Search NASA⌕ Search

SEARCH · Search NASA

Results for “metastable”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8

Radiative transitions involving the (2p2)(3 Pe) metastable autodetaching of H(-)

The absorption coefficient for the free-bound transition H (ls) + e(-)+ h omega yields H(-)(2 sq p,(3)P(e)) is calculated (together with the differential emission rate for the inverse process) using ls - 2s - 2p close coupling continuum wave functions and a Hylleraas bound state wave function. A maximum in the absorption and emission spectra is found to occur at a photon wavelength of 1219.5 A, which is 2 A closer to the Lyman alpha line than predicted by the calculations of Drake, and is in closer agreement with the stellar absorption feature identified by Heap and Stecher. The free-bound absorption process appears to be a significant source of continuous ultraviolet opacity.

Jacobs, V. L.↗

Laboratory studies on the excitation and collisional deactivation of metastable atoms and molecules in the aurora and airglow

The aeronomy group at the University of Pittsburgh is actively engaged in a series of coordinated satellite, sounding rocket, and laboratory studies designed to expand and clarify knowledge of the physics and chemistry of planetary atmospheres. Three major discoveries have been made that will lead ultimately to a complete and dramatic revision of our ideas on the ionospheres of Mars, Venus, and the Earth and on the origin of their vacuum ultraviolet airglows. The results have already suggested a new generation of ionosphere studies which probably can be carried out best by laser heterodyning techniques. Laboratory studies have also identified, for the first time, the physical mechanism responsible for the remarkable nitric oxide buildup observed in some auroral arcs. This development is an important break-through in auroral physics, and has military ramifications of considerable interest to the Department of Defense. This work may also shed some light on related NO and atomic nitrogen problems in the mesosphere.

Zipf, E. C.↗

Perturbation of the calcium principal series by metastable calcium atoms

The absorption of the principal series of calcium is observed with about 4% of the atoms placed in the 4s4p 3P level by selective laser excitation, and is compared with the absorption with all atoms in the ground state. We observe a broadening of the absorption lines accompanied by a shift to longer wavelengths and the occurrence of satellite lines at shorter wavelengths.

Mcilrath, T. J.↗

Radiative transitions involving the /2p2/ 3Pe metastable autodetaching state of H-

A Hylleraas bound-state wave function and 1s-2s-2p close-coupling continuum wave functions are used to calculate the absorption coefficient for the free-bound transition of H(1s) + e + quantum to a H anion in (2p2,3Pe) and the differential emission rate for the inverse process. The absorption and emission spectral maximum is found to be at a photon wavelength of 1219.5 A, an improvement of 2 A on other calculations. This free-bound absorption process appears to be a significant source of continuous ultraviolet opacity.

Jacobs, V. L.↗

Metastable 2P oxygen ions in the daytime thermosphere

Dayglow radiation at 7319 A has been measured by the visible airglow experiment on Atmosphere Explorer C. The overhead surface brightness measured at 15.4 hours local solar time on January 27, 1974, was 250 plus or minus 10 R. The volume emission rate had a peak value of 20 photons per cu cm per sec at a height of about 210 km. The data show clear evidence of quenching by collisons with thermal electrons at the higher altitudes and with neutral particles at lower altitudes. Quenching by neutral particles occurs at nearly the gas kinetic rate.

Walker, J. C. G.↗

Production of N2O/+/ by reaction of metastable O2/+/ ions with N2

Photoionization mass spectrometry examination of the production of N2O(+) was undertaken to determine whether N2(+) or O2(+) ions are responsible for onset of N2O(+). It appears that the N2(+) ion does not contribute significantly to the production of N2O(+) in this experiment. Therefore, it is clear that excited O2(+) is responsible for the formation of N2O(+) near the appearance potential of these ions.

Ajello, J. M.↗

Metastable 2D atomic nitrogen in the mid-latitude nocturnal ionosphere

The only source at night at midlatitudes of N(2D) in the F region is the dissociative recombination of the positive NO ion, and the only important sinks are quenching by atomic oxygen and electrons. Ground-based measurements of the 5200 angstrom emission line resulting from the transition from N(2D) to N(4S) combined with satellite observations of neutral and ion densities and temperatures and the shape of the 5200 angstrom profile are used to relate the rate of quenching by atomic oxygen and the efficiency of production of N(2D) to the rate of quenching by electrons. A rate of quenching by atomic oxygen of 1.5-2.5 x 10 to the minus 12th cu cm/s and an efficiency of (0.8-1.0) plus or minus 30% for the production of N(2D) are obtained.

Torr, M. R.↗

The origin of chondrules - Experimental investigation of metastable liquids in the system Mg2SiO4-SiO2

Laser-melted magnesium silicate droplets were supercooled 400-750 C below their equilibrium liquidus temperatures before crystallization and their texture was compared with that of meteoritic and lunar chondrules. Crystal morphology, width and texture were studied in relation to nucleation temperature and bulk composition. It was found that the only phase to nucleate from the forsterite-enstatite normative melts was forsterite. Highly siliceous glass, about 65% SiO2 by weight, was identified interstitially to the forsterite crystals in seven of the MgSiO4 spherules and was thought to be present in all.

Blander, M.↗

Photodissociation of CO2 and quenching of metastables

Investigations in four different areas were carried out to further our understanding of the chemistry of the atmospheres of Mars and Venus. CO2 photodissociation quantum yields were determined in the 1300-1500 A spectral region by measuring both CO and oxygen atoms. The O(1S) quantum yield was determined for CO2 photodissociation in the 1060-1175 A spectral region. The measurement resolves the differences between two earlier experiments, and demonstrates that the O(1S) yield is unity throughout most of the measured region. The pathways for the quenching of O(1S) by N2O, CO2, H2O and NO were investigated and the source of the Venus nightglow, detected by Venera 9 and 10, was investigated. What appears to be a new O2 band system, was detected although the identity of the transition is not yet evident.

Slanger, T. G.↗