Deciphering Dynamic Structural and Mechanistic Complexity in Cu/CeO2/ZSM-5 Catalysts for the Reverse Water-Gas Shift Reaction
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99 GENERAL AND MISCELLANEOUS↗
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Parametric Study of the Influence of Support Type, Presence of Platinum on Support, and Ionomer Content on the Microstructure of Polymer Electrolyte Fuel Cell Catalyst Layers
We report Ultra-small angle X-ray scattering (USAXS) was employed to investigate the effects of carbon support type, the presence of platinum on carbon, and ionomer loading on the microstructure of polymer electrolyte fuel cell (PEFC) catalyst layers (CLs). Particle size distributions (PSDs), obtained from fitting the measured scattering data were used to interpret the size of carbon aggregates (40–300 nm) and agglomerates (>400 nm) from two-component carbon/ionomer and three-component platinum/carbon/ionomer CLs. Two types of carbon supports were investigated: high surface area carbon (HSC) and Vulcan XC-72. CLs with a range of perfluorosulfonic acid (PFSA) ionomer to carbon (I/C) ratios (0.2–1.2) and also with perfluoroimide acid (PFIA) ionomer were studied to evaluate the effect of ionomer on CL microstructure. The carbon type, the presence of platinum, and ionomer loading were all found to significantly impact carbon agglomeration. The extent of Pt/C agglomeration in the CL was found to increase with increasing ionomer and platinum concentration and to decrease with increasing carbon surface area. Platinum electrochemically-active surface area (ECSA) and local oxygen transport resistance (R nF ) were correlated to the CL microstructure to yield relationships affecting electrode performance.
25 ENERGY STORAGE↗
Corrosion of simulated bearing components of three bearing steels in the presence of chloride-contaminated lubricant
Corrosion tests were run with AISI 52100, AISI M-50 and AMS 5794 under conditions that simulate the crevice corrosion found in aircraft ball and roller bearings rejected at overhaul for corrosion. Test specimens were fabricated that simulated the contacts of balls or rollers and the raceways. Corrosion cells were assembled in the presence of a lubricant contaminated with water and chloride ions. The cell was then thermally cycled between 339 K (150 F) and 276 K (37 F). The corrosion observed after 14 cycles was that of crevice and pitting corrosion typically found in aircraft bearings. AMS 5749 showed a very slight amount of corrosion. No appreciable differences were noted between AISI 52100 and AISI M-50, but both showed much greater corrosion than AMS 5749. The corrosion pits observed in AISI M-50 appeared to be fewer in number but generally deeper and larger than in AISI 52100.
Parker, R. J.↗
High angular resolution infrared mapping of the compact H II regions W51 and DR 21/W75
Far-infrared maps of W51/G49.5-0.4, W51/G49.4-0.3, and the DR 21 W75 S regions are presented. The simultaneous 50 and 100 micron maps enable a determination of the dust temperature and density structure in these areas. In G49.5-0.4 a luminosity and dust column-density peak at the position of the W51-Main maser is found, suggesting that this is the dominant luminosity source in W51. In G49.4-0.3 three components associated with the three known 2.7 GHz sources are resolved. A comparison of the total far-infrared luminosity with the radio continuum brightness in both G49.5-0.4 and G49.4-0.3 shows that the ratio of Lyman continuum to total luminosity of the exciting stars in not consistent with excitation by a single ZAMS star if most of the Lyman continuum photons are being absorbed bay gas rather than dust. In DR 21 micron far-infrared data and some new 2-20 micron results reveal a region of hot dust associated with the 2 micron H2 emission to the east and west of DR 21. Finally, a new 1.5-100 micron 'protostellar' source 2 deg north of W75 S at the position of a 1 mm continuum peak is reported.
Harvey, P. M.↗
Three-dimensional boundary layer flow with streamwise adverse pressure gradient
The present study examines the effects of a strong adverse pressure gradient on a 3D turbulent boundary layer in an axisymmetric spinning cylinder geometry. Velocity measurements made with a three-component laser Doppler velocimeter include all three mean flow components, all six Reynolds stress components, and all ten triple-product correlations. Total Reynolds shear stress diminishes as the flow becomes 3D. Lower levels of shear stress were found to persist under adverse pressure gradient conditions. This low stress level was observed to roughly correlate with the magnitude of the crossflow. Variations in the pressure gradient do not alter this correlation. It is inferred that a 3D boundary layer is more prone to separate than a 2D boundary layer.
Driver, David M.↗
Technology for Smoother Transit
Langley Research Center has developed a portable, self contained ride quality meter for accessing ride quality during vehicle operation. System is applicable to air, sea, road, or track vehicles for estimating passenger ride comfort in the presence of complex vibrations and interior noise. Meter has three components: a package of three vibration sensors, a microphone, and a computer. Installed on the floor of the vehicle being tested, sensors measure vibrations in five different axes, microphone measures noise level, and computer processes input from both and gives user a printed readout including a number of options for assessing ride quality.
Source record↗
Interferometric Estimation of theThree-Dimensional Ice-Flow Velocity Vector Using Ascending and Descending Passes
Satellite radar interferometry provides an importatn new tool for determining ice-flow velocity. Interferometric measurements made from a single track direction are sensitive only to a single component of the three-dimensional velocity vector. Observations from along thre different track directions would allow the full velocity vector to be determined. A north/south-looking SAR could provide these observations over large portions of the globe but not over large areas of the polar ice sheets. We develop and demonstrate a technique that allows the full three-component velocity vector to be determined from data acquired along two track directions (ascending and descending) under a surface-parallel flow assumption.
interferometry satellite radar interferometry ice-↗
Turbulent solution of the Navier-Stokes equations for uniform shear flow
To study the nonlinear physics of uniform turbulent shear flow, the unaveraged Navier-Stokes equations are solved numerically. This extends our previous work in which mean gradients were absent. For initial conditions, modified three-dimensional-cosine velocity fluctuations are used. The boundary conditions are modified periodic conditions on a stationary three-dimensional numerical grid. A uniform mean shear is superimposed on the initial and boundary conditions. The three components of the mean-square velocity fluctuations are initially equal for the conditions chosen. As in the case of no shear the initially nonrandom flow develops into an apparently random turbulence at higher Reynolds number. Thus, randomness or turbulence can apparently arise as a consequence of the structure of the Navier-Stokes equations. Except for an initial period of adjustment, all fluctuating components grow with time. The initial equality of the three intensity components is destroyed by the shear, the transverse components becoming smaller than the longitudinal one, in agreement with experiment. Also, the shear creates a small-scale structure in the turbulence. The nonlinear solutions are compared with linearized ones.
Deissler, R. G.↗
Statistical study of ULF wave occurrence in the dayside magnetosphere
Ultralow-frequency (ULF) waves are observed almost everywhere in the dayside magnetosphere. The mechanism by which these waves are generated and transformed in the dayside magnetosphere is still not understood. Here we report a statistical study of these waves based on magnetic field data from the International Sun-Earth Explorer 1 (ISEE 1) spacecraft. Data from the first traversal of the spacecraft through the entire dayside magnetosphere have been examined to determine the spatial distribution of wave occurrence. Successive 20-min segments of data were transformed to a field-aligned coordinate system. The parallel component was detrended and all three components of the field spectrally analyzed. Wave occurrence was defined by the presence of significant peaks in the power spectra. Wave events were categorized by three wave frequency bands: Pc 3 with T approximately 10-45 s; Pc 4 with T approximately 45-150 s; the short-period part of the Pc 5 wave band with T approximately 150-324 s. Properties of the spectral peaks were then entered into a data base. The data base was next sorted to determine the spatial occurrence pattern for the waves. Our results show that Pc 3 waves most frequently occur just outside synchronous orbit and are approximately centered on local noon. Pc 4 waves have a similar distribution with its peak further out. Pc 5 waves have high occurrence rate at the two flanks of the magnetosphere. Peaks in spectra obtained near the magnetopause are less clearly defined than those deeper in the magnetosphere.
Cao, M.↗
Optical, infrared and radio studies of compact H II regions. I - The complex in S 106
The paper reports on combined optical, infrared, and radio observations of the compact complex S 106. The source could be resolved into ten components, three of which are compact components of size approximately 0.2 pc and were detected at 12.6 microns and 2.7 GHz. Two of the components are point-like sources detected at 8000 A. One of the components detected at 8000 A is spatially coincident with a strong 3.5 micron source and is suggested as a possible exciting star for the complex.
Pipher, J. L.↗
Investigation of digital encoding techniques for television transmission
Composite color television signals are sampled at four times the color subcarrier and transformed using intraframe two dimensional Walsh functions. It is shown that by properly sampling a composite color signal and employing a Walsh transform the YIQ time signals which sum to produce the composite color signal can be represented, in the transform domain, by three component signals in space. By suitably zonal quantizing the transform coefficients, the YIQ signals can be processed independently to achieve data compression and obtain the same results as component coding. Computer simulations of three bandwidth compressors operating at 1.09, 1.53 and 1.8 bits/ sample are presented. The above results can also be applied to the PAL color system.
Schilling, D. L.↗
Preference for internucleotide linkages as a function of the number of constituents in a mixture
Phosphoimidazolide-activated ribomononucleotides (*pN; see Scheme I) are useful substrates for the nonenzymatic synthesis of oligonucleotides. In the presence of metal ions dilute neutral aqueous solutions of *pN (0.01 M) typically yield only small amounts of dimers and traces of oligomers; most of *pN hydrolyzes to yield nucleoside 5'-monophosphate (5'NMP). An earlier investigation of *pN reactions in highly concentrated aqueous solutions (up to 1.4 M) showed, as expected, that the percentage yield of the condensation products increases and the yield of the hydrolysis product correspondingly decreases with *pN concentration (Kanavarioti 1997). Here we report product distributions in reactions with one, two, or three reactive components at the same total nucleotide concentration. *pN used as substrates were the nucleoside 5'-phosphate 2-methylimidazolides, 2-MeImpN, with N = cytidine (C), uridine (U), or guanosine (G). Reactions were conducted as self-condensations, i. e., one nucleotide only, with two components in the three binary U,C, U,G, and C,G mixtures, and with three components in the ternary U,C, G mixture. The products are 5'NMP, 5',5'-pyrophosphate-, 2',5'-, 3', 5'-linked dimers, cyclic dimers, and a small percentage of longer oligomers. The surprising finding was that, under identical conditions, including the same total monomer concentration, the product distribution differs substantially from one reaction to another, most likely due to changing intermolecular interactions depending on the constituents. Even more unexpected was the observed trend according to which reactions of the U,C,G mixture produce the highest yield of internucleotide-linked dimers, whereas the self-condensations produce the least and the reactions with the binary mixtures produce yields that fall in between. What is remarkable is that the approximately two-fold increase in the percentage yield of internucleotide-linked dimers is not due to a concentration effect or a catalyst, but to the increased complexity of the system from a single to two and three components. These observations, perhaps, provide an example of how increased complexity in relatively simple chemical systems leads to organization of the material and consequently to chemical evolution. A possible link between prebiotic chemistry and the postulated RNA world is discussed.
NASA Discipline Exobiology↗
Reynolds shear stress measurements in a separated boundary layer flow
Turbulence measurements were obtained for two cases of boundary layer flow with an adverse pressure gradient, one attached and the other separated. A three-component laser Doppler velocimeter system was used to measure three mean velocity components, all six Reynolds stress components, and all ten velocity triple product correlations. Independent measurements of skin-friction obtained with a laser oil-flow interferometer were used to examine the law of the wall in adverse pressure gradient flows where p(+) is less than 0.05. Strong similiarities were seen between the two adverse pressure gradient flows and free shear layer type flows. Eddy viscosities, dissipation rates, and pressure-strain rates were deduced from the data and compared to various turbulence modeling assumptions.
Driver, David M.↗
[Determination of six main components in compound theophylline tablet by convolution curve method after prior separation by column partition chromatography]
On a partition chromatographic column in which the support is Kieselguhr and the stationary phase is sulfuric acid solution (2 mol/L), three components of compound theophylline tablet were simultaneously eluted by chloroform and three other components were simultaneously eluted by ammonia-saturated chloroform. The two mixtures were determined by computer-aided convolution curve method separately. The corresponding average recovery and relative standard deviation of the six components were as follows: 101.6, 1.46% for caffeine; 99.7, 0.10% for phenacetin; 100.9, 1.31% for phenobarbitone; 100.2, 0.81% for theophylline; 99.9, 0.81% for theobromine and 100.8, 0.48% for aminopyrine.
NASA Program Flight↗
XRISM Spectroscopy of the Fe Kα Emission Line in the Seyfert Active Galactic Nucleus NGC 4151 Reveals the Disk, Broad-line Region, and Torus
Abstract We present an analysis of the first two XRISM/Resolve spectra of the well-known Seyfert-1.5 active galactic nucleus (AGN) in NGC 4151, obtained in 2023 December. Our work focuses on the nature of the narrow Fe K α emission line at 6.4 keV, the strongest and most common X-ray line observed in AGN. The total line is found to consist of three components. Even the narrowest component of the line is resolved with evident Fe K α ,1 (6.404 keV) and K α ,2 (6.391 keV) contributions in a 2:1 flux ratio, fully consistent with neutral gas with negligible bulk velocity. Subject to the limitations of our models, the narrowest and intermediate-width components are consistent with emission from optically thin gas, suggesting that they arise in a disk atmosphere and/or wind. Modeling the three line components in terms of Keplerian broadening, they are readily associated with (1) the inner wall of the “torus,” (2) the innermost optical “broad-line region” (or “X-ray BLR”), and (3) a region with a radius of r ≃ 100 GM / c 2 that may signal a warp in the accretion disk. Viable alternative explanations of the broadest component include a fast-wind component and/or scattering; however, we find evidence of variability in the narrow Fe K α line complex on timescales consistent with small radii. The best-fit models are statistically superior to simple Voigt functions, but when fit with Voigt profiles the time-averaged lines are consistent with a projected velocity broadening of FWHM = 1600 − 200 + 400 km s − 1 . Overall, the resolution and sensitivity of XRISM show that the narrow Fe K line in AGN is an effective probe of all key parts of the accretion flow, as it is currently understood. We discuss the implications of these findings for our understanding of AGN accretion, future studies with XRISM, and X-ray-based black hole mass measurements.
Audard, Marc (ORCID:000000034721034X)↗
Forced free-shear layer measurements
Detailed three-dimensional three-component phase averaged measurements of the spanwise and streamwise vorticity formation and evolution in acoustically forced plane free-shear flows have been obtained. For the first time, phase-averaged measurements of all three velocity components have been obtained in both a mixing layer and a wake on three-dimensional grids, yielding the spanwise and streamwise vorticity distributions without invoking Taylor's hypothesis. Initially, two-frequency forcing was used to phase-lock the roll-up and first pairing of the spanwise vortical structures in a plane mixing layer. The objective of this study was to measure the near-field vortical structure morphology in a mixing layer with 'natural' laminar initial boundary layers. For the second experiment the second and third subharmonics of the fundamental roll-up frequency were added to the previous two-frequency forcing in order to phase-lock the roll-up and first three pairings of the spanwise rollers in the mixing layer. The objective of this study was to determine the details of spanwise scale changes observed in previous time-averaged measurements and flow visualization of unforced mixing layers. For the final experiment, single-frequency forcing was used to phase-lock the Karman vortex street in a plane wake developing from nominally two-dimensional laminar initial boundary layers. The objective of this study was to compare measurements of the three-dimensional structure in a wake developing from 'natural' initial boundary layers to existing models of wake vortical structure.
Leboeuf, Richard L.↗
On computations of the integrated space shuttle flowfield using overset grids
Numerical simulations using the thin-layer Navier-Stokes equations and chimera (overset) grid approach were carried out for flows around the integrated space shuttle vehicle over a range of Mach numbers. Body-conforming grids were used for all the component grids. Testcases include a three-component overset grid - the external tank (ET), the solid rocket booster (SRB) and the orbiter (ORB), and a five-component overset grid - the ET, SRB, ORB, forward and aft attach hardware, configurations. The results were compared with the wind tunnel and flight data. In addition, a Poisson solution procedure (a special case of the vorticity-velocity formulation) using primitive variables was developed to solve three-dimensional, irrotational, inviscid flows for single as well as overset grids. The solutions were validated by comparisons with other analytical or numerical solution, and/or experimental results for various geometries. The Poisson solution was also used as an initial guess for the thin-layer Navier-Stokes solution procedure to improve the efficiency of the numerical flow simulations. It was found that this approach resulted in roughly a 30 percent CPU time savings as compared with the procedure solving the thin-layer Navier-Stokes equations from a uniform free stream flowfield.
Chiu, I-T.↗