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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Bonding Lexan and sapphire to form high-pressure, flame-resistant window

Flammable materials have been studied in normal gravity and microgravity for many years. Photography plays a major role in the study of the combustion process giving a permanent visual record that can be analyzed. When these studies are extended to manned spacecraft, safety becomes a primary concern. The need for a high-pressure, flame-resistant, shatter-resistant window permitting photographic recording of combustion experiments in manned spacecraft prompted the development of a method for bonding Lexan and sapphire. Materials that resist shattering (e.g., Lexan) are not compatible with combustion experiments; the material loses strength at combustion temperatures. Sapphire is compatible with combustion temperatures in oxygen-enriched atmospheres but is subject to shattering. Combining the two materials results in a shatter-resistant, flame-resistant window. Combustion in microgravity produces a low-visibility flame; however, flame propagation and flame characteristics are readily visible as long as there is no deterioration of the image. Since an air gap between the Lexan and the sapphire would reduce transmission, a method was developed for bonding these unlike materials to minimize light loss.

Richardson, William R.↗

A high flux pulsed source of energetic atomic oxygen

The design and demonstration of a pulsed high flux source of nearly monoenergetic atomic oxygen are reported. In the present test setup, molecular oxygen under several atmospheres of pressure is introduced into an evacuated supersonic expansion nozzle through a pulsed molecular beam valve. A 10J CO2 TEA laser is focused to intensities greater than 10 to the 9th W/sq cm in the nozzle throat, generating a laser-induced breakdown with a resulting 20,000-K plasma. Plasma expansion is confined by the nozzle geometry to promote rapid electron-ion recombination. Average O-atom beam velocities from 5-13 km/s at fluxes up to 10 to the 18th atoms/pulse are measured, and a similar surface oxygen enrichment in polyethylene samples to that obtained on the STS-8 mission is found.

Krech, Robert H.↗

Procedure for the selection of materials for use in oxygen systems at the John F. Kennedy Space Center

This paper describes tests used at the John F. Kennedy Space Center (KSC) in the material selection procedure for evaluating materials suitable for use in oxygen systems. Special attention is given to the basic selection criteria for materials used in oxygen enriched environments. The flow chart for the material selection procedure is presented, and information that must be supplied by vendors requesting batch/lot certification support from KSC is given.

Bryan, Coleman J.↗

Propulsion requirements for the supply of lunar-derived oxygen for a manned Mars mission

The use of lunar-derived liquid oxygen with hydrogen for robust manned explorations beyond earth is discussed. The propellant mixture ratio for optimal performance is near the current design point of r = 6. The results of NASA-sponsored studies of missions using cryogenic bipropellant H2-O2 for most functions reveal the potential benefits from a propellant terminal in cis-lunar space. The main propulsion technologies associated with Mars mission case studies include: in-space fluid transfer, zero-g ignition, oxygen-enriched propellant mixtures, throttling of main engines, and H2-O2 based auxiliary propulsion.

Wrobel, J. Richard↗

Laser supported detonation wave source of atomic oxygen for aerospace material testing

A pulsed high-flux source of nearly monoenergetic atomic oxygen was developed to perform accelerated erosion testing of spacecraft materials in a simulated low-earth orbit (LEO) environment. Molecular oxygen is introduced into an evacuated conical expansion nozzle at several atmospheres pressure through a pulsed molecular beam valve. A laser-induced breakdown is generated in the nozzle throat by a pulsed CO2 TEA laser. The resulting plasma is heated by the ensuing laser-supported detonation wave, and then it rapidly expands and cools. An atomic oxygen beam is generated with fluxes above 10 to the 18th atoms per pulse at 8 + or - 1.6 km/s with an ion content below 1 percent for LEO testing. Materials testing yielded the same surface oxygen enrichment in polyethylene samples as observed on the STS mission, and scanning electron micrographs of the irradiated polymer surfaces showed an erosion morphology similar to that obtained on low earth orbit.

Krech, Robert H.↗

Computation of hypersonic flows with finite rate condensation and evaporation of water

A computer program for modelling 2D hypersonic flows of gases containing water vapor and liquid water droplets is presented. The effects of interphase mass, momentum and energy transfer are studied. Computations are compared with existing quasi-1D calculations on the nozzle of the NASA Langley Eight Foot High Temperature Tunnel, a hypersonic wind tunnel driven by combustion of natural gas in oxygen enriched air.

Perrell, Eric R.↗

Transition frequencies and absolute strengths of H2 O-17 and H2 O-18 in the 6.2-micron region

High-resolution spectra of oxygen-enriched samples of water vapor were recorded with a Fourier-transform spectrometer covering transitions in the (010)-(000) bands. The measured line frequencies were used along with measurements taken from studies at microwave and far-infrared frequencies to obtain rotational energy levels in the (000) and (010) states of H2 O-17 and H2 O-18. Measurements of the line strengths were fitted to a model in which as many as 18 transition moment parameters were determined. The results produced computed line-strength values that are in excellent agreement with the 623 H2 O-17 experimental transition strengths and 696 H2 O-18 values. These results provide a more accurate representation of the line positions and strengths for the (010)-(000) bands of H2 O-17 and H2 O-18 than those previously available.

Toth, Robert A.↗

Dual Use Space Technology Transfer Conference Paper

New textile fibers have been developed or modified to meet the complex and constraining criteria of space applications. The most common of these criteria are light weight, nonflammability or flame retardancy, and high strength and durability in both deep space environment and the oxygen enriched crew bay area of the spacecraft. The fibers which successfully pass the tests of flammability and toxicity, and display the desired mechanical properties are selected for space applications. Such advanced fibers developed for the Crew and Thermal Systems Division (CTSD) at the Johnson Space Center include 'Beta' fiber, heat stabilized polybenzimidazole and polyimide, as well as modified aramid Durette(TM), multi-fibrous Ortho(TM) fabric, and flame resistant cotton. The physical, mechanical, and chemical properties of these fibers are briefly discussed. The testing capabilities in the CTSD laboratory to ascertain some of the properties of these and other fibrous materials are also discussed. Most of these materials developed for spacecraft, space suit, and flight equipment applications have found other commercial applications. These advanced textile fibers are used mostly for aircraft, transportation, public buildings, hospitals, and protective clothing applications.

Orndoff, Evelyne↗

Obtaining NASA Approval for use of Non-Metallic Materials in Manned Space Flight

Material manufacturers and suppliers are often surprised when a material commonly provided to industry is not approved for use on manned spacecraft. Often the reason is a lack of test data in environments that simulate those encountered in space applications, especially oxygen-enriched conditions, which significantly increase both the likelihood of material combustion and the propagation of a fire. This paper introduces the requirements for flight approval of non-metallic materials, focusing on material testing for human-rated space flight programs; it reviews the history of flight materials requirements and provides the rationale for such and introduces specific requirements related to testing and to good material engineering and design practices. After describing the procedure for submitting materials to be tested, the paper outlines options available if a material fails testing. In addition, this treatise introduces the National Aeronautics and Space Administration's (NASA's) Materials and Processes Technical Information System (MAPTIS), a database housing all test data produced in accordance with NASA-STD-6001, Flammability, Odor, Offgassing, and Compatibility Requirements and Test Procedures for Materials in Environments that Support Combustion.

Davis, Samuel E.↗

Improved pulmonary function in working divers breathing nitrox at shallow depths

INTRODUCTION: There is limited data about the long-term pulmonary effects of nitrox use in divers at shallow depths. This study examined changes in pulmonary function in a cohort of working divers breathing a 46% oxygen enriched mixture while diving at depths less than 12 m. METHODS: A total of 43 working divers from the Neutral Buoyancy Laboratory (NBL), NASA-Johnson Space Center completed a questionnaire providing information on diving history prior to NBL employment, diving history outside the NBL since employment, and smoking history. Cumulative dive hours were obtained from the NBL dive-time database. Medical records were reviewed to obtain the diver's height, weight, and pulmonary function measurements from initial pre-dive, first year and third year annual medical examinations. RESULTS: The initial forced vital capacity (FVC) and forced expiratory volume in 1 s (FEV1) were greater than predicted, 104% and 102%, respectively. After 3 yr of diving at the NBL, both the FVC and FEV1 showed a significant (p < 0.01) increase of 6.3% and 5.5%, respectively. There were no significant changes in peak expiratory flow (PEF), forced mid-expiratory flow rate (FEF(25-75%)), and forced expiratory flow rates at 25%, 50%, and 75% of FVC expired (FEF25%, FEF50%, FEF75%). Cumulative NBL dive hours was the only contributing variable found to be significantly associated with both FVC and FEV1 at 1 and 3 yr. CONCLUSIONS: NBL divers initially belong to a select group with larger than predicted lung volumes. Regular diving with nitrox at shallow depths over a 3-yr period did not impair pulmonary function. Improvements in FVC and FEV1 were primarily due to a training effect.

Non-programmatic↗

Smoldering News From STS-77 Endeavour

The Microgravity Smoldering Combustion (MSC) experiment lifted off aboard the Space Shuttle Endeavour for its second flight in May 1996, as part of the STS-77 mission. This experiment is part of a series of studies focused on the smolder characteristics of porous combustible materials in a microgravity environment. Smoldering is a nonflaming form of combustion that takes place in the interior of combustible materials. Common examples of smoldering are nonflaming embers, charcoal briquettes, and cigarettes. The objective of this study is to provide a better understanding of the controlling mechanisms of smoldering in microgravity and normal Earth gravity (1g). As with other forms of combustion, gravity affects the availability of air and transport of heat, and therefore, the rate of combustion. The results of the microgravity experiments will be compared with identical ones carried out in 1g. In addition, they will be used to verify present theories of smolder combustion and will provide new insights into the process of smoldering combustion, enhancing our fundamental understanding of this frequently encountered combustion process and guiding improvements in fire safety practices. Two smoldering combustion tests with polyurethane foam were successfully accomplished during the STS-77 mission. The tests investigated smoldering combustion in a quiescent (no-flow) enriched oxygen environment, and in an air environment with a 2-mm/sec airflow through the fuel sample. The primary data from the tests are the ignition characteristics, spread rate, smolder reaction temperature, and products of combustion (solid and gas). On both the first mission on STS-69 and the second mission on STS-77, a smolder front propagated the length of the forced-flow samples, with the spread rate between the corresponding upward and downward 1g smolder rates. Neither of the quiescent cases propagated combustion (the first case was due in part to a problem with the experiment electronics). These results show a dramatic difference from the normal gravity results, where smolder propagation is very rapid and complete for both of these conditions. The experiment was conceived by Prof. A. Carlos Fernandez-Pello at the University of California-Berkeley. The MSC hardware was designed and built at the NASA Lewis Research Center by a team of civil servants and contractors from NYMA, Inc., and Aerospace Design & Fabrication, Inc. (ADF). The hardware consists of two sealed aluminum combustion chambers (each being a half a cylinder). The chambers hold the MSC test section, data acquisition electronics, power distribution electronics, and instrumentation. The hardware is fitted into a 5-ft(sup 3) Get-Away-Special (GAS) canister that is mounted in the shuttle cargo bay. The test section consists of a quartz cylinder that contains the polyurethane foam sample and an igniter. This igniter, which is an electrically heated wire sandwiched between two porous ceramic disks, is mounted in contact with the end of the foam sample. An array of 12 thermocouples placed axially and radially along the foam sample provide temperature histories, which are used to determine the rate of smolder propagation, and the characteristics of the reaction.

Koudelka, John M.↗

Dual-Pump CARS Temperature and Species Concentration Measurements in a Supersonic Combustor

The dual-pump coherent anti-Stokes Raman scattering (CARS) method was used to measure temperature and the mole fractions of N2 and O2 in a supersonic combustor. Experiments were conducted in NASA Langley Research Center s Direct Connect Supersonic Combustion Test Facility. In this facility, H2 and oxygen-enriched air burn to increase the enthalpy of the simulated air test gas. This gas is expanded through a Mach 2 nozzle and into a combustor model consisting of a short constant-area section followed by a small rearward-facing step and another constant-area section. At the end of this straight section, H2 fuel is injected at Mach 2 and at a 30 angle with respect to the freestream. One wall of the duct then expands at a 3 angle for over 1 meter. The ensuing combustion is probed optically through ports in the side of the combustor. Dual-pump CARS measurements were performed at the facility nozzle exit and at four planes downstream of fuel injection. Maps are presented of the mean temperature, as well as N2 and O2 mean mole fraction fields. Correlations between fluctuations of the different measured parameters are also presented.

O'Byrne, S.↗

Survey of Software Problems with Impacts to 'Campout' Protocol Extravehicular Activity (EVA) Prebreathe

During International Space Station campout protocol ExtraVehicular Activity (EVA) preparations, the crew is isolated overnight in the small airlock volume in a reduced pressure, oxygen enriched atmosphere. As such, there are special considerations for the software in terms of air composition, pressure control and emergency responses. For one, the ISS software must monitor and manage two distinct atmospheres. Also, the small airlock volume is especially sensitive to small changes in the environment, and what would be a minor emergency in the larger vehicle volume can have catastrophic results in the isolated airlock. Finally, in cases of emergency, the crew needs to rapidly egress the airlock, which requires an aggressive automatic repressurization to equalize pressure on the hatch. This paper will describe the software which is modified for the airlock campout protocol. In addition, the paper will describe the software problems and hardware problems with software workarounds which have affected campout protocol.

Diderich, Greg↗

Determination of Pass/Fail Criteria for Promoted Combustion Testing

Promoted ignition testing is used to determine the relative flammability of metal rods in oxygen-enriched atmospheres. In these tests, a promoter is used to ignite each metal rod to start the sample burning. Experiments were performed to better understand the promoted ignition test by obtaining insight into the effect a burning promoter has on the preheating of a test sample. Test samples of several metallic materials were prepared and coupled to fast-responding thermocouples along their length. Various ignition promoters were used to ignite the test samples. The thermocouple measurements and test video was synchronized to determine temperature increase with respect to time and length along each test sample. A recommended length of test sample that must be consumed to be considered a flammable material was determined based on the preheated zone measured from these tests. This length was determined to be 30 mm (1.18 in.). Validation of this length and its rationale are presented.

Sparks, Kyle M.↗

Heat Effects of Promoters and Determination of Burn Criterion in Promoted Combustion Testing

Promoted ignition testing (NASA Test 17) [1] is used to determine the relative flammability of metal rods in oxygen-enriched atmospheres. A promoter is used to ignite a metal sample rod, initiating sample burning. If a predetermined length of the sample burns, beyond the promoter, the material is considered flammable at the condition tested. Historically, this burn length has been somewhat arbitrary. Experiments were performed to better understand this test by obtaining insight into the effect a burning promoter has on the preheating of a test sample. Test samples of several metallic materials were prepared and coupled to fast-responding thermocouples along their length. Thermocouple measurements and test video were synchronized to determine temperature increase with respect to time and length along each test sample. A recommended flammability burn length, based on a sample preheat of 500 F, was determined based on the preheated zone measured from these tests. This length was determined to be 30 mm (1.18 in.). Validation of this length and its rationale are presented.

Sparks, Kyle M.↗

Design and Manufacture of a Highly Reliable, Miniaturized and Low Mass Shutter Mechanism

This paper describes the development, manufacturing and testing of a lightweight shutter mechanism made of titanium for the MERTIS Instrument. MERTIS is a thermal infrared imaging spectrometer onboard ESA's future BepiColombo mission to Mercury. The mechanism is built as a parallelogram arrangement of flexible hinges, actuated by a voice coil. In a first test run, it was shown that the selected EDM processing led to the generation of titanium oxides and an oxygen-enriched surface layer on the substrate (so called alpha-case layer). In the revised version of the shutter, it was possible to manufacture the complex geometry by micro-milling and an adjacent pickling procedure. The adequacy of this approach was verified by lifetime and vibration testing.

Manhart, M.↗

Flow Friction or Spontaneous Ignition?

"Flow friction," a proposed ignition mechanism in oxygen systems, has proved elusive in attempts at experimental verification. In this paper, the literature regarding flow friction is reviewed and the experimental verification attempts are briefly discussed. Another ignition mechanism, a form of spontaneous combustion, is proposed as an explanation for at least some of the fire events that have been attributed to flow friction in the literature. In addition, the results of a failure analysis performed at NASA Johnson Space Center White Sands Test Facility are presented, and the observations indicate that spontaneous combustion was the most likely cause of the fire in this 2000 psig (14 MPa) oxygen-enriched system.

Stoltzfus, Joel M.↗

Gaseous Non-Premixed Flame Research Planned for the International Space Station

Thus far, studies of gaseous diffusion flames on the International Space Station (ISS) have been limited to research conducted in the Microgravity Science Glovebox (MSG) in mid-2009 and early 2012. The research was performed with limited instrumentation, but novel techniques allowed for the determination of the soot temperature and volume fraction. Development is now underway for the next experiments of this type. The Advanced Combustion via Microgravity Experiments (ACME) project consists of five independent experiments that will be conducted with expanded instrumentation within the stations Combustion Integrated Rack (CIR). ACMEs goals are to improve our understanding of flame stability and extinction limits, soot control and reduction, oxygen-enriched combustion which could enable practical carbon sequestration, combustion at fuel lean conditions where both optimum performance and low emissions can be achieved, the use of electric fields for combustion control, and materials flammability. The microgravity environment provides longer residence times and larger length scales, yielding a broad range of flame conditions which are beneficial for simplified analysis, e.g., of limit behaviour where chemical kinetics are important. The detailed design of the modular ACME hardware, e.g., with exchangeable burners, is nearing completion, and it is expected that on-orbit testing will begin in 2016.

microgravity↗