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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,441 records · Page 80

Intact, Commercial Lithium-Polymer Batteries: Spatially Resolved Grating-Based Interferometry Imaging, Bragg Edge Imaging, and Neutron Diffraction

We survey several neutron imaging and diffraction methods for non-destructive testing and evaluation of intact, commercial lithium-ion batteries. Specifically, far-field interferometry was explored as an option to probe a wide range of autocorrelation lengths within the batteries via neutron imaging. The dark-field interferometry images change remarkably from fresh to worn batteries, and from charged to discharged batteries. When attempting to search for visual evidence of battery degradation, neutron Talbot-Lau grating interferometry exposed battery layering and particle scattering through dark-field imaging. Bragg edge imaging also reveals battery wear and state of charge. Neutron diffraction observed chemical changes between fresh and worn, charged and discharged batteries. However, the utility of these methods, for commercial batteries, is dependent upon battery size and shape, with 19 to 43 mAh prismatic batteries proving most convenient for these experimental methods. This study reports some of the first spatially resolved, small angle scattering (dark-field) images showing battery degradation.

36 MATERIALS SCIENCE↗

Reliable Determination of Pulses and Pulse-Shape Instability in Ultrashort Laser Pulse Trains Using Polarization-Gating and Transient-Grating Frequency-Resolved Optical Gating Using the RANA Approach

Devices that measure the presence of instability in the pulse shapes in trains of ultrashort laser pulses do not exist, so this task necessarily falls to pulse-measurement devices, like Frequency-Resolved Optical Gating (FROG) and its variations, which have proven to be a highly reliable class of techniques for measuring stable trains of ultrashort laser pulses. Fortunately, multi-shot versions of FROG have also been shown to sensitively distinguish trains of stable from those of unstable pulse shapes by displaying readily visible systematic discrepancies between the measured and retrieved traces in the presence of unstable pulse trains. However, the effects of pulse-shape instability and algorithm stagnation can be indistinguishable, so a never-stagnating algorithm—even when instability is present—is required and is generally important. In previous work, we demonstrated that our recently introduced Retrieved-Amplitude N-grid Algorithmic (RANA) approach produces highly reliable (100%) pulse-retrieval in the second-harmonic-generation (SHG) version of FROG for thousands of sample trains of pulses with stable pulse shapes. Further, it does so even for trains of unstable pulse shapes and thus both reliably distinguishes between the two cases and provides a rough measure of the degree of instability as well as a reasonable estimate of most typical pulse parameters. Here, we perform the analogous study for the polarization-gating (PG) and transient-grating (TG) versions of FROG, which are often used for higher-energy pulse trains. We conclude that PG and TG FROG, coupled with the RANA approach, also provide reliable indicators of pulse-shape instability. In addition, for PG and TG FROG, the RANA approach provides an even better estimate of a typical pulse in an unstable pulse train than SHG FROG does, even in cases of significant pulse-shape instability.

47 OTHER INSTRUMENTATION↗

The BIRDIES Experiment: Measuring Beryllium Isotopes to Resolve Dynamics in the Stratosphere

Cosmogenic beryllium-10 and beryllium-7, and the ratio of the two (10Be/7Be), are powerful atmospheric tracers of stratosphere–troposphere exchange (STE) processes; however, measurements are sparse for altitudes well above the tropopause. We present a novel high-altitude balloon campaign aimed to measure these isotopes in the mid-stratosphere called Beryllium Isotopes for Resolving Dynamics in the Stratosphere (BIRDIES). BIRDIES targeted gravity waves produced by tropopause-overshooting convection to study their propagation and impact on STE dynamics, including the production of turbulence in the stratosphere. Two custom-designed payloads called FiSH and GASP were flown at altitudes approaching 30 km to measure in situ turbulence and beryllium isotopes (on aerosols), respectively. These were flown on nine high-altitude balloon flights over Kansas, USA, in summer 2022. The atmospheric samples were augmented with a ground-based rainfall collection targeting isotopic signatures of deep convection overshooting. Our GASP samples yielded mostly negligible amounts of both 10Be and 7Be collected in the mid-stratosphere but led to design improvements to increase aerosol capture in low-pressure environments. Observations from FiSH and the precipitation collection were more fruitful. FiSH showed the presence of turbulent velocity, temperature, and acoustic fluctuations in the stratosphere, including length scales in the infra-sonic range and inertial subrange that indicated times of elevated turbulence. The precipitation collection, and subsequent statistical analysis, showed that large spatial datasets of 10Be/7Be can be measured in individual rainfall events with minimum terrestrial contamination. While the spatial patterns in rainfall suggested some evidence for overshooting convection, inter-event temporal variability was clearly observed and predicted with good agreement using the 3D chemical transport model GEOS-CHEM.

58 GEOSCIENCES↗

Protein Structural Dynamics of Wild-Type and Mutant Homodimeric Hemoglobin Studied by Time-Resolved X-Ray Solution Scattering

The quaternary transition between the relaxed (R) and tense (T) states of heme-binding proteins is a textbook example for the allosteric structural transition. Homodimeric hemoglobin (HbI) from Scapharca inaequivalvis is a useful model system for investigating the allosteric behavior because of the relatively simple quaternary structure. To understand the cooperative transition of HbI, wild-type and mutants of HbI have been studied by using time-resolved X-ray solution scattering (TRXSS), which is sensitive to the conformational changes. Herein, we review the structural dynamics of HbI investigated by TRXSS and compare the results of TRXSS with those of other techniques.

Yang, Cheolhee↗

Energy-Resolved Neutron Imaging for Reconstruction of Strain Introduced by Cold Working

Energy-resolved neutron transmission imaging is used to reconstruct maps of residual strains in drilled and cold-expanded holes in 5-mm and 6.4-mm-thick aluminum plates. The possibility of measuring the positions of Bragg edges in the transmission spectrum in each 55 × 55 µm2 pixel is utilized in the reconstruction of the strain distribution within the entire imaged area of the sample, all from a single measurement. Although the reconstructed strain is averaged through the sample thickness, this technique reveals strain asymmetries within the sample and thus provides information complementary to other well-established non-destructive testing methods.

Tremsin, Anton (ORCID:0000000324437576)↗

Excited-State Dynamics of All the Mono-cis and the Major Di-cis Isomers of β-Apo-8′-Carotenal as Revealed by Femtosecond Time-Resolved Transient Absorption Spectroscopy

Cis isomers of carotenoids play important roles in light harvesting and photoprotection in photosynthetic bacteria, such as the reaction center in purple bacteria and the photosynthetic apparatus in cyanobacteria. Carotenoids containing carbonyl groups are involved in efficient energy transfer to chlorophyll in light-harvesting complexes, and their intramolecular charge–transfer (ICT) excited states are known to be important for this process. Previous studies, using ultrafast laser spectroscopy, have focused on the central-cis isomer of carbonyl-containing carotenoids, revealing that the ICT excited state is stabilized in polar environments. However, the relationship between the cis isomer structure and the ICT excited state has remained unresolved. In this study, we performed steady-state absorption and femtosecond time-resolved absorption spectroscopy on nine geometric isomers (7-cis, 9-cis, 13-cis, 15-cis, 13′-cis, 9,13′-cis, 9,13-cis, 13,13′-cis, and all-trans) of β-apo-8′-carotenal, whose structures are well-defined, and discovered correlations between the decay rate constant of the S1 excited state and the S0−S1 energy gap, as well as between the position of the cis-bend and the degree of stabilization of the ICT excited state. Our results demonstrate that the ICT excited state is stabilized in polar environments in cis isomers of carbonyl-containing carotenoids and suggest that the position of the cis-bend plays an important role in the stabilization of the excited state.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

The Principle of Maximum Conformality Correctly Resolves the Renormalization-Scheme-Dependence Problem

In this paper, we clarify a serious misinterpretation and consequent misuse of the Principle of Maximum Conformality (PMC), which also can serve as a mini-review of PMC. In a recently published article, P. M. Stevenson has claimed that “the PMC is ineffective and does nothing to resolve the renormalization-scheme-dependence problem”, concluding incorrectly that the success of PMC predictions is due to the PMC being a “laborious, ad hoc, and back-door” version of the Principle of Minimal Sensitivity (PMS). We show that such conclusions are incorrect, deriving from a misinterpretation of the PMC and an overestimation of the applicability of the PMS. The purpose of the PMC is to achieve precise fixed-order pQCD predictions, free from conventional renormalization schemes and scale ambiguities. We demonstrate that the PMC predictions satisfy all the self-consistency conditions of the renormalization group and standard renormalization-group invariance; the PMC predictions are thus independent of any initial choice of renormalization scheme and scale. The scheme independence of the PMC is also ensured by commensurate scale relations, which relate different observables to each other. Moreover, in the Abelian limit, the PMC dovetails into the well-known Gell-Mann–Low framework, a method universally revered for its precision in QED calculations. Due to the elimination of factorially divergent renormalon terms, the PMC series not only attains a convergence behavior far superior to that of its conventional counterparts but also deftly curtails any residual scale dependence caused by the unknown higher-order terms. This refined convergence, coupled with its robust suppression of residual uncertainties, furnishes a sound and reliable foundation for estimating the contributions from unknown higher-order terms. Anchored in the bedrock of standard renormalization-group invariance, the PMC simultaneously eradicates the factorial divergences and eliminates superfluous systematic errors, which inversely provides a good foundation for achieving high-precision pQCD predictions. Consequently, owing to its rigorous theoretical underpinnings, the PMC is eminently applicable to virtually all high-energy hadronic processes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

RESOLVING IONIZATION AND METALLICITY ON PARSEC SCALES ACROSS MRK 71 WITH HST-WFC3

Blue compact dwarf (BCD) galaxies in the nearby universe provide a means for studying feedback mechanisms and star formation processes in low-metallicity environments in great detail. Owing to their vicinity, these local analogs to primordial young galaxies are well suited for high-resolution studies that are unfeasible for high-redshift galaxies. Here we present Hubble Space Telescope Wide Field Camera 3 observations of one such BCD, Mrk 71, one of the most powerful local starbursts known, in the light of [O ii], He ii, Hβ, [O iii], Hα, and [S ii]. At D ≃ 3.44 Mpc, this extensive suite of emission-line images enables us to explore the chemical and physical conditions of Mrk 71 on ∼2 pc scales. We use emission-line diagnostics to distinguish ionization mechanisms on a pixel-by-pixel basis and show that despite the previously reported hypersonic gas and superbubble blowout, the gas in Mrk 71 is photoionized, with no sign of shock-excited emission. He ii emission line images are used to identify up to six Wolf-Rayet stars, three of which lie on the edge of a blowout region. Using strong-line metallicity diagnostics, we present the first “metallicity image” of a galaxy, revealing chemical inhomogeneity on scales of <50 pc. We additionally demonstrate that while chemical structure can be lost at large scales, metallicity diagnostics can break down on spatial scales smaller than an H ii region. This study highlights not only the benefits of high-resolution spatially resolved observations in assessing the effects of feedback mechanisms but also the potential limitations when employing emission-line diagnostics; these results are particularly relevant as we enter the era of extremely large telescopes.

79 ASTRONOMY AND ASTROPHYSICS↗

RESOLVED CO GAS INTERIOR TO THE DUST RINGS OF THE HD 141569 DISK

The disk around HD 141569 is one of a handful of systems whose weak infrared emission is consistent with a debris disk, but still has a significant reservoir of gas. Here we report spatially resolved millimeter observations of the CO(3-2) and CO(1-0) emission as seen with the Submillimeter Array and CARMA. We find that the excitation temperature for CO is lower than expected from cospatial blackbody grains, similar to previous observations of analogous systems, and derive a gas mass that lies between that of gas-rich primordial disks and gas-poor debris disks. The data also indicate a large inner hole in the CO gas distribution and an outer radius that lies interior to the outer scattered light rings. This spatial distribution, with the dust rings just outside the gaseous disk, is consistent with the expected interactions between gas and dust in an optically thin disk. This indicates that gas can have a significant effect on the location of the dust within debris disks.

79 ASTRONOMY AND ASTROPHYSICS↗

RESOLVING GAS FLOWS IN THE ULTRALUMINOUS STARBURST IRAS 23365+3604 WITH KECK LGSAO/OSIRIS

Keck OSIRIS/LGSAO observations of the ultraluminous galaxy IRAS 23365+3604 resolve a circumnuclear bar (or irregular disk) of semimajor axis 0.″42 (520 pc) in Paα emission. The line-of-sight velocity of the ionized gas increases from the northeast toward the southwest; this gradient is perpendicular to the photometric major axis of the infrared emission. Two pairs of bends in the zero-velocity line are detected. The inner bend provides evidence for gas inflow onto the circumnuclear disk/bar structure. We interpret the gas kinematics on kiloparsec scales in relation to the molecular gas disk and multiphase outflow discovered previously. In particular, the fast component of the ouflow (detected previously in line wings) is not detected, adding support to the conjecture that the fast wind originates well beyond the nucleus. These data directly show the dynamics of gas inflow and outflow in the central kiloparsec of a late-stage, gas-rich merger and demonstrate the potential of integral field spectroscopy to improve our understanding of the role of gas flows during the growth phase of bulges and supermassive black holes.

79 ASTRONOMY AND ASTROPHYSICS↗

RESOLVING THE ROTATION MEASURE OF THE M87 JET ON KILOPARSEC SCALES

We investigate the distribution of Faraday rotation measure (RM) in the M87 jet at arcsecond scales by using archival polarimetric Very Large Array data at 8, 15, 22 and 43 GHz. We resolve the structure of the RM in several knots along the jet for the first time. We derive the power spectrum in the arcsecond-scale jet and find indications that the RM cannot be associated with a turbulent magnetic field with a 3D Kolmogorov spectrum. Our analysis indicates that the RM probed on jet scales has a significant contribution of a Faraday screen associated with the vicinity of the jet, in contrast with that on kiloparsec scales, typically assumed to be disconnected from the jet. Comparison with previous RM analyses suggests that the magnetic fields giving rise to the RMs observed in jet scales have different properties and are well less turbulent than those observed in the lobes.

79 ASTRONOMY AND ASTROPHYSICS↗

The radial distribution of H{sub 2} and CO in TW Hya as revealed by resolved ALMA observations of CO isotopologues

CO is widely used as a tracer of molecular gas. However, there is now mounting evidence that gas phase carbon is depleted in the disk around TW Hya. Previous efforts to quantify this depletion have been hampered by uncertainties regarding the radial thermal structure in the disk. Here we present resolved ALMA observations of {sup 13}CO 3-2, C{sup 18}O 3-2, {sup 13}CO 6-5, and C{sup 18}O 6-5 emission in TW Hya, which allow us to derive radial gas temperature and gas surface density profiles, as well as map the CO abundance as a function of radius. These observations provide a measurement of the surface CO snowline at ∼30 AU and show evidence for an outer ring of CO emission centered at 53 AU, a feature previously seen only in less abundant species. Further, the derived CO gas temperature profile constrains the freeze out temperature of CO in the warm molecular layer to <21 K. Combined with the previous detection of HD 1-0, these data constrain the surface density of the warm H{sub 2} gas in the inner ∼30 AU such that Σ{sub warmgas}=4.7{sub −2.9}{sup +3.0} g cm{sup −2}(R/10au){sup −1/2}. We find that CO is depleted by two orders of magnitude from R=10--60 AU, with the small amount of CO returning to the gas phase inside the surface CO snowline insufficient to explain the overall depletion. Finally, this new data is used in conjunction with previous modeling of the TW Hya disk to constrain the midplane CO snowline to 17–23 AU.

79 ASTRONOMY AND ASTROPHYSICS↗

SPACE-BASED MICROLENS PARALLAX OBSERVATION AS A WAY TO RESOLVE THE SEVERE DEGENERACY BETWEEN MICROLENS-PARALLAX AND LENS-ORBITAL EFFECTS

In this paper, we demonstrate the severity of the degeneracy between the microlens-parallax and lens-orbital effects by presenting the analysis of the gravitational binary-lens event OGLE-2015-BLG-0768. Despite the obvious deviation from the model based on the linear observer motion and the static binary, it is found that the residual can be almost equally well explained by either the parallactic motion of the Earth or the rotation of the binary-lens axis, resulting in the severe degeneracy between the two effects. We show that the degeneracy can be readily resolved with the additional data provided by space-based microlens parallax observations. By enabling us to distinguish between the two higher-order effects, space-based microlens parallax observations will not only make it possible to accurately determine the physical lens parameters but also to further constrain the orbital parameters of binary lenses.

79 ASTRONOMY AND ASTROPHYSICS↗

DEBRIS DISKS IN THE SCORPIUS–CENTAURUS OB ASSOCIATION RESOLVED BY ALMA

We present a CO(2-1) and 1240 μ m continuum survey of 23 debris disks with spectral types B9-G1, observed at an angular resolution of 0.″5–1″ with the Atacama Large Millimeter/Submillimeter Array (ALMA). The sample was selected for large infrared excess and age ∼10 Myr, to characterize the prevalence of molecular gas emission in young debris disks. We identify three CO-rich debris disks, plus two additional tentative (3 σ) CO detections. Twenty disks were detected in the continuum at the >3 σ level. For the 12 disks in the sample that are spatially resolved by our observations, we perform an independent analysis of the interferometric continuum visibilities to constrain the basic dust disk geometry, as well as a simultaneous analysis of the visibilities and broadband spectral energy distribution to constrain the characteristic grain size and disk mass. The gas-rich debris disks exhibit preferentially larger outer radii in their dust disks, and a higher prevalence of characteristic grain sizes smaller than the blowout size. The gas-rich disks do not exhibit preferentially larger dust masses, contrary to expectations for a scenario in which a higher cometary destruction rate would be expected to result in a larger mass of both CO and dust. The three debris disks in our sample with strong CO detections are all around A stars: the conditions in disks around intermediate-mass stars appear to be the most conducive to the survival or formation of CO.

79 ASTRONOMY AND ASTROPHYSICS↗

A megacam survey of outer halo satellites. VI. The spatially resolved star-formation history of the carina dwarf spheroidal galaxy

We present the spatially resolved star-formation history (SFH) of the Carina dwarf spheroidal galaxy, obtained from deep, wide-field g and r imaging and a metallicity distribution from the literature. Our photometry covers ∼2 deg{sup 2}, reaching up to ∼10 times the half-light radius of Carina with a completeness higher than 50% at g ∼ 24.5, more than one magnitude fainter than the oldest turnoff. This is the first time a combination of depth and coverage of this quality has been used to derive the SFH of Carina, enabling us to trace its different populations with unprecedented accuracy. We find that Carina’s SFH consists of two episodes well separated by a star-formation temporal gap. These episodes occurred at old (>10 Gyr) and intermediate (2–8 Gyr) ages. Our measurements show that the old episode comprises the majority of the population, accounting for 54 ± 5% of the stellar mass within 1.3 times the King tidal radius, while the total stellar mass derived for Carina is 1.60±0.09×10{sup 6} M{sub ⊙}, and the stellar mass-to-light ratio is 1.8 ± 0.2. The SFH derived is consistent with no recent star formation, which hints that the observed blue plume is due to blue stragglers. We conclude that the SFH of Carina evolved independently of the tidal field of the Milky Way, since the frequency and duration of its star-formation events do not correlate with its orbital parameters. This result is supported by the age–metallicity relation observed in Carina and the gradients calculated indicating that outer regions are older and more metal-poor.

79 ASTRONOMY AND ASTROPHYSICS↗

Resolving the Circumstellar Environment of the Galactic B[e] Supergiant Star MWC 137 from Large to Small Scales

The Galactic object MWC 137 has been suggested to belong to the group of B[e] supergiants. However, with its large-scale optical bipolar ring nebula and high-velocity jet and knots, it is a rather atypical representative of this class. We performed multiwavelength observations spreading from the optical to the radio regimes. Based on optical imaging and long-slit spectroscopic data, we found that the northern parts of the large-scale nebula are predominantly blueshifted, while the southern regions appear mostly redshifted. We developed a geometrical model consisting of two double cones. Although various observational features can be approximated with such a scenario, the observed velocity pattern is more complex. Using near-infrared integral-field unit spectroscopy, we studied the hot molecular gas in the vicinity of the star. The emission from the hot CO gas arises in a small-scale disk revolving around the star on Keplerian orbits. Although the disk itself cannot be spatially resolved, its emission is reflected by the dust arranged in arc-like structures and the clumps surrounding MWC 137 on small scales. In the radio regime, we mapped the cold molecular gas in the outskirts of the optical nebula. We found that large amounts of cool molecular gas and warm dust embrace the optical nebula in the east, south, and west. No cold gas or dust was detected in the north and northwestern regions. Despite the new insights into the nebula kinematics gained from our studies, the real formation scenario of the large-scale nebula remains an open issue.

79 ASTRONOMY AND ASTROPHYSICS↗

Time-resolved WISE /NEOWISE Coadds

We have used the first ~3 years of 3.4 μm (W1) and 4.6 μm (W2) observations from the WISE and NEOWISE missions to create a full-sky set of time-resolved coadds. As a result of the WISE survey strategy, a typical sky location is visited every six months and is observed during ≳ 12 exposures per visit, with these exposures spanning a ~1 day time interval. We have stacked the exposures within such ~1 day intervals to produce one coadd per band per visit - that is, one coadd every six months at a given position on the sky in each of W1 and W2. For most parts of the sky, we have generated six epochal coadds per band, with one visit during the fully cryogenic WISE mission, one visit during NEOWISE, and then, after a 33-month gap, four more visits during the NEOWISE-Reactivation mission phase. These coadds are suitable for studying long-timescale mid-infrared variability and measuring motions to ~1.3 mag fainter than the single-exposure detection limit. In most sky regions, our coadds span a 5.5-year time period and therefore provide a >10× enhancement in time baseline relative to that available for the AllWISE catalog's apparent motion measurements. As such, the signature application of these new coadds is expected to be motion-based identification of relatively faint brown dwarfs, especially those cold enough to remain undetected by Gaia.

79 ASTRONOMY AND ASTROPHYSICS↗

Resolved Imaging of the AR Puppis Circumbinary Disk

Circumbinary disks are common around post-asymptotic giant branch (post-AGB) stars with a stellar companion on orbital timescales of a few 100 to few 1000 days. The presence of a disk is usually inferred from the system’s spectral energy distribution and confirmed, for a sub-sample, by interferometric observations. We used the Spectro-Polarimetric High-contrast Exoplanet REsearch (SPHERE) instrument on the Very Large Telescope to obtain extreme adaptive optics assisted scattered light images of the post-AGB binary system AR Puppis. Data have been obtained in the V, I, and H bands. Our observations have produced the first resolved images of AR Puppis’s circumbinary disk and confirm its edge-on orientation. In our high-angular-resolution and high-dynamic-range images we identify several structural components such as a dark mid-plane, the disk surface, and arc-like features. We discuss the nature of these components and use complementary photometric monitoring to relate them to the orbital phase of the binary system. Because the star is completely obscured by the disk at visible wavelengths, we conclude that the long-term photometric variability of the system must be caused by variable scattering, not extinction, of starlight by the disk over the binary orbit. Finally, we discuss how the short disk lifetimes and fast evolution of the host stars compared to the ages at which protoplanetary disks are typically observed make systems like AR Puppis valuable extreme laboratories to study circumstellar disk evolution and constrain the timescale of dust grain growth during the planet formation process.

79 ASTRONOMY AND ASTROPHYSICS↗