electrolytic cell and the configuration of the furnace were supported by modeling the thermal environment of the system in an effort to realize a balance between external heating and internal joule heating. We will discuss the impact these simulations and experimental findings have on the design of a suitable prototype for lunar applications

Sibille, Laurent↗