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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Small-Signal Angle Stability-Oriented False Data Injection Cyber-Attacks on Power Systems

The small-signal angle stability (SSAS) of a power system is determined by the property of operation points. The widely applied false data injection (FDI) cyber-attack, however, is able to stealthily mislead the optimal power flow (OPF) and thus compromise operation points, leading to damages to the SSAS margin. Here, to provide insights for cyber defenders, this paper proposes and investigates a stealthy SSAS-oriented FDI cyber-attack focusing on two attacking purposes, i.e., the SSAS margin and operation cost, with higher priority on the former one. First, this paper establishes a novel bi-level model with an implicit SSAS constraint based on a structure preserving model to compromise operation points. Then, for the SSAS interarea mode in a typical two-area system, this paper formulates closed-form expressions of how the SSAS margin and operation cost behave with respect to stealthy injections. By comparison, for the SSAS local mode in general power systems, this paper proposes a moving target cyber-attack-based hierarchical solution algorithm. Simulation results on a two-area system, a Kundur 11 bus system, and a modified IEEE 14 bus system demonstrate the significant damaging effects of the proposed SSAS-oriented FDI cyber-attack and the conflict between the two attacking purposes.

Benders decomposition↗
DOE OSTI2022

\(J/\psi \) and \(\psi (2S)\) Production in Small Systems with PHENIX

The suppression of the ψ(2S) nuclear modification factor has been seen as a trademark signature of final-state effects in large collision systems for decades. In small systems, deviations of the nuclear modification from unity had been attributed to cold nuclear matter effects until the observation of strong differential suppression of the ψ(2S) state in p/d+A collisions, which suggests the presence of final-state effects. Here in this paper, we present results of J/ψ and ψ(2S) measurements in the dimuon decay channel for p + p, p+Al, and p+Au collision systems at $\sqrt{s_{NN}}$ = 200 GeV. Key results include the nuclear modification factors R pA as a function of centrality and rapidity. The measurements are compared with shadowing and transport model predictions, as well as complementary measurements at LHC energies.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2014

Magic Numbers in Small Iron Clusters: A First-Principles Study

We perform ab initio spin-polarized density functional calculations of Fen aggregates with n ≤ 17 atoms to reveal the origin of the observed magic numbers, which indicate particularly high stability of clusters with 7, 13 and 15 atoms. Our results clarify the controversy regarding the ground state geometry of clusters such as Fe5and indicate that magnetism plays an important role in determining the stability and magic numbers in small iron clusters.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2017

Surface Pb nanoparticle aggregation, coalescence and differential capacitance in a deep eutectic solvent using a simultaneous sample-rotated small angle x-ray scattering and electrochemical methods approach [Surface Pb nanoparticle aggregation, coalescence and differential capacitance in a deep eutectic solvent using a simultaneous grazing transmission small angle x-ray scattering and electrochemical methods approach]

Nanoparticle electrodeposition is a simple and scalable approach to synthesizing supported nanoparticles. Used with a deep eutectic solvent (DES), surface nanoparticles can be assembled and exhibit unique surface charge separation when the DES is adsorbed on the nanoparticle surface. Key to understanding and controlling the assembly and the capacitance is a thorough understanding of surface particle mobility and charge screening, which requires an in-situ approach. In this study, Pb particle formation, size, shape and capacitance are resolved in a 1:2 choline Cl – : urea deep eutectic solvent whilst sweeping the cell potential in the range: 0.2 V to –1.2 V (vs. Ag/AgCl). These system parameters were resolved using a complementary suite of sample-rotated small angle X-ray scattering (SR-SAXS) and electrochemical impedance spectroscopy (EIS), which are presented and discussed in detail. This approach is able to show that both particle and ion transport are impeded in the DES, as aggregation occurs over the course of 6 minutes, and dissolved Pb ions accumulate and remain near the surface after a nucleation pulse is applied. The DES-Pb interactions strongly depend on the cell potential as evidenced by the specific differential capacitance of the Pb deposit, which has a maximum value of 2.5 +/– 0.5 F g –1 at –1.0 V vs. Ag/AgCl. Together, the SR-SAXS-EIS approach is able to characterize the unique nanoparticle capacitance, mobility and ion mobility in a DES and can be used to study a wide range of nanoparticle deposition systems in-situ .

36 MATERIALS SCIENCE↗
DOE OSTI2011

Impact of [{sup 18}F]Fluorodeoxyglucose PET-CT Staging on Treatment Planning in Radiotherapy Incorporating Elective Nodal Irradiation for Non-Small-Cell Lung Cancer: A Prospective Study;Non-small-cell lung cancer; PET; Radiotherapy; Elective nodal irradiation

Purpose: To evaluate prospectively how positron emission tomography (PET) information changes treatment plans for non-small-cell lung cancer (NSCLC) patients receiving or not receiving elective nodal irradiation (ENI). Methods and Materials: One hundred consecutive patients referred for curative radiotherapy were included in the study. Treatment plans were carried out with CT data sets only. For stage III patients, mediastinal ENI was planned. Then, patients underwent PET-CT for diagnostic/planning purposes. PET/CT was fused with the CT data for final planning. New targets were delineated. For stage III patients with minimal N disease (N0-N1, single N2), the ENI was omitted in the new plans. Patients were treated according to the PET-based volumes and plans. The gross tumor volume (GTV)/planning tumor volume (PTV) and doses for critical structures were compared for both data sets. The doses for areas of potential geographical misses derived with the CT data set alone were compared in patients with and without initially planned ENI. Results: In the 75 patients for whom the decision about curative radiotherapy was maintained after PET/CT, there would have been 20 cases (27%) with potential geographical misses by using the CT data set alone. Among them, 13 patients would receive ENI; of those patients, only 2 patients had the PET-based PTV covered by 90% isodose by using the plans based on CT alone, and the mean of the minimum dose within the missed GTV was 55% of the prescribed dose, while for 7 patients without ENI, it was 10% (p = 0.006). The lung, heart, and esophageal doses were significantly lower for plans with ENI omission than for plans with ENI use based on CT alone. Conclusions: PET/CT should be incorporated in the planning of radiotherapy for NSCLC, even in the setting of ENI. However, if PET/CT is unavailable, ENI may to some extent compensate for an inadequate dose coverage resulting from diagnostic uncertainties.

62 RADIOLOGY AND NUCLEAR MEDICINE↗
DOE OSTI2019

Long-range collectivity in small collision systems with two- and four-particle correlations at STAR

New STAR measurements of two- and four-particle (c 2 {4}) azimuthal angle correlations are reported for p+Au collisions at 200 GeV and d+Au collisions from 19.6 to 200 GeV. A negative c 2 {4}, consistent with collective anisotropic flow, is observed in high multiplicity d+Au events at 62.4 and 200 GeV where the statistical significance of the data allows an analysis. A template fitting method, employed to subtract non-flow contributions to the two-particle correlations, allows the extraction of the anisotropy coefficients (ν 2 ) for these systems at their respective energies. The ν 2 results for different energies show a common dependence on the charged particle multiplicity density ( < dN ch /dη > ), which provide important insight on the nature of collective behavior in small collision systems.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2017

Mixing Behavior in Small Molecule: Fullerene Organic Photovoltaics [On the Mixing Behavior in Small Molecule: Fullerene Organic Photovoltaics]

Here, we report a novel method to determine the amount of pure, aggregated phase of donor and acceptor in organic photovoltaic (OPV) bulk heterojunctions. By determination of the diffraction intensity per unit volume for both donor and acceptor, the volume content of pure, aggregated donor and acceptor in the blend can be determined. We find that for the small molecule X2:[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) system, in contrast to most polymer systems, all the PCBM is aggregated, indicating there is negligible miscibility of PCBM with X2. This provides an explanation why the performance of OPV devices of X2:PCBM are high over a large range of PCBM concentrations. This is in contrast to many other OPV blends, where PCBM forms a mixed phase with the donor and does not provide sufficient transport for electrons when the PCBM concentration is low. This study demonstrates that a mixed phase is not necessarily a requirement for good OPV device performance.

14 SOLAR ENERGY↗
DOE OSTI2018

Facilitating the Operation of Lithium-Ion Cells with High-Nickel Layered Oxide Cathodes with a Small Dose of Aluminum

Layered oxide cathodes with a high Ni content of >0.6 are promising for high-energy-density lithium-ion batteries. However, parasitic electrolyte oxidation of the charged cathode and mechanical degradation arising from phase transitions significantly deteriorate the cell performance and cycle life as the Ni content increases. Here we demonstrate here a significantly prolonged cycle life with superior cell performance by substituting a small-dose of Al (2 mol %) for Ni in LiNi 0.92 Co 0.06 Al 0.02 O 2 ; the capacity retention after operating a full cell fabricated with graphite anode for 1000 cycles increases from 47% to 83% on going from the Al-free LiNi 0.94 Co 0.06 O 2 to the Al-doped LiNi 0.92 Co 0.06 Al 0.02 O 2 cathode. Through in situ X-ray diffraction, we provide the operando evidence that the Al-doping tunes the H2–H3 phase transition process from a two-phase reaction to a quasi-monophase reaction, minimizing the mechanical degradation. Furthermore, secondary-ion mass spectrometry reveals considerably suppressed transition-metal dissolution with Al-doping, effectively preventing sustained parasitic reactions and active Li trapping due to chemical crossover on graphite anodes. This work offers a viable approach for adopting high-Ni cathodes in lithium-ion batteries.

25 ENERGY STORAGE↗
DOE OSTI2013

Effect of Small Molecule Osmolytes on the Self-Assembly and Functionality of Globular Protein-Polymer Diblock Copolymers

Blending the small molecule osmolytes glycerol and trehalose with the model globular protein–polymer block copolymer mCherry-b-poly(N-isopropyl acrylamide) (mCherry-b-PNIPAM) is demonstrated to improve protein functionality in self-assembled nanostructures. The incorporation of either additive into block copolymers results in functionality retention in the solid state of 80 and 100% for PNIPAM volume fractions of 40 and 55%, respectively. This represents a large improvement over the 50–60% functionality observed in the absence of any additive. Furthermore, glycerol decreases the thermal stability of block copolymer films by 15–20 °C, while trehalose results in an improvement in the thermal stability by 15–20 °C. These results suggest that hydrogen bond replacement is responsible for the retention of protein function but suppression or enhancement of thermal motion based on the glass transition of the osmolyte primarily determines thermal stability. While both osmolytes are observed to have a disordering effect on the nanostructure morphology with increasing concentration, this effect is less pronounced in materials with a larger polymer volume fraction. Glycerol preferentially localizes in the protein domains and swells the nanostructures, inducing disordering or a change in morphology depending on the PNIPAM coil fraction. In contrast, trehalose is observed to macrophase separate from the block copolymer, which results in nanodomains becoming more disordered without changing significantly in size.

Thomas, Carla S.↗