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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

The life cycle of the Interstellar Medium in other galaxies

Gas in spiral galaxies cycles between the diffuse and dense phases as clouds collapse, form stars and are dispersed back into the ISM. Far infrared observations of continuum emission from interstellar dust and line emission from interstellar gas have revealed a wealth of information on the state of the ISM in galaxies of different morphological types. The analysis of these observations gives us information about the processes of star formation and about the evolution of the ISM. Star formation rates vary widely from galaxy to galaxy, with the rates in starburst galaxies being 10 - 100 times those in quiescent spiral galaxies. Far infrared spectroscopy of star-forming galaxies shows that the interstellar pressure increases with star formation rate. The structure of the interstellar medium in starburst galaxies is quite different from that of quiescent galaxies - much of the mass and volume are in HII regions and photodissociation regions. The size distribution of dust grains seems to depend on environment; small grains are abundant in the diffuse interstellar medium but not in dense molecular star forming regions. Quiescent spiral and elliptical galaxies contain a significant population of small grains, but starburst galaxies do not. Dwarf irregular galaxies also seem to contain few small grains; this may be the result of the higher UV flux in these galaxies. The star forming regions in dwarf irregulars also have a higher ratio of atomic to molecular gas than do those in the Galaxy. These results show that the ISM in galaxies of different morphological types reaches different equilibria, resulting in different modes of star formation and global galaxy evolution.

Knapp, G. R.↗
NASA NTRS1979

Electron impact on atmospheric gases. III - Spatial yield spectra for N2

Spatial yield spectra have been calculated for electron energy degradation into molecular nitrogen gas using a Monte Carlo method for 0.1- to 5.0-keV incident electrons. The spectra contain the spatial yield information about the electron degradation process and can be employed to calculate a 'yield' for any inelastic state at any position in the medium. Because of the spectrum's useful nature and simple characteristics, the three-variable spatial yield spectrum U(E, z, E sub zero) is analytically represented as well. This analytic form can then be easily applied to atmospheric and laboratory problems dealing with energetic electron degradation.

Jackman, C. H.↗
NASA NTRS1985

Relevance of cosmic gamma rays to the mass of gas in the galaxy

The bulk of the diffuse gamma-ray flux comes from cosmic ray interactions in the interstellar medium. A knowledge of the large scale spatial distribution of the Galactic gamma-rays and the cosmic rays enables the distribution of the target gas to be examined. An approach of this type is used here to estimate the total mass of the molecular gas in the galaxy. It is shown to be much less than that previously derived, viz., approximately 6 x 10 to the 8th power solar masses within the solar radius as against approximately 3 x 10 to the 9th power based on 2.6 mm CO measurements.

Bhat, C. L.↗
NASA NTRS1992

158 micrometers (CII) mapping of NGC 6946: Probing the atomic medium

The strong 158 micrometers (C2) cooling line of the NGC 6946 galaxy is investigated. The data was acquired with a far infrared imaging Fabry-Perot interferometer with 55 minutes resolution. About 1 percent of the total far infrared luminosity of the galaxy is analyzed. The (C2) emission comes from a mizture of components of interstellar gas. The brightest emission is associated with the nucleus, a second component traces the spiral arms and the largest star forming/H2 regions contained within them, and a third extended component of low brightness can be detected at least 12 kpc from the nucleus. The nuclear and spiral arm components are most likely associated with dense photon dominated regions at molecular cloud surfaces that are exposed to ultraviolet radiation produced by young massive stars. The (C2) emission is analyzed and the cooling rate in the atomic medium is consistent with photoelectric heating by diffuse ultraviolet radiation.

Madden, S. C.↗
NASA NTRS1990

Interstellar grain chemistry and organic molecules

The detection of prominant infrared absorption bands at 3250, 2170, 2138, 1670 and 1470 cm(-1) (3.08, 4.61, 4.677, 5.99 and 6.80 micron m) associated with molecular clouds show that mixed molecular (icy) grain mantles are an important component of the interstellar dust in the dense interstellar medium. These ices, which contain many organic molecules, may also be the production site of the more complex organic grain mantles detected in the diffuse interstellar medium. Theoretical calculations employing gas phase as well as grain surface reactions predict that the ices should be dominated only by the simple molecules H2O, H2CO, N2, CO, O2, NH3, CH4, possibly CH3OH, and their deuterated counterparts. However, spectroscopic observations in the 2500 to 1250 cm(-1)(4 to 8 micron m) range show substantial variation from source reactions alone. By comparing these astronomical spectra with the spectra of laboratory-produced analogs of interstellar ices, one can determine the composition and abundance of the materials frozen on the grains in dense clouds. Experiments are described in which the chemical evolution of an interstellar ice analog is determined during irradiation and subsequent warm-up. Particular attention is paid to the types of moderately complex organic materials produced during these experiments which are likely to be present in interstellar grains and cometary ices.

Allamandola, L. J.↗
NASA NTRS2008

The Herschel Oxygen Project: Herschel Space Observatory Open Time Key Project

Topics include: Why oxygen and why at submillimeter wavelengths; gas phase chemistry for water, oxygen, and carbon monoxide is relatively simple; molecular oxygen structure; lower rotational levels and transitions of oxygen; oxygen abundance in interstellar clouds; SWAS spectra of terrestrial oxygen; what Herschel offers HOP; key regions for probing oxygen in the dense interstellar medium; HOP sources and strategy; and HOP data and analysis.

astrochemistry↗
DOE OSTI2022

Genetic-algorithm retrieval of the molecular alignment distribution with high-order harmonics generated from transiently aligned CO 2 molecules

Using genetic algorithm, we propose a method to retrieve the alignment distribution of transiently aligned CO 2 molecules from the high-order harmonic generation (HHG) spectra. The retrieval method is based on the quantitative rescattering (QRS) model where averaged photorecombination transition dipole can be factored out from the parallel (or perpendicular) harmonic spectra after the propagation of the harmonic fields in the gas medium. We examine how the retrieved alignment distributions are affected by uncertainty in alignment dependent ionization probability and on multiple orbital contribution to the HHG. We further confirm that alignment distribution is more accurately retrieved by using the minima in the HHG spectra driven by a long-wavelength laser. In addition, we show that earlier experimental data on the ratios between the perpendicular and the parallel HHG components of aligned CO 2 molecules are in better agreement with the QRS model if the macroscopic propagation and multiple orbital interference are included in the theoretical calculation.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS2002

Infrared Emission From Interstellar PAHs, New Probes of the Interstellar Medium

Tremendous strides have been made in the understanding of interstellar material over the past twenty years thanks to significant, parallel developments in two closely related areas: observational IR astronomy and laboratory astrophysics. Twenty years ago the composition of interstellar dust was largely unknown and the notion of abundant, gas phase, polycyclic aromatic hydrocarbons (PAHs) anywhere in the interstellar medium (ISM) considered impossible. Today the dust composition of the diffuse and dense ISM is reasonably well constrained and the spectroscopic case for interstellar PAHs, impossibly large molecules by early interstellar chemistry standards, is very strong. PAH spectral features are now being used as new probes of the ISM. PAH ionization states reflect the ionization balance of the medium while PAH size and structure reflect the energetic and chemical history of the medium. Aromatic carbon-rich materials ranging in size from PAHs and PAH nanoclusters, to sub-micron and micron-sized dust grains represent an important component of the ISM. These species: (1) dominate the heating and cooling of interstellar clouds via energetic photoelectron ejection and infrared (IR) emission; (2) moderate the ionization balance in photodissociation regions and molecular clouds; (3) moderate the composition of the gas phase and play an important role in determining the chemistry of the ISM; (4) contribute to the interstellar extinction in the near IR, visible, and UV spectral regions; and (5) convert UV, visible, and near-IR radiation to mid- and far-IR radiation in the ISM and, as such, are responsible for the well known, widespread family of mid-IR emission features with major components near 3.3, 6.2, 7.7, 8.6, and 11.3 microns.

Hudgins, D. M.↗
DOE OSTI2024

Infrared bands of neutral gas-phase carbon clusters in a broad spectral range

The identification of species in the interstellar medium requires precise and molecule-specific spectroscopic information in the laboratory framework, in broad spectral ranges and under conditions relevant to interstellar environments. In this work, we measure the gas-phase infrared spectra of neutral carbon clusters, C N (N = 6–11), in a molecular beam. The C N distribution is formed by photofragmentation of C 60 molecules, concurrently showing a top-down formation mechanism. A broad spectral range in the infrared between 500–3200 cm -1 (20–3.125 μm) is investigated. We observe strong bands between 5 and 6 μm, in conjunction with novel features in the 3 μm region. Density functional theory calculations reveal that these short wavelength modes correspond to combination bands with significant infrared intensity. Moreover, we identify the N ≤ 10 clusters as linear, while C 11 adopts a ring configuration, placing the linear-to-ring transition at N = 11 under our molecular beam conditions. The linearity of C 10 is discussed based on the formation pathway from larger clusters in energetic conditions. Given the vast and very precise infrared information already been released from the James Webb Space Telescope mission, this infrared spectroscopic data set in conjunction with information on formation mechanisms is of major relevance for identifying neutral carbon clusters in astronomical environments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1988

Low-mass spiral galaxies with little molecular gas and prodigious star formation

A comparison of CO and H I properties is used here to demonstrate that many CO-poor low-mass Virgo spiral galaxies are rich in atomic gas, which implies that the lack of CO emission from them is due, at least partly, to a lack of molecular gas. Despite the paucity of molecular gas, these H I-rich, CO-poor, low-mass spiral galaxies are undergoing extensive massive star formation. A column density of 10 to the 21st nuclei/sq cm is a necessary but insufficient condition for the creation of an H2-dominated interstellar medium.

Kenney, Jeffrey D.↗
NASA NTRS1977

Absorption of X-rays in the interstellar medium

The X-ray photoabsorption cross sections (per hydrogen atom) of interstellar clouds and the intercloud medium are calculated separately, taking into account abundance evolution, self-blanketing by grains, molecule formation, and ionization structure. A reference cross section describing a neutral monatomic gas of elements in solar abundances is computed for purposes of comparison, the cross section of the intercloud medium is calculated by assuming that 15% of the hydrogen is ionized, and the cross section of the clouds is computed for the cases where all hydrogen is in either molecular or atomic form. A comparison of the reference cross section with the others shows that a cross section is increased relative to the reference if abundances are enhanced or if molecular hydrogen exists and is decreased if atoms exist in grains or if hydrogen is ionized. It is noted that the total cross section will be a linear combination of the cross sections of the clouds and the intercloud medium and can reflect the characteristics of a particular line of sight.

Ride, S. K.↗
NASA NTRS1993

High-resolution radio observations of the supernova remnant 3C 391 - Possible breakout morphology

We present radio observations of the bright compact SNR 3C 391 (G31.9+0.0) made with the VLA2 at 6 arcsec resolution. The remnant's morphology suggests expansion into a medium with a very strong density gradient. We interpret radio and X-ray morphologies as evidence for a breakout of the expanding material into a region of abruptly lower density. The CO survey of Sanders et al. (1986), though not fully sampled, shows the presence of molecular gas at the position of the remnant, with a radial velocity of 90-110 km/s similar to the highest velocity absorption features seen in H I toward 3C 391. This gas may thus be near the remnant, though direct evidence of interaction is lacking. More detailed CO observations, and searches for evidence of shocked molecular gas such as 2.12 micron emission from H2, might confirm or refute the tantalizing possibility that 3C 391 is interacting with an observable molecular cloud.

Reynolds, Stephen P.↗
NASA NTRS1990

CI, CII, and CO as tracers of gas phase carbon

In the dense interstellar medium, we find that about 20 percent of the total carbon abundance is in the form of CO, about 3 percent in C(sub I), and 100 percent in C(sub II) with uncertainties of factors of order 2. The abundance of other forms of gaseous carbon is negligible. CO is widespread throughout molecular clouds as is C(sub I). C(sub II) has only been observed near bright star-formation regions so far because of its high excitation energy. Further from ultraviolet sources it may be less abundant. Altogether we have accounted for about 1/3 of the total carbon abundance associated with dense molecular clouds. Since the other gaseous forms are thought to have negligible abundances, the rest of the carbon is probably in solid form.

Keene, Jocelyn↗
NASA NTRS1984

IUE Observations of the Gaseous Component of the Local Interstellar Medium

Discovery of interstellar Ge, Ga, and Kr is reported. Several intercombination lines of Fe 2 are detected. The depletion is most pronounced in Ca, Ti, and V. The highly ionized gas C 4 and Si 4 is not co-extensive with the Si 2 and C 2 gas nor with the O 6 gas. The molecular gas (CO) shows very small velocity dispersion (b approximately 1 km/sec). HD 149404 has the richest interstellar spectrum (except molecules) of all the stars in this study. HD 147889, the heavily obscured star in the Rho Oph cloud, has the strongest interstellar CO spectrum. Noisy nature of the spectra precludes detection of other molecules.

Gilra, D. P.↗
DOE OSTI2025

Simulation insights into wetting properties of hydrogen-brine-clay for hydrogen geo-storage

Hydrogen geo-storage is attracting substantial interdisciplinary interest as a cost-effective and sustainable option for medium- and long-term storage. Hydrogen can be stored underground in diverse formations, including aquifers, salt caverns, and depleted oil and gas reservoirs. The wetting dynamics of the hydrogen-brine-rock system are critical for assessing both structural and residual storage capacities, and ensuring containment safety. Through molecular dynamics simulations, we explore how varying concentrations of cushion gases (CO 2 or CH 4 ) influence the wetting properties of hydrogen-brine-clay systems under geological conditions (15 MPa and 333 K). We employed models of talc and the hydroxylated basal face of kaolinite (kaoOH) as clay substrates. Our findings reveal that the effect of cushion gases on hydrogen-brine-clay wettability is strongly dependent on the clay-brine interactions. Notably, CO 2 and CH 4 reduce the water wettability of talc in hydrogen-brine-talc systems, while exerting no influence on the wettability of hydrogen-brine-kaoOH systems. Detailed analysis of free energy of cavity formation near clay surfaces, clay-brine interfacial tensions, and the Willard-Chandler surface for gas-brine interfaces elucidate the molecular mechanisms underlying wettability changes. Our simulations identify empirical correlations between wetting properties and the average free energy required to perturb a flat interface when clay-brine interactions are less dominant. Here, our thorough thermodynamic analysis of rock-fluid and fluid-fluid interactions, aligning with key experimental observations, underscores the utility of simulated interfacial properties in refining contact angle measurements and predicting experimentally relevant properties. These insights significantly enhance the assessment of gas geo-storage potential. Prospectively, the approaches and findings obtained from this study could form a basis for more advanced multiscale simulations that consider a range of geological and operational variables, potentially guiding the development and improvement of geo-storage systems in general, with a particular focus on hydrogen storage.

25 ENERGY STORAGE↗
DOE OSTI2023

Low-Temperature Gas-Phase Formation of Methanimine (CH 2 NH; X 1 A')–the Simplest Imine–under Single-Collision Conditions

The D1-methanimine molecule (CHDNH; X 1 A') – the simplest (deuterated) imine – has been prepared through the elementary reaction of the D1-methylidyne (CD; X 2 Π) with ammonia (NH 3 ; X 1 A 1 ) under single collision conditions. As a highly reactive species with a carbon-nitrogen double bond and a key building block of biomolecules like amino acids and nucleobases, methanimine is of particular significance in coupling the nitrogen and carbon chemistries in the interstellar medium and in hydrocarbon-rich atmospheres of planets and their moons. However, the underlying formation mechanisms of methanimine in these extreme environments are still elusive. Here, the directed, low-temperature gas-phase formation of D1-methanimine will deepen our fundamental understanding of low-temperature molecular growths processes via carbon-nitrogen bond coupling. Considering the recent detection of the interstellar D1-methylidyne radical, the investigation of the CD–NH 3 system also suggests a promising pathway for future astronomical observations of D1-methanimine as a molecular tracer of gas phase deuterium-enrichment in deep space.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1993

Radiative Cooling of Warm Molecular Gas

We consider the radiative cooling of warm (T >= 100 K), fully molecular astrophysical gas by rotational and vibrational transitions of the molecules H2O, CO, and H2. Using an escape probability method to solve for the molecular level populations, we have obtained the cooling rate for each molecule as a function of temperature, density, and an optical depth parameter. A four-parameter expression proves useful in fitting the run of cooling rate with density for any fixed values of the temperature and optical depth parameter. We identify the various cooling mechanisms which are dominant in different regions of the astrophysically relevant parameter space. Given the assumption that water is very abundant in warm regions of the interstellar medium, H2O rotational transitions are found to dominate the cooling of warm interstellar gas over a wide portion of the parameter space considered. While chemical models for the interstellar medium make the strong prediction that water will be produced copiously at temperatures above a few hundred degrees, our assumption of a high water abundance has yet to be tested observationally. The Infrared Space Observatory and the Submillimeter Wave Astronomy Satellite will prove ideal instruments for testing whether water is indeed an important coolant of interstellar and circumstellar gas.

Neufeld, David A.↗
NASA NTRS2012

The Galactic Centre Mini-Spiral in the MM-Regime

Context: The mini-spiral is a feature of the interstellar medium in the central approx.2 pc of the Galactic center. It is composed of several streamers of dust and ionised and atomic gas with temperatures between a few 100 K to 10(exp 4) K. There is evidence that these streamers are related to the so-called circumnuclear disk of molecular gas and are ionized by photons from massive, hot stars in the central parsec. Aims: We attempt to constrain the emission mechanisms and physical properties of the ionized gas and dust of the mini-spiral region with the help of our multiwavelength data sets. Methods: Our observations were carried out at 1.3 mm and 3 mm with the mm interferometric array CARMA in California in March and April 2009, with the MIR instrument VISIR at ESO's VLT in June 2006, and the NIR Bry with VLT NACO in August 2009. Results: We present high resolution maps of the mini-spiral, and obtain a spectral index of 0.5 +/- 0.25 for Sgr A *, indicating an inverted synchrotron spectrum. We find electron densities within the range 0.8-1.5 x 10(exp 4)/cu cm for the mini-spiral from the radio continuum maps, along with a dust mass contribution of approx. 0.25 Mo from the MIR dust continuum. and extinctions ranging from 1.8-3 at 2.16 microns in the Bry line. Conclusions: We observe a mixture of negative and positive spectral indices in our 1.3 mm and 3 mm observations of the extended emission of the mini-spiral, which we interpret as evidence that there are a range of contributions to the thermal free-free emission by the ionized gas emission and by dust at 1.3 mm.

Kunneriath, D.↗