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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Application of Electrochemical Methods to Molten Salt Reactors: Draft TLR Documenting Assessment of Electrochemical Monitoring

Nuclear Regulatory Commission (NRC) is developing the regulatory framework and technical expertise to support regulatory review of advanced non-water reactors, including molten salt reactors (MSRs). In an MSR, it is essential that the salt chemistry be maintained in a desired range in terms of redox potential for reliable operation and mitigation of corrosion to structural materials in the reactor, particularly the reactor vessel and heater exchanger. Measuring the redox potential of the salt in the reactor would also allow for the material lifetimes to be predicted more accurately, and chemical issues to be diagnosed more quickly. In addition to the chemical composition analysis by ICP-MS, electrochemical methods including potentiometry and linear wave scanning (LSC) were also used in molten salt reactor experiment (MSRE) for redox potential monitoring purposes. Electrochemcial methods offers unique advantages such as quick turnaround in results and unique capability of in-line monitoring of redox potential, and are considered popular electroanalytical techniques that can be used to monitor redox potentials and salt chemistry including impurities. The last two decades have seen significant advances in science and engineering of electrochemical methods for potential application to molten salts. The primary goal of this report is to assist NRC in understanding the monitoring of the salt chemistry by electrochemical methods and provide NRC reviewers with necessary information and tools to support regulatory review of MSR designs. This reports consists of two majors parts—Part 1, chemical potential of molten salts and effects by fission process in MSR; Part 2, assessment of electrochemical methods for application to MSRs. The TRLs of the typical relevant electrochemical methods for molten salts were evaluated based on the DOE TRL guidelines and upon a review of the current status of the electrochemical methods for two typical salt systems, fluoride and chloride, for MSRs.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NiCrMoNb age hardenable alloy for creep-resistant high temperature applications, and methods of making

Nickel alloys, methods of making nickel alloys, articles including the nickel alloys, uses of the alloys, and methods of treating nickel alloys are described. The inventive heat resistant structural materials are suitable for applications requiring high yield stress at room temperature and good creep strength at high temperatures, such as in gas turbines, steam turbines, fossil energy boilers, aero engines, power generation systems using fluids such as supercritical carbon dioxide (e.g., advanced ultra-supercritical power plants), concentrated solar power plants, nuclear power plants, molten salt reactors: turbine blades, casings, valves, heat exchangers and recuperators.

Detrois, Martin↗

NiCrMoNb age hardenable alloy for creep-resistant high temperature applications, and methods of making

Nickel alloys, methods of making nickel alloys, articles including the nickel alloys, uses of the alloys, and methods of treating nickel alloys are described. The inventive heat resistant structural materials are suitable for applications requiring high yield stress at room temperature and good creep strength at high temperatures, such as in gas turbines, steam turbines, fossil energy boilers, aero engines, power generation systems using fluids such as supercritical carbon dioxide (e.g., advanced ultra-supercritical power plants), concentrated solar power plants, nuclear power plants, molten salt reactors: turbine blades, casings, valves, heat exchangers and recuperators.

Detrois, Martin↗

Probabilistic structural analysis methods and applications

An advanced algorithm for simulating the probabilistic distribution of structural responses due to statistical uncertainties in loads, geometry, material properties, and boundary conditions is reported. The method effectively combines an advanced algorithm for calculating probability levels for multivariate problems (fast probability integration) together with a general-purpose finite-element code for stress, vibration, and buckling analysis. Application is made to a space propulsion system turbine blade for which the geometry and material properties are treated as random variables.

Cruse, T. A.↗

Quasiparticle random-phase approximation calculations for M 1 transitions with the noniterative finite-amplitude method and application to neutron radiative capture cross sections

Here, we derive the equations of quasiparticle random-phase approximation (QRPA) based on the finite amplitude method with the Hartree-Fock+Bardeen–Cooper–Schrieffer (HF+BCS) single-particle states, and calculate the magnetic dipole (M⁢1) transition for deformed gadolinium isotopes. Our QRPA calculation shows both large spin-flip transitions in the 5 to 10 MeV excitation energy and the low energy orbital transition that would correspond to the M⁢1 scissors mode observed in nuclear experiments. Then, we calculate neutron capture reactions based on the statistical Hauser-Feshbach theory with the photoabsorption cross sections of even-even nuclei given by QRPA. We find that the capture cross section is enhanced due to the contribution from the low energy M⁢1 transition although the calculated capture cross section still underestimates the experimental data. This issue in the calculated capture cross section could be improved by uncertainties of the low energy E⁢1 transition neglected in our QRPA calculation.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Backscattering by nonspherical hydrometeors as calculated by the coupled-dipole method - An application in radar meteorology

The severest test of a theory of scattering by particles is how well it calculates scattering in the backward direction. The coupled-dipole method can be used for accurately calculating backscattering at 94 GHz by hexagonal ice crystals. Backscattering by columns is markedly different from that by plates, which indicates that it might be possible to infer size and shape distributions of ice crystals using recently developed millimeter wave radar.

Dungey, Clifton E.↗

Entry Debris Field Estimation Methods and Application to Compton Gamma Ray Observatory Disposal

For public safety reasons, the Compton Gamma Ray Observatory (CGRO) was intentionally deorbited on June 4, 2000. This deorbit was NASA's first intentional controlled deorbit of a satellite, and more will come including the eventual deorbit of the International Space Station. To maximize public safety, satellite deorbit planning requires conservative estimates of the debris footprint size and location. These estimates are needed to properly design a deorbit sequence that places the debris footprint over unpopulated areas, including protection for deorbit contingencies. This paper details a method for estimating the length (range), width (crossrange), and location of entry and breakup debris footprints. This method utilizes a three degree-of-freedom Monte Carlo simulation incorporating uncertainties in all aspects of the problem, including vehicle and environment uncertainties. The method incorporates a range of debris characteristics based on historical data in addition to any vehicle-specific debris catalog information. This paper describes the method in detail, and presents results of its application as used in planning the deorbit of the CGRO.

Mrozinski, Richard B.↗

Multivariate approximation methods and applications to geophysics and geodesy

The first report in a series is presented which is intended to be written by the author with the purpose of treating a class of approximation methods of functions in one and several variables and ways of applying them to geophysics and geodesy. The first report is divided in three parts and is devoted to the presentation of the mathematical theory and formulas. Various optimal ways of representing functions in one and several variables and the associated error when information is had about the function such as satellite data of different kinds are discussed. The framework chosen is Hilbert spaces. Experiments were performed on satellite altimeter data and on satellite to satellite tracking data.

Munteanu, M. J.↗

The ICARE Method

The ICARE method is a flexible, widely applicable method for systems engineers to solve problems and resolve issues in a complete and comprehensive manner. The method can be tailored by diverse users for direct application to their function (e.g. system integrators, design engineers, technical discipline leads, analysts, etc.). The clever acronym, ICARE, instills the attitude of accountability, safety, technical rigor and engagement in the problem resolution: Identify, Communicate, Assess, Report, Execute (ICARE). This method was developed through observation of Space Shuttle Propulsion Systems Engineering and Integration (PSE&I) office personnel approach in an attempt to succinctly describe the actions of an effective systems engineer. Additionally it evolved from an effort to make a broadly-defined checklist for a PSE&I worker to perform their responsibilities in an iterative and recursive manner. The National Aeronautics and Space Administration (NASA) Systems Engineering Handbook states, engineering of NASA systems requires a systematic and disciplined set of processes that are applied recursively and iteratively for the design, development, operation, maintenance, and closeout of systems throughout the life cycle of the programs and projects. ICARE is a method that can be applied within the boundaries and requirements of NASA s systems engineering set of processes to provide an elevated sense of duty and responsibility to crew and vehicle safety. The importance of a disciplined set of processes and a safety-conscious mindset increases with the complexity of the system. Moreover, the larger the system and the larger the workforce, the more important it is to encourage the usage of the ICARE method as widely as possible. According to the NASA Systems Engineering Handbook, elements of a system can include people, hardware, software, facilities, policies and documents; all things required to produce system-level results, qualities, properties, characteristics, functions, behavior and performance. The ICARE method can be used to improve all elements of a system and, consequently, the system-level functional, physical and operational performance. Even though ICARE was specifically designed for a systems engineer, any person whose job is to examine another person, product, or process can use the ICARE method to improve effectiveness, implementation, usefulness, value, capability, efficiency, integration, design, and/or marketability. This paper provides the details of the ICARE method, emphasizing the method s application to systems engineering. In addition, a sample of other, non-systems engineering applications are briefly discussed to demonstrate how ICARE can be tailored to a variety of diverse jobs (from project management to parenting).

Henke, Luke↗

Numerical phase space optics methods and applications to the analysis of fiber coupling efficiency in atmospheric turbulence

A fundamental requirement of free-space optical communication is the ability to efficiently couple atmospherically distorted light from a telescope to a detector. A numerical method is presented for modeling fiber-based receiver performance in atmospheric conditions based on phase space optics which does not rely on Monte Carlo methods. This method is employed to analyze the waveguide insertion loss and optimal coupling geometry in atmospheric conditions for step-index fibers, graded-index fibers, and photonic lanterns with and without tilt compensation and central obscurations in the telescope.

free-space optical communication↗

Numerical phase space optics methods and applications to the analysis of fiber coupling efficiency in atmospheric turbulence

A fundamental requirement of free-space optical communication is the ability to efficiently couple atmospherically distorted light from a telescope to a detector. A numerical method is presented for modeling fiber-based receiver performance in atmospheric conditions based on phase space optics which does not rely on Monte Carlo methods. This method is employed to analyze the waveguide insertion loss and optimal coupling geometry in atmospheric conditions for step-index fibers, graded-index fibers, and photonic lanterns with and without tilt compensation and central obscurations in the telescope.

free-space optical communication↗

An inexact semismooth Newton method with application to adaptive randomized sketching for dynamic optimization

In many applications, one can only access the inexact gradients and inexact hessian times vector products. Thus it is essential to consider algorithms that can handle such inexact quantities with a guaranteed convergence to solution. An inexact adaptive and provably convergent semismooth Newton method is considered to solve constrained optimization problems. In particular, dynamic optimization problems, which are known to be highly expensive, are the focus. A memory efficient semismooth Newton algorithm is introduced for these problems. The source of efficiency and inexactness is the randomized matrix sketching. Further, applications to optimization problems constrained by partial differential equations are also considered.

97 MATHEMATICS AND COMPUTING↗

Further Development of the Tamped Richtmyer-Meshkov Instability Method and Application to Molybdenum Dynamic Strength Calibration and Tabulation

The high pressure and high strain rate dynamic strength of Mo is experimentally and computationally investigated in the 3–20 GPa stress, 50–600 C temperature, and 10 5 –10 6 /s strain rate regimes using a modified tamped Richtmyer-Meshkov instability (RMI) method. Modifications to the tamped RMI method include a method to determine loading states during strain, a new strength calibration function based on interface shape, and a robust uncertainty quantification method. These modifications improve fidelity of the tamped RMI method, allowing evaluation of the compensating effects of pressure hardening, strain rate hardening, strain hardening, and thermal softening. The new calibration function based on interface shape is not limited to sinusoidal corrugations and could be applied to additional interface shapes. Plate impact experiments are performed at Argonne National Laboratory’s Advanced Photon Source’s Dynamic Compression Sector operated by Washington State University (DCS), driving a planar shock front through a corrugated Mo-D 2 O or Mo-C 8 F 18 interface, forcing the corrugation to significantly deform. The extent of interfacial deformation, RMI growth, is experimentally observed using X-ray phase contrast imaging at the DCS. RMI jet lengths and jet shapes are extracted from the experimental radiographs, then used to calibrate numerical simulations performed with the Sandia National Laboratories (SNL) hydrocode CTH. Mo yield strength, Y, as a function of shock pressure, P, strain rate, $\dot{\varepsilon }$, accumulated strain, ϵ, relative volumetric compression, RD , and temperature, T , is determined for each impact experiment and presented. The calibrated Mo yield strength values range 1.2–1.8 GPa, with strength generally decreasing as the impact stress increases. This trend is likely caused by thermal softening or strain localization. The tabular yield strength versus loading condition data presented in this paper can be used to fit complex strength models.

Voorhees, T. J. [Sandia National Lab. (SNL-CA), Li↗

Trajectory Optimization Methods and Applications at NASA Goddard

The process of spacecraft trajectory design frequently incorporates an optimization step in which one or more objectives, such as propellant consumption or time of flight, is minimized. Optimization is especially crucial for low-thrust mission design, due to the need to specify a thrust vector at every instant in time along a trajectory. At NASA's Goddard Space Flight Center (GSFC) a number of open-source tools have been developed for spacecraft trajectory optimization that utilize direct shooting and collocation methods. These tools have been effectively applied to cislunar, libration point, and interplanetary mission design for the Lunar IceCube, SWFO, and DAVINCI missions, among others. This presentation outlines the theory underlying these optimization tools along with the details of their application to several trajectory design problems, with a focus on the Lunar IceCube (LIC) mission. The LIC mission required a low-thrust trajectory from a high-energy deployment state to a lunar orbit, and its limited control authority necessitated the use of optimization tools and low-energy trajectory design techniques. The tools discussed demonstrate how the use of optimization methods expands mission capabilities and enables transformational science.

Robert Pritchett↗

Effects of CMAS Application on the Isothermal and Gradient Thermal Cycling Behavior of a Yb 2 Si 2 O 7 EBC

Environmental barrier coatings (EBCs) are critical to the continued advancement of gas turbine hot section materials technology. EBCs are required to protect Si-based ceramics such as silicon carbide fiber-reinforced silicon carbide (SiC/SiC) ceramic matrix composites (CMCs) from oxidation and corrosion in the combustion environment. One of the current challenges concerning EBC lifetime is the thermochemical reactions between calcium-magnesium-aluminosilicate (CMAS) deposits and the EBC that leads to changes in both composition and stress state. These changes can severely reduce the integrity of the EBC leading to crack formation, delamination, and spallation. Current techniques for evaluating CMAS in the laboratory rely on the pre-application of CMAS. Two commonly used application methods to deposit CMAS on EBC materials are tape-casting and air spray. In both methods, the CMAS is applied to the EBC surface at ambient temperature, and then subject to a heat treatment process for binder burnout. The purpose of this study is to compare the tape-cast and air spray methods on the CMAS corrosion of an ytterbium disilicate (Yb 2 Si 2 O 7 ) EBC subject to isothermal, and gradient thermal cycling. The results highlight if any differences exist in the CMAS infiltration kinetics between the two application methods.

Environmental barrier coatings (EBCs)↗