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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Pulse compressor architecture to enable next-generation high-energy petawatt-class lasers

The maximum energy obtainable within a single aperture of a high-energy petawatt-class (HEPW) laser is typically limited by the pulse compressor. This work evaluates the potential impact of two new pulse compression grating technologies (HELD gratings and TM polarization) on HEPW laser systems. A compressor architecture is proposed that implements these grating advancements in order to support ∼6× higher pulse energies than currently demonstrated. This increase in energy and intensity could have substantial benefits to high-flux secondary sources and enable new applications.

47 OTHER INSTRUMENTATION↗
NASA NTRSDate not supplied

An Interim Set of TNT Curves for LOX/LNG Explosions

Space launch companies are actively developing, or in some cases have already developed, new vehicles that use large quantities of liquid oxygen (LOX) and liquid natural gas (LNG) propellants. This propellant mixture currently lacks sound/verified explosive safety standards for use in explosive siting and flight safety analysis. In the U.S., multiple government and commercial organizations have conducted limited testing, or are preparing to conduct tests, intended to provide a sound technical basis for LOX/LNG explosive standards applicable to space launch vehicle ground and flight operations. The limited testing and analysis conducted so far indicates the potential to produce extremely energetic explosions due to the miscibility of LOX/LNG (methane), a unique feature relative to previously used propellant mixtures such as hydrogen/oxygen or kerosene/oxygen. MOX is a homogenous mixture of methane and oxygen that is possible because of methane’s 100% miscibility in LOX. Preliminary testing by N2L, Inc. described in this paper shows that it is possible to form MOX with a variety of mixing methods, and that MOX is a sensitive high explosive capable of producing overpressures greater than comparable masses of C-4. The limited amount and quality of large-scale LOX/LNG explosive test data, and the potential formation of high-explosive MOX, create significant unknowns in the determination of hazard areas (cleared of the public) for ground operations (such as a static fire test) and flights of launch vehicles with LOX/LNG propellant. This paper will review the methods used by NASA to develop and validate the LOX/LH2 blast model using large-scale explosive test programs such as Project PYRO, the Hydrogen-Oxygen Vertical Impact (HOVI), and the Large-Scale Hydrogen-Oxygen Explosion (LSHOE) tests. This paper will describe how the same process was used to prepare an interim LOX/LNG blast model that applies to various LV failure scenarios and conservatively accounts for potential MOX formation. This paper also summarizes past and future testing and modeling efforts funded by a consortium of NASA, the US Federal Aviation Administration (FAA), and the US Space Force (USSF). These test programs should be concluded within the next 3 years and are intended to provide empirical data for model verification and validation.

Liquid Oxygen↗
NASA NTRSDate not supplied

An Interim Set of TNT Curves for LOX/LNG Explosions

Space launch companies are actively developing, or in some cases have already developed, new vehicles that use large quantities of liquid oxygen (LOX) and liquid natural gas (LNG) propellants. This propellant mixture currently lacks sound/verified LOX/LNG explosive safety standards for use in explosive siting and flight safety analysis. In the U.S., multiple government and commercial organizations have conducted limited testing, or are preparing to conduct tests, intended to provide a sound technical basis for explosive standards applicable to space launch vehicle ground and flight operations. The limited testing and analysis conducted so far indicates the potential to produce extremely energetic explosions due to the miscibility of LOX/LNG (methane), a unique feature relative to previously used propellant mixtures such as hydrogen/oxygen or kerosene/oxygen. MOX is a homogenous mixture of methane and oxygen that is possible because of methane’s 100% miscibility in LOX. Preliminary testing by N2L, Inc. described in this paper shows that it is possible to form MOX with a variety of mixing methods, and that MOX is a sensitive high explosive capable of producing overpressures greater than comparable masses of C-4. The limited amount and quality of large-scale LOX/LNG explosive test data, and the potential formation of high-explosive MOX, create significant unknowns in the determination of hazard areas (cleared of the public) for ground operations (such as a static fire test) and flights of launch vehicles with LOX/LNG propellant. This paper will review the methods used by NASA to develop and validate the LOX/LH2 blast model using large-scale explosive test programs such as Project PYRO, the Hydrogen-Oxygen Vertical Impact (HOVI), and the Large-Scale Hydrogen-Oxygen Explosion (LSHOE) tests. This paper will describe how the same process was used to prepare an interim LOX/LNG blast model that applies to various LV failure scenarios and conservatively accounts for potential MOX formation. This paper also summarizes past and future testing and modeling efforts funded by a consortium of NASA, the US Federal Aviation Administration (FAA), and the US Space Force (USSF). These test programs should be concluded within the next 3 years and are intended to provide empirical data for model verification and validation.

Liquid Oxygen↗
NASA NTRS1978

Power management and control for space systems

Power management and control technology for the large, high-power spacecraft of the 1980's is discussed. Systems weight optimization that indicate a need for higher bus voltages are shown. Environmental interactions that are practical limits for the maximum potential on exposed surfaces are shown. A dual-voltage system is proposed that would provide the weight savings of a high-voltage distribution system and take into account the potential environmental interactions. The technology development of new components and circuits is also discussed.

Finke, R. C.↗
DOE OSTI2025

In Situ MOVPE Smoothing of Acoustically Spalled GaAs for Substrate Reuse

High material costs, especially for substrates, have limited the widespread adoption of III-V photovoltaics. A potential to reduce this cost is to reuse the III-V substrate via acoustic spalling, however this technique can leave a rough surface, hindering subsequent device performance. This research investigates the potential of using metalorganic vapor-phase epitaxy growth as a buffer layer to smooth the surface of acoustically spalled germanium and gallium arsenide (GaAs) substrates for improved III-V photovoltaic cell yield and performance, while retaining the maximum number of reuses of a substrate. Three potential smoothing layers were explored: lightly doped C:GaAs, highly doped Se:GaInP, and lightly doped Se:GaInP. C:GaAs showed the most promise as a smoothing layer, while Se:GaInP tended to conform to the underlying morphology, potentially increasing roughness in some areas. Utilizing 5 ..mu..m of C:GaAs as a planarizing buffer increased the average efficiency (without an antireflection coating) from an as-spalled baseline from 2.1% to 4.9% and performing a 5-min 30 degrees C 8:1:1 H2SO4:H2O2:H2O etch prior to a 5 ..mu..m of C:GaAs as a planarizing buffer further increased efficiency to 11.1%.

14 SOLAR ENERGY↗
DOE OSTI2025

Signal amplification in a solid-state sensor through asymmetric many-body echo

Electronic spins of nitrogen–vacancy centres in diamond constitute a promising system for micro- and nanoscale magnetic sensing, because of their operation under ambient conditions, ease of placement in close proximity to sensing targets and biological compatibility. At high densities, the electronic spins interact through dipolar coupling, which typically limits but can also potentially enhance sensing performance. Here we report the experimental demonstration of many-body signal amplification in a solid-state, room-temperature quantum sensor. Our approach uses time-reversed two-axis-twisting interactions, engineered through dynamical control of the quantization axis and Floquet engineering in a two-dimensional ensemble of nitrogen–vacancy centres. We observe that optimal amplification occurs when the backward evolution time equals twice the forward evolution time, in sharp contrast to the conventional Loschmidt echo. These observations can be understood as resulting from an underlying time-reversed mirror symmetry of the microscopic dynamics, providing key insights into signal amplification and opportunities for practical entanglement-enhanced quantum sensing.

quantum information↗
DOE OSTI2026

Back to Basics: Lanthanide and Heavy Actinide Chelation at High pH by Niobium Polyoxometalates

Niobium polyoxometalates (Nb-POMs) form in alkaline media, which limits their use as ligands for acidic cations, particularly lanthanides and actinides. Metal-Nb-POM moieties have the potential for emergent and enhanced properties, based on strong complexation behavior and high stability of the resultant materials. Here, in this study, we probe interactions of lanthanides (Pr 3+ , Nd 3+ , Sm 3+ , Eu 3+ , Tb 3+ , Dy 3+ ) and actinides (Am 3+ , Cm 3+ ) with a Nb-POM [Nb 6 O 19 ] 8– (Nb 6 ) in alkaline media. Nb 6 , the most charge-dense Nb-POM, enhances f-element luminescence emission by up to × 10 6 , via Nb-POM-mediated sensitization. Lengthened emission lifetimes correlate with the release of the metal-cation hydration sphere, replaced by multidentate Nb-POMs. The Nb 6 –Ln(An) complexes resist carbonate and phosphate displacement, and Nb 6 –Ln(An) complexation is retained upon isolation of the solids from solution. Electrospray ionization mass spectrometry (ESI-MS) and Raman spectroscopy both indicate the formation of the unprecedented Peacock–Weakley Nb-POM ([LnIII(Nb 5 O 18 ) 2 ] 19- ) in addition to simple Nb 6 –Ln coordination complexes. Luminescence emission spectra support the presence of simple Nb 6 –Ln coordination complexes. Small-angle X-ray scattering (SAXS) evidence the formation of Ln-Nb-POM aggregates. This foundational investigation highlights the potential of Nb-POMs as metal–ligands at basic pH, with value-added properties including scaffolding extended materials and controlling light absorption and emission.

organic↗
DOE OSTI2026

Alpha-Imaging Detector System Development for Large Area Monitoring

Effective management and disposal of legacy nuclear waste are essential for ensuring safe work environments and minimizing environmental impacts. Monitoring airborne actinide contamination is particularly critical due to the high internal dose potential of alpha-emitting radionuclides. Traditional continuous air monitoring systems (CAMs) used in the industry are limited in the volume of air they can sample, potentially leading to inaccurate radiation detection over large areas. For example, in 2018, elevated levels of airborne Plutonium-239 were detected beyond the controlled areas of the Hanford Plutonium Finishing Plant, highlighting the potential risks to both plant workers and nearby residents. To address these challenges, high-efficiency particulate absorbing (HEPA) air purifiers can enhance air flow by up to 1.5 orders of magnitude, thereby increasing monitoring efficiency and providing a cost-effective solution for large-area surveillance. To quantify the activities of alpha-emitting radionuclides on HEPA filters, the Savannah River National Laboratory is developing an advanced alpha-imaging detection system. This system includes scintillating materials combined with a digital scientific camera. A significant concern in operating such a large-area airborne monitoring system is the handling of HEPA filters, which may be contaminated with radioactive particles. To mitigate these hazards, it is crucial to ensure that any contamination is securely fixed onto the filters. Efforts have been made to optimize the sensitivity of scintillator-epoxy composites and apply them to HEPA filters. These materials were characterized using fluoroscence spectroscopy. These techniques confirmed the purity of the raw materials, the dispersion of scintillators in the epoxy matrix, and the stability of their optical and structural properties post-modification. The optimal scintillator-epoxy composite was selected for use on alpha-spiked HEPA filters to evaluate the efficiency of the sprayer. HEPA filters, embedded with alpha particles collected by an air purifier deployed in an airborne radiation area, have been tested to assess detection efficiency. Future work will focus on employing multiple imaging sensors simultaneously to enhance sensitivity across different regions of the HEPA filter.

Pham, Phuong [Savannah River National Laboratory (↗
NASA NTRS2000

Diagnostic Techniques Used to Study Chemical-Vapor-Deposited Diamond Films

The advantages and utility of chemical-vapor-deposited (CVD) diamond as an industrial ceramic can only be realized if the price and quality are right. Until recently, this technology was of interest only to the academic and basic research community. However, interest has grown because of advances made by leading CVD diamond suppliers: 1) Reduction of the cost of CVD polycrystalline diamond deposition below $5/carat ($8/sq cm); 2) Installation of production capacity; 3) Epitaxial growth of CVD single-crystal diamond. Thus, CVD diamond applications and business are an industrial reality. At present, CVD diamond is produced in the form of coatings or wafers. CVD diamond film technology offers a broader technological potential than do natural and high-pressure synthetic diamonds because size, geometry, and eventually cost will not be as limiting. Now that they are cost effective, diamond coatings - with their extreme properties - can be used in a variety of applications. Diamond coatings can improve many of the surface properties of engineering substrate materials, including erosion, corrosion, and wear resistance. Examples of actual and potential applications, from microelectromechanical systems to the wear parts of diamond coatings and related superhard coatings are described. For example, diamond coatings can be used as a chemical and mechanical barrier for the space shuttles check valves, particularly on the guide pins and seat assemblies.

Miyoshi, Kazuhisa↗
NASA NTRS2022

SMAP Soil Moisture Assimilation To Enhance Streamflow Estimates Across South Asia

Streamflow estimation across areas facing water scarcity is important considering the evolving climatic conditions. In this study, the impact of assimilating Soil Moisture Active Passive (SMAP) soil moisture retrievals on the modeled streamflow across three main river basins in South Asia is explored. Model estimated runoff was hydraulically routed using the HYMAP routing model within the NASA Land Information System (LIS) framework. Streamflow estimates via soil moisture assimilation highlighted the potential improvements in streamflow across low-flow river tributaries in irrigated regions. Limited relative change was noted along high-flow river tributaries. Modeled streamflow tended to underestimate the flow magnitude at upstream stations and overestimated the streamflow at downstream stations within the Indus basin due to missing physics related to reservoir operation. Improvement of the modeling systems representativeness of the ground conditions by the inclusion of water management information would potentially improve the current streamflow modeling capability across South Asia.

Jawairia Ahmad↗
NASA NTRS2021

Resilience Engineering's Potential for Advanced Air Mobility (AAM)

The national airspace (NAS) will rapidly evolve in the next ten to twenty years. Plans for Advanced Air Mobility (AAM) during that period envision highly automated airspace management systems and electrically powered vehicles. AAM concepts also anticipate limited human roles. The goal of limiting the human role is to minimize the potential for misadventures, yet how the human role is limited needs to be carefully considered in order to also preserve the potential for human successes. The field of resilience engineering (RE) focuses on how systems can change in order to seize an opportunity or withstand an unforeseen challenge. RE methods rely on the use of empirical data to optimize the ability of any system to adapt. RE studies have shown how individual and team initiatives ensure resilient system performance by creating safety through flexibility. Benefits of the RE approach include improved awareness of operational circumstances and how system elements depend on each other, and the ability to allocate limited resources and prepare for surprise. RE offers the ability to account for and incorporate the human role as an essential element in order to ensure NAS systems’ resilient performance. Data on the human contribution to safe and resilient system performance, which is termed “work as done,” are available but are not being considered as the NAS evolves. We present an approach that describes how use of RE can enable the evolving NAS to adapt, and perform, in a resilient manner.

Aviation Safety↗
NASA NTRS1982

Subsonic balance and pressure investigation of a 60 deg delta wing with leading edge devices

Low supersonic wave drag makes the thin highly swept delta wing the logical choice for use on aircraft designed for supersonic cruise. However, the high-lift maneuver capability of the aircraft is limited by severe induced-drag penalties attributed to loss of potential flow leading-edge suction. This drag increase may be alleviated through leading-edge flow control to recover lost aerodynamic thrust through either retention of attached leading-edge flow to higher angles of attack or exploitation of the increased suction potential of separation-induced vortex flow. A low-speed wind-tunnel investigation was undertaken to examine the high-lift devices such as fences, chordwise slots, pylon vortex generators, leading-edge vortex flaps, and sharp leading-edge extensions. The devices were tested individually and in combinations in an attempt to improve high-alpha drag performance with a minimum of low-alpha drag penalty. This report presents an analysis of the force, moment, and static pressure data obtained in angles of attack up to 23 deg, at Mach and Reynolds numbers of 0.16 and 3.85 x 10 to the 6th power per meter, respectively. The results indicate that all the devices produced drag and longitudinal/lateral stability improvements at high lift with, in most cases, minor drag penalties at low angles of attack.

Tingas, S. A.↗
DOE OSTI2024

Vacuum deposition of χ(2) nonlinear organic single crystal films on silicon

Integrating second order nonlinear (χ(2)) optical materials on chip is an ongoing challenge for Si photonics. Noncentrosymmetric molecular crystals have the potential to deliver high χ(2) nonlinearity with good thermal stability, but so far have been limited to growth from solution or the melt, which are both difficult to control and scale up in manufacturing. Here, we show that large (>100 μm) single crystal domains of the nonlinear molecule 2-[3-(4-hydroxystyryl)-5,5-dimethylcyclohex-2-enylidene] malononitrile (OH1) can be grown monolithically on either glass or Si via vacuum evaporation, followed by a short thermal annealing step. The crystallites are tens of nanometer thick and exhibit strong second harmonic generation with their primary χ(2) tensor component lying predominantly in plane. Remarkably, we find that a single domain can grow uninterrupted through nearby channels etched on a Si wafer, which may provide a path to integrate OH1 on Si or Si3N4 waveguides for a broad range of χ(2)-based photonic integrated circuit functionality.

Physics↗
DOE OSTI2026

The Use of Machine Learning Models for Predicting the Dielectric Strength of Gases

Technological advancements in high voltage systems have pushed sulfur hexafluoride (SF6) to its operational limits. Furthermore, this gas has other drawbacks including a high liquefaction temperature and a high global warming potential. Therefore, there has been an urgent need to find alternative gases with high dielectric strength (DS). In this work, density functional theory (DFT) is used to calculate molecular descriptors that are fed into an artificial neural network (ANN) and a random forest (RF). These machine learning (ML) models are then used to predict the DS for hundreds of molecules. A finite element model (FEM) is also used to calculate the electric field profile of multiple simple electrode geometries as the applied voltage to the system is increased. Results indicate that the random forest model has better generalization to unseen data than the neural network. The highest DS value predicted by the RF was 2.16 relative to the experimental DS of SF6. The results also demonstrate how choosing a gas with a higher DS and a geometry with minimal edges and corners can significantly increase the operating voltage of an electrical system. Due to its superior generalization, the RF represents the most promising path toward an accurate DS predictor once sufficient experimental data are available.

Mileski, Matthew [AFIT]↗
NASA NTRS1983

Constitutive Equations for Use in Design Analyses of Long-life Elevated Temperature Components

Design analysis needs and procedures relative to elevated temperature components in liquid metal fast breeder reactor (LMFBR) system were examined. The effects of the thermal transients on the pressure boundary components are enhanced by the excellent heat transfer properties of the liquid sodium coolant. Design criteria for high temperature nuclear reactor components recognize the potential occurrence of inelastic structural response. Specifically, criteria and limits were developed which reflect a recognition of this potential and employ design by analysis concepts that requires that inelastic (elastic-plastic and creep) analyses be performed. Constitutive equations to represent multiaxial time-dependent responses of LMFBR alloys are established. The development of equations applicable under cyclic loading conditions are outlined.

Pugh, C. E.↗
NASA NTRS1985

Effect of bond coat creep and oxidation on TBC integrity

The potential of thermal barrier coatings (TBCs) on high-pressure turbine (HPT) nozzles and blades is limited at present by the inability to quantitatively predict TBC life for these components. The goal is to isolate the major TBC failure mechanisms, which is part of the larger program aimed at developing TBC life prediction models. Based on the results of experiments to isolate TBC failure mechanisms, the effects of bond coat oxidation and bond coat creep on TBC integrity is discussed. In bond coat oxidation experiments, Rene prime 80 specimens coated with a NiCrAlY/ZrO2-8 percent Y2O3 TBC received isothermal pre-exposures at 2000 F in static argon, static air, or received no pre-exposure. The effects of oxidation due to the pre-exposures were determined by thermal cycle tests in both static air and static argon at 2000 F. To study the effect of bond coat creep on TBS behavior, four bond coats with different creep properties were evaluated by thermal cycle tests in air at 2000 F. The test results, the relative importance of these two failure mechanisms, and how their effects may be quantified will also be discussed.

Duderstadt, E. C.↗
NASA NTRS1995

Chemical Stability of the Fiber Coating/Matrix Interface in Silicon-Based Ceramic Matrix Composites

Carbon and boron nitride are used as fiber coatings in silicon-based composites. In order to assess the long-term stability of these materials, reactions of carbon/Si3N4 and BN/SiC were studied at high temperatures with Knudsen effusion, coupon tests, and microstructural examination. In the carbon/Si3N4 system, carbon reacted with Si3N4 to form gaseous N2 and SiC. The formation of SiC limited further reaction by physically separating the carbon and Si3N4. Consequently, the development of high p(N2) at the interface, predicted from thermochemical calculations, did not occur, thus limiting the potential deleterious effects of the reaction on the composite. Strong indications of a reaction between BN and SiC were shown by TEM and SIMS analysis of the BN/SiC interface. In long-term exposures, this reaction can lead to a depletion of a BN coating and/or an unfavorable change of the interfacial properties, limiting the beneficial effects of the coating.

Lee, Kang N.↗
NASA NTRS1996

Design of intelligent mesoscale periodic array structures utilizing smart hydrogel

Mesoscale Periodic Array Structures (MPAS, also known as crystalline colloidal arrays), composed of aqueous or nonaqueous dispersions of self-assembled submicron colloidal spheres are emerging toward the development of advanced optical devices for technological applications. This is because of their unique optical diffraction properties and the ease with which these intriguing properties can be modulated experimentally. Moreover our recent advancements in this area which include 'locking' the liquid MPAS into solid or semisolid polymer matrices for greater stability with longer life span, and incorporation of CdS quantum dots and laser dyes into colloidal spheres to obtain nonlinear optical (NLO) responses further corroborate the use of MPAS in optical technology. Our long term goal is fabrication of all-optical and electro-optical devices such as spatial light modulators for optical signal processing and flat panel display devices by utilizing intelligent nonlinear periodic array structural materials. Here we show further progress in the design of novel linear MPAS which have the ability to sense and respond to an external source such as temperature. This is achieved by combining the self-assembly properties of polymer colloidal spheres and thermoshrinking properties of smart polymer gels. At selected temperatures the periodic array efficiently Bragg diffracts light and transmits most of the light at other temperatures. Hence these intelligent systems are of potential use as fixed notch filters optical switches or limiters to protect delicate optical sensors from high intensity laser radiation.

Sunkara, H. B.↗