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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Organic wastewater treatment by a single-atom catalyst and electrolytically produced H2O2

The presence of organic contaminants in wastewater poses considerable risks to the health of both humans and ecosystems. Although advanced oxidation processes that rely on highly reactive radicals to destroy organic contaminants are appealing treatment options, substantial energy and chemical inputs limit their practical applications. Here we demonstrate that Cu single atoms incorporated in graphitic carbon nitride can catalytically activate H 2 O 2 to generate hydroxyl radicals at pH 7.0 without energy input, and show robust stability within a filtration device. We further design an electrolysis reactor for the on-site generation of H 2 O 2 from air, water and renewable energy. Coupling the single-atom catalytic filter and the H 2 O 2 electrolytic generator in tandem delivers a wastewater treatment system. These findings provide a promising path toward reducing the energy and chemical demands of advanced oxidation processes, as well as enabling their implementation in remote areas and isolated communities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A High-Fidelity Electromagnetic Transient Model of Inverter-based Resources Integrated to an IEEE-9 Bus System for Benchmarking Studies

An inverter-based resource (IBR) is a source of electricity that is asynchronously connected to the electrical grid via an electronic power converter. These power sources lack the intrinsic behaviors of the standard power plants, presenting specific challenges to system stability. These power sources lack the intrinsic behaviors of the standards power plants and their features are almost entirely defined by the control strategy used on them, presenting specific challenges to system stability as their penetration increases into the already fragile Bulk Power System (BPS). Utilizing renewable energy has a great upside but the electrical industry needs to understand the requirements like performing electromagnetic transient (EMT) simulation studies in planning and/or in interconnection studies. This paper presents the development of a high-fidelity EMT model based on commercial equipment and field parameters, which at the same time aims to study the increasing penetration of IBRs and their impact on the actual BPS. The open-source EMT model developed will be a benchmarking example that can be used to evaluate algorithms in the power grid (including evaluating grid-forming controls, power system monitoring and operation, etc.).

Martinez Montejano, Misael↗

Design and Operation of Energy Systems with Large Amounts of Variable Generation: IEA Wind TCP Task 25 (Final Summary Report)

This report summarizes findings on wind integration from the 17 countries or sponsors participating in the International Energy Agency Wind Technology Collaboration Program (IEA Wind TCP) Task 25 from 2006-2020. Both real experience and studies are reported. Many wind integration studies incorporate solar energy, and most of the results discussed here are valid for other variable renewables in addition to wind. The national case studies address several impacts of wind power on electric power systems. In this report, they are grouped under long-term planning issues and short-term operational impacts. Long-term planning issues include grid planning and capacity adequacy. Short-term operational impacts include reliability, stability, reserves, and maximizing the value of wind in operational timescales (balancing related issues). The first section presents the variability and uncertainty of power system-wide wind power, and the last section presents recent studies toward 100% shares of renewables. The appendix provides a summary of ongoing research in the national projects contributing to Task 25 for 2021-2024. The design and operation of power and energy systems is an evolving field. As ambitious targets toward net-zero carbon energy systems are announced globally, many scenarios are being made regarding how to reach these future decarbonized energy systems, most of them involving large amounts of variable renewables, mainly wind and solar energy. The secure operation of power systems is increasingly challenging, and the impacts of variable renewables, new electrification loads together with increased distribution system resources will lead to somewhat different challenges for different systems. Tools and methods to study future power and energy systems also need to evolve, and both short-term operational aspects (such as power system stability) and long-term aspects (such as resource adequacy) will probably see new paradigms of operation and design. The experience of operating and planning systems with large amounts of variable generation is accumulating, and research to tackle the challenges of inverter-based, nonsynchronous generation is on the way. Energy transition and digitalization also bring new flexibility opportunities, both short and long term.

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A Comparison of Machine Learning Methods for Frequency Nadir Estimation in Power Systems

An increasing penetration level of inverter-based renewable energy resources changes the inertia of power systems, posing challenges for maintaining the desired system frequency stability. An accurate frequency nadir estimation is crucial for power system operators to prepare preventive actions against large frequency excursions. In this paper, five machine learning methods - linear regression, gradient boosting, support vector regression, an artificial neural network, and XGBoost - are applied to two different datasets, i.e., 1) the unit generation dataset and 2) the system total inertia and headroom dataset, for the prediction of the frequency nadir. The training and testing datasets are generated through extensive generation scheduling simulations using Multi-timescale Integrated Dynamic and Scheduling (MI-DAS) toolbox on the Western Electricity Coordinating Council 240-bus system with high renewable penetration levels. Numerical results show that all five machine learning methods perform well in predicting the nadir frequency of the system. Among them, the gradient boosting and the XGBoost are clear winners yielding the best prediction accuracy in terms of four evaluation metrics.

data driven↗

Hydrogen as Part of a 100% Clean Energy System: Exploring Its Decarbonization Roles

Today's energy system uses a variety of fuels and energy carriers in molecular forms, such as coal, oil, and natural gas, each contributing to CO2 emissions (Figure 1). As solar and wind levels grow and the energy system becomes more electrified, fossil molecular fuels will contribute a progressively smaller fraction of overall energy. As shown in Figure 2, hydroelectric storage and molecules, such as coal and natural gas, provide substantial storage and dispatch functionality today that will become increasingly critical for electricity operation and stability. Emerging low-carbon gases, such as hydrogen, can support the efficient integration of renewables in the transition from today's energy system to one that is 100% clean from a carbon emissions perspective.

clean energy system↗

Prolonged Stability of Pb-Catalyzed CO 2 Electroreduction to Methyl Formate in Acidic Methanol

Electrochemical CO 2 reduction from renewable energy is a promising route to mitigate greenhouse gas emissions from waste sources while generating value-added products. CO 2 electroreduction in methanol is particularly interesting due to the increased CO 2 solubility compared to water and the propensity to form methyl formate, a product absent in aqueous electrolysis. Here, four factors have been identified as critical to achieving prolonged high selectivity for methyl formate production on a Pb cathode in methanol: high pH near the electrode, low bulk pH, low water content, and regeneration of Pb 2+ sites. Increasing concentration of the formic acid product was observed to induce a selectivity shift towards hydrogen, which was mitigated by the in-situ conversion of the formic acid to methyl formate via an esterification reaction. Furthermore, co-electrolysis of CO 2 with dilute molecular oxygen (4% O 2 ) led to Pb catalyst repair through in-situ surface oxidation. Using CO 2 and dilute O 2 along with single-pass catholyte flow to maintain a low formic acid concentration, sustained high selectivity for methyl formate was attained at ~60% faradaic efficiency at -20 mA cm -2 for over 72 hours.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Ensuring Transient Stability With Guaranteed Region of Attraction in DC Microgrids

DC microgrids have promising applications in renewable integration due to their better energy efficiency when connecting DC components. However, they might be unstable since many loads in a DC microgrid are regulated as constant power loads (CPLs) that have a destabilizing negative impedance effect. As a result, the state trajectory displacement caused by abrupt load changes or contingencies can easily lead to instability. Many existing works have been devoted to studying the region of attraction (ROA) of a DC microgrid, in which the system is guaranteed to be asymptotically stable. Nevertheless, existing work either focuses on using numerical methods for ROA approximations that generally have no performance guarantees or cannot ensure a desired ROA for a general DC microgrid. To close this gap, this paper develops an innovative control synthesis algorithm to make a general DC microgrid have a theoretically guaranteed ROA, for example, to cover the entirety of its operating range regarding state trajectories. Here, we first study the nonlinear dynamics of a DC microgrid to derive a novel transient stability condition to rigorously certify whether a given operating range is a subset of the ROA; then, we formulate a control synthesis optimization problem to guarantee the condition’s satisfaction. This condition is a linear constraint, and the optimization problem resembles an optimal power flow problem and has a good computational behavior. Simulation case studies verify the validity of the proposed work.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Aqueous titanium redox flow batteries—State-of-the-art and future potential

Market-driven deployment of inexpensive (but intermittent) renewable energy sources, such as wind and solar, in the electric power grid necessitates grid-stabilization through energy storage systems Redox flow batteries (RFBs), with their rated power and energy decoupled (resulting in a sub-linear scaling of cost), are an inexpensive solution for the efficient electrochemical storage of large amounts of electrical energy. Titanium-based RFBs, first developed by NASA in the 1970s, are an interesting albeit less examined chemistry and are the focus of the present review. Ti, constituting 0.6% of the Earth’s crust and an ingredient in inexpensive white paints, is amongst the few elements (V and Mn being some others) which exhibit multiple soluble oxidation states in aqueous electrolytes. Further, the very high (approaching 10 M) solubility of Ti in low pH solutions suggests the possibility of developing exceptionally high energy density aqueous Redox Flow Batteries systems. With these advantages in mind, we present the state-of the-art in Ti-RFBs with a focus on Ti/Mn, Ti/Fe and Ti/Ce couples and systems that use Ti as an additive (such as Ti/V/Mn). The inherent advantages of inexpensive Ti actives and relatively high energy density is contrasted with potential side-reactions resulting in reduced energy efficiency. Technological pathways are presented with a view to overcoming critical bottlenecks and a vision is presented for the future development of Ti-RFBs.

25 ENERGY STORAGE↗

Machine Learning-Assisted Stability Boundary Determination of Multiport Autonomous Reconfigurable Solar Power Plants

The multiport autonomous reconfigurable solar (MARS) power plant is a promising solution to integrate renewable resources and energy storage systems into the alternating current (ac) power grid and an high-voltage direct current (HVdc) link. In the MARS system, various input power sources are connected to the individual submodules (SMs) through direct current (dc)–dc converters. However, the presence of external power sources can result in unbalanced capacitor voltages of SMs, thereby violating stability constraints under multiple/diverse operating conditions. This article aims to address the gap by accurately determining the stability boundary of the MARS system. As such, a novel machine learning (ML)-assisted energy balancing control (EBC) criterion is proposed. Further, in conjunction with a refined EBC, this approach ensures balanced capacitor voltages across various types of SMs, significantly enhancing the overall system efficiency. The proposed EBC criterion effectively controls EBC activation and deactivation, achieving remarkable accuracy. Both power systems computer aided design (PSCAD)/electromagnetic transients including direct current (EMTDC) simulations and control hardware-in-the-loop (cHIL) tests are conducted to validate the feasibility and efficiency of the proposed method. By combining the EBC and ML-assisted EBC criterion, efficient energy management is achieved for systems featuring multiple input power sources, such as MARS. This approach enables the system to fully exploit its potential across an expanded operational range while upholding high-efficiency standards.

14 SOLAR ENERGY↗

Explainable Bayesian Neural Network for Probabilistic Transient Stability Analysis Considering Wind Energy

While several data-driven models have been developed for transient stability assessment, how to consider the uncertainties from load and renewable generations and provide interpretation of data-driven assessment results are still open. This paper proposes an explainable Bayesian Neural Network (BNN) for probabilistic transient stability assessment (TSA). By extracting the uncertainties from loads and wind farms, the BNN model can make a reliable prediction and quantify the prediction uncertainties. We also develop the Gradient Shap algorithm to make the global and local explanations for the probabilistic TSA model, a significant advantage over existing black-box data-driven methods. Numerical results on the modified IEEE 39-bus system show that the proposed method outperforms the existing methods in terms of prediction accuracy and uncertainty quantification capabilities. The explainability of the proposed method allows system operators to design preventive controls for enhancing system stability.

Bayesian Neural Network↗

A review of Geological Thermal Energy Storage for seasonal, grid-scale dispatching

Energy storage is essential for the decarbonization of the U.S. energy grid, especially with the increasing deployment of variable renewable energy sources like solar and wind. Geological thermal energy storage (GeoTES) has emerged as a promising long duration, grid scale solution, providing stability and security through flexible operations and valuable grid services. GeoTES utilizes subsurface reservoirs to store thermal energy for power generation and direct-use heating and cooling. This approach significantly enhances the use of low-temperature reservoirs, which would otherwise be unsuitable for geothermal power plants. It also aligns well with depleted oil and gas reservoirs, concentrating solar power, non-flexible renewables (photovoltaic and wind), and geothermal-related power cycles. Given the favorable marginal costs of GeoTES as storage duration increases, it becomes particularly competitive for seasonal, grid-scale dispatch, where few technologies are viable. This paper provides a comprehensive review of GeoTES systems and the research underpinning itsr development. This analysis begins by defining and categorizing the unique characteristics of thermal energy storage techniques, setting GeoTES apart from other technologies. The various components, configurations, subsurface characteristics, and modeling efforts that guide GeoTES development are then explored. Finally, challenges in GeoTES research, development, and deployment are discussed, along with mitigation strategies and lessons from related technologies. Beyond their economic benefits, GeoTES systems support grid resilience and decarbonize industrial processes. Their scalability, broad distribution, seasonal storage potential, and flexible dispatch capacity make GeoTES a valuable tool for expanding renewable energy deployment and addressing climate change.

15 - GEOTHERMAL ENERGY↗

Uncertainty quantification of a physics-informed model based on sparse identification of a Thermal Energy Distribution System

Integrated energy systems (IES)s are crucial for enhancing the economy and efficiency of power generation sources (e.g., nuclear energy) necessary to unleash American energy dominance. These systems can be integrated with thermal energy storage (TES) and intermittent renewable energies to optimize overall energy use, peak-load regulation, and demand-side responses. However, the stabilization of energy generation, transport, and utilization introduces operational complexities that exceed the challenges of managing each sub-component individually. Currently, though IESs rely on human operators for efficiency and stability, reducing human error risk and enhancing performance through automation is highly desirable. Recent advances at Idaho National Laboratory have demonstrated successful control of the Thermal Energy Distributed System (TEDS). However, the automatic control system depends on a deterministic Sparse Identification of Nonlinear Dynamics with Control (SINDyC) model, which are trained based on simulation data from physics-based simulations. Because of uncertainties in physics-based simulation, SINDyC model results in large discrepancies against experimental data and cannot be reliably used in automatic control. In this paper, we present an innovative approach to address these discrepancies by quantifying uncertainties and developing a more robust model. We first generated trajectories by using first-principles physics codes to encapsulate the experiment. Next, we trained thousands of models by randomly sampling these trajectories. We then collapsed all those models into one probabilistic SINDyC by fitting a multivariate Gaussian distribution onto the resulting coefficient’s distribution. Despite its simplicity, our approach successfully produced 95% confidence intervals that captured the experimental trajectories. It even did so with a higher probability and better U-pooling score across six of the seven relevant quantities of interest (QoIs), as compared to other classical approaches. In conclusion, ongoing research is focusing on generating new experimental trajectories to validate this approach, and on employing Bayesian calibration to refine parametric uncertainties and guide future model development efforts.

22 - GENERAL STUDIES OF NUCLEAR REACTORS↗

Indolo[2,3- b ]quinoxaline as a Low Reduction Potential and High Stability Anolyte Scaffold for Nonaqueous Redox Flow Batteries

Redox flow batteries (RFBs) are a promising stationary energy storage technology for leveling power supply from intermittent renewable energy sources with demand. A central objective for the development of practical, scalable RFBs is to identify affordable and high-performance redox-active molecules as storage materials. Herein, we report the design, synthesis, and evaluation of a new organic scaffold, indolo[2,3-b]quinoxaline, for highly stable, low-reduction potential, and high-solubility anolytes for nonaqueous redox flow batteries (NARFBs). The mixture of 2- and 3-(tert-butyl)-6-(2-methoxyethyl)-6H-indolo[2,3-b]quinoxaline exhibits a low reduction potential (-2.01 V vs Fc/Fc + ), high solubility (>2.7 M in acetonitrile), and remarkable stability (99.86% capacity retention over 49.5 h (202 cycles) of H-cell cycling). This anolyte was paired with N-(2-(2-methoxyethoxy)-ethyl)phenothiazine (MEEPT) to achieve a 2.3 V all-organic NARFB exhibiting 95.8% capacity retention over 75.1 h (120 cycles) of cycling.

25 ENERGY STORAGE↗

AI-Based Faster-Than-Real-Time Stability Assessment of Large Power Systems with Applications on WECC System

Achieving clean energy goals will require significant advances in regard to addressing the computational needs for next-generation renewable-dominated power grids. One critical obstacle that lies in the way of transitioning today’s power grid to a renewable-dominated power grid is the lack of a faster-than-real-time stability assessment technology for operating a fast-changing power grid. This paper proposes an artificial intelligence (AI) -based method that predicts the system’s stability margin information (e.g., the frequency nadir in the frequency stability assessment and the critical clearing time (CCT) value in the transient stability assessment) directly from the system operating conditions without performing the conventional time-consuming time-domain simulations over detailed dynamic models. Since the AI method shifts the majority of the computational burden to offline training, the online evaluation is extremely fast. This paper has tested the AI-based stability assessment method using multiple dispatch cases that are converted and tuned from actual dispatch cases of the Western Electricity Coordinating Council (WECC) system model with more than 20,000 buses. The results show that the AI-based method could accurately predict the stability margin of such a large power system in less than 0.2 milliseconds using the offline-trained AI agent. Therefore, the proposed method has great potential to achieve faster-than-real-time stability assessment for practical large power systems while preserving sufficient accuracy.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Scalable Unit Commitment with Security Constrained AC Power Flow via ADMM and Hybrid Modeling Strategies

This research introduces a more efficient way to optimize power grid operations, breaking the problem into manageable steps and using advanced mathematical techniques to speed up calculations. By incorporating smart heuristics, improved preprocessing, and contingency analysis, the approach allows operators to make better decisions faster. These innovations enhance our understanding of how to optimize energy generation, making it possible to anticipate failures before they happen, reduce system costs, and improve overall grid performance. Ultimately, this research helps bridge the gap between theoretical models and real-world applications, paving the way for a smarter, more resilient power grid. This research directly benefits the public by making electricity more affordable, reliable, and sustainable. By improving how power grids schedule and distribute electricity, the project helps energy providers reduce operational costs, which can lead to lower electricity prices for consumers. Additionally, the ability to predict and prevent power system failures enhances grid reliability, reducing the likelihood of blackouts that can disrupt homes, businesses, and critical infrastructure such as hospitals. From an environmental perspective, optimizing power generation reduces energy waste and lowers carbon emissions, contributing to cleaner air and a more sustainable energy system. Furthermore, with extreme weather events becoming more frequent, these advancements make the power grid more resilient, ensuring communities are better prepared for emergencies and natural disasters. By strengthening the nation's energy infrastructure, this research plays a crucial role in improving economic stability, public safety, and environmental sustainability.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Integration of Storage in the DC Link of a Full Converter-Based Distributed Wind Turbine

Energy storage is known to support the dispatchability of variable renewable resources. In this paper, we model a battery energy storage system (BESS) integrated with the DC link of a Type IV full converter-based wind turbine and the necessary controls to achieve efficient dispatch. To support the validation of control methodologies, we build a detailed model of a Type IV research wind turbine at the National Renewable Energy Laboratory (NREL), the Controls Advanced Research Turbine (CART 3), and we integrated a lithium-ion BESS model in grid-following mode into the model. The simulation results illustrate the sizing and control of the DC link-integrated BESS for a given variable wind resource and varying dispatch strategies (i.e., under constant, uncertain, and ramping wind scenarios). The integrated storage can smooth variabilities in distributed wind output, hedge against uncertainties, provide the ramping capability, as well as support stability under voltage and frequency transients. All of these have been illustrated in MATLAB/Simulink.

DC-link voltage↗

Impedance Methods for Analyzing Stability Impacts of Inverter-Based Resources: Stability Analysis Tools for Modern Power Systems

Power systems around the world are undergoing a major transformation because of the increasing shares of renewable energy, growing deployment of energy storage systems, proliferation of distributed energy resources, electrification of other sectors, and so on. In the United States, wind and solar provided almost 10% of electricity in 2019. The U.S. Energy Information Administration, in its 2020 Annual Energy Outlook, forecasted that the share of electricity from renewables will reach 38% by 2050, of which more than 80% will come from wind and solar. Wind and solar, along with battery energy storage systems, interface with the grid using power electronic inverters; hence, they are collectively referred to as inverter-based resources (IBRs). The increasing annual share of electricity from IBRs in a power system means that during more times of the year, the system will operate at a much higher concentration of IBRs. Figure 1 presents the hourly share of wind and solar generation in the Electric Reliability Council of Texas (ERCOT) system in Texas in 2019. While the annual wind share was at 20%, the instantaneous percentage share was much higher. Moments of high shares of IBRs (>50%) will continue to grow as more IBRs will be deployed in a power system.

24 POWER TRANSMISSION AND DISTRIBUTION↗