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NASA NTRS1981

Texture measurements from Seasat - SAR images for urban land use interpretation

Different grey tones in Seasat Synthetic Aperture Radar (SAR) images for the same type of urban land cover considerably impair the possibilities of establishing automatic classification procedures for these types of data. Since the orientation of the main features like street patterns and buildings with respect to the azimuth angle of the radar antenna is the crucial factor for the observed differences in grey tone, prior information on these elements and special processing of the data would be required to eliminate this effect. Another approach suggested in this paper is to make use of the textural information in the image rather than of its grey tone. For different study sites within the Los Angeles urbanized area texture measures could be derived which result in characteristic values for specific types of land cover and are largely independent of the azimuth angle effect. At the same time the results for the study area indicate an improvement of the overall separability for the different land cover types included in the analysis.

Fasler, F.↗

NASA NTRS1983

Laboratory measurements of D/H ratios in interplanetary dust

Measurements of noble gas elemental and isotopic abundance patterns have provided evidence that a subset of the particles collected in the upper atmosphere by NASA aircraft are micrometeorites. It is found that the deuterium in two such particles is enriched relative to hydrogen by 500-1100 per thousand when compared with the terrestrial SMOW standard. This result confirms the extraterrestrial origin of the dust particles and demonstrates that the material preserves a potentially unique isotopic record which may reflect a memory of processes occurring during or before the formation of the solar system. In addition, the deuterium enrichment seen in the particles is analogous to that observed in bulk samples of one carbonaceous meteorite and two unequilibrated ordinary chondrites as well as in chemical separates of a number of other meteorites.

Zinner, E.↗

NASA NTRS2005

Airborne Sunphotometer and Solar Spectral Flux Radiometer Measurements During INTEX/ITCT 2004

During the period 12 July - 8 August 2004, the NASA Ames 14-channel Airborne Tracking Sunphotometer (MTS-14) and Solar Spectral Flux Radiometer (SSFR) were operated aboard a Jetstream 31 (J31) aircraft and acquired measurements during nineteen science flights (approx. 53 flight hours) over the Gulf of Maine in support of the INTEX-NA (INtercontinental chemical Transport Experiment-North America) and ITCT (Intercontinental Transport and Chemical Transformation of anthropogenic pollution) field studies. In this paper, we will present results from analyses of those data sets. AATS-14 measures the direct solar beam transmission at fourteen discrete wavelengths (354-2138 nm), and provides instantaneous measurements of aerosol optical depth (AOD) spectra and water vapor column content, in addition to vertical profiles of aerosol extinction and water vapor density during suitable aircraft ascents and descents. SSFR consists of separate nadir and zenith viewing hemispheric FOV sensors that yield measurements of up- and downwelling solar irradiance at a spectral resolution of approx. 8-12 nm over the wavelength range 300-1700 nm. The objectives of the J31-based measurements during INTEX/ITCT were to provide AOD data for the evaluation of MODIS (MODerate-resolution Imaging Spectroradiometer) and MISR (Multi-angle Imaging Spectro-Radiometer) AOD retrievals, quantify sea surface spectral albedo (which can contribute the largest uncertainty to satellite aerosol retrievals for low aerosol loading), test closure (consistency) among suborbital results, test chemical-transport models using AOD profiles, and assess regional radiative forcing by combining satellite and suborbital results. Specific J31 flight patterns were designed to achieve these objectives, and they included a mixture of vertical profiles (spiral and ramped ascents and descents) and constant altitude horizontal transects at a variety of altitudes. Additional information is included in the original extended abstract.

Russell, P. B.↗

DOE OSTI2019

Insight into a highly polymorphic endophyte isolated from the roots of the halophytic seepweed Suaeda salsa: Laburnicola rhizohalophila sp. nov. (Didymosphaeriaceae, Pleosporales)

In this work, we surveyed root endophytic fungi of the coastal halophyte Suaeda salsa and detected a population of a novel species that we described here as Laburnicola rhizohalophila sp. nov. No sexual sporulating structure was observed. Instead, it produced a large amount of thalloconidia, 0–1 transverse septa, hyaline to darkly pigmented, often peanut-shaped and sometimes dumbbell-shaped, both ends enlarged with numerous oil droplets inside the hyphal cells. Surprisingly, a high degree of phenotypic and physiological intraspecific variation (e.g., salinity tolerance, growth under different carbon:nitrogen ratios, and carbon utilization pattern) was recorded. The inoculation test indicated that the isolates could successfully infect host roots and form microsclerotia-like structures in cortical cells, a typical trait of dark septate endophytes (DSEs). Furthermore, most isolates were shown to promote host seedling growth. To evaluate conspecificity and infer its phylogenetic affinity, multiloci data including nuclear rRNA loci (ITS1 and 2, partial 28S), partial RNA Polymerase II second-largest subunit ( rpb2 ), and partial translation elongation factor-1α ( tef1 ) were characterized. Genealogical concordance phylogenetic species recognition (GCPSR) detected a genetically isolated clade of L. rhizohalophila within the Pleosporales in the Didymosphaeriaceae. Maximum likelihood phylogenetic reconstruction revealed that the endophytic fungus was genetically close to L aburnicola dactylidis but separated by a relatively long genetic distance. Our work highlights that the pleosporalean taxa might represent an underexplored reservoir of root DSEs.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS1986

Navier-Stokes computations of lee-side flows over delta wings

Solutions to the Navier-Stokes equations for the flow over delta wings are computed with emphasis on the separated vortical flows developing on the lee side at high angles of attack. A recently developed implicit algorithm is used which employs upwind differencing for the pressure and convection terms and central differencing for the shear stress and heat transfer terms. Solutions to both the three-dimensional equations and the approximate conical flow equations are compared parametrically with an extensive experimental data base at supersonic speeds. The computations indicate that the conical flow approximation provides results in close agreement with the three-dimensional equations, even to angles of attack as high as 20 degrees. Good agreement with experimentally measured pressures and vapor screen photographs is obtained for the conditions investigated. The method predicts the classical pattern of vortical flow over a delta wing and transition to other flow patterns as the leading edge sweep angle and leading edge normal Mach number are varied.

Thomas, J. L.↗

NASA NTRS1998

MAPS of Cancer

Our goal was to produce an interactive visualization from a mathematical model that successfully predicts metastases from head and neck cancer. We met this goal early in the project. The visualization is available for the public to view. Our work appears to fill a need for more information about this deadly disease. The idea of this project was to make an easily interpretable visualization based on what we call "functional maps" of disease. A functional map is a graphic summary of medical data, where distances between parts of the body are determined by the probability of disease, not by anatomical distances. Functional maps often beat little resemblance to anatomical maps, but they can be used to predict the spread of disease. The idea of modeling the spread of disease in an abstract multidimensional space is difficult for many people. Our goal was to make the important predictions easy to see. NASA must face this problem frequently: how to help laypersons and professionals see important trends in abstract, complex data. We took advantage of concepts perfected in NASA's graphics libraries. As an analogy, consider a functional map of early America. Suppose we choose travel times, rather than miles, as our measures of inter-city distances. For Abraham Lincoln, travel times would have been the more meaningful measure of separation between cities. In such a map New Orleans would be close to Memphis because of the Mississippi River. St. Louis would be close to Portland because of the Oregon Trail. Oklahoma City would be far from Little Rock because of the Cheyenne. Such a map would look puzzling to those of us who have always seen physical maps, but the functional map would be more useful in predicting the probabilities of inter-site transit. Continuing the analogy, we could predict the spread of social diseases such as gambling along the rivers and cattle rustling along the trails. We could simply print the functional map of America, but it would be more interesting to show meaningful patterns of dispersal. We had previously published the functional map of the head and neck, but it was difficult to explain to either patients or surgeons because that view of our body did not resemble anatomy. This discrepancy between functional and physical maps is just a mathematical restatement of the well-known fact that some diseases, such as head and neck cancer, spread in complex patterns, not always to the next nearest site. We had discovered that a computer could re-arrange anatomy so that this particular disease spreads to the next nearest site. The functional map explains over 95% of the metastases in 1400 patients. In a sense, we had graphed what our body "looks like" to a tumor. The tumor readily travels between adjacent areas in the functional map. The functional map is a succinct visual display of trends that are not easily appreciated in tables of probabilities.

Gray, Lincoln↗

DOE OSTI2025

High resolution variability in wet deposition in the southeastern United States

Rainwater chemistry is determined by atmospheric pollutants and particles which vary spatially and temporally. Industrial and agricultural activities and meteorological events (e.g. sea breezes, severe weather, blowing dust) alter atmospheric particle and trace gas compositions. These gases and particles are scavenged by cloud and rain droplets that drive wet deposition. During an Intensive Operation Period (IOP) from April to October 2021, rainwater was collected at higher frequency intervals, usually daily, after precipitation events at three locations on the Savannah River Site (SRS). The farthest locations were separated by approximately 20 km. The mean concentration (μeq/L) of seven ions followed the Cl⁻ > SO 4 2− > Na⁺ > NO 3 ⁻ > K⁺ > Mg 2+ > Ca 2+ downward trend. Ion concentrations were compared to background ion concentrations from the National Atmospheric Deposition Program (NADP). The high frequency monthly averaged SRS data compared well with the monthly averaged NADP background but demonstrated extensive variability. In some months in 2021, the high frequency data compared better to the NADP site near the coast while in other months inland sites compared better. Strong spatial variability for ion concentrations was observed across SRS which was attributed to localized impacts in rainfall spatial variability. High frequency measurements allowed for comparison to regional weather patterns indicating influences from the Atlantic Ocean, Gulf of Mexico, and cities. This can account for spatial variability in the wet deposition flux. Sea breezes, Saharan dust, and anthropogenic sources were shown to impact wet deposition flux variability. Higher frequency precipitation chemistry sampling at numerous locations better captures ion concentration variability and improves measurement representativeness.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1986

Earth's compressional foreshock boundary revisited Observations by the ISEE 1 magnetometer

A 'solar foreshock coordinate' (SFC) system is introduced in which the positions of foreshock components can be collated with a minimum of assumptions about the physical processes involved. Location behind the interplanetary magnetic field (IMF) tangent surface to the bow shock and rotational symmetry around the solar wind flow (X) axis are the only presuppositions. The SFC system has been applied to over 300 observations of the boundary of the ULF compressional waves recorded by ISEE 1's magnetometer in 1978 and 1979. The boundary locations form a coherent pattern in the SFC frame. A selection of those cases for which the cone angle of the IMF was between 40 and 50 deg, corresponding to the average stream angle, yields a least square line whose mapping back to the solar ecliptic coordinates frame has slope of about 85 deg, very close to that of the tangent ULF boundary deduced earlier from more primitive methods with entirely different data sets. The line, being parallel to neither the IMF, the typical reflected beam, nor the shock, cannot be compatible with any model of wave production by beam-solar wind interaction that depends on uniform beam distribution or fixed growth rate. Rather, its tangency suggests the influence of a separate, escaping ion population.

Greenstadt, E. W.↗

NASA NTRS1990

ER-2 lidar measurements of stratocumulus cloud top structure on July 14, 1987

On July 14, 1987 NASA's ER-2 high altitude aircraft flew a mission to measure the structure of stratocumulus clouds off the coast of California. A flight pattern was executed so that the two-dimensional variability of the clouds could be detected. The technique of analysis of the lidar data to measure cloud tops follows. First each signal is searched for its maximum in return strength. This maximum is caused by scattering of the laser light off cloud particles or from the ocean surface. Next the variance of the signal return above the level of maximum backscatter is determined. Cloud top is assigned to a level (above the level of maximum backscatter) where the backscatter exceeds the average variance. This two-step process is necessary because the level of maximum backscatter does not correspond to the cloud top. Ocean surface returns are easily separated from cloud returns in this process, described in detail by Boers, Spinhirne, and Hart (1988). Analysis of the data so far has shown that there were very few breaks in the clouds. Furthermore the layer top was very flat with local oscillations not exceeding 30 m. Such small cloud top variations are still well within the range of detectability, because the precision of this technique of cloud top detection has previously been established to be 13 to 15 m. Data are presently being analyzed to compute cloud top distributions and fractional cloudiness. The aim of this research is to relate the fractional cloudiness to the mean thermodynamic structure of the boundary layer. Researchers plan to compute spectral scales of the cloud top variability in two dimensions to determine the orientation of the clouds with respect to the mean wind. Furthermore the lidar derived cloud top distribution will be used in the computation of the thermodynamic and radiation budget of the boundary layer.

Boers, Reinout↗

NASA NTRS1996

CFD Study of Turbo-Ramjet Interactions in Hypersonic Airbreathing Propulsion System

Advanced airbreathing propulsion systems used in Mach 4-6 mission scenarios, usually involve turbo-ramjet configurations. As the engines transition from turbojet to ramjet, there is an operational envelope where both engines operate simultaneously. In the first phase of our study, an over/under nozzle configuration was analyzed. The two plumes from the turbojet and ramjet interact at the end of a common 2-D cowl, where they both reach an approximate Mach 3.0 condition and then jointly expand to Mach 3.6 at the common nozzle exit plane. For the problem analyzed, the turbojet engine operates at a higher nozzle pressure ratio than the ramjet, causes the turbojet plume overpowers the ramjet plume, deflecting it approximately 12 degrees downward and in turn the turbojet plume is deflected 6 degrees upward. In the process, shocks were formed at the deflections and a shear layer formed at the confluence of the two jets. This particular case was experimentally tested and the data were used to compare with a computational fluid dynamics (CFD) study using the PARC2D code. The CFD results were in good agreement with both static pressure distributions on the cowl separator and on nozzle walls. The thrust coefficients were also in reasonable agreement. In addition, inviscid relationships were developed around the confluence point, where the two exhaust jets meet, and these results compared favorably with the CFD results. In the second phase of our study, a 3-D CFD solution was generated to compare with the 2-D solution. The major difference between the 2-D and 3-D solutions was the interaction of the shock waves, generated by the plume interactions, on the sidewall. When a shock wave interacts with a sidewall and sidewall boundary layer, it is called a glancing shock sidewall interaction. These interactions entrain boundary layer flow down the shockline into a vortical flow pattern. The 3-D plots show the streamlines being entrained down the shockline. The pressure of the flow also decreases slightly as the sidewall is approached. Other difference between the 2-D and 3-D solutions were a lowering of the nozzle thrust coefficient value from 0.9850 (2-D) to 0.9807 (3-D), where the experimental value was 0.9790. In the third phase of our study, a different turbo-ramjet configuration was analyzed. The confluence of a supersonic turbojet and a subsonic ramjet in the turbine based combined-cycle (TBCC) propulsion system was studied by a 2-D CFD code. In the analysis, Mach 1.4 primary turbojet was mixed with the subsonic ramjet secondary flow in an ejector mode operation. Reasonable agreements were obtained with the supplied I-D TBCC solutions. For low downstream backpressure, the Fabri choke condition (Break-Point condition) was observed in the secondary flow within mixing zone. For sufficient high downstream backpressure, the Fabri choke no longer exist, the ramjet flow was reduced and the ejector flow became backpressure dependent. Highly non-uniform flow at ejector exit were observed, indicated that for smooth downstream combustion, the mixing of the two streams probably required some physical devices.

Chang, Ing↗

NASA NTRS2015

Detection of DNA Damage by Space Radiation in Human Fibroblast Cells Flown on the International Space Station

Although charged particles in space have been detected with radiation detectors on board spacecraft since the early discovery of the Van Allen Belt, reports on effects of direct exposure to space radiation in biological systems have been limited. Measurement of biological effects of space radiation has been difficult due to the low dose and low dose rate nature of the radiation environment, and the difficulty in separating the radiation effects from microgravity and other space environmental factors. In astronauts, only a small number of changes, such as increased chromosome aberrations in lymphocytes and early onset of cataracts, attributed primarily to the exposure to space radiation. In a recent experiment, human fibroblast cells were flown on the International Space Station (ISS). Cells fixed on Days 3 and 14 after reaching orbit were analyzed for phosphorylation of a histone protein H2AX by immunofluorescent staining of cells, which is a widely used marker for DNA double strand breaks. The 3-dimensional gamma-H2AX foci were captured with a laser confocal microscope. Quantitative analysis revealed a small fraction of foci that were larger and displayed a track pattern in the flight samples in comparison to the ground control. Human fibroblast cells were also exposed to low dose rate gamma rays, as well as to protons and Fe ions. Comparison of the pattern and distribution of the foci after gamma ray and charged particle exposure to our flight results confirmed that the foci found in the flown cells were indeed induced by space radiation.

Wu, Honglu↗

DOE OSTI2021

In Situ, Protein-Mediated Generation of a Photochemically Active Chlorophyll Analogue in a Mutant Bacterial Photosynthetic Reaction Center

All possible natural amino acids have been substituted for the native LeuL185 positioned near the B-side bacteriopheophytin (H B ) in the bacterial reaction center (RC) from Rhodobacter sphaeroides. Additional mutations are present that enhance electron transfer to the normally inactive B-side cofactors. About half the isolated RCs with Glu at L185 contain a magnesium chlorin (C B ) in place of H B . The chlorin is not the common BChl a oxidation product 3-desvinyl-3-acetyl chlorophyll a with a C-C bond in ring D and a C=C bond in ring B, but has properties consistent with reversal of these bond orders, giving 17,18-didehydro BChl a. In such RCs, charge-separated state P + C B – forms with ~5% yield. The other half of the GluL185-containing RCs have a bacteriochlorophyll a (BChl a) denoted β B in place of H B . Residues His, Asp, Asn and Gln at L185 yield RCs with ≥85% β B in the H B site, while most other amino acids result in RCs that retain H B (≥95%). To our knowledge, neither bacterial RCs that harbor five BChl a and one chlorophyll analog nor ones with six BChl a have been reported previously. The finding that altering the local environment within a cofactor binding site of a transmembrane complex leads to in situ generation of a photoactive chlorin with an unusual ring oxidation pattern suggests new strategies for amino-acid control over pigment type at specific sites in photosynthetic proteins.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2017

Wave Events: Climatology, Trends, and Relationship to Northern Hemisphere Winter Blocking and Weather Extremes

Diagnostics of finite-amplitude local wave activity (LWA) are applied to the 500-hPa geopotential height field to diagnose persistent synoptic weather events of anomalously large wave activity in the Northern Hemisphere. By considering the cyclonic and anticyclonic components of LWA separately, persistent weather systems associated with large-amplitude troughs and ridges are detected. While anticyclonic wave events are predominantly found over Europe and Alaska, cyclonic wave events usually occur over East Asia and northeastern Canada. Those preferred regions correspond to the location of planetary-scale ridges and troughs, which contribute, together with transient anomalies, to the formation of wave events. Although wave events are not blocking events per definition, they are typically associated with increased blocking in their vicinity. Their spatial relationship to blocking, however, varies depending on their cyclonic or anticyclonic nature and the type of wave-breaking signatures. Wave events are also shown to be accompanied by warm or cold temperature extremes, whose spatial pattern depends on the type of events, cyclonic or anticyclonic, and the sector affected. Trends in the frequency of wave events indicate that cyclonic wave events and the associated cold extremes affecting East Asia have become more frequent in recent decades and could be linked to recent trends toward La Niña–like conditions in the Pacific and trends toward the negative phase of Arctic Oscillation.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1990

The analysis of polar clouds from AVHRR satellite data using pattern recognition techniques

The cloud cover in a set of summertime and wintertime AVHRR data from the Arctic and Antarctic regions was analyzed using a pattern recognition algorithm. The data were collected by the NOAA-7 satellite on 6 to 13 Jan. and 1 to 7 Jul. 1984 between 60 deg and 90 deg north and south latitude in 5 spectral channels, at the Global Area Coverage (GAC) resolution of approximately 4 km. This data embodied a Polar Cloud Pilot Data Set which was analyzed by a number of research groups as part of a polar cloud algorithm intercomparison study. This study was intended to determine whether the additional information contained in the AVHRR channels (beyond the standard visible and infrared bands on geostationary satellites) could be effectively utilized in cloud algorithms to resolve some of the cloud detection problems caused by low visible and thermal contrasts in the polar regions. The analysis described makes use of a pattern recognition algorithm which estimates the surface and cloud classification, cloud fraction, and surface and cloudy visible (channel 1) albedo and infrared (channel 4) brightness temperatures on a 2.5 x 2.5 deg latitude-longitude grid. In each grid box several spectral and textural features were computed from the calibrated pixel values in the multispectral imagery, then used to classify the region into one of eighteen surface and/or cloud types using the maximum likelihood decision rule. A slightly different version of the algorithm was used for each season and hemisphere because of differences in categories and because of the lack of visible imagery during winter. The classification of the scene is used to specify the optimal AVHRR channel for separating clear and cloudy pixels using a hybrid histogram-spatial coherence method. This method estimates values for cloud fraction, clear and cloudy albedos and brightness temperatures in each grid box. The choice of a class-dependent AVHRR channel allows for better separation of clear and cloudy pixels than does a global choice of a visible and/or infrared threshold. The classification also prevents erroneous estimates of large fractional cloudiness in areas of cloudfree snow and sea ice. The hybrid histogram-spatial coherence technique and the advantages of first classifying a scene in the polar regions are detailed. The complete Polar Cloud Pilot Data Set was analyzed and the results are presented and discussed.

Smith, William L.↗

NASA NTRS1989

High-power low-threshold graded-index separate confinement heterostructure AlGaAs single quantum well lasers on Si substrates

A high-power low-threshold graded-index separate confinement heterostructure AlGaAs single quantum well laser on Si substrates has been demonstrated for the first time by a hybrid growth of migration-enhanced molecular beam epitaxy followed by metalorganic vapor phase epitaxy. The quantum well laser showed an output power of more than 400 mW per facet under pulsed conditions. A room-temperature threshold current of 300 mA was obtained with a differential quantum efficiency of 40 percent without facet coating. The threshold current density was 550 A/sq cm for a cavity length of 500 microns. These results show the highest peak power reported to date for low-threshold lasers on Si substrates. The full width at half maximum of the far-field pattern parallel to the junction was 6 deg. Threshold current densities as low as 250 A/sq cm were obtained for lasers on GaAs substrates.

Kim, Jae-Hoon↗

NASA NTRS2002

Evidence of an Intrinsic Intraseasonal Oscillation over Tropical South America During Austral Summer

The intraseasonal variation (ISV) in the 30-60 day band, also known as Madden-Julian oscillation (MJO), has been studied for decades. Madden and Julian showed that the oscillation originated from the western Indian Ocean, propagated eastward, got enhanced over the maritime continent and weakened after passing over the dateline. Composite studies showed evidences of a signal in upper and lower level zonal wind propagating around the globe during an oscillation. Theoretical studies pointed out that the interaction with the warm ocean surface and the coupling with the convective and radiative processes in the atmosphere could manifest the oscillation, which propagates eastward via mutual feedbacks between the wave motions and the cumulus heating. Over tropical South America, no independent 30-60 day oscillation has been reported so far, despite that Amazon is the most distinct tropical convection center over the western hemisphere and the fluxes from its surface of tropical rainforests are close to that from the warm tropical ocean. Liebmann et al. showed a distinct spectral peak of 40-50 day oscillation in outgoing longwave radiation (OLR) over tropical South America and considered that was manifested by the MJO propagation. Nogues-Paegle et al. (2000) focused on a dipole pattern of the OLR anomaly with centers of action over the South Atlantic Convergence Zone (SACZ) and the subtropical plain. They used the regional 10-90 day filtered data and demonstrated this pattern could be represented by the fifth mode of the rotated empirical orthogonal function. Its principal component was further analyzed using the singular spectrum analysis. Their result showed two oscillatory modes with periods of 36-40 days and 22-28 days, of which the former was related to the MJO influence and the latter linked to the remote forcing over southwest of Australia, which produced a wave train propagating southeastward, rounding the southern tip of South America and returning back toward the northeast. The 22-28 day mode has distinct impact on SACZ, responsible for the regional seesaw pattern of alternating dry and wet conditions. In this study we will focus on the 30-60-day spectral band and investigate whether the independent oscillation source over tropical South America is existed. First, we will show the seasonal dependence of the tropical South American ISV in Section 3. Then, the leading principal modes of 30-60 day bandpass filtered 850-hPa velocity potential (VP850) will be computed to distinguish the stationary ISV over tropical South America (SISA) from the propagating MJO in the austral summertime in Section 4. The importance of SISA in representing the regional ISV over South America will be discussed. In Section 5, we will demonstrate the mass oscillation regime of SISA, which is well separated from that of MJO by the Andes, and the convective coupling with rainfall. The dynamical response of SISA and the impact on the South American summer monsoon (SASM) will be presented. Finally, we will give the concluding remarks.

Zhou, Jiayu↗

NASA NTRS2002

Speech motor control and acute mountain sickness

BACKGROUND: An objective method that accurately quantifies the severity of Acute Mountain Sickness (AMS) symptoms is needed to enable more reliable evaluation of altitude acclimatization and testing of potentially beneficial interventions. HYPOTHESIS: Changes in human articulation, as quantified by timed variations in acoustic waveforms of specific spoken words (voice onset time; VOT), are correlated with the severity of AMS. METHODS: Fifteen volunteers were exposed to a simulated altitude of 4300 m (446 mm Hg) in a hypobaric chamber for 48 h. Speech motor control was determined from digitally recorded and analyzed timing patterns of 30 different monosyllabic words characterized as voiced and unvoiced, and as labial, alveolar, or velar. The Environmental Symptoms Questionnaire (ESQ) was used to assess AMS. RESULTS: Significant AMS symptoms occurred after 4 h, peaked at 16 h, and returned toward baseline after 48 h. Labial VOTs were shorter after 4 and 39 h of exposure; velar VOTs were altered only after 4 h; and there were no changes in alveolar VOTs. The duration of vowel sounds was increased after 4 h of exposure and returned to normal thereafter. Only 1 of 15 subjects did not increase vowel time after 4 h of exposure. The 39-h labial (p = 0.009) and velar (p = 0.037) voiced-unvoiced timed separations consonants and the symptoms of AMS were significantly correlated. CONCLUSIONS: Two objective measures of speech production were affected by exposure to 4300 m altitude and correlated with AMS severity. Alterations in speech production may represent an objective measure of AMS and central vulnerability to hypoxia.

NASA Discipline Space Human Factors↗

DOE OSTI2022

Magnetic exchange interactions in binuclear and tetranuclear iron(III) complexes described by spin‐flip DFT and Heisenberg effective Hamiltonians

Abstract Low‐energy spectra of single‐molecule magnets (SMMs) are often described by Heisenberg Hamiltonians. Within this formalism, exchange interactions between magnetic centers determine the ground‐state multiplicity and energy separation between the ground and excited states. In this contribution, we extract exchange coupling constants ( J ) for a set of iron (III) binuclear and tetranuclear complexes from all‐electron calculations using non‐collinear spin‐flip time‐dependent density functional theory (NC‐SF‐TDDFT). For 12 binuclear complexes with J ‐values ranging from −6 to −132 cm −1 , our benchmark calculations using the short‐range hybrid ω PBEh functional and 6‐31G(d,p) basis set agree well with the experimentally derived values (mean absolute error of 4.7 cm −1 ). For the tetranuclear SMMs, the computed J constants are within 6 cm −1 from the experimentally derived values. We explore the range of applicability of the Heisenberg model by analyzing bonding patterns in these Fe(III) complexes using natural orbitals (NO), their occupations, and the number of effectively unpaired electrons. The results illustrate the efficiency of the spin‐flip protocol for computing the exchange couplings and the utility of the NO analysis in assessing the validity of effective spin Hamiltonians.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗