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At least 145 records · Page 8
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NASA NTRS2019

Sensitivity of Inherent Optical Properties from Ocean Reflectance Inversion Models to Satellite Instrument Wavelength Suites

The Earth science community seeks to develop climate data records (CDRs) from satellite measurements of ocean color, a continuous data record that now exceeds 20 years. Space agencies will launch additional instruments in the coming decade that will continue this data record, including the NASA PACE spectrometer. Inherent optical properties (IOPs) quantitatively describe the absorbing and scattering constituents of seawater and can be estimated from satellite-observed spectroradiometric data using semi-analytical algorithms (SAAs). SAAs exploit the contrasting optical signatures of constituent matter at spectral bands observed by satellite sensors. SAA performance, therefore, depends on the spectral resolution of the satellite spectroradiometer. A CDR spanning SeaWiFS, MODIS, OLCI, and PACE, for example, would include IOPs derived using varied wavelength suites if all available wavelengths were considered. Here, we explored differences in derived IOPs that stem simply from the use of (eight) different wavelength suites of input radiometric measurements. Using synthesized data and SeaWiFS Level-3 mission-long composites, we demonstrated equivalent SAA performance for all wavelength suites, but that IOP retrievals vary by several percent across wavelength suites and as a function of water type. The differences equate to roughly ≤ 6, 12, and 7% for a(sub dg)(443), a(sub ph)(443), and b(sub bp)(443), respectively, for waters with C(sub a) ≤ 1 mg -cu m. These values shrink for sensors with similar wavelength suites (e.g., SeaWiFS, MODIS, and MERIS) and rise to substantially larger values for higher C(sub a) waters. Our results also indicate that including 400 nm (in the case of OLCI) influences the derived IOPs, using longer wavelengths (>600 nm) influences the derived IOPs when there is a red signal, and, including additional spectral information shows potential for improved IOP estimation, but not without revisiting SAA parameterizations and execution. While modest in scope, we believe this study contributes to the knowledge base for CDR development. The implication of ignoring such an analysis as CDRs continue to be developed is a prolonged inability to distinguish between algorithmic and environmental contributions to trends and anomalies in the IOP time-series.

ocean color satellites↗
NASA NTRS1992

A rare gas optics-free absolute EUV photon spectrometer for solar system studies

We have developed a prototype spectrometer for space applications which require long term absolute EUV photon flux measurements. In this recently developed spectrometer, the energy spectrum of the incoming photons is transformed directly into an electron energy spectrum by taking advantage of the photoelectric effect in one of several rare gases at low pressures. Using an electron energy spectrometer operating at a few eV, and followed by an electron multiplying detector, pulses due to individual electrons are counted. The overall efficiency of this process is essentially independent of gain drifts in the signal path, and the secular degradation of optical components which is often a problem in other techniques is avoided.

Daybell, M. D.↗
NASA NTRS1998

CNO Processing in Massive Algol Binaries

This program, used ultraviolet observations by the IUE Observatory along with other tools to search for abundance anomalies indicative of CNO processing in the secondary (mass-donating) stars of six interacting binary systems. Related IUE-based activities were also undertaken under this grant. Two Supplements to the grant were awarded. Supplement No. 1 was in connection with the NASA Grant Supplements for Education program, for a workshop for elementary school science teachers. The two sessions of the workshop were held October 24 and November 14, 1992. Eighteen school teachers from central Pennsylvania, grades 1-7, participated in the workshop, for which they received one unit of in-service training credit from their Intermediate Unit. Supplement No. 2 was awarded for additional IUE observations of the Algol stars V342 Aql and TU Mon. Observations of all six candidate stars were made with IUE, and attention was narrowed to TU Mon in particular, for which further IUE observations were made using Director's discretionary time. Observations of TU Mon were also carried out with the Voyager UV spectrometers, and optical spectroscopy was obtained on several occasions at Penn State's Black Moshannon Observatory. Photometric data on TU Mon were acquired by Dr. Paul Etzel at Mt. Laguna Observatory (MLO). McGouldrick was employed part-time during the Fall academic semester to assist in accessing the IUE Archive, and to correlate data on some cataclysmic variables and related objects that were observed with both IUE and the Voyager Far Ultraviolet Spectrometers. Approximately 21 relevant binary systems were observed with the Voyager UVS over the past decade, and a paper is being prepared for eventual publication that will serve as an index to the UVS data archive on these stars, providing observation dates, mean count rates in far and extreme UV bands, and a discussion of the relevant literature concerning the far UV behavior (including correlative IUE information from the archive and the literature). Much of the activity under the grant was in connection with V342 Aquilae, a 3.39 day Algol system thought to be in a state of rapid mass transfer. The goal was to combine optical and ultraviolet data to arrive at a robust, informative interpretation of this unique binary system. Complete orbital phase coverage of V342 Aql was obtained spectroscopically and photometrically.

Wade, Richard A.↗
NASA NTRSDate not supplied

UAS Payload Design for In-Situ Smoke Plume Sensing

To aid in the detection of harmful aerosols and trace gases emitted in wildfires and prescribed burns, we are designing a smoke-specific payload which can be flown on the Black Swift S2™ Uncrewed Aerial System (UAS) platform. The payload will be custom and mounted within the nosecone, equipped with a trace gas sensor suite and particle spectrometer for characterization of wildfire and prescribed burn emissions. This data will aid in the improvement of HYSPLIT3 modeling to make more informed decisions regarding prescribed burns, particularly for mountain valleys in the Pacific Northwest. The trace gas suite will be composed of 8 low-cost trace gas sensors (CH4, CO2, CO, HCN, NO2, NO, O3, and Volatile Organic Compounds (VOCs)). Portable Optical Particle Spectrometer (POPS) measures particle size range between 0.14 to 3 µm, which is crucial for assessing public health impact, air quality, and visibility.

Henry Miller↗
NASA NTRS2007

Bench-Top Antigen Detection Technique that Utilizes Nanofiltration and Fluorescent Dyes which Emit and Absorb Light in the Near Infrared

This article discusses the development of a bench-top technique to detect antigens in fluids. The technique involves the use of near infrared NIR fluorescent dyes conjugated to antibodies, centrifugation, nanofilters, and spectrometry. The system used to detect the antigens utilizes a spectrometer, fiber optic cables, NIR laser, and laptop computer thus making it portable and ideally suited for desk top analysis. Using IgM as an antigen and the secondary antibody, anti-IgM conjugated to the near infrared dye, IRDye (trademark) 800, for detection, we show that nanofiltration can efficiently and specifically separate antibody-antigen complexes in solution and that the complexes can be detected by a spectrometer and software using NIR laser excitation at 778 nm and NIR dye offset emission at 804 nm. The peak power detected at 778 nm for the excitation emission and at 804 nm for the offset emission is 879 pW (-60.06 dBm) and 35.7 pW (-74.5 dBm), respectively.

Varaljay-Spence, Vanessa A.↗
NASA NTRS1984

Optical and other property changes of M-50 bearing steel surfaces for different lubricants and additive prior to scuffing

An ester lubricant base oil containing one or more standard additives to protect against wear, corrosion, and oxidation was used in an experimental ball/plate elastohydrodynamic contact under load and speed conditions such as to induce scuffing failure in short times. Both the ball and the plate were of identically treated M-50 steel. After various periods of operating time the wear track on the plate was examined with an interference microscope of plus or minus 30 A depth resolution and sometimes also with a scanning ellipsometer and an Auger spectrometer. The optically deduced surface profiles varied with wavelength, indicating the presence of surface coatings, which were confirmed by the other instruments. As scuffing was approached, a thin (approximately A) oxide layer and a carbide layer formed in the wear track in particular when tricresylphosphate antiwear additive was present in the lubricant. The rates of the formation of these layers and their reactivity toward dilute alcholic HCl depended strongly on the lubricant and additives. Based on these results suggestions for improved formulations and a test method for bearing reliability could be proposed.

Lauer, J. L.↗
NASA NTRS1986

Optical and other properties changes of M-50 bearing steel surfaces for different lubricants and additives prior to scuffing

An ester lubricant base oil containing one or more standard additives to protect against wear, corrosion, and oxidation was used in an experimental ball/plate elastohydrodynamic contact under load and speed conditions such as to induce scuffing failure in short times. Both the ball and the plate were of identically treated M-50 steel. After various periods of operating time the wear track on the plate was examined with an interference microscope of plus or minus 30 A depth resolution and sometimes also with a scanning ellipsometer and an Auger spectrometer. The optically deduced surface profiles varied with wavelength, indicating the presence of surface coatings, which were confirmed by the other instruments. As scuffing was approached, a thin (approximately A) oxide layer and a carbide layer formed in the wear track in particular when tricresylphosphate antiwear additive was present in the lubricant. The rates of the formation of these layers and their reactivity toward dilute alcoholic HCl depended strongly on the lubricant and additives. Based on these results suggestions for improved formulations and a test method for bearing reliability could be proposed.

Lauer, J. L.↗
NASA NTRS2012

Investigations Using Laboratory Testbeds to Interpret Flight Instrument Datasets from Mars Robotic Missions

The Astromaterials Research and Exploration Science Directorate at the NASA Johnson Space Center (JSC) has laboratory instrumentation that mimic the capabilities of corresponding flight instruments to enable interpretation of datasets returned from Mars robotic missions. The lab instruments have been and continue to be applied to datasets for the Moessbauer Spectrometer (MB) on the Mars Exploration Rovers (MER), the Thermal & Evolved Gas Analyzer (TEGA) on the Mars Phoenix Scout, the CRISM instrument on the Mars Reconnaissance Orbiter Missions and will be applied to datasets for the Sample Analysis at Mars (SAM), Chemistry and Mineralogy (CheMin) and Chemistry & Camera (ChemCam) instruments onboard the Mars Science Laboratory (MSL). The laboratory instruments can analyze analog samples at costs that are substantially lower than engineering models of flight instruments, but their success to enable interpretation of flight data depends on how closely their capabilities mimic those of the flight instrument. The JSC lab MB instruments are equivalent to the MER instruments except without flight qualified components and no reference channel Co-57 source. Data from analog samples were critical for identification of Mg-Fe carbonate at Gusev crater. Fiber-optic VNIR spectrometers are used to obtain CRISM-like spectral data over the range 350-2500 nm, and data for Fephyllosilicates show irreversible behavior in the electronic transition region upon dessication. The MB and VNIR instruments can be operated within chambers where, for example, the absolute H2O concentration can be measured and controlled. Phoenix's TEGA consisted of a calorimeter coupled to a mass spectrometer (MS). The JSC laboratory testbed instrument consisted of a differential scanning calorimeter (DSC) coupled to a MS configured to operate under total pressure (12 mbar), heating rate (20 C/min), and purge gas composition (N2) analogous to the flight TEGA. TEGA detected CO2 release at both low (400-680 C) and high (725-820 C) temperature and an endothermic reaction in concert with the high temperature release. The high-temperature thermal decomposition is consistent with calcite, dolomite, or ankerite, (3-6 wt.%) or any combination of these phase based upon laboratory testbed experiments. Recent laboratory experiments suggest that the low temperature CO2 release was caused by a reaction between calcium carbonate and hydrated magnesium perchlorate; although, CO2 release by the oxidation of organic materials and Fe-/Mg-rich carbonates cannot be ruled out. MSL landed in Gale crater on August 5, 2012. Although numerous analog samples have been analyzed on the JSC laboratory testbeds, no SAM, CheMin, or ChemCam analyses have been acquired by MSL to date. The JSC SAM laboratory testbed consists of a thermal analyzer coupled with a MS configured to operate under total pressure (30 mbar), heating rate (35 C/min), and purge gas composition (He) analogous to the flight SAM. The CheMin and ChemCam laboratory testbeds were developed and built by inXitu, Inc. and Los Alamos National Laboratory, respectively, to acquire datasets relevant to the MSL CheMin and ChemCam flight instruments.

Ming, D. W.↗
NASA NTRS1980

High-resolution spectrometer

Proposed spectrometer combines optical and imaging devices and cryogenic cooling to measure infrared radiation in 1-to-15 micrometer wavelength range with spatial resolution of 1 arc-second and average spectral resolution of about 0.1 cm(-1). Compact, lightweight unit is suitable for laboratory or field use. Pollution monitoring is possible application.

Beer, R.↗
NASA NTRS1982

Preparation and analysis of standardized waste samples for Controlled Ecological Life Support Systems (CELSS)

The preparation and analysis of standardized waste samples for controlled ecological life support systems (CELSS) are considered. Analysis of samples from wet oxidation experiments, the development of ion chromatographic techniques utilizing conventional high pressure liquid chromatography (HPLC) equipment, and an investigation of techniques for interfacing an ion chromatograph (IC) with an inductively coupled plasma optical emission spectrometer (ICPOES) are discussed.

Carden, J. L.↗
NASA NTRS1989

Liquid water content and droplet size calibration of the NASA Lewis Icing Research Tunnel

The icing research tunnel at the NASA Lewis Research Center underwent a major rehabilitation in 1986 to 1987, necessitating recalibration of the icing cloud. The methods used in the recalibration, including the procedure used to establish a uniform icing cloud and the use of a standard icing blade technique for measurement of liquid water content are described. PMS Forward Scattering Spectrometer and Optical Array probes were used for measurement of droplet size. Examples of droplet size distributions are shown for several median volumetric diameters. Finally, the liquid water content/droplet size operating envelopes of the icing tunnel are shown for a range of airspeeds and are compared to the FAA icing certification criteria.

Ide, Robert F.↗
NASA NTRS1989

High accuracy motor controller for positioning optical filters in the CLAES Spectrometer

The Etalon Drive Motor (EDM), a precision etalon control system designed for accurate positioning of etalon filters in the IR spectrometer of the Cryogenic Limb Array Etalon Spectrometer (CLAES) experiment is described. The EDM includes a brushless dc torque motor, which has an infinite resolution for setting an etalon filter to any desired angle, a four-filter etalon wheel, and an electromechanical resolver for angle information. An 18-bit control loop provides high accuracy, resolution, and stability. Dynamic computer interaction allows the user to optimize the step response. A block diagram of the motor controller is presented along with a schematic of the digital/analog converter circuit.

Thatcher, John B.↗
NASA NTRS1990

Liquid water content and droplet size calibration of the NASA Lewis Icing Research Tunnel

The icing research tunnel at the NASA Lewis Research Center underwent a major rehabilitation in 1986 to 1987, necessitating recalibration of the icing cloud. The methods used in the recalibration, including the procedure used to establish a uniform icing cloud and the use of a standard icing blade technique for measurement of liquid water content are described. PMS Forward Scattering Spectrometer and Optical Array probes were used for measurement of droplet size. Examples of droplet size distributions are shown for several median volumetric diameters. Finally, the liquid water content/droplet size operating envelopes of the icing tunnel are shown for a range of airspeeds and are compared to the FAA icing certification criteria.

Ide, Robert F.↗
NASA NTRS1990

Acousto-optic tunable filter (AOTF) imaging spectrometer for NASA applications - System issues

A recently developed AOTF operating in the visible, 0.4-0.8 micron bandpass is presently compared with other spectrometer designs, with a view to the advantages it may uniquely offer for prospective NASA missions. Since spectral identification is accomplished by this system through the scanning of a few spectral bands, data storage requirements for spectral image analysis can be significantly reduced. Attention is given to spectral and imaging capabilities and their applicability to defense, remote sensing, and industrial uses.

Yu, Jeffrey↗
NASA NTRS1991

Remote sensing of atmospheric chemistry; Proceedings of the Meeting, Orlando, FL, Apr. 1-3, 1991

The present volume on remote sensing of atmospheric chemistry discusses special remote sensing space observations and field experiments to study chemical change in the atmosphere, network monitoring for detection of stratospheric chemical change, stratospheric chemistry studies, and the combining of model, in situ, and remote sensing in atmospheric chemistry. Attention is given to the measurement of tropospheric carbon monoxide using gas filter radiometers, long-path differential absorption measurements of tropospheric molecules, air quality monitoring with the differential optical absorption spectrometer, and a characterization of tropospheric methane through space-based remote sensing. Topics addressed include microwave limb sounder experiments for UARS and EOS, an overview of the spectroscopy of the atmosphere using an FIR emission experiment, the detection of stratospheric ozone trends by ground-based microwave observations, and a FIR Fabry-Perot spectrometer for OH measurements.

Mcelroy, James L.↗