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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

The oxygen and carbon dioxide balance in the earth's atmosphere

The oxygen-carbon dioxide cycle is described in detail, and steps which are sensitive to perturbation or instability are identified. About half of the carbon dioxide consumption each year in photosynthesis occurs in the oceans. Phytoplankton, which are the primary producers, have been shown to assimilate insecticides and herbicides. The impact of such materials on phytoplankton photosynthesis, both direct and as the indirect result of detrimental effects higher up in the food chain, cannot be assessed. Net oxygen production is very small in comparison with the total production and occurs almost exclusively in a few ocean areas with anoxic bottom conditions and in peat-forming marshes which are sensitive to anthropogenic disturbances. The carbon dioxide content of the atmosphere is increasing at a relatively rapid rate as the result of fossil fuel combustion. Increases in photosynthesis as the result of the hothouse effect may in turn reduce the carbon dioxide content of the atmosphere, leading to global cooling.

Johnson, F. S.↗

Southern Hemisphere Additional Ozonesondes (SHADOZ) Ozone Climatology (2005-2009): Tropospheric and Tropical Tropopause Layer (TTL) Profiles with Comparisons to Omi-based Ozone Products

We present a regional and seasonal climatology of SHADOZ ozone profiles in the troposphere and tropical tropopause layer (TTL) based on measurements taken during the first five years of Aura, 2005-2009, when new stations joined the network at Hanoi, Vietnam; Hilo, Hawaii; Alajuela Heredia, Costa Rica; Cotonou, Benin. In all, 15 stations operated during that period. A west-to-east progression of decreasing convective influence and increasing pollution leads to distinct tropospheric ozone profiles in three regions: (1) western Pacific eastern Indian Ocean; (2) equatorial Americas (San Cristobal, Alajuela, Paramaribo); (3) Atlantic and Africa. Comparisons in total ozone column from soundings, the Ozone Monitoring Instrument (OMI, on Aura, 2004-) satellite and ground-based instrumentation are presented. Most stations show better agreement with OMI than they did for EPTOMS comparisons (1998-2004; Earth-ProbeTotal Ozone Mapping Spectrometer), partly due to a revised above-burst ozone climatology. Possible station biases in the stratospheric segment of the ozone measurement noted in the first 7 years of SHADOZ ozone profiles are re-examined. High stratospheric bias observed during the TOMS period appears to persist at one station. Comparisons of SHADOZ tropospheric ozone and the daily Trajectory-enhanced Tropospheric Ozone Residual (TTOR) product (based on OMIMLS) show that the satellite-derived column amount averages 25 low. Correlations between TTOR and the SHADOZ sondes are quite good (typical r2 0.5-0.8), however, which may account for why some published residual-based OMI products capture tropospheric interannual variability fairly realistically. On the other hand, no clear explanations emerge for why TTOR-sonde discrepancies vary over a wide range at most SHADOZ sites.

gravity waves↗

Production of organic compounds in plasmas: A comparison among electric sparks, laser-induced plasmas and UV light

In order to study the production of organic compounds in plasmas (and shocks), various mixtures of N2, CH4, and H2, modeling the atmosphere of Titan, were exposed to discrete sparks, laser-induced plasmas (LIP) and ultraviolet light. The yields of HCN and simple hydrocarbons were measured and compared to those calculated from a simple quenched thermodynamic equilibrium model. The agreement between experiment and theory was fair for HCN and C2H2. However, the yields of C2H6 and other hydrocarbons were much higher than those predicted by the model. Our experiments suggest that photolysis by ultraviolet light from the plasma is an important process in the synthesis. This was confirmed by the photolysis of gas samples exposed to the light, but not to the plasma or shock waves. The results of these experiments demonstrate that, in addition to the well-known efficient synthesis of organic compounds in plasmas, the yields of saturated species, e.g., ethane, may be higher than predicted by theory and that LIP provide a convenient and clean way of simulating planetary lightning and impact plasmas in the laboratory.

Scattergood, T. W.↗

Battery‐Grade Lithium Materials: Virgin Production and Recycling, a Techno‐Economic Comparison

Lithium has been identified as an essential mineral to the economic and national security of the United States. It is vital for rechargeable batteries that surround us daily from the personal electronics to large-scale energy storage. With a comprehensive techno-economic analysis, the cost of battery-grade lithium compounds production, i.e., lithium carbonate (LC) is evaluated and lithium hydroxide monohydrate (LHM), from both virgin (spodumene ore and brine) and recycled feedstocks (spent lithium-ion batteries). The goal of this study is to inform about the economics of lithium compounds production with comprehensive insights into differences in manufacturing routes and pave a pathway to explore more innovative, domestic manufacturing processes in future for their cost competitiveness and environmental impact. The study includes details on mining and extraction operations as well as unit level operation in the refining process. Moreover, process level information has been collected for pyrometallurgical and hydrometallurgical battery recycling routes. This analysis shows that brine and direct lithium extraction are the cheapest pathways to produce LC or LHM (between $\$3.39$ and 6.20 kg −1 ). The cost of production in the ore and recycling routes can range between $\$4.17$ and $\$53.41$ kg −1 and is highly depending on capital equipment investment, plant location, and the price of spodumene concentrate SC6.0.

battery recycling↗

Comparisons of Temporal and Spatial Trends in the Spatially Complete Global Spectral Surface Albedos Products

Five years of spatially complete snow-free land surface albedo data have been prepared using high quality white-sky and black-sky land surface albedo observations (MOD43B3) from the MODIS instrument aboard NASA's Terra satellite platform. The data were generated using an updated ecosystem-dependent temporal interpolation technique. In this paper, we describe the refinements in the technique and the creation of a spatially complete snow-free five-year aggregate climatology product. This paper also describes an error analysis of the interpolation technique. The filled albedo products are examined through comparisons of temporal and spatial trends for pixels that have been filled versus pixels that have been retained in the original MOD43B3 values. The variability in the trends showcase how the filling technique maintains the pixel-level spatial, spectral, and temporal integrity of the MOD43B3 data. These comparisons are made for both a single-year of filled data, year 2002, and for the five-year aggregate climatology product.

Moody, Eric G.↗

Study of the impact of cruise speed on scheduling and productivity of commercial transport aircraft

A comparison is made between airplane productivity and utilization levels derived from commercial airline type schedules which were developed for two subsonic and four supersonic cruise speed aircraft. The cruise speed component is the only difference between the schedules which are based on 1995 passenger demand forecasts. Productivity-to-speed relationships were determined for the three discrete route systems: North Atlantic, Trans-Pacific, and North-South America. Selected combinations of these route systems were also studied. Other areas affecting the productivity-to-speed relationship such as aircraft design range and scheduled turn time were examined.

Bond, E. Q.↗

Production of organic compounds in plasmas - A comparison among electric sparks, laser-induced plasmas, and UV light

In order to ascertain the features of organic compound-production in planetary atmospheres under the effects of plasmas and shocks, various mixtures of N2, CH4, and H2 modeling the atmosphere of Titan were subjected to discrete sparks, laser-induced plasmas, and UV radiation. The experimental results obtained suggest that UV photolysis from the plasma is an important organic compound synthesis process, as confirmed by the photolysis of gas samples that were exposed to the light but not to the shock waves emitted by the sparks. The thermodynamic equilibrium theory is therefore incomplete in the absence of photolysis.

Scattergood, Thomas W.↗

An independent analysis of bias sources and variability in wind plant pre-construction energy yield estimation methods

The wind resource assessment community has long had the goal of reducing the bias between wind plant pre-construction energy yield assessment (EYA) and the observed annual energy production (AEP). This comparison is typically made between the 50% probability of exceedance (P50) value of the EYA and the long-term corrected operational AEP (hereafter OA P50), and is known as the P50 bias. The industry has critically lacked an independent analysis of bias reduction investigated across multiple consultants to identify the greatest sources of uncertainty and variance in the EYA process and the best opportunities for uncertainty reduction. The present study addresses this gap by benchmarking consultant methodologies against each other and against operational data at a scale not seen before in industry collaborations. We consider data from 10 wind plants and evaluate discrepancies between eight consultancies in the steps taken from estimates of gross to net energy. Consultants tend to overestimate the gross energy produced at the turbines and then compensate by further overestimating downstream losses, leading to a mean P50 bias near zero, still with significant variability among the individual wind plants. Within our data sample, we find that consultant estimates of all loss categories, except environmental losses, tend to reduce the project-to-project variability of the P50 bias. The disagreement between consultants, however, remains flat throughout the addition of losses. Finally, we find that differences in consultants’ estimates of project performance can lead to differences up to $10/MWh in the levelized cost of energy for a wind plant.

Todd, Austin C.↗

Comparisons of the MG II index products from the NOAA-9 and NOAA-11 SBUV/2 instruments

The Mg II index is a proxy indicator of solar UV activity which is produced from measurements of the chromospheric Mg II absortion line at 280 nm. Mg II index data sets have been derived from the NOAA-9 and NOAA-11 SBUV/2 irradiance data sets using both discrete scan measurements about the Mg II line and continuous scan (sweep) measurements over the UV spectrum from 160 - 400 nm. This paper will discuss the rationale behind the creation of the different Mg II index products, and make a quantitative assessment of the differences between these products. Recommendations for future use of the Mg II index will also be presented.

Deland, M. T.↗

Adapting CALIPSO Climate Measurements for Near Real Time Analyses and Forecasting

The Cloud-Aerosol Lidar and Infrared Pathfinder satellite Observations (CALIPSO) mission was originally conceived and designed as a climate measurements mission, with considerable latency between data acquisition and the release of the level 1 and level 2 data products. However, the unique nature of the CALIPSO lidar backscatter profiles quickly led to the qualitative use of CALIPSO?s near real time (i.e., ? expedited?) lidar data imagery in several different forecasting applications. To enable quantitative use of their near real time analyses, the CALIPSO project recently expanded their expedited data catalog to include all of the standard level 1 and level 2 lidar data products. Also included is a new cloud cleared level 1.5 profile product developed for use by operational forecast centers for verification of aerosol predictions. This paper describes the architecture and content of the CALIPSO expedited data products. The fidelity and accuracy of the expedited products are assessed via comparisons to the standard CALIPSO data products.

Vaughan, Mark A.↗

Saildrone Baja Field Campaign: A Comparison of Surface Meteorology with GEOS Products

The Saildrone Baja field campaign was an international effort to collect measurements across the air-sea interface for a 62-day period between April 11-June 11, 2018. The field campaign was executed using a saildrone, an unmanned surface vehicle (USV) carrying a comprehensive suite of instruments to measure meteorological, ocean surface, and subsurface data. We use these data to validate near-surface meteorology and ocean surface temperature fields in theGlobal Earth Observing System (GEOS). This is the first study using Saildrone data to validate GEOS products. As these USV platforms become more prevalent, they could be used to improve model representation of the air-sea interface variables.

Akella, Santha↗

Bionutrients-1: Utilizing Genomics and Transcriptomics to Assess the Reliability of Microorganisms for In Situ Nutrient Production on Long Duration Missions

The resupply of current long-duration crewed missions to the ISS relies on ground-launched supplies. As NASA looks toward Mars, ground-based resupply will no longer be an option. Critical nutrients, including vitamin C, vitamin K, folate, and thiamin, degrade during long-term storage, and regular consumption of these nutrients is essential for astronaut health. Another challenge of current food systems is the difficulty of consuming sufficient calories when subsisting on the limited flavors of freeze-dried food, which can lead to weight loss. The inclusion of microorganism-based food systems could alleviate both concerns. For example, the fermentation of rehydrated milk into yogurt with microorganisms genetically incorporating genes to produce critical vitamins would allow for both in situ production of nutrients and a fresh food product with additional flavor profiles. In comparison to plant food production, microorganisms require less flight infrastructure. The BioNutrients-1 mission is demonstrating viability of microbial fermentation food production in microgravity and testing the reliability of this approach for long-duration missions lacking resupply. While the BioNutrients-1 mission includes the collection of multiple phenotypic measurements, this status update will focus on the processing of samples for genomics and transcriptomics analyses as well as the planned analysis pipelines. First, the BioNutrients-1 mission seeks to identify microorganisms capable of surviving long-duration storage at ambient temperatures while maintaining genetic fidelity. To achieve this, nine commonly employed microbial species were stored at ambient temperatures in Stasis Packs on the ISS for five years. The viability and mutation rates will be measured at multiple time points for both flown and ground control samples. From an omics perspective, the changes in the bulk rates of point mutations and genetic rearrangements across the Stasis Pack species during the five years of storage will be determined, providing valuable insights into the potential of these microorganisms for long-duration space missions. Second, the BioNutrients-1 mission is characterizing the impact of microgravity on fermentation. Two strains of the yeast Saccharomyces cerevisiae, each encoding antioxidants (β-carotene or zeaxanthin) were flown to ISS for storage and fermentation within simplified bioreactors (Production Packs). The impact of microgravity on the expression of the antioxidant production genes and general metabolic genes will be determined using RNA sequencing. Ultimately, the transcriptome data will be compared to phenotypic measurements, such as the antioxidant yield, end-state biomass, and the production of EtOH, to determine the impacts of microgravity and long-term storage on microbial fermentation. The findings from this research will be instrumental in understanding the challenges and opportunities of microorganism-based food systems in space missions.

BioNutrients↗

Comparison of AGR-3/4 Fission Product Transport Model to Measurements and Extraction of Diffusivities via Analytical Fits

A one-dimensional finite-element model based on the MOOSE framework has been constructed, and overall transport estimates are predicted based on available diffusivities and sorption isotherms in the extant literature. The predicted transport profiles are compared to experimental results, where such results are available, including total inventory analysis of gamma emitters, liquid scintillation results for Sr-90 concentrations, radial deconsolidation leach-burn-leach within compacts, tomographic reconstructions based on detailed gamma scanning and destructive physical sampling of several rings. The magnitude of expected transport to the sink ring is generally predicted by the model for silver and cesium, however, modeled detailed concentration profiles are not consistent with experimental results. Strontium and europium transport is not well characterized by model results.

07 ISOTOPE AND RADIATION SOURCES↗

A Comparison of the GPROF Algorithm Results in the 2A-CLIM and 2A Data Products

The GPROF algorithm is used to retrieve precipitation values from all the GPM mission partner radiometers (i.e. GMI, MHS, ATMS, SSMIS, AMSR2). GPM produces two precipitation retrieval products (processing at level 2) using the GPROF algorithm. One has the type designation 2A and the other the designation 2A-CLIM. As a result understanding the difference between the two products is important for using and understanding them. Both of these GPROF products use exactly the same algorithm and a-priori databases. The only difference between the two types is the ancillary products used in the initial processing step. In the case of the 2A-CLIM products, ECMWF ERA-I is used as ancillary data. In the case of the 2A products, JMA's GANAL product is used as ancillary data. This presentation will provide a comparison between the two products using zonal mean comparisons. It will provide comparisons separately for land and ocean retrievals. It will compare the GMI differences over the entire current GPM mission life. As the only difference between the two products is the ancillary information used to create them, the comparison provides an elementary sensitivity study of the variables used from the reanalysis products and their impact on the GPROF retrieval. The purpose of the presentation is to provide users with an insight into the two GPROF products and provide them key information useful when using either of the products in scientific studies. Lastly, the presentation also discusses the reasons why only the 2A-CLIM product can be produced for the 17+ years of TRMM era data products.

GPM↗

Validation of TRMM Multi-Satellite Precipitation Analysis (TMPA) Products in the Peruvian Andes

The relevance of accurate and timely rainfall estimates cannot be overstated. The rainfall gauge network is still insufficient across significant areas worldwide. Rainfall estimates fromspaceborne sensors present an opportunity to supplement the existing network and enable the development of critical, near real time applications. However, the societal benefits of such systems can only be realized if the estimates are properly validated and the performance of existing products accurately described. In this study, two products generated by the Tropical Rainfall Measuring Mission (TRMM) Multisatellite Precipitation Analysis (TMPA) are validated for the Peruvian Andes. This is a region of complex topography that poses significant challenges to the retrieval of rainfall values fromspace. The TMPA products, both research grade (3B42V7) and near real time (3B42RT), are compared against in situ data. Different observation lengths are studied and the results are analyzed in light of geographic, topographic and climatic constraints. The Time Series of the science grade product were also studied under Dynamic TimeWarping and Hierarchical Clustering to streamline intertile comparisons. The TMPA products showa good agreementwith the gauge values, especially formore prolonged observation periods (over 8 days). The validation results display a strong regional dependence as a consequence of differences in the climate and topography. This region-specific performance calls for additional, detailed case studies and localized validation efforts. Overall the TMPAwas found to performadequately and provide quality information for a number of applications requiring timely estimates in convenient formats.

satellites↗

Potential of VIIRS Time Series Data for Aiding the USDA Forest Service Early Warning System for Forest Health Threats: A Gypsy Moth Defoliation Case Study

This report details one of three experiments performed during FY 2007 for the NASA RPC (Rapid Prototyping Capability) at Stennis Space Center. This RPC experiment assesses the potential of VIIRS (Visible/Infrared Imager/Radiometer Suite) and MODIS (Moderate Resolution Imaging Spectroradiometer) data for detecting and monitoring forest defoliation from the non-native Eurasian gypsy moth (Lymantria dispar). The intent of the RPC experiment was to assess the degree to which VIIRS data can provide forest disturbance monitoring information as an input to a forest threat EWS (Early Warning System) as compared to the level of information that can be obtained from MODIS data. The USDA Forest Service (USFS) plans to use MODIS products for generating broad-scaled, regional monitoring products as input to an EWS for forest health threat assessment. NASA SSC is helping the USFS to evaluate and integrate currently available satellite remote sensing technologies and data products for the EWS, including the use of MODIS products for regional monitoring of forest disturbance. Gypsy moth defoliation of the mid-Appalachian highland region was selected as a case study. Gypsy moth is one of eight major forest insect threats listed in the Healthy Forest Restoration Act (HFRA) of 2003; the gypsy moth threatens eastern U.S. hardwood forests, which are also a concern highlighted in the HFRA of 2003. This region was selected for the project because extensive gypsy moth defoliation occurred there over multiple years during the MODIS operational period. This RPC experiment is relevant to several nationally important mapping applications, including agricultural efficiency, coastal management, ecological forecasting, disaster management, and carbon management. In this experiment, MODIS data and VIIRS data simulated from MODIS were assessed for their ability to contribute broad, regional geospatial information on gypsy moth defoliation. Landsat and ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer) data were used to assess the quality of gypsy moth defoliation mapping products derived from MODIS data and from simulated VIIRS data. The project focused on use of data from MODIS Terra as opposed to MODIS Aqua mainly because only MODIS Terra data was collected during 2000 and 2001-years with comparatively high amounts of gypsy moth defoliation within the study area. The project assessed the quality of VIIRS data simulation products. Hyperion data was employed to assess the quality of MODIS-based VIIRS simulation datasets using image correlation analysis techniques. The ART (Application Research Toolbox) software was used for data simulation. Correlation analysis between MODIS-simulated VIIRS data and Hyperion-simulated VIIRS data for red, NIR (near-infrared), and NDVI (Normalized Difference Vegetation Index) image data products collectively indicate that useful, effective VIIRS simulations can be produced using Hyperion and MODIS data sources. The r(exp 2) for red, NIR, and NDVI products were 0.56, 0.63, and 0.62, respectively, indicating a moderately high correlation between the 2 data sources. Temporal decorrelation from different data acquisition times and image misregistration may have lowered correlation results. The RPC experiment also generated MODIS-based time series data products using the TSPT (Time Series Product Tool) software. Time series of simulated VIIRS NDVI products were produced at approximately 400-meter resolution GSD (Ground Sampling Distance) at nadir for comparison to MODIS NDVI products at either 250- or 500-meter GSD. The project also computed MODIS (MOD02) NDMI (Normalized Difference Moisture Index) products at 500-meter GSD for comparison to NDVI-based products. For each year during 2000-2006, MODIS and VIIRS (simulated from MOD02) time series were computed during the peak gypsy moth defoliation time frame in the study area (approximately June 10 through July 27). Gypsy moth defoliation mapping products from simated VIIRS and MOD02 time series were produced using multiple methods, including image classification and change detection via image differencing. The latter enabled an automated defoliation detection product computed using percent change in maximum NDVI for a peak defoliation period during 2001 compared to maximum NDVI across the entire 2000-2006 time frame. Final gypsy moth defoliation mapping products were assessed for accuracy using randomly sampled locations found on available geospatial reference data (Landsat and ASTER data in conjunction with defoliation map data from the USFS). Extensive gypsy moth defoliation patches were evident on screen displays of multitemporal color composites derived from MODIS data and from simulated VIIRS vegetation index data. Such defoliation was particularly evident for 2001, although widespread denuded forests were also seen for 2000 and 2003. These visualizations were validated using aforementioned reference data. Defoliation patches were visible on displays of MODIS-based NDVI and NDMI data. The viewing of apparent defoliation patches on all of these products necessitated adoption of a specialized temporal data processing method (e.g., maximum NDVI during the peak defoliation time frame). The frequency of cloud cover necessitated this approach. Multitemporal simulated VIIRS and MODIS Terra data both produced effective general classifications of defoliated forest versus other land cover. For 2001, the MOD02-simulated VIIRS 400-meter NDVI classification produced a similar yet slightly lower overall accuracy (87.28 percent with 0.72 Kappa) than the MOD02 250-meter NDVI classification (88.44 percent with 0.75 Kappa). The MOD13 250-meter NDVI classification had a lower overall accuracy (79.13 percent) and a much lower Kappa (0.46). The report discusses accuracy assessment results in much more detail, comparing overall classification and individual class accuracy statistics for simulated VIIRS 400-meter NDVI, MOD02 250-meter NDVI, MOD02-500 meter NDVI, MOD13 250-meter NDVI, and MOD02 500-meter NDMI classifications. Automated defoliation detection products from simulated VIIRS and MOD02 data for 2001 also yielded similar, relatively high overall classification accuracy (85.55 percent for the VIIRS 400-meter NDVI versus 87.28 percent for the MOD02 250-meter NDVI). In contrast, the USFS aerial sketch map of gypsy moth defoliation showed a lower overall classification accuracy at 73.64 percent. The overall classification Kappa values were also similar for the VIIRS (approximately 0.67 Kappa) versus the MOD02 (approximately 0.72 Kappa) automated defoliation detection product, which were much higher than the values exhibited by the USFS sketch map product (overall Kappa of approximately 0.47). The report provides additional details on the accuracy of automated gypsy moth defoliation detection products compared with USFS sketch maps. The results suggest that VIIRS data can be effectively simulated from MODIS data and that VIIRS data will produce gypsy moth defoliation mapping products that are similar to MODIS-based products. The results of the RPC experiment indicate that VIIRS and MODIS data products have good potential for integration into the forest threat EWS. The accuracy assessment was performed only for 2001 because of time constraints and a relative scarcity of cloud-free Landsat and ASTER data for the peak defoliation period of the other years in the 2000-2006 time series. Additional work should be performed to assess the accuracy of gypsy moth defoliation detection products for additional years.The study area (mid-Appalachian highlands) and application (gypsy moth forest defoliation) are not necessarily representative of all forested regions and of all forest threat disturbance agents. Additional work should be performed on other inland and coastal regions as well as for other major forest threats.

Spruce, Joseph P.↗