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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Uranium Nitride as LWR TRISO Fuel: Thermodynamic Modeling of U-C-N and Thermomechanics

A new concept for light water reactor (LWR) nuclear fuel has recently been proposed that utilizes pellets of tristructural isotropic (TRISO) fuel particles embedded in a SiC or zirconium alloy matrix, replacing sintered urania pellets. The fuel is considered significantly more accident tolerant than urania as the SiC matrix or coated/protected zirconium alloy and TRISO particles would be highly resistant to oxidation and fission product release under beyond-design-basis accident conditions. As is well understood, failed fuel rods release gaseous and volatile fission products, and that is greatly exacerbated as urania oxidizes from UO 2+x to higher oxidations states in failed fuel pin with resulting expansion, loss of integrity, and significant further release of fission products.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Improving the Thermomechanical Stability of High Efficiency Perovskite Solar Cells via Polymeric Nanofiber Reinforcement

We show that the mechanical stability of perovskite thin films can be increased by an order of magnitude by nanocompositing with polymeric nanofibers using a scalable method. We discuss the increase in fracture resistance energy, Gc, in the nanocomposite samples with respect to nanofiber orientation. We demonstrate this platform with commodity polymeric nanofibers including nylon-6,6 and polyvinyl alcohol. The fiber network reduces the mechanical fragility of the PSCs by increasing their fracture energy several-fold, while maintaining comparable morphology, chemical composition, and device efficiencies to pristine perovskite. Improved power conversion efficiency stability of the nanocomposites under accelerated aging conditions is demonstrated. This platform is a promising advance toward the commercial viability of PSCs.

Samoylov, Anton↗

EIC ESR beam position monitors thermal and thermomechanical study preliminary design

The Electron Ion Collider (EIC) Electron Storage Ring (ESR) Beam Position Monitors (BPM) are designed to monitor the electron beam orbit position on a turn-by-turn and bunch-by-bunch basis in the vacuum chamber. Large variations in ESR fill pattern and bunch intensity imposes a large dynamic range on the BPM system design. And given the large ESR beam current - up to 2.5 A with 1160 x 20 nC bunches – the heating by synchrotron radiation (SR) and beam impedance is a significant concern. The high energy of the electrons – up to 18 GeV – leads to scat tering of the SR that produces high radiation doses and as sociated heating of structures away from the SR impact area. Because of this intense heating, and stringent position stability requirements, an in-depth engineering analysis was carried out. This paper will review the analysis made of the preliminary design and its main outcomes.

43 PARTICLE ACCELERATORS↗

Improving perovskite solar module stability by understanding and mitigating scribe-induced chemo-thermomechanical degradation

Recognizing the correlation between the design of perovskite solar module (PSM) and their degradation mechanisms under environmental stressors helps to enable their long- term reliability. This work reports on the impact of the hole-transport layer (HTL) on thermal cyclability and degradation mechanisms of p-i-n PSMs by comparing 3 HTLs: NiO x , MeO-2PACz (a self-assembled monolayer), and a bilayer HTL of MeO-2PACz on NiO x . We observe surprising thermal cyclability from a performance standpoint despite generating clear degradation products. We find that without a fully dense HTL, seemingly insignificant moisture/oxygen ingress through the edge of the PSMs can lead to rapid destabilization of the metal halide perovskite (MHP) layer due to reactions between MHP degradation byproducts and the indium-tin oxide layer. We also show that illumination-induced cation phase segregation is dependent on the presence of an inactive area (regions of the substrate uncovered by the top electrode). As such, we find that a dense interface between the MHP and ITO is necessary for chemically robust PSMs and highlight criteria for testing field-relevant configurations in lab-scale architectures.

14 SOLAR ENERGY↗

Multiscale Thermomechanical Damage Model with Internal State Variables for Ceramic Matrix Composites

A length scale-dependent matrix damage model has been developed to simulate the response of ceramic matrix composites (CMCs). This model captures damage initiation and propagation in the brittle matrix material by employing internal state variable (ISV) theory within a multiscale modeling framework to obtain damaged matrix stress-strain constitutive relationships at each length scale. Material degradation due to matrix cracking is captured by a damage variable determined using fracture mechanics and the self-consistent scheme. An additional state variable is introduced to capture the nucleation and growth of matrix porosity, a key mechanism contributing to matrix nonlinearity. Porosity occurs as a result of material diffusion around grain boundaries and the growth of the porosity state variable is related to the material entropy dissipation and the volumetric strain. The nonlinear predictive capabilities of the material model are demonstrated for monolithic silicon carbide, unidirectional (UD) carbon fiber/silicon carbide matrix (C/SiC) CMC, and five-harness satin (5HS) woven C/SiC CMC.

Skinner, Travis D.↗

Thermomechanical Properties of Neutron Irradiated Al 3 Hf-Al Thermal Neutron Absorber Materials

A thermal neutron absorber material composed of Al 3 Hf particles in an aluminum matrix is under development for the Advanced Test Reactor. This metal matrix composite was fabricated via hot pressing of high-purity aluminum and micrometer-size Al 3 Hf powders at volume fractions of 20.0, 28.4, and 36.5%. Room temperature tensile and hardness testing of unirradiated specimens revealed a linear relationship between volume fraction and strength, while the tensile data showed a strong decrease in elongation between the 20 and 36.5% volume fraction materials. Tensile tests conducted at 200 °C on unirradiated material revealed similar trends. Evaluations were then conducted on specimens irradiated at 66 to 75 °C to four dose levels ranging from approximately 1 to 4 dpa. Tensile properties exhibited the typical increase in strength and decrease in ductility with dose that are common for metallic materials irradiated at ≤0.4T m . Hardness also increased with neutron dose. The difference in strength between the three different volume fraction materials was roughly constant as the dose increased. Nanoindentation measurements of Al 3 Hf particles in the 28.4 vol% material showed the expected trend of increased hardness with irradiation dose. Transmission electron microscopy revealed oxygen at the interface between the Al 3 Hf particles and aluminum matrix in the irradiated material. Scanning electron microscopy of the exterior surface of tensile tested specimens revealed that deformation of the material occurs via plastic deformation of the Al matrix, cracking of the Al 3 Hf particles, and to a lesser extent, tearing of the matrix away from the particles. The fracture surface of an irradiated 28.4 vol% specimen showed failure by brittle fracture in the particles and ductile tearing of the aluminum matrix with no loss of cohesion between the particles and matrix. The coefficient of thermal expansion decreased upon irradiation, with a maximum change of –6.3% for the annealed irradiated 36.5 vol% specimen.

36 MATERIALS SCIENCE↗