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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Holistic Numerical Calibration of the iMESA Electrostatic Analyzer

A drifted Maxwellian velocity distribution is the most common model used to interpret the data from low-energy charged-particle instruments onboard spacecraft that are used to investigate the ambient plasma environment in the low Earth orbit (LEO). An original method is presented for determining the flow parameters (density, temperature, and flow energy) of such a distribution from the output of the integrated miniaturized electrostatic analyzer, which has been successfully flown on several LEO missions. Rather than attempting to deconvolve from the on-orbit data the analyzer’s response to an ideal, monoenergetic input, numerical simulation is used to predict and parameterize the response of the device to an input distribution that includes an isotropic, non-zero temperature, yielding a straightforward method for extracting the flow parameters from the spacecraft data. The method is computationally simple enough to be incorporated into a robust algorithm suitable for rapid batch processing or real-time analysis of data.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

HAT-P-68b: A Transiting Hot Jupiter around a K5 Dwarf Star

We report the discovery by the ground-based Hungarian-made Automated Telescope Network (HATNet) survey of the transiting exoplanet HAT-P-68b, which has a mass of 0.724 ± 0.043 M {sub J}, and radius of 1.072 ± 0.012 R {sub J}. The planet is in a circular P = 2.2984 day orbit around a moderately bright V = 13.937 ± 0.030 magnitude K-dwarf star of mass 0.673{sub −0.014}{sup +0.020} M {sub ⊙}, and radius 0.6726 ± 0.0069 R {sub ⊙}. The planetary nature of this system is confirmed through follow-up transit photometry obtained with the Fred L. Whipple Observatory (FLWO) 1.2 m telescope, high-precision radial velocities measured using Keck I/High Resolution Echelle Spectrometer (HIRES), FLWO 1.5 m/Tillinghast Reflector Echelle Spectrograph (TRES), and Observatoire de Haute-Provence (OHP) 1.9 m/Sophie, and high-spatial-resolution speckle imaging from WIYN 3.5 m/DSSI. HAT-P-68 is at an ecliptic latitude of +3° and outside the field of view of both the NASA Transiting Exoplanet Survey Satellite primary mission and the K2 mission. The large transit depth of 0.036 mag (r band) makes HAT-P-68b a promising target for atmospheric characterization via transmission spectroscopy.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Detecting Atmospheric Molecules of Nontransiting Temperate Terrestrial Exoplanets Using High-resolution Spectroscopy in the Mid-infrared Domain

Motivated by the development of high-dispersion spectrographs in the mid-infrared (MIR) range, we study their application to the atmospheric characterization of nearby nontransiting temperate terrestrial planets around M-type stars. We examine the detectability of CO{sub 2}, H{sub 2}O, N{sub 2}O, and O{sub 3 }features in high-resolution planetary thermal emission spectra at 12–18 μm assuming an Earth-like profile and a simplified thermal structure. The molecular line width of such planets can be comparable to or broader than the Doppler shift due to the planetary orbital motion. Given the likely difficulty in knowing the high-resolution MIR spectrum of the host star with sufficient accuracy, we propose observing the target system at two quadrature phases and extracting the differential spectra as the planetary signal. In this case, the signals can be substantially suppressed compared with the case where the host star spectrum is perfectly known, as some parts of the spectral features do not remain in the differential spectra. Despite this self-subtraction, the CO{sub 2} and H{sub 2}O features of nearby (≲5 pc) systems with mid-/late-M host stars would be feasible with a 6.5 m class cryogenic space telescope, and orbital inclination could also be constrained for some of them. For CO{sub 2} and N{sub 2}O in a 1 bar Earth-like atmosphere, this method would be sensitive when the mixing ratio is 1–10{sup 3} ppm. The detectability of molecules except O{sub 3} is not significantly improved when the spectral resolution is higher than R≳10,000, although the constraint on the orbital inclination is improved. This study provides some benchmark cases useful for assessing the value of MIR high-resolution spectroscopy in terms of characterization of potentially habitable planets.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

ARES. V. No Evidence For Molecular Absorption in the HST WFC3 Spectrum of GJ 1132 b

We present a study on the spatially scanned spectroscopic observations of the transit of GJ 1132 b, a warm (∼500 K) super-Earth (1.13 R {sub ⊕}) that was obtained with the G141 grism (1.125–1.650 μm) of the Wide Field Camera 3 (WFC3) on board the Hubble Space Telescope. We used the publicly available Iraclis pipeline to extract the planetary transmission spectra from the five visits and produced a precise transmission spectrum. We analyzed the spectrum using the TauREx3 atmospheric retrieval code, with which we show that the measurements do not contain molecular signatures in the investigated wavelength range and are best fit with a flat-line model. Our results suggest that the planet does not have a clear primordial, hydrogen-dominated atmosphere. Instead, GJ 1132 b could have a cloudy hydrogen-dominated atmosphere, have a very enriched secondary atmosphere, be airless, or have a tenuous atmosphere that has not been detected. Due to the narrow wavelength coverage of WFC3, these scenarios cannot be distinguished yet, but the James Webb Space Telescope may be capable of detecting atmospheric features, although several observations may be required to provide useful constraints.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Systematic KMTNet Planetary Anomaly Search. I. OGLE-2019-BLG-1053Lb, a Buried Terrestrial Planet

In order to exhume the buried signatures of “missing planetary caustics” in Korea Microlensing Telescope Network (KMTNet) data, we conducted a systematic anomaly search of the residuals from point-source point-lens fits, based on a modified version of the KMTNet EventFinder algorithm. This search revealed the lowest-mass-ratio planetary caustic to date in the microlensing event OGLE-2019-BLG-1053, for which the planetary signal had not been noticed before. The planetary system has a planet–host mass ratio of q = (1.25 ± 0.13) × 10{sup -5}. A Bayesian analysis yielded estimates of the mass of the host star, M{sub host}=0.61{sub -0.24}{sup +0.29} M{sub ⊙}, the mass of its planet, M{sub planet}=2.48{sub -0.98}{sup +1.19} M{sub ⊕}, the projected planet–host separation, a{sub ⊥}=3.4{sub -0.5}{sup +0.5} au, and the lens distance, D{sub L}=6.8{sub -0.9}{sup +0.6} kpc. The discovery of this very-low-mass-ratio planet illustrates the utility of our method and opens a new window for a large and homogeneous sample to study the microlensing planet–host mass ratio function down to q ~ 10{sup -5}.

47 OTHER INSTRUMENTATION↗
DOE OSTI2023

Design and Characterization of a Lens-Coupled System for Dynamic X-Ray Diffraction

X-ray diffraction (XRD) is a necessary technique for understanding states of materials under static and dynamic loading conditions. The higher-pressure Equation of State (EOS) of many materials can only be explored via shock or ramp compression at temperatures and pressures of interest. While static XRD work has yielded EOS measurements in the 100 - 200 GPa regime, dynamic X-ray diffraction (DXRD) can explore EOS phases in the TPa regime, which closely resembles inner-core planetary conditions. DXRD hinges on the ability to measure the exact phase or phase change of a material while under dynamic loading conditions. Macroscopic diagnostic systems (e.g. velocimetry and pyrometry) can infer a phase change but not identify the specific phase entered by a material. While microscopic (atomic-level) diagnostic systems (e.g. DXRD) have been designed and implemented in Department of Energy’s (DOE) National Laboratories complex, the unique nature of Sandia National Laboratories’ Pulsed Power Facility (Z Machine) prohibits the use of such devices. The destructive nature of Z experiments presents a challenge to data capture and retrieval. Furthermore there are electromagnetic interference, X-ray background, and mechanical constraints to consider. Thus, a multi-part X-ray diagnostic for use on the Z Machine and Z-Beamlet Laser system has been designed and analyzed. Portions of this new DYnamic SCintillator Optic (DYSCO) have been built, tested and fielded. A data analysis software has been written. Finally, the radiance profile of the DYSCO’s scintillator has been characterized through experiments performed at the University of Arizona.

36 MATERIALS SCIENCE↗
DOE OSTI2021

TESS Observations of the WASP-121 b Phase Curve

We study the red-optical photometry of the ultrahot Jupiter WASP-121 b as observed by the Transiting Exoplanet Survey Satellite (TESS) and model its atmosphere through a radiative transfer simulation. Given its short orbital period of ∼1.275 days, inflated state, and bright host star, WASP-121 b is exceptionally favorable for detailed atmospheric characterization. Toward this purpose, we use allesfitter to characterize its full red-optical phase curve, including the planetary phase modulation and secondary eclipse. We measure the day- and nightside brightness temperatures in the TESS passband as 3012{sub −42}{sup +40} and 2022{sub −602}{sup +254} K, respectively, and do not find a statistically significant phase shift between the brightest and substellar points. This is consistent with inefficient heat recirculation on the planet. We then perform an atmospheric retrieval analysis to infer the dayside atmospheric properties of WASP-121 b, such as its bulk composition, albedo, and heat recirculation. We confirm the temperature inversion in the atmosphere and suggest H{sup −}, TiO, and VO as potential causes of the inversion, absorbing heat at optical wavelengths at low pressures. Future Hubble Space Telescope and James Webb Space Telescope observations of WASP-121 b will benefit from its first full phase curve measured by TESS.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Boundary Layer Climatology at ARM Southern Great Plains

Operational since 1992, the Atmospheric Radiation Measurement (ARM) southern great plains (SGP) site at Oklahoma, USA has become a reference research site for meteorological studies. Due to an open data policy the ARM data are used by researchers all over the world. In this report, we review the long-term climatology of the atmospheric boundary layer, SGP instrumentations, the site and some site-specific atmospheric conditions which potentially effect wind turbines within the region. As the atmospheric boundary layer is bounded and influenced by the surface, observations of surface radiation components and heat fluxes are crucial in understanding land-atmosphere interactions. The entrainment of air, updrafts, downdrafts and boundary layer height characteristics is needed for understanding the structure and growth of the atmospheric boundary layer. Therefore, measurements from both surface in-situ and remote sensing observations at SGP provide an overall climatology and their interactions from surface up to the boundary layer. Measurements from a 60 m meteorological tower, surface flux stations, disdrometers, soil temperature and moisture flux plates, coherent Doppler lidar, Raman lidar, radiosondes, and satellite data at SGP central facility were analyzed. All the measurements were generally within a few square kilometers of each other at the central facility. This report focuses on data from January 2010 to June 2020 at SGP central facility. The various sections describe the ARM SGP site and surrounding wind turbines; in-situ and remote sensing instrumentation used in the report; provides mathematical equations to analyze fluxes, turbulence and other boundary layer parameters; a climatological analysis of surface winds, fluxes and thermodynamic parameters for several years; an analysis of observed winds in the framework of Monin-Obukhov Similarity Theory; an analysis of the boundary layer winds and direction from a Doppler lidar; multi-year turbulence estimates through the boundary layer from a Doppler lidar; atmospheric boundary layer water vapor and relative humidity profiles from Raman lidar; cloud base height and boundary layer height from multiple sensors and satellite data; and finally site specific atmospheric conditions, such as nocturnal low-level jets. Diurnal, seasonal and yearly variations of surface, sub-surface and boundary layer quantities, such as wind speed, direction, temperature, atmospheric stability, soil temperature, and various atmospheric fluxes at SGP showed distinct trends useful for focused modeling studies. The applicability of surface similarity theory on ARM SGP data is also evaluated, which showed northerly flows are aligned with MO theory estimates compared to southerly flows. Boundary layer winds and direction profiles for several years from a Doppler lidar shows a consistent presence of a nocturnal low-level jet and predominant southerly wind directions through the boundary layer at SGP. The inter-annual variability at SGP is low (<3.5%), with a mean annual wind speed of approximately 7 m s -1 at 100 m above ground level. Boundary layer turbulence and moisture transport from Doppler and Raman lidars are evaluated, which provides evidence of increased water vapor mass flux into the great plains during nocturnal low-level jets. The moisture flux from nocturnal low-level jets is observed to be maximum during summer periods. A novel machine learning algorithm is implemented to accurately estimate the planetary boundary layer height, providing further insights into growth and destruction of the convective boundary layer height during various seasons and land-atmosphere conditions. The high frequency of low-level clouds during winter, spring and fall seasons is validated using the multi-sensor array and satellite estimates of cloud top height. Satellite vegetative fraction data provides insight into seasonal surface roughness and vegetation variability around SGP site.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

The Feasibility of Directly Imaging Nearby Cold Jovian Planets with MIRI/JWST

The upcoming launch of the James Webb Space Telescope (JWST) will dramatically increase our understanding of exoplanets, particularly through direct imaging. Microlensing and radial velocity surveys indicate that some M dwarfs host long-period giant planets. Some of these planets will likely be just a few parsecs away and a few astronomical units from their host stars, a parameter space that cannot be probed by existing high-contrast imagers. We studied whether the coronagraphs on the Mid-infrared Instrument on JWST can detect Jovian-type planets around nearby M dwarfs. For a sample of 27 very nearby M dwarfs, we simulated a sample of Saturn–Jupiter-mass planets with three atmospheric configurations and three orbital separations, observed in three different filters. We found that the f1550c 15.5 μm filter is best suited for detecting Jupiter-like planets. Jupiter-like planets with patchy cloud cover, 2 au from their star, are detectable at 15.5 μm around 14 stars in our sample, while Jupiters with clearer atmospheres are detectable around all stars in the sample. Saturns were most detectable at 10.65 and 11.4 μm (f1065c and f1140c filters), but only with cloud-free atmospheres and within 3 pc (six stars). Surveying all 27 stars would take <170 hr of JWST integration time, or just a few hours for a shorter survey of the most favorable targets. There is one potentially detectable known planet in our sample: GJ 832 b. Observations aimed at detecting this planet should occur in 2024–2026, when the planet is maximally separated from the star.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

On the Detection of Habitable Trojan Planets in the Kepler Circumbinary Systems

We present the results of a study of the prospect of detecting habitable Trojan planets in the Kepler Habitable Zone circumbinary planetary systems (Kepler-16, -47, -453, -1647, and -1661). We integrated the orbits of 10,000 separate N-body systems (N = 4, 6), each with a one Earth-mass body in a randomly selected orbit near the L {sub 4} and L {sub 5} Lagrangian points of the host HZ circumbinary planet. We find that stable Trojan planets are restricted to a narrow range of semimajor axes in all five systems and limited to small eccentricities in Kepler-16, -47, and -1661. To assess the prospect of the detection of these habitable Trojan planets, we calculated the amplitudes of the variations they cause in the transit timing of their host bodies. Results show that the mean amplitudes of the transit timing variations (TTVs) correlate with the mass of the transiting planet and range from 70 minutes for Kepler-16b to 390 minutes for Kepler-47c. Our analysis indicates that the TTVs of the circumbinary planets caused by these Trojan bodies fall within the detectable range of timing precision obtained from the Kepler telescope’s long-cadence data. The latter points to Kepler data as a viable source to search for habitable Trojan planets.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Data Science and Computation for Rapid and Dynamic Compression Experiment Workflows at Experimental Facilities, September 8-11, 2020. Workshop Report

The application of high pressure to materials has enabled discoveries in scientific fields such as planetary science, materials science, and materials synthesis. Recent advances in X-ray user light sources and other facilities, co-location and integration of user facilities with high-pressure drivers, availability of high-performance computing (HPC) platforms, and the development of new data science techniques have created opportunities for, and challenges in, advancing data analytics for rapid and dynamic compression experiments. To address these challenges, harness the emerging technology now available, and expedite scientific discovery, Los Alamos National Laboratory (LANL) hosted a virtual workshop entitled “Data Science and Computation for Rapid and Dynamic Compression Workflows at Experimental Facilities” from September 8 to 11, 2020. The workshop included 95 registered scientists and analytics experts from 15 universities, 9 United States (US) national laboratories, 5 US and European X-ray light sources, neutron sources such as the Los Alamos Neutron Science Center (LANSCE), other big science facilities such as the National Ignition Facility (NIF), and an industry representative. The workshop included 31 invited talks and 4 lightning talks by students and postdocs.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Gemini Planet Imager Spectroscopy of the Dusty Substellar Companion HD 206893 B

We present new near-infrared Gemini Planet Imager (GPI) spectroscopy of HD 206893 B, a substellar companion orbiting within the debris disk of its F5V star. The J, H, K1, and K2 spectra from GPI demonstrate the extraordinarily red colors of the object, confirming it as the reddest substellar object observed to date. The significant flux increase throughout the infrared presents a challenging atmosphere to model with existing grids. Best-fit values vary from 1200 to 1800 K for effective temperature and from 3.0 to 5.0 for log(g), depending on which individual wavelength band is fit and which model suite is applied. The extreme redness of the companion can be partially reconciled by invoking a high-altitude layer of submicron dust particles, similar to dereddening approaches applied to the peculiar red field L dwarf population. However, reconciling the HD 206893 B spectra with even those of the reddest low-gravity L dwarf spectra still requires the contribution of additional atmospheric dust, potentially due to the debris disk environment in which the companion resides. Orbit fitting from 4 yr of astrometric monitoring is consistent with a ∼30 yr period, an orbital inclination of 147°, and a semimajor axis of 10 au, well within the estimated disk inner radius of ∼50 au. As one of a very few substellar companions imaged interior to a circumstellar disk, the properties of this system offer important dynamical constraints on companion–disk interaction and provide a benchmark for substellar and planetary atmospheric study.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

The TESS-Keck Survey. II. An Ultra-short-period Rocky Planet and Its Siblings Transiting the Galactic Thick-disk Star TOI-561

We report the discovery of TOI-561, a multiplanet system in the galactic thick disk that contains a rocky, ultra-short-period planet. This bright (V = 10.2) star hosts three small transiting planets identified in photometry from the NASA TESS mission: TOI-561 b (TOI-561.02, P = 0.44 days, R {sub p} = 1.45 ± 0.11 R {sub ⊕}), c (TOI-561.01, P = 10.8 days, R {sub p} = 2.90 ± 0.13 R {sub ⊕}), and d (TOI-561.03, P = 16.3 days, R {sub p} = 2.32 ± 0.16 R {sub ⊕}). The star is chemically ([Fe/H] = −0.41 ± 0.05, [α/Fe] = +0.23 ± 0.05) and kinematically consistent with the galactic thick-disk population, making TOI-561 one of the oldest (10 ± 3 Gyr) and most metal-poor planetary systems discovered yet. We dynamically confirm planets b and c with radial velocities from the W. M. Keck Observatory High Resolution Echelle Spectrometer. Planet b has a mass and density of 3.2 ± 0.8 M {sub ⊕} and 5.5{sub −1.6}{sup +2.0} g cm{sup −3}, consistent with a rocky composition. Its lower-than-average density is consistent with an iron-poor composition, although an Earth-like iron-to-silicates ratio is not ruled out. Planet c is 7.0 ± 2.3 M {sub ⊕} and 1.6 ± 0.6 g cm{sup −3}, consistent with an interior rocky core overlaid with a low-mass volatile envelope. Several attributes of the photometry for planet d (which we did not detect dynamically) complicate the analysis, but we vet the planet with high-contrast imaging, ground-based photometric follow-up, and radial velocities. TOI-561 b is the first rocky world around a galactic thick-disk star confirmed with radial velocities and one of the best rocky planets for thermal emission studies.

47 OTHER INSTRUMENTATION↗
DOE OSTI2021

Giant Outer Transiting Exoplanet Mass (GOT ‘EM) Survey. I. Confirmation of an Eccentric, Cool Jupiter with an Interior Earth-sized Planet Orbiting Kepler-1514

Despite the severe bias of the transit method of exoplanet discovery toward short orbital periods, a modest sample of transiting exoplanets with orbital periods greater than 100 days is known. Long-term radial velocity (RV) surveys are pivotal to confirming these signals and generating a set of planetary masses and densities for planets receiving moderate to low irradiation from their host stars. Here we conduct RV observations of Kepler-1514 from the Keck I telescope using the High Resolution Echelle Spectrometer. From these data, we measure the mass of the statistically validated giant (1.108 ± 0.023 R {sub J}) exoplanet Kepler-1514 b with a 218-day orbital period as 5.28 ± 0.22 M {sub J}. The bulk density of this cool (∼390 K) giant planet is 4.82{sub −0.25}{sup +0.26}g cm{sup −3}, consistent with a core supported by electron degeneracy pressure. We also infer an orbital eccentricity of 0.401{sub −0.014}{sup +0.013} from the RV and transit observations, which is consistent with planet–planet scattering and disk cavity migration models. The Kepler-1514 system contains an Earth-size, Kepler Object of Interest on a 10.5-day orbit that we statistically validate against false-positive scenarios, including those involving a neighboring star. The combination of the brightness (V = 11.8) of the host star and the long period, low irradiation, and high density of Kepler-1514 b places this system among a rare group of known exoplanetary systems and as one that is amenable to continued study.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

PSF–NET: A Nonparametric Point-spread Function Model for Ground-based Optical Telescopes

Ground-based optical telescopes are seriously affected by atmospheric turbulence induced aberrations. Understanding properties of these aberrations is important both for instrument design and image restoration method development. Because the point-spread function can reflect performance of the whole optic system, it is appropriate to use the point-spread function to describe atmospheric turbulence induced aberrations. Assuming point-spread functions induced by the atmospheric turbulence with the same profile belong to the same manifold space, we propose a nonparametric point-spread function—PSF–NET. The PSF–NET has a cycle convolutional neural network structure and is a statistical representation of the manifold space of PSFs induced by the atmospheric turbulence with the same profile. Testing the PSF–NET with simulated and real observation data, we find that a well trained PSF–NET can restore any short exposure images blurred by atmospheric turbulence with the same profile. Besides, we further use the impulse response of the PSF–NET, which can be viewed as the statistical mean PSF, to analyze interpretation properties of the PSF–NET. We find that variations of statistical mean PSFs are caused by variations of the atmospheric turbulence profile: as the difference of the atmospheric turbulence profile increases, the difference between statistical mean PSFs also increases. The PSF–NET proposed in this paper provides a new way to analyze atmospheric turbulence induced aberrations, which would benefit the development of new observation methods for ground-based optical telescopes.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Data generated during the 2018 LAPSE-RATE campaign: an introduction and overview

Unmanned aircraft systems (UASs) offer innovative capabilities for providing new perspectives on the atmosphere, and therefore atmospheric scientists are rapidly expanding their use, particularly for studying the planetary boundary layer. In support of this expansion, from 14 to 20 July 2018 the International Society for Atmospheric Research using Remotely piloted Aircraft (ISARRA) hosted a community flight week, dubbed the Lower Atmospheric Profiling Studies at Elevation – a Remotely-piloted Aircraft Team Experiment (LAPSE-RATE; de Boer et al., 2020a). This field campaign spanned a 1-week deployment to Colorado's San Luis Valley, involving over 100 students, scientists, engineers, pilots, and outreach coordinators. These groups conducted intensive field operations using unmanned aircraft and ground-based assets to develop comprehensive datasets spanning a variety of scientific objectives, including a total of nearly 1300 research flights totaling over 250 flight hours. This article introduces this campaign and lays the groundwork for a special issue on the LAPSE-RATE project. The remainder of the special issue provides detailed overviews of the datasets collected and the platforms used to collect them. All of the datasets covered by this special issue have been uploaded to a LAPSE-RATE community set up at the Zenodo data archive (https://zenodo.org/communities/lapse-rate/, last access: 3 December 2020).

47 OTHER INSTRUMENTATION↗
DOE OSTI2020

The Hubble Space Telescope's Near-UV and Optical Transmission Spectrum of Earth as an Exoplanet

We observed the 2019 January total lunar eclipse with the Hubble Space Telescope’s STIS spectrograph to obtain the first near-UV (1700–3200 Å) observation of Earth as a transiting exoplanet. The observatories and instruments that will be able to perform transmission spectroscopy of exo-Earths are beginning to be planned, and characterizing the transmission spectrum of Earth is vital to ensuring that key spectral features (e.g., ozone, or O{sub 3}) are appropriately captured in mission concept studies. O{sub 3} is photochemically produced from O{sub 2}, a product of the dominant metabolism on Earth today, and it will be sought in future observations as critical evidence for life on exoplanets. Ground-based observations of lunar eclipses have provided the Earth’s transmission spectrum at optical and near-IR wavelengths, but the strongest O{sub 3} signatures are in the near-UV. We describe the observations and methods used to extract a transmission spectrum from Hubble lunar eclipse spectra, and identify spectral features of O{sub 3} and Rayleigh scattering in the 3000–5500 Å region in Earth’s transmission spectrum by comparing to Earth models that include refraction effects in the terrestrial atmosphere during a lunar eclipse. Our near-UV spectra are featureless, a consequence of missing the narrow time span during the eclipse when near-UV sunlight is not completely attenuated through Earth’s atmosphere due to extremely strong O{sub 3} absorption and when sunlight is transmitted to the lunar surface at altitudes where it passes through the O{sub 3} layer rather than above it.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Ultraviolet Photooxidation of Smectite-Bound Fe(II) and Implications for the Origin of Martian Nontronites

Clay minerals detected with orbital and in situ instruments in ancient Martian terrains constrain Mars' climate and aqueous alteration history. Early in its history, Mars experienced an atmospheric redox change and iron-bearing clay minerals may preserve the effects of that transition. Ferrous smectites, the thermodynamically predicted product of chemical weathering of basalts under anoxic conditions, may have undergone oxidation by exposure to chemical oxidants in the atmosphere or regolith, or by direct photooxidation at the surface. To assess these potential oxidation pathways, ferrous trioctahedral smectites of varying initial iron content were synthesized and subjected to oxidation by ultraviolet (UV) irradiation. Experimental UV irradiation under an anoxic atmosphere equivalent to approximately 7 years of flux on the Martian surface caused partial oxidation of smectite-bound Fe (Fe 3+ /ΣFe = 16–18%) and octahedral sheet contraction. Metal-OH vibrational bands in visible/near infrared (VNIR) reflectance spectra of oxidized smectites changed in band depth and asymmetry with higher iron content. X-ray diffraction patterns of UV irradiated samples indicate the formation of a mixed di- and trioctahedral smectite or a secondary nontronite phase, possibly on the surfaces of higher iron content smectites. Furthermore, these experiments suggest that UV irradiation is able to oxidize structurally bound iron in smectites without the presence of other chemical oxidants. Photooxidation may have influenced the mineralogy, both syndepositionally and postdepositionally, of Martian alteration assemblages formed near the surface and this process needs not be limited to one part of their formation history.

58 GEOSCIENCES↗