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At least 145 records · Page 8

Derivation of surface properties from Magellan altimetry data

The fit of the Hagfors model to the Magellan altimetry data provides a means to characterize the surface properties of Venus. However, the derived surface properties are only meaningful if the model provides a good representation of the data. The Hagfors model provides a good representation of the data. The Hagfors model is generally a realistic fit to surface scattering properties of a nadir-directed antenna such as the Magellan altimeter; however, some regions of the surface of Venus are poorly described by the existing model, according to the goodness of fit parameter provided on the ARCDR CD-ROMs. Poorly characterized regions need to be identified and fit to new models in order to derive more accurate surface properties for use in inferring the geological processes that affect the surface in those regions. We have compared the goodness of fit of the Hagfors model to the distribution of features across the planet, and preliminary results show a correlation between steep topographic slopes and poor fits to the standard model, as has been noticed by others. In this paper, we investigate possible relations between many classes of features and the ability of the Hagfors model to fit the observed echo profiles. In the regions that are not well characterized by existing models, we calculate new models that compensate for topographic relief in order to derive improved estimates of surface properties. Areas investigated to date span from longitude 315 through 45, at all latitudes covered by Magellan. A survey of those areas yields preliminary results that suggest that topographically high regions are well suited to the current implementation of the Hagfors model. Striking examples of such large-scale good fits are Alpha Regio, the northern edges of Lada Terra, and the southern edge of Ishtar Terra. Other features that are typically well fit are the rims of coronae such as Heng-O and the peaks of volcanos such as Gula Mons. Surprisingly, topographically low regions, such as the ubiquitous plains areas, are modeled poorly in comparison. However, this generalization has has exceptions: Lakshmi Planum is an elevated region that is not well fit compared to the rest of neighboring Ishtar, while the southern parts of topographically low Guinevere Planitia are characterized quite well by the Hagfors model. Features that are candidates for improved models are impact craters, coronae, ridges of significant scale, complex ridged terrains, moderate-sized mountains, and sharp terrain boundaries. These features are chosen because the goodness of fit is likely to be most affected either by departures from normal incidence angles or by sharp changes in terrain type within a single footprint. Most large features that are elevated with respect to their surroundings will suffer from steep slope effects, and smaller coronae and impact craters will probably suffer due to rapid changes in their appearance within a single footprint (10-20 km).

Lovell, Amy J.↗

Validation of Proposed Metrics for Two-Body Abrasion Scratch Test Analysis Standards

Abrasion of mechanical components and fabrics by soil on Earth is typically minimized by the effects of atmosphere and water. Potentially abrasive particles lose sharp and pointed geometrical features through erosion. In environments where such erosion does not exist, such as the vacuum of the Moon, particles retain sharp geometries associated with fracturing of their parent particles by micrometeorite impacts. The relationship between hardness of the abrasive and that of the material being abraded is well understood, such that the abrasive ability of a material can be estimated as a function of the ratio of the hardness of the two interacting materials. Knowing the abrasive nature of an environment (abrasive)/construction material is crucial to designing durable equipment for use in such surroundings. The objective of this work was to evaluate a set of standardized metrics proposed for characterizing a surface that has been scratched from a two-body abrasion test. This is achieved by defining a new abrasion region termed Zone of Interaction (ZOI). The ZOI describes the full surface profile of all peaks and valleys, rather than just measuring a scratch width. The ZOI has been found to be at least twice the size of a standard width measurement; in some cases, considerably greater, indicating that at least half of the disturbed surface area would be neglected without this insight. The ZOI is used to calculate a more robust data set of volume measurements that can be used to computationally reconstruct a resultant profile for de tailed analysis. Documenting additional changes to various surface roughness par ameters also allows key material attributes of importance to ultimate design applications to be quantified, such as depth of penetration and final abraded surface roughness. Further - more, by investigating the use of custom scratch tips for specific needs, the usefulness of having an abrasion metric that can measure the displaced volume in this standardized manner, and not just by scratch width alone, is reinforced. This benefit is made apparent when a tip creates an intricate contour having multiple peaks and valleys within a single scratch. The current innovation consists of a software- driven method of quantitatively evaluating a scratch profile. The profile consists of measuring the topographical features of a scratch along the length of the scratch instead of the width at one location. The digitized profile data is then fed into software code, which evaluates enough metrics of the scratch to reproduce the scratch from the evaluated metrics. There are three key differences between the current art and this innovation. First, scratch width does not quantify how far from the center of the scratch damage occurs (ZOI). Second, scratch width does not discern between material displacement and material removal from the scratch. Finally, several scratches may have the same width but different zones of interactions, different displacements, and different material removals. The current innovation allows quantitative assessment of all three.

Street, Kenneth W., Jr.↗

Synergistic ground and orbital observations of iron oxides on Mt. Sharp and Vera Rubin ridge

Visible/short-wave infrared spectral data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) show absorptions attributed to hematite at Vera Rubin ridge (VRR), a topographic feature on northwest Mt. Sharp. The goals of this study are to determine why absorptions caused by ferric iron are strongly visible from orbit at VRR, and to improve interpretation of CRISM data throughout lower Mt. Sharp. These goals are achieved by analyzing coordinated CRISM and in situ spectral data along the Curiosity Mars rover’s traverse. VRR bedrock within areas that have the deepest ferric absorptions in CRISM data also have the deepest ferric absorptions measured in situ. This suggests strong ferric absorptions are visible from orbit at VRR because of the unique spectral properties of VRR bedrock. Dust and mixing with basaltic sand additionally inhibit the ability to measure ferric absorptions in bedrock stratigraphically below VRR from orbit. There are two implications of these findings: (1) Ferric absorptions in CRISM data initially dismissed as noise could be real, and ferric phases are more widespread in lower Mt. Sharp than previously reported, (2) Patches with the deepest ferric absorptions in CRISM data are, like VRR, reflective of deeper absorptions in the bedrock. One model to explain this spectral variability is late-stage diagenetic fluids that changed the grain size of ferric phases, deepening absorptions. Curiosity’s experience highlights the strengths of using CRISM data for spectral absorptions and associated mineral detections, and the caveats in using these data for geologic interpretations and strategic path planning tools.

58 GEOSCIENCES↗

The CheMin X-ray Diffractometer on MSL Curiosity: A Decade of Mineralogical Observations from Gale Crater, Mars

For more than a decade, the CheMin X-ray Diffraction instrument on the Mars Science Laboratory rover Curiosity has been returning quantitative mineralogical data from Gale crater, Mars. CheMin receives and analyzes sieved soil and powdered rock samples from Curiosity’s Sample Acquisition / Sample Processing and Handling (SA/SPaH) system. To date, 38 samples have been analyzed over the course of a 28 km transit. These samples document more than 600 vertical meters of flat-lying lacustrine, fluvial and aeolian sediments that comprise the lower part of the central mound of Gale crater (commonly called Mt. Sharp).The principal mineralogy of the sediments is basaltic, with evidence of early and late-stage diagenetic overprinting. The rocks in many cases preserve most of their primary mineralogy and sedimentary features, suggesting that they were never strongly heated or deformed. Using aeolian soil composition as a proxy for the composition of the deposited and lithified sediment, it appears that in many cases the diagenetic changes observed are principally isochemical. Exceptions to this include secondary nodules, calcium sulfate veining and rare alteration halos. A striking hematite-rich feature in lower Mt. Sharp called Vera Rubin Ridge is interpreted to be lake sediment diagenetically altered by silica-poor fluids. A surprising and as yet poorly understood observation is that nearly all of the 3.7 Gyr old sedimentary rocks analyzed to date are comprised of 25-50% X-ray amorphous material. Overall, this 600 m vertical section of sedimentary rock explored in lower Mt. Sharp documents a perennial shallow lake environment grading upward into alternating lacustrine/fluvial and aeolian environments. The mineralogical changes observed going up-section include a transition from trioctahedral to dioctahedral clay minerals and a transition from magnetite to hematite. More recently, in the last 150 m of section, CheMin has documented an overall decrease in clay minerals and increase in Fe3+ oxides and oxyhydroxides. The mineralogical changes observed in Gale crater may document the gradual drying out and oxidation of the martian hydrosphere.

CHEMIN↗

One arc-minute resolution maps of the Orion Nebula at 20, 50, and 100 microns

The paper presents maps of the central regions of the Orion Nebula which are based on observations made at wavelengths of 20, 50, and 100 microns with a resolution of 1 arcmin. The 50- and 100-micron observations were made with the NASA 91-cm Airborne Infrared Telescope. The principal far-IR features observed include a sharp emission peak near the position of the IR cluster, about 1 arcmin northwest of the Trapezium; a ridge of emission that is elongated north-south about this peak; and a barlike feature running northeast to southwest about 2 arcmin southeast of the Trapezium. The following conclusions are reached about the nature of the far-IR emission: (1) the total luminosity (between 10 and 1000 microns) of the IR cluster exceeds the solar luminosity by a factor of at least 120,000; (2) heating by both the IR cluster and the Trapezium stars is important in producing the central emission ridge; (3) the IR cluster is located within the molecular cloud; (4) the Trapezium stars are no more than 0.1 pc from that cloud; and (5) the bar of emission southeast of the Trapezium can be identified with an optically visible ionization front.

Werner, M. W.↗

Detection and analysis of photospheric CNO features in the ultraviolet spectrum of the hot DO white dwarf PG 1034 + 001

An analysis of PG 1034 + 001 extended to include the high-dispersion IUE spectra and the high-resolution optical multiple-mirror telescope echelle spectra is discussed. The observations reveal the presence of absorption lines (C IV at 1548 and 1551 A, N V at 1238 and 1242 A, and O V at 1371 A) from highly ionized species with large redshifts (+ 40-50) km/s) relative to the interstellar lines. The results of a preliminary abundance analysis of the photospheric lines, together with the results of a search of sharp shortward-shifted features are presented. An interpretation of the observed abundances is made in terms of selective radiative forces acting in a high-temperature photosphere. Some speculations on the evolutionary status of DO stars like PG 1034 + 001 are given.

Sion, E. M.↗

Use of carbonyldiimidazole as a derivatization agent for the detection of pinacolyl alcohol, a forensic marker for Soman, by EI-GC–MS and LC-HRMS in official OPCW proficiency test matrices

Pinacolyl alcohol (PA), a key forensic marker for the nerve agent Soman (GD), is a particularly difficult analyte to detect by various analytical methods. In this work, we have explored the reaction between PA and 1,1'-carbonyldiimidazole (CDI) to yield pinacolyl 1H-imidazole-1-carboxylate (PIC), a product that can be conveniently detected by gas chromatography–mass spectrometry (GC–MS) and liquid chromatography-high-resolution mass spectrometry (LC-HRMS). Regarding its GC–MS profile, this new carbamate derivative of PA possesses favorable chromatographic features such as a sharp peak and a longer retention time (RT = 16.62 min) relative to PA (broad peak and short retention time, RT = 4.1 min). Additionally, the derivative can also be detected by LC-HRMS, providing an avenue for the analysis of this chemical using this technique where PA is virtually undetectable unless present in large concentrations. From a forensic science standpoint, detection of this low molecular weight alcohol signals the past or latent presence of the nerve agent Soman (GD) in a given matrix (i.e., environmental or biological). The efficiency of the protocol was tested separately in the analysis and detection of PA by EI-GC–MS and LC-HRMS when present at a 10 μg/mL in a soil matrix featured in the 44th PT and in a glycerol-rich liquid matrix featured in the 48th Official Organization for the Prohibition of Chemical Weapons (OPCW) Proficiency Test when present at a 5 μg/mL concentration. In both scenarios, PA was successfully transformed into PIC, establishing the protocol as an additional tool for the analysis of this unnatural and unique nerve agent marker by GC–MS and LC-HRMS.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Carbon Monoxide Mediated Hydrogen Release from PtCu Single-Atom Alloys: The Punctured Molecular Cork Effect

Pt-based materials are used extensively in heterogeneous catalytic processes, yet they are notoriously susceptible to poisoning by CO. In contrast, highly dilute binary alloys formed of isolated Pt atoms in a Cu metal host, known as PtCu single-atom alloys (SAAs), are more resilient to CO poisoning during catalytic hydrogenation reactions. In this article, we describe how CO affects the adsorption and desorption of H 2 from a model PtCu(111) SAA surface and gain a microscopic understanding of these species’ interaction at the Pt atom active sites. By combining temperature-programmed desorption and scanning tunneling microscopy with first-principles kinetic Monte Carlo, we identify CO as a Pt site blocker that prevents the low temperature adsorption and desorption of H 2 , the so-called molecular cork effect , first realized when examining PdCu SAAs. Intriguingly, for the case of PtCu, H 2 desorption occurs before CO release is detected. Additionally, desorption experiments show a nonlinear relationship between CO coverage of the Pt sites and H 2 desorption peak temperature. When all the Pt atoms are saturated by CO, a very sharp H 2 desorption feature is observed 55 K above the regular desorption temperature of H 2 . Our simulations reveal that the origin of these effects is the fact that desorption of just one CO molecule from a Pt site facilitates the fast release of many molecules of H 2 . In fact, just 0.7% of the CO adsorbed at Pt sites has desorbed when the H 2 desorption peak maximum is reached. The release of H 2 from CO-corked PtCu SAA surfaces is analogous to the escape of gas from a pressurized container with a small puncture. Given that small changes in CO surface coverage lead to large changes in H 2 evolution energetics, the punctured molecular cork effect must be considered when modeling reaction mechanisms on similar alloy systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization

Lithium (Li) pulverization and associated large volume expansion during cycling is one of the most critical barriers for the safe operation of Li-metal batteries. Here, we report an approach to minimize the Li pulverization using an electrolyte based on a fluorinated orthoformate solvent. The solid–electrolyte interphase (SEI) formed in this electrolyte clearly exhibits a monolithic feature, which is in sharp contrast with the widely reported mosaic- or multilayer-type SEIs that are not homogeneous and could lead to uneven Li stripping/plating and fast Li and electrolyte depletion over cycling. The highly homogeneous and amorphous SEI not only prevents dendritic Li formation, but also minimizes Li loss and volumetric expansion. Furthermore, this new electrolyte strongly suppresses the phase transformation of the LiNi 0.8 Co 0.1 Mn 0.1 O 2 cathode (from layered structure to rock salt) and stabilizes its structure. In conclusion, tests of high-voltage Li||NMC811 cells show long-term cycling stability and high rate capability, as well as reduced safety concerns.

25 ENERGY STORAGE↗

Modelling a Transition-Edge Sensor X-Ray Microcalorimeter Linear Array for Compton Profile Measurements and Energy Dispersive Diffraction

Transition-edge sensors (TES) are a type of superconducting detector that offers high energy resolution based on their sharp resistance-temperature feature in the superconducting-to-normal transition. TES X-ray microcalorimeters have typically been designed and used for spectroscopic applications. In this work, we present a design optimization for a TES X-ray microcalorimeter array for high-energy scattering and diffraction measurements. Specifically, Compton scattering provides information about the electron momentum distribution, while energy dispersive diffraction provides structural information about dense engineering materials. Compton scattering and energy dispersive diffraction experiments must be conducted in the very hard X-ray regime (~100 keV), demanding a high X-ray stopping power in the detector; therefore, an absorber with a large heat capacity is needed in conjunction with the TES. In addition, both applications would benefit from an array composed of parallel strips. We propose a design for a TES X-ray microcalorimeter optimized for such applications. In particular, we model the longitudinal position dependence due to the finite thermal diffusion time in the absorber.

47 OTHER INSTRUMENTATION↗

Low-Level Mesoscale and Cloud-Scale Interactions Promoting Deep Convection Initiation

Data from scanning radars, radiosondes, and vertical profilers deployed during three field campaigns are analyzed to study interactions between cloud-scale updrafts associated with initiating deep moist convection and the surrounding environment. Three cases are analyzed in which the radar networks permitted dual-Doppler wind retrievals in clear air preceding and during the onset of surface precipitation. These observations capture the evolution of (i) the mesoscale and boundary layer flow, and (ii) low-level updrafts associated with deep moist convection initiation (CI) events yielding sustained or short-lived precipitating storms. The elimination of convective inhibition did not distinguish between sustained and unsustained CI events, though the vertical distribution of convective available potential energy may have played a role. The clearest signal differentiating the initiation of sustained versus unsustained precipitating deep convection was the depth of the low-level horizontal wind convergence associated with the mesoscale flow feature triggering CI, a sharp surface wind shift boundary, or orographic upslope flow. The depth of the boundary layer relative to the height of the LFC failed to be a consistent indicator of CI potential. Widths of the earliest detectable low-level updrafts associated with sustained precipitating deep convection were ~3–5 km, larger than updrafts associated with surrounding boundary layer turbulence (~1–3 km wide). It is hypothesized that updrafts of this larger size are important for initiating cells to survive the destructive effects of buoyancy dilution via entrainment.

54 ENVIRONMENTAL SCIENCES↗

M-Edge Spectroscopy of Transition Metals: Principles, Advances, and Applications

M-edge X-ray absorption spectroscopy (XAS), which probes 3p→3d transitions in first-row transition metals, provides detailed insights into oxidation states, spin-states, and local electronic structure with high element and orbital specificity. Operating in the extreme ultraviolet (XUV) region, this technique provides sharp multiplet-resolved features with high sensitivity to ligand field and covalency effects. Compared to K- and L-edge XAS, M-edge spectra exhibit significantly narrower full widths at half maximum (typically 0.3–0.5 eV versus >1 eV at the L-edge and >1.5–2 eV at the K-edge), owing to longer 3p core-hole lifetimes. M-edge measurements are also more surface-sensitive due to the lower photon energy range, making them particularly well-suited for probing thin films, interfaces, and surface-bound species. The advent of tabletop high-harmonic generation (HHG) sources has enabled femtosecond time-resolved M-edge measurements, allowing direct observation of ultrafast photoinduced processes such as charge transfer and spin crossover dynamics. This review presents an overview of the fundamental principles, experimental advances, and current theoretical approaches for interpreting M-edge spectra. We further discuss a range of applications in catalysis, materials science, and coordination chemistry, highlighting the technique’s growing impact and potential for future studies.

M-edge XANES↗

Spectrally resolved localized states in GaAs 1– x Bi x

In this study, the role of localized states and their influence on the broader band structure remains a crucial question in understanding the band structure evolution in GaAs 1-x Bi x . Here in this work, we present clear spectroscopic observations of recombination at several localized states in GaAs 1-x Bi x . Sharp and recognizable photoluminescence features appear in multiple samples and redshift as a function of GaBi fraction between x = 0.16% and 0.4% at a linearized rate of 34 meV per % Bi, weaker than the redshift associated with band-to-band recombination. Interpreting these results in terms of radiative recombination between localized holes and free electrons sheds light on the relative movement of the conduction band minimum and the characteristics of localized bismuth-related trap states in GaAs 1-x Bi x alloys.

36 MATERIALS SCIENCE↗

High spectral resolution ground-based observations of Venus in the 450- to 1250 kayser region

Ground-based observations of Venus were made with a 5-cm drive Michelson interferometer during December 1970 and December 1973. The thermal emission spectrum of the central portion of the apparent disk was recorded from 450-1250 kaysers with an apodized spectral resolution of 0.25 kaysers. All statistically significant sharp line-absorption features in the spectrum have been identified with gaseous CO2. Comparison between the observed spectrum and a synthetic spectrum computed from a model atmosphere, assuming gaseous CO2 and a sulfuric acid haze as opacity sources, indicates good agreement. A broad diffuse absorption feature associated with the sulfuric acid haze is evident in the 870- to 930 kayser region. With the exception of the rotational lines of the 927 kayser CO2 band, the above feature appears as a continuum down to 0.25 kayser resolution. In the 750- to 1250 kayser range, the spectrum exhibits moderate thermal contrast with maximum brightness temperatures of 234-238 K occurring near 825 kaysers. These temperatures are in general agreement with previous measurements.

Kunde, V. G.↗

Stromgren Trails of Hot White Dwarfs

High resolution IUE spectra of Feige 24 reveal sharp C IV absorption features at both the stellar velocity and the velocity of the interstellar lines. It was shown that the ionization zone created by Feige 24 itself accounts for the interstellar components of C IV and Si IV, and that the density of hot white dwarfs in the galaxy implies that similar ionized zones around hot white dwarfs make a significant contribution to the C IV column densities observed toward distant O and B stars. Typical white dwarf velocities of around 30 km/s and C IV ionization zone diameters less than 1 pc imply that the crossing time is comparable to the ionization time, so that nonequilibrium ionization models are required. Models of the resulting elongated trails are presented.

Raymond, J. C.↗

Estimating the arrival times of photon-limited laser pulses in the presence of shot and speckle noise

Maximum-likelihood (ML) receivers are frequently used to optimize the timing performance of laser-ranging and laser-altimetry systems in the presence of shot and speckle noise. Monte Carlo method was used to examine ML-receiver performance with return signals in the 10-5000-photoelectron (pe) range. The simulations were performed for shot noise only and for shot and speckle noise. The results agree with previous theory for signal strengths greater than about 100 pe's but show that the theory can significantly underestimate timing errors for weaker received signals. Sharp high-bandwidth features in the detected signals are shown to improve timing performance only if their signal levels are greater than 4-5 pe's.

Abshire, James B.↗

Digging in the coronal graveyard - A Rosat observation of the red giant Arcturus

A deep exposure of the bright star Arcturus (Alpha Bootis: K1 III) with the Roentgensatellit (Rosat) failed to detect soft X-ray emission from the archetype 'noncoronal' red giant. The 3-sigma upper limit in the energy band 0.1-2.4 keV corresponds to an X-ray luminosity of less than 3 x 10 to the 25th erg/s, equivalent to a coronal surface flux density of less than 0.0001 solar. The nondetection safely eliminates coronal irradiation as a possible mechanism to produce the highly variable He I 10830 feature and emphasizes the sharp decline in solarlike coronal activity that accompanies the evolution of low-mass single stars away from the main sequence. While the most conspicuous object in the Rosat field of view was not visible in X-rays, at least one fainter star is among the about 60 sources recorded: the Sigma Sct variable CN Boo, an A8 giant in the UMa Stream.

Ayres, Thomas R.↗

An Acoustic Emission and Acousto-Ultrasonic Analysis of Impact Damaged Composite Pressure Vessels

The research presented herein summarizes the development of acoustic emission (AE) and acousto-ultrasonic (AU) techniques for the nondestructive evaluation of filament wound composite pressure vessels. Vessels fabricated from both graphite and kevlar fibers with an epoxy matrix were examined prior to hydroburst using AU and during hydroburst using AE. A dead weight drop apparatus featuring both blunt and sharp impactor tips was utilized to produce a single known energy 'damage' level in each of the vessels so that the degree to which the effects of impact damage could be measured. The damage levels ranged from barely visible to obvious fiber breakage and delamination. Independent neural network burst pressure prediction models were developed from a sample of each fiber/resin material system. Here, the cumulative AE amplitude distribution data collected from low level proof test (25% of the expected burst for undamaged vessels) were used to measure the effects of the impact on the residual burst pressure of the vessels. The results of the AE/neural network model for the inert propellant filled graphite/epoxy vessels 'IM7/3501-6, IM7/977-2 and IM7/8553-45' demonstrated that burst pressures can be predicted from low level AE proof test data, yielding an average error of 5.0%. The trained network for the IM7/977-2 class vessels was also able to predict the expected burst pressure of taller vessels (three times longer hoop region length) constructed of the same material and using the same manufacturing technique, with an average error of 4.9%. To a lesser extent, the burst pressure prediction models could also measure the effects of impact damage to the kevlar/epoxy 'Kevlar 49/ DPL862' vessels. Here though, due to the higher attenuation of the material, an insufficient amount of AE amplitude information was collected to generate robust network models. Although, the worst case trial errors were less than 6%, when additional blind predictions were attempted, errors as high as 50% were produced. An acousto-ultrasonic robotic evaluation system (AURES) was developed for mapping the effects of damage on filament wound pressure vessels prior to hydroproof testing. The AURES injects a single broadband ultrasonic pulse into each vessel at preprogrammed positions and records the effects of the interaction of that pulse on the material volume with a broadband receiver. A stress wave factor in the form of the energy associated with the 750 to 1000 kHz and 1000 to 1250 kHz frequency bands were used to map the potential failure sites for each vessel. The energy map associated with the graphite/epoxy vessels was found to decrease in the region of the impact damage. The kevlar vessels showed the opposite trend, with the energy values increasing around the damage/failure sites.

Walker, James L.↗