Results for “monolithic” — Page 8

DOE OSTI2025

Microstructurally validated stable and predictable swelling in low-enriched uranium monolithic U-10Mo fuel mini-plates

Qualification of the low-enriched uranium (LEU) monolithic U-10 wt%Mo (U-10Mo) plate-type fuel system requires a demonstration of a stable and predictable fuel swelling behavior over the anticipated operating conditions of the United States high-performance research reactors (USHPRRs) selected for conversion to LEU operation. This will allow each reactor to develop appropriate safety margins that will retain fuel element lifetime coolability. Additionally, the fuel system must maintain performance attributes when fabricated at a commercial scale. The Mini-plate 1 experiment represents the first irradiation test of commercially fabricated miniaturized monolithic LEU U-10Mo fuel plates. Here, the swelling behavior within this experiment was compared against that of historical fuel developmental tests to reveal that the commercially fabricated fuel performed within the current recommended U-10Mo swelling model's predictions. Additionally, the fuel microstructural evolution was evaluated to link initial conditions to subtle variations detected in the swelling response, providing validation and confidence that the fuel system is robust.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

DOE OSTI2024

Tunnel junction-enabled monolithically integrated GaN micro-light emitting transistor

GaN/InGaN microLEDs are a very promising technology for next-generation displays. Switching control transistors and their integration are key components in achieving high-performance, efficient displays. Monolithic integration of microLEDs with GaN switching devices provides an opportunity to control microLED output power with capacitive (voltage)-controlled rather than current-controlled schemes. This approach can greatly reduce system complexity for the driver circuit arrays while maintaining device opto-electronic performance. In this work, we demonstrate a 3-terminal GaN micro-light emitting transistor that combines a GaN/InGaN blue tunneling-based microLED with a GaN n-channel FET. Further, the integrated device exhibits excellent gate control, drain current control, and optical emission control. This work provides a promising pathway for future monolithic integration of GaN FETs with microLED to enable fast switching, high-efficiency microLED display and communication systems.

42 ENGINEERING↗

DOE OSTI2014

Effects of the foil flatness on the stress-strain characteristics of U10Mo alloy based monolithic mini-plates

The effects of the foil flatness on stress-strain behavior of monolithic fuel mini-plates during fabrication and irradiation were studied. Monolithic plate-type fuels are a new fuel form being developed for research and test reactors to achieve higher uranium densities. This concept facilitates the use of low-enriched uranium fuel in the reactor. These fuel elements are comprised of a high density, low enrichment, U–Mo alloy based fuel foil encapsulated in a cladding material made of Aluminum. To evaluate the effects of the foil flatness on the stress-strain behavior of the plates during fabrication, irradiation and shutdown stages, a representative plate from RERTR-12 experiments (Plate L1P756) was considered. Both fabrication and irradiation processes of the plate were simulated by using actual irradiation parameters. The simulations were repeated for various foil curvatures to observe the effects of the foil flatness on the peak stress and strain magnitudes of the fuel elements. Results of fabrication simulations revealed that the flatness of the foil does not have a considerable impact on the post fabrication stress-strain fields. Furthermore, the irradiation simulations indicated that any post-fabrication stresses in the foil would be relieved relatively fast in the reactor. While, the perfectly flat foil provided the slightly better mechanical performance, overall difference between the flat-foil case and curved-foil case was not significant. Even though the peak stresses are less affected, the foil curvature has several implications on the strain magnitudes in the cladding. It was observed that with an increasing foil curvature, there is a slight increase in the cladding strains.

42 ENGINEERING↗

DOE OSTI2022

Monolithic Multigrid for a Reduced-Quadrature Discretization of Poroelasticity

Advanced finite-element discretizations and preconditioners for models of poroelasticity have attracted significant attention in recent years. The equations of poroelasticity offer significant challenges in both areas, due to the potentially strong coupling between unknowns in the system, saddle-point structure, and the need to account for wide ranges of parameter values, including limiting behavior such as incompressible elasticity. This paper was motivated by an attempt to develop monolithic multigrid preconditioners for the discretization developed in [C. Rodrigo et al., Comput. Methods App. Mech. Engrg, 341 (2018), pp. 467--484]; we show here why this is a difficult task and, as a result, we modify the discretization in [Rodrigo et al.] through the use of a reduced-quadrature approximation, yielding a more “solver-friendly” discretization. Local Fourier analysis is used to optimize parameters in the resulting monolithic multigrid method, allowing a fair comparison between the performance and costs of methods based on Vanka and Braess--Sarazin relaxation. Further, numerical results are presented to validate the local Fourier analysis predictions and demonstrate efficiency of the algorithms. Finally, a comparison to existing block-factorization preconditioners is also given.

97 MATHEMATICS AND COMPUTING↗

DOE OSTI2015

Pt-based Bi-metallic Monolith Catalysts for Partial Upgrading of Microalgae Oil

Valicor’s proprietary wet extraction process in conjunction with thermochemical pre-treatment was performed on algal biomass from two different algae strains, Nannochloropsis Salina (N.S.) and Chlorella to produce algae oils. Polar lipids such as phospholipids were hydrolyzed, and metals and metalloids, known catalyst poisons, were separated into the aqueous phase, creating an attractive “pre-refined” oil for hydrodeoxygenation (HDO) upgrading by Stevens. Oil content and oil extraction efficiency of approximately 30 and 90% respectively were achieved. At Stevens, we formulated a Pt-based bi-metallic catalyst which was demonstrated to be effective in the hydro-treating of the algae oils to produce ‘green’ diesel. The bi-metallic catalyst was wash-coated on a monolith, and in conjunction with a high throughput high pressure (pilot plant) reactor system, was used in hydrotreating algae oils from N.S. and Chlorella. Mixtures of these algae oils and refinery light atmospheric gas oil (LAGO) supplied by our petroleum refiner partner, Marathon Petroleum Corporation, were co-processed in the pilot plant reactor system using the Pt-based bi-metallic monolith catalyst. A 26 wt% N.S. algae oil/74 wt % LAGO mixture hydrotreated in the reactor system was subjected to the ASTM D975 Diesel Fuel Specification Test and it met all the important requirements, including a cetane index of 50.5. An elemental oxygen analysis performed by an independent and reputable lab reported an oxygen content of trace to none found. The successful co-processing of a mixture of algae oil and LAGO will enable integration of algae oil as a refinery feedstock which is one of the goals of DOE-BETO. We have presented experimental data that show that our precious metal-based catalysts consume less hydrogen than the conventional hydrotreating catalyst NiMo Precious metal catalysts favor the hydrodecarbonylation/hydrodecarboxylation route of HDO over the dehydration route preferred by base metal catalysts, and consumes less hydrogen, if methanation can be mitigated. Our methanation data on Pt and Rh indicate effective suppression of methanation. Our data also show that our catalysts are less susceptible to coking; and unlike NiMo and CoMo, precious metal catalysts are not deactivated by water, a by-product of HDO of algae oil. Finally, our catalysts do not need to be sulfided to be active. A rigorous techno-economic analysis of our process for commercial scale production of 10,000 barrels per day of hydrotreated algae oil, with nutraceuticals co-product claiming only 0.05% of the raw algae oil, indicates an estimated plant gate price of ~$10/gal. Sensitivity analysis shows that critical parameters affecting sale price include (1) algae doubling time (2) biomass oil content (3) CAPEX, and (4) moisture content of post extracted algae residue. Modest improvements in these areas will result in enhanced and competitive economics. Based on a life cycle assessment for greenhouse gas emission, we found that if algae oil replaced 10% of the US consumption, this would result in a CO2e reduction of 210,000 tons per day. Improving the drying process for animal feed by 50% would result in further significant reduction in CO2e.

09 BIOMASS FUELS↗

NASA NTRS2019

The Non-Destructive Separation of Diverse Astrobiologically Relevant Organic Molecules By Customizable Capillary Zone Electrophoresis and Monolithic Capillary Electrochromatography

The in situ detection of organic molecules in space is key to understanding the variety and the distribution of the building blocks of life, and possibly the detection of extraterrestrial life itself. Gas chromatography mass spectrometry (GC-MS) has been the most sensitive analytical instrument for organic analyses in flight, and was used on missions from NASA’s Viking, Phoenix, Curiosity missions to ESA’s Rosetta space probe. While pyrolysis GC-MS revealed the first organics on Mars, this step alters or degrades certain fragile molecules that are excellent biosignatures including polypeptides, oligonucleotides and polysaccharides, rendering the intact precursors undetectable. We have identified a solution tailored to the detection of biopolymers and other biomarkers by the use of liquid-based capillary electrophoresis and electrochromatography. In this study, we show that a capillary electrochromatography (CEC) approach using monolithic stationary phases with tailor-made surface chemistry can separate and identify various polycyclic aromatic hydrocarbons (PAHs), nucleobases and aromatic acids that could be formed under astrophysically relevant conditions. In order to simulate flyby organic sample capture, we conducted hypervelocity impact experiments which consisted of accelerating peptide-soaked montmorillonite particles to a speed of 5.6 km/sec, and capturing them in an amorphous silica aerogel of 10 and 30 mg/cc bulk density. Bulk peptide extraction from aerogel followed by capillary zone electrophoresis led to the detection of only two stereoisomeric peptide peaks. The recovery rates of each step of the extraction procedure after the hypervelocity impact suggest that major peptide loss occurred during the impact. Our study provides initial exploration of feasibility of this approach for capturing intact peptides, and subsequently detecting candidate biomolecules during flight missions that would be missed by GC-MS alone. As the monolith-based electrochromatography technology could be customized to detect specific classes of compounds as well as miniaturized, these results demonstrate the potential of the instrumentation for future astrobiology-related spaceflight missions.

Flyby sample return↗

DOE OSTI2019

Size effects on thermo-mechanical performance of U-10Mo monolithic fuel plates

Monolithic fuel is a fuel form that is considered for the conversion of high performance research reactors. This plate-type fuel consists of a high density U-Mo fuel in monolithic form that is sandwiched between zirconium diffusion barriers, and encapsulated in an aluminum cladding. To date, large number of plates have been irradiated with satisfactory perforamce. The program is now moving into the qualification phase, a predecessor to the timely conversion of the target reactors. It must be shown that the fuel system meets the safety standards and performs well in reactor. The requirement to satisfactory irradiation performance under normal operating conditions is primarily demonstrated by a successful testing. Since each reactor employs distinct fuel plate geometries for various consideration with unique plate design features and attributes, a single “generic” plate geometry capturing all of the extremities is not achievable. Furthermore, testing all these geometric and irradiation parameters on a large size plate is not practical. Therefore, a smaller, “down-scaled” versions of fuel plates, are often employed for experimental purposes. This limitation consequently requires much more cautious performance evaluations, as thermal and mechanical response of a plate with certain geometry may not be representative for a plate with a different geometry. To investigate if plate size has any effects on irradiation performance, the plates with various geometric dimensions were parametrically evaluated. In particular, length and width of the plates were varied between the bounding values. Temperature, deformation, stress values were comparatively evaluated. The results have indicated that effects of geometric ratios and plate size variations in length and width directions are insignificant. However, wider plates could become more prone to a warping-type deformation, if there are nonlinearities.

42 ENGINEERING↗

DOE OSTI2019

Size effects on thermo-mechanical performance of U-10Mo monolithic fuel plates

Monolithic fuel is a fuel form that is considered for the conversion of high performance research reactors. This plate-type fuel consists of a high density U-Mo fuel in monolithic form that is sandwiched between zirconium diffusion barriers, and encapsulated in an aluminum cladding. To date, large number of plates have been irradiated with satisfactory perforamce. The program is now moving into the qualification phase, a predecessor to the timely conversion of the target reactors. It must be shown that the fuel system meets the safety standards and performs well in reactor. The requirement to satisfactory irradiation performance under normal operating conditions is primarily demonstrated by a successful testing. Since each reactor employs distinct fuel plate geometries for various consideration with unique plate design features and attributes, a single “generic” plate geometry capturing all of the extremities is not achievable. Furthermore, testing all these geometric and irradiation parameters on a large size plate is not practical. Therefore, a smaller, “down-scaled” versions of fuel plates, are often employed for experimental purposes. This limitation consequently requires much more cautious performance evaluations, as thermal and mechanical response of a plate with certain geometry may not be representative for a plate with a different geometry. To investigate if plate size has any effects on irradiation performance, the plates with various geometric dimensions were parametrically evaluated. In particular, length and width of the plates were varied between the bounding values. Temperature, deformation, stress values were comparatively evaluated. The results have indicated that effects of geometric ratios and plate size variations in length and width directions are insignificant. However, wider plates could become more prone to a warping-type deformation, if there are nonlinearities.

42 ENGINEERING↗

DOE OSTI2019

Effects of Plate Curvature on Thermo-Mechanical Performance of U-10Mo Monolithic Fuel Plates

Monolithic fuel is a candidate fuel form being considered for the conversion of high-performance research reactors. This plate-type fuel consists of a high-density, U-Mo fuel in a monolithic form that is sandwiched between zirconium diffusion barriers, and encapsulated in an aluminum cladding. To date, large number of plates have been irradiated with satisfactory performance. The program is now moving into the qualification phase, a predecessor to the timely conversion of the target reactors. Since each reactor employs distinct fuel plate geometries for various consideration, resulting nearly 50 distinct plate geometries with unique plate design features, a single “generic” plate geometry capturing all of the extremities is not achievable. This limitation consequently requires much more cautious performance evaluations, as thermal and mechanical response of a plate with certain geometry may not be representative for a plate with a different geometry. To evaluate the performance of the plates for various geometric parameters, parametric sensitives studies have been employed. One of the important geometric parameters may have potential effects on the performance is the plate curvature. In this study, curved-plates were parametrically simulated to investigate if this geometric parameter has any effects on overall performance, In particular, radius of curvatures of the plates were varied between the bounding values, and the plates were simulated for comparable irradiation histories. The resulted temperature, deformation, stress-strain results were comparatively evaluated. The results have indicated that preferential deformations occur. This consequently caused shifting of plate centerline on curved plates. The magnitude of centerline shifts increased with increasing plate curvatures.

42 ENGINEERING↗

DOE OSTI2019

Effects of Plate Curvature on Thermo-Mechanical Performance of U-10Mo Monolithic Fuel Plates

Monolithic fuel is a candidate fuel form being considered for the conversion of high-performance research reactors. This plate-type fuel consists of a high-density, U-Mo fuel in a monolithic form that is sandwiched between zirconium diffusion barriers, and encapsulated in an aluminum cladding. To date, large number of plates have been irradiated with satisfactory performance. The program is now moving into the qualification phase, a predecessor to the timely conversion of the target reactors. Since each reactor employs distinct fuel plate geometries for various consideration, resulting nearly 50 distinct plate geometries with unique plate design features, a single “generic” plate geometry capturing all of the extremities is not achievable. This limitation consequently requires much more cautious performance evaluations, as thermal and mechanical response of a plate with certain geometry may not be representative for a plate with a different geometry. To evaluate the performance of the plates for various geometric parameters, parametric sensitives studies have been employed. One of the important geometric parameters may have potential effects on the performance is the plate curvature. In this study, curved-plates were parametrically simulated to investigate if this geometric parameter has any effects on overall performance, In particular, radius of curvatures of the plates were varied between the bounding values, and the plates were simulated for comparable irradiation histories. The resulted temperature, deformation, stress-strain results were comparatively evaluated. The results have indicated that preferential deformations occur. This consequently caused shifting of plate centerline on curved plates. The magnitude of centerline shifts increased with increasing plate curvatures.

42 ENGINEERING↗

DOE OSTI2022

3D printing of void-free glass monoliths: rheological and geometric considerations

Direct ink writing (DIW) is a versatile additive manufacturing technique capable of printing 3D architectures from a broad range of materials. The key advantage of DIW is the ability to spatially control both the architecture and the composition of the printed part, which enables the production of components with previously unachievable combinations of functionalities. One emergent application space for DIW has been in additively manufactured glass optics, where a “green body” is patterned layer-by-layer by extruding a silica-based slurry through a microfluidic nozzle and then thermally consolidated to transparent glass. A critical aspect of the process is ensuring that the printed part is completely free of voids that can occur in the interstitial spaces between the extruded filaments. This outcome is governed by the interplay between ink rheology and strains imposed by the printing process and geometric packing of the filaments. Here, we explore the strain- and rate-dependent deformation events in the DIW process to determine conditions that enable the printing of void-free monoliths without sacrificing shape fidelity. We focus on yield stress fluids consisting of fumed silica nanoparticles dispersed in organic solvents at varied volume fractions to control the rheological properties. We investigate the printability of these ink materials as a function of print process variables and devise the appropriate dimensionless parameters that capture the geometry-dependent and rate-dependent effects on the deformation of the extruded ink. Lastly, we use these scaling arguments to construct a phase diagram for void-free monolith printability.

36 MATERIALS SCIENCE↗

DOE OSTI2014

Development and validation of capabilities to measure thermal properties of layered monolithic U-Mo alloy plate-type fuel

The uranium-molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the world’s highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of thermal conductivity behavior of the fuel system as a function of temperature and expected irradiation conditions. The purpose of this paper is to verify and validate the functionality of equipment methods installed in hot cells for eventual measurements on irradiated uranium-molybdenum (U-Mo) monolithic fuel specimens, procedures to operate the equipment, and models to extract the desired thermal properties. The results presented here demonstrate the adequacy of the equipment, procedures and models that have been developed for this purpose based on measurements conducted on surrogate depleted uranium-molybdenum (DU-Mo) alloy samples containing a zirconium diffusion barrier and clad in aluminum alloy 6061 (AA6061). The results are in excellent agreement with thermal property data reported in the literature for similar U-Mo alloys as a function of temperature.

multi-layer↗

DOE OSTI2017

U-Mo Monolithic Fuel for Nuclear Research and Test Reactors

The metallic fuel selected to replace the current HEU fuels in the research and test reactors is the LEU-10 weight % Mo alloy in the form of a thin sheet or foil encapsulated in AA6061 aluminum alloy with a zirconium interlayer. In order to effectively lead this pursuit, new developments in processing and fabrication of the fuel elements have been initiated, along with a better understanding of material behavior before and after irradiation as a result of these new developments. This editorial note gives an introduction about research and test reactors, need for HEU to LEU conversion, fuel requirements, high uranium density monolithic fuel development and an overview of the four articles published in the December 2017 issue of JOM under a special topic titled “U-Mo Monolithic Fuel for Nuclear Research and Test Reactors”.

LEU fuel development↗

DOE OSTI2020

Nanoarray-Based Monolithic Adsorbers for SO 2 Removal

Nanoarray-based monolithic catalysts have been developed for various applications, including CO oxidation, hydrocarbon combustion, lean NO x trapping, and low-pressure CO 2 hydrogenation. In this work, SO 2 adsorption properties have been explored and evaluated on the cordierite honeycomb monoliths grown with zinc oxide nanoarray (ZnO), zinc oxide nanoarray washcoated by BaCO 3 nanoparticles (ZnO/BaCO 3 ), and manganese oxide nanowire array with cryptomelane structure (MnO x ) at a temperature range from 50 to 425 °C. All samples show temperature-dependent SO 2 adsorption behaviors. The adsorption results reveal the performance order: MnO x > ZnO/BaCO 3 > ZnO, with ~ 90% SO 2 adsorbed in MnO x at 425 °C. Washcoated BaCO 3 contributes to the improvement of SO 2 adsorption in ZnO nanoarray, and the best performance displayed in MnO x may be attributed to their high specific surface area. After regeneration, nanoarrays all exhibit good thermal stability during test-regeneration cycles. No additional phase is formed in regenerated ZnO nanoarrays (ZnO-R), while BaCO 3 is converted to BaSO 4 in the regenerated ZnO/BaCO 3 nanoarrays (ZnO/BaCO 3 -R), and the sulfur species (possibly MnSO 4 ) and Mn 2 O 3 are found in regenerated MnO x nanoarrays (MnO x -R). It is noted that a small amount of sulfur species (possibly MnSO 4 ) may promote the SO 2 adsorption of MnO x -R at a lower temperature, while the formed Mn 2 O 3 contributes to the deactivation of MnO x -R.

36 MATERIALS SCIENCE↗

DOE OSTI2023

Balanced Fast-SpaciMS capillary configurations provide practically noninvasive channel-average measurements in catalytic monoliths

Spatially resolved capillary-inlet mass spectrometry (SpaciMS) provides a detailed picture of the spatiotemporal evolution of reaction network in catalytic monoliths. In the present work, we combine the SpaciMS experiments with a newly developed non-isothermal 3D CFD model for heterogeneously catalyzed reactive flows, including diffusion and permeation through the coated catalyst and channel wall. We explore how the capillary size and sampling rate can be balanced to minimize the impact on probed-channel conversions and provide species concentration measurements representative of the free channel average. In all studied configurations, the balanced sampling-rate fraction is noticeably higher than the corresponding capillary occlusion fraction. For a typical 350-micron capillary that occupies 11% of the channel cross- section, the balanced sampling rate represents 43% of the channel flow. Furthermore, the present work shows that together, a balanced SpaciMS configuration and numerical simulation provide accurate channel-averaged information of a monolithic catalyst under realistic operation conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2022

Sol-gel processing of a covalent organic framework for the generation of hierarchically porous monolithic adsorbents

Covalent organic frameworks (COFs) have emerged as a versatile material platform for such applications as chemical separations, chemical reaction engineering, and energy storage. Their inherently low mechanical stability, however, frequently renders existing methods of pelletization ineffective, contributing to pore collapse, pore blockage, or insufficient densification of crystallites. Here, we present a process for the shaping and densifying of COFs into robust centimeter-scale porous monoliths without the need for templates, additives, or binders. This process minimizes mechanical damage from shear-induced plastic deformation and further provides a network of interparticle mesopores that we exploit in accessing analyte capacities above those achievable from the intrinsic COF structure. Using a lattice-gas model, we accurately capture the monolithic structure across the mesoporous range and tie pore architecture to performance in both gas-storage and -separation applications. Collectively, these results represent a substantial step in the practical applicability of COFs and other mechanically weak porous materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2019

Effect of cycling and thermal control on the storage and dynamics of a 40-L monolithic adsorbed natural gas tank

Adsorbed natural gas systems have been proposed as a cost-effective storage alternative to compressed and liquefied natural gas. This has led many groups to search and design sorbent materials with large methane storage capacities since natural gas is approximately 90% methane. The other 10% of natural gas contains larger hydrocarbons which can decrease the useable storage capacity of adsorbent systems. In this work, the effect of large hydrocarbons on the storage and dynamics of a 40-L adsorbed natural gas system, containing 20.5 kg of monolithic carbon adsorbent, produced by the University of Missouri, is reported. It was found that over the course of 20 cycles, due to the retention of 1.9 kg of non-methane components by the monoliths, the useable volumetric storage dropped 16%, and the amount of gas delivered dropped 10%. A second cycling experiment found that by using thermal control while the system discharged, the mass retention decreased to 0.91 kg, and the useable volumetric storage and delivered mass only dropped 7% and 5%, respectively. The effects of the mass retention, storage loss, and thermal control on the system’s charge and discharge dynamics were then analyzed to provide a complete picture of the long-term effects of cycling large scale adsorbed natural gas systems with and without active thermal control.

03 NATURAL GAS↗

DOE OSTI2020

Size- and concentration-dependent Eu 2+ /Eu 3+ mixed luminescent characteristics of rare-earth-doped CaF 2 nanoparticles and their monolithic epoxy nanocomposites

CaF 2 is a promising luminescent host material for a wide range of applications, due to its high transparency, non-hygroscopy, low refractive index, low density, low backscattering efficiency, and abundance in nature. Here we report the photoluminescence (PL) and cathodoluminescence (CL) characteristics of rare-earth-doped CaF 2 nanoparticles and their composite monoliths with epoxy with visible emissions. The CaF 2 nanoparticles of ca. 36, 108 and 305 nm were prepared by a facile solution-mixing process and subsequent hydrothermal treatment. As the particle size decreases, the luminescence intensity increases for single-doped particles, while oppositely decreases for codoped particles because of energy transfer. Further, Eu 2+ - and Tb 3+ -codoped CaF 2 nanoparticles exhibit red emission, providing an efficient path for red emission through an energy transfer by Tb 3+ bridging without direct Eu 3+ doping. The effects of size and concentration are found to be pronounced in CL than PL, as the charge transfer between Eu 2+ and Eu 3+ reduces the concentration quenching in CL. The luminescence emission characteristics of epoxy/CaF 2 monoliths are different from those of particles due to the interactions with the epoxy molecules, and thus the energy transfer is hindered in PL while not in CL, enabling them for high-energy irradiation applications.

36 MATERIALS SCIENCE↗