Search NASA⌕ Search

SEARCH · Search NASA

Results for “spectroscopic techniques”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Investigation of PTFE transfer films by infrared emission spectroscopy and phase-locked ellipsometry

When a PTFE sheet was rubbed unidirectionally over a smooth surface of stainless steel an essentially monomolecular transfer film was formed. by ellipsometric and emission infrared spectroscopic techniques it was shown that the film was 10 to 15 A thick and birefringent. From the intensity differences of infrared bands obtained with a polarizer passing radiation polarized in mutually perpendicular planes, it was possible to deduce transfer film orientation with the direction of rubbing. After standing in air for several weeks the transfer films apparently increased in thickness by as much as threefold. At the same time both the index of refraction and the absorption index decreased. Examination of the surfaces by optical and electron microscopies showed that the films had become porous and flaky. These observations were consistent with previous tribological measurements. The coefficients of friction decreased with the formation of the transfer film but increased again as the film developed breaks. The applicability of the ellipsometric and polarized infrared emission techniques to the identification of monomolecular tribological transfer films of polymers such as PTFE has been demonstrated.

Lauer, James L.↗
NASA NTRS1988

CCD camera system for cometary research

The objective is to upgrade the NASA/GSFC 36 inch telescope instrumentation, primarily with a new charge coupled device (CCD) camera system, to permit an effective monitoring program of cometary activity by means of narrowband imaging and spectroscopic techniques. Researchers have twice taken delivery of the CCD camera system from Princeton Scientific Instruments and twice returned it within six weeks for repair. During the times they had the camera system in the lab, they measured the instrumental performance of the TEK 512 x 512 CCD chip (e.g., readout noise, dark current, etc) and developed the complete operational software for the camera system plus several useful observing and data reduction routines for use at the telescope. The CCD camera system is controlled by an IBM-AT computer. The peripheral equipment and software to permit the efficient transfer of large amounts of data to the LASP's computers (VAXs) and subsequent timely reductions are also in place. The Io torus (S II) emission was monitored with a Fabry-Perot scanning spectrometer, in conjunction with the International Jupiter Watch. The CCD camera system will be coupled to a narrowband interference filter imager and a long-slit spectrograph to provide regular and well-calibrated spatial and spectral observations of comets.

Oliversen, R. J.↗
NASA NTRS1989

New transformations between crystalline and amorphous ice

High-pressure optical and spectroscopic techniques were used to obtain directly the ice I(h) - hda-ice transformation in a diamond-anvil cell, and the stability of the amorphous form is examined as functions of pressure and temperature. It is demonstrated that hda-ice transforms abruptly at 4 GPa and 77 K to a crystalline phase close in structure to orientationally disordered ice-VII and to a more highly ordered, ice-VIII-like structure at higher temperatures. This is the first time that an amorphous solid is observed to convert to a crystalline solid at low temperatures by compression alone. Phase transitions of this type may be relevant on icy planetary satellites, and there may also be implications for the high-pressure behavior of silica.

Hemley, R. J.↗
NASA NTRS1989

The origin, composition and history of cometary ices from spectroscopic studies

The spectroscopic analysis of pristine cometary material provides a very important probe of the chemical identity of the material as well as of the physical and chemical conditions which prevailed during the comet's history. Concerning classical spectroscopy, the spectral regions which will most likely prove most useful are the infrared, the visible and ultraviolet. Newer spectroscopic techniques which have the potential to provide equally important information include nuclear magnetic resonance (NMR) and electron spin resonance (ESR). Each technique is summarized with emphasis placed on the kind of information which can be obtained.

Allamandola, L. J.↗
NASA NTRS1991

Laser Spectroscopic Measurement Of Temperature And Density

Report discusses research on use of laser-induced fluorescence in oxygen and Raman scattering in air for simultaneous measurement of temperature and density of air. Major application of laser spectroscopic techniques, measurement of fluctuations of temperature and density in hypersonic flows in wind tunnels.

Mckenzie, Robert L.↗
NASA NTRS1991

Ultrafast IR detector response in high Tc superconducting thin films

The response from a high Tc superconducting multielement optical detector made of a laser deposited Y-Ba-Cu-O thin film has been evaluated. Several microscopic and spectroscopic techniques were used to establish the presence of the correct phase of the thin film. Optical pulses from a laser diode at 830 nm and from a Q-switched CO2-laser at 10.6 microns were used. The detector responded to 50 ps (FWHM) pulses. A comparison between dR/dT of the film and the response amplitude as a function of temperature indicated a bolometric response.

Lindgren, Mikael↗
NASA NTRS1991

Detectability of Martian carbonates from orbit using thermal neutrons

Numerical simulations of Martian neutron leakage flux spectra are made in order to explore the detectability of magnesium and calcium carbonate deposits using neutron spectroscopic techniques from orbit. The primary signature of such deposits is found to be an enhanced thermal amplitude. Although this enhancement is weakened by: (1) partial burial beneath an aeolian regolith blanket; (2) admixture with regolith on a microscopic (centimeter) or macroscopic (tens of centimeters) scale; and (3) reduction in the areal size of the deposit, near-surface stratigraphies of carbonates hypothesized by some authors as possible on Mars are still detectable by simple neutron sensors from orbit. However, the large variations in the magnitude of the thermal neutron enhancements caused by different carbonate deposit configurations found in this study require a combined gamma ray and neutron analysis for their unique specification.

Feldman, W. C.↗
NASA NTRS1992

State-to-state rotational energy-transfer measurements in the nu(2) = 1 state of ammonia by infrared-infrared double resonance

The state-resolved rotational (R-R, R-T) energy transfer in (N-14)H3 (for NH3-NH3 and NH3-Ar collisions) was studied using an IR double-resonance laser spectroscopic technique. Measurements of both the total rate of depopulation by collisions, and the rates of transfer into specific final rovibrational states (v,J,K) were performed using time-resolved tunable diode laser absorption spectroscopy. A kinetic master-equation analysis of time-resolved level populatons was carried out, yielding state-to-state rate constants and propensity rules for NH3-NH3 and NH3-Ar collisions.

Abel, Bernd↗
NASA NTRS1993

The APX Spectrometer for Martian Missions

Obtaining the chemical composition of any planetary body should be a prime science objective of each planetary mission. The APX spectrometer has been designed to provide a detailed and complete chemical composition of all major (except H) and minor elements with high accuracy, in situ and remotely. From such complete analyses a first-order mineralogy of analyzed samples can be deduced. Laboratory studies in the past have shown that rock types (e.g., dunites, basalts, Philippinate 300 sample) were a uniquely in blind test analyses. Such identification is more accurate than can be obtained from any other remote spectroscopic technique. The APX technique is based on three modes of nuclear and atomic interactions of alpha particles with matter resulting in three different energy spectra containing the compositional information. The instrument uses 50 to 100 mCi of Cm-242 or Cm-244 transuranium radioisotopes to provide a monoenergetic beam of alpha particles (6.01 MeV and 5.80 MeV respectively) and solid-state detectors for acquiring the energy spectra.

Economou, T.↗
NASA NTRS1993

Electron beam flourescence measurements in low density free jets of heated nitrogen

Rotational temperatures have been measured in heated free jet expansions of low density nitrogen using the electron beam flourescence technique. Spectroscopic measurements of the (0,0) band of the first negative system of nitrogen revealed the rotational nonequilibrium behavior in the flow field upstream of and through the Mach disk, as well as the flow field farther downstream. These results are compared to free jet expansion data and computations regarding Mach disk location and terminal rotational temperature. Comparisons indicate a rotational relaxation-collision number of about 3. Both measurements and calculations show that these flow fields are generated from stagnation conditions of 240 to 475 Torr-mm and 700 to 1325 K. Results are also presented for shock thickness based on rotational temperature.

Gochberg, L. A.↗
NASA NTRS1992

Potentiostatic and ac impedance studies of the hydrogen electrodes used in Ni/H2 batteries

In a study of electrode activity for hydrogen evolution and hydrogen ionization, knowledge of the detailed kinetics and of the surface coverage by adsorbed hydrogen is essential. In the Ni/H2 battery, the hydrogen electrode is subjected to high hydrogen pressure; elucidation of the variation of kinetic parameters with hydrogen pressure is therefore of interest. Potentiostatic and ac impedance spectroscopic techniques were used in the present study. The equivalent circuit of the reaction, the kinetic parameters, and their pressure dependence have been determined.

Le Helloco, Jean-Guy↗
NASA NTRS1993

Simulated space environmental effects on a polyetherimide and its carbon fiber-reinforced composites

The selection of materials for spacecraft construction requires identification of candidate materials which can perform reliably in the space environment. Understanding the effects of the space environment on the materials is an important step in the selection of candidate materials. This work examines the effects of energetic electrons, thermal cycling, electron radiation in conjunction with thermal cycling, and atomic oxygen on a thermoplastic polyetherimide and its carbon-fiber-reinforced composites. Composite materials made with non-sized fibers as well as materials made with fibers sized with an epoxy were evaluated. The mechanical and thermomechanical properties of the materials were studied and spectroscopic techniques were used to investigate the mechanisms for the observed effects. Considerations for future material development are suggested.

Kern, Kristen T.↗
NASA NTRS1992

Studies of radiative emission from the simulated shock layer of the Huygens probe

An investigation has been conducted to determine the radiative heating of the Huygens probe. The shock tube facility at Stanford University was used to generate plasma behind strong shocks, which simulates the flow field around the probe. Spectroscopic techniques have been used to measure thermophysical quantities of the plasma in the shock tube. A numerical code has been developed using a three temperature model in order to generate one dimensional flow field solutions for comparison with these experimental data. Based on this analysis, the radiative heat transfer at the stagnation point of the prove was approximated.

Park, C. S.↗
NASA NTRS1993

The abundance of sulfur dioxide below the clouds of Venus

We present a new method for determining the abundance of sulfur dioxide below the clouds of Venus. Absorption by the 3nu3 band of SO2 near 2.45 microns has been detected in high-resolution spectra of the night side of Venus recorded at the Canada-France Hawaii telescope in 1989 and 1991. The inferred SO2 abundance is 130 +/- 40 ppm at all observed locations and pertains to the 35-45 km region. These values are comparable to those measured by the Pioneer Venus and Venera 11/12 entry probes in 1978. This stability stands in contrast to the apparent massive decrease in SO2 observed at the cloud tops since these space missions. These results are consistent with laboratory and modeling studies of the SO2 destruction rates in the lower atmosphere of Venus. The new spectroscopic technique presented here allows a remote monitoring of the SO2 abundance below the clouds, a likely tracer of Venusian volcanism.

Bezard, Bruno↗
NASA NTRS1995

High temperature kinetic study of the reactions H + O2 = OH + O and O + H2 = OH + H in H2/O2 system by shock tube-laser absorption spectroscopy

The reactions: (1) H + O2 = OH + O; and (2) O + H2 = OH + H are the most important elementary reactions in gas phase combustion. They are the main chain-branching reaction in the oxidation of H2 and hydrocarbon fuels. In this study, rate coefficients of the reactions and have been measured over a wide range of composition, pressure, density and temperature behind the reflected shock waves. The experiments were performed using the shock tube - laser absorption spectroscopic technique to monitor OH radicals formed in the shock-heated H2/O2/Ar mixtures. The OH radicals were detected using the P(1)(5) line of (0,0) band of the A(exp 2) Sigma(+) from X(exp 2) Pi transition of OH at 310.023 nm (air). The data were analyzed with the aid of computer modeling. In the experiments great care was exercised to obtain high time resolution, linearity and signal-to-noise. The results are well represented by the Arrhenius expressions. The rate coefficient expression for reaction (1) obtained in this study is k(1) = (7.13 +/- 0.31) x 10(exp 13) exp(-6957+/- 30 K/T) cu cm/mol/s (1050 K less than or equal to T less than or equal to 2500 K) and a consensus expression for k(1) from a critical review of the most recent evaluations of k(1) (including our own) is k(1) = 7.82 x 10(exp 13) exp(-7105 K/T) cu cm/mol/s (960 K less than or equal to T less than or equal to 5300 K). The rate coefficient expression of k(2) is given by k(2) = (1.88 +/- 0.07) x 10(exp 14) exp(-6897 +/- 53 K/T) cu cm/mol/s (1424 K less than or equal to T less than or equal to 2427 K). For k(1), the temperature dependent A-factor and the correlation between the values of k(1) and the inverse reactant densities were not found. In the temperature range of this study, non-Arrhenius expression of k(2) which shows the upward curvature was not supported.

Ryu, Si-Ok↗
NASA NTRS1994

Oscillator strengths of selected resonance transitions in neutral sulfur

Mean lives and branching ratios for the 4s (3)S(sup 0 sub 1) and 4s(double prime) (3)P(sup 0 sub 1, 2) levels of neutral sulfur were determined at the Toledo Heavy Ion Accelerator using beam-foil spectroscopic techniques. The mean lives obtained for the 4s (3)S(sup 0 sub 1) 4s(double prime) (3)P(sup 0 sub 1), and (3)P(sup 0 sub 2) levels, 1.875 +/- 0.094 ns, 2.034 +/- 0.102 ns, and 2.146 +/- 0.129 ns, respectively, represent the most accurate results available to date. Oscillator strengths for the transitions 3p(sup 4)(3)P(sub 2, 1, 0)-4s (3)S(sup 0 sub 1) and 3p(sup 4)(3)P(sub 2, 1, 0)-4s(double prime) (3)P(sup 0 sub 1, 2) were derived from these mean lives together with the measured branching ratios. For comparison with published results which present only multiplet f-values, such f-values were computed from the measured individual line oscillator strengths. The value obtained for the 3p(sup 4)(3)P-4s(sup 3)S(sup 0) multiplet at 1814 A is 0.088 +/- 0.005, in good agreement with the mean of previous experimental measurements and theoretical calculations. With the mean life for the 4s(double prime) 3P(sup 0 sub 0) level set equal to the mean of our determination for the other two 4s(double prime) (3)P(sup 0) levels (a valid assumption for LS coupling conditions, and consistent with the observed equality of the mean lives within the accuracy of our measurement), an oscillator strength for the 1299 A multiplet of 0.121 +/- 0.004 was found. Both results are in good agreement with recent large-scale theoretical calculations that incorporate the effects of configuration interaction.

Beideck, D. J.↗
NASA NTRS1995

Spectroscopic Measurement Of Temperature And Pressure of O(2)

Spectroscopic technique useful in measuring temperature and pressure of oxygen in laboratory experiments involving high temperatures and/or high pressures. Devised for use in experiments in which oxygen or gas containing oxygen subjected to sudden adiabatic compression, as in shock tube. Also useful in combustion experiments and other experiments in which gaseous oxygen plays role.

Tapphorn, Ralph M.↗
NASA NTRS1993

Experimental and analytical ion thruster research

The results of further spectroscopic studies on the plume from a 3 cm ion source operated on an argon propellant is reported on. In particular, it is shown that it should be possible to use the spectroscopic technique to measure the plasma density of the ion plume close to the grids, where it is difficult to use electrical probe measurements. How the technique, along with electrical probe measurements in the far downstream region of the plume, can be used to characterize the operation of a three-grid, 15 cm diameter thruster from NASA JPL is outlined. Pumping speed measurements on the Vacuum Research Facility have shown that this facility should be adequate for testing the JPL thruster at pressures in the low 10(exp -5) Torr range. Finally, we describe a simple analytical model which can be used to calculate the grid impingement current which results from charge-exchange collisions in the ion plume.

Ruyten, Wilhelmus M.↗