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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,459 records · Page 81

Generation of Highly Oblique Lower Band Chorus Via Nonlinear Three-Wave Resonance

Chorus in the inner magnetosphere has been observed frequently at geomagnetically active times, typically exhibiting a two-band structure with a quasi-parallel lower band and an upper band with a broad range of wave normal angles. But recent observations by Van Allen Probes confirm another type of lower band chorus, which has a large wave normal angle close to the resonance cone angle. It has been proposed that these waves could be generated by a low-energy beam-like electron component or by temperature anisotropy of keV electrons in the presence of a low-energy plateau-like electron component. This paper, however, presents an alternative mechanism for generation of this highly oblique lower band chorus. Through a nonlinear three-wave resonance, a quasi-parallel lower band chorus wave can interact with a mildly oblique upper band chorus wave, producing a highly oblique quasi-electrostatic lower band chorus wave. This theoretical analysis is confirmed by 2-D electromagnetic particle-in-cell simulations. Furthermore, as the newly generated waves propagate away from the equator, their wave normal angle can further increase and they are able to scatter low-energy electrons to form a plateau-like structure in the parallel velocity distribution. As a result, the three-wave resonance mechanism may also explain the generation of quasi-parallel upper band chorus which has also been observed in the magnetosphere.

58 GEOSCIENCES↗

A Noble-Transition Alloy Excels at Hot-Carrier Generation in the Near Infrared

Above-equilibrium “hot”-carrier generation in metals is a promising route to convert photons into electrical charge for efficient near-infrared optoelectronics. However, metals that offer both hot-carrier generation in the near-infrared and sufficient carrier lifetimes remain elusive. Alloys can offer emergent properties and new design strategies compared to pure metals. In this work, it is shown that a noble-transition alloy, Au x Pd 1-x , outperforms its constituent metals concerning generation and lifetime of hot carriers when excited in the near-infrared. At optical fiber wavelengths (e.g., 1550 nm), Au 50 Pd 50 provides a 20-fold increase in the number of ≈0.8 eV hot holes, compared to Au, and a threefold increase in the carrier lifetime, compared to Pd. The discovery that noble-transition alloys can excel at hot-carrier generation reveals a new material platform for near-infrared optoelectronic devices.

36 MATERIALS SCIENCE↗

Electron‐Assisted Generation and Straight Movement of Skyrmion Bubble in Kagome TbMn 6 Sn 6

Abstract Topological magnetic textures are promising candidates as binary data units for the next‐generation memory device. The precise generation and convenient control of nontrivial spin topology at zero field near room temperature endows the critical advantages in skyrmionic devices but is not simultaneously integrated into one material. Here, in the Kagome plane of quantum TbMn 6 Sn 6 , the expedient generation of the skyrmion bubbles in versatile forms of lattice, chain, and isolated one by converging the electron beam, where the electron intensity gradient contributes to the dynamic generation from local anisotropy variation near spin reorientation transition (SRT) is reported. Encouragingly, by utilizing the dynamic shift of the SRT domain interface, the straight movement is actualized with the skyrmion bubble slave to the SRT domain interface forming an elastic composite object, avoiding the usual deflection from the skyrmion Hall effect. The critical contribution of the SRT domain interface via conveniently electron‐assisted heating is further theoretically validated in micromagnetic simulation, highlighting the compatible application possibility in advanced devices.

Li, Zhuolin↗

Porphyrin Covalent Organic Framework (POF)-Based Interface Engineering for Solar Steam Generation

Through replacement of traditional energy sources with sunlight as the heat source, solar steam generation has emerged as a promising technology for water purification and residuals management. Despite significant efforts to develop efficient photothermal materials for solar steam devices, challenges associated with scalable fabrication of high-performance materials remain. Moreover, most existing methods cannot be easily engineered to produce steam-generating devices with both arbitrary control over shape and high photothermal efficiency. Herein, a flexible porphyrin organic framework (POF)-based interface engineering method is introduced to produce high-performance solar steam generators. POFs, a recently discovered class of materials, are demonstrated to grow readily on a diverse range of porous substrates, including membranes, fabrics, sponges, and wood. Wood@POF exhibits particularly strong performance, achieving approximate to 80% light-to-steam conversion efficiency. This study demonstrates a universal, simple, and scalable interface engineering strategy for the fabrication of solar steam generators based on POF materials.

36 MATERIALS SCIENCE↗

Uncertainty analysis of correlated parameters in automated reaction mechanism generation

Abstract Uncertainty analysis is a useful tool for inspecting and improving detailed kinetic mechanisms because it can identify the greatest sources of model output error. Owing to the very nonlinear relationship between kinetic and thermodynamic parameters and computed concentrations, model predictions can be extremely sensitive to uncertainties in some parameters while uncertainties in other parameters can be irrelevant. Error propagation becomes even more convoluted in automatically generated kinetic models, where input uncertainties are correlated through kinetic rate rules and thermodynamic group values. Local and global uncertainty analyses were implemented and used to analyze error propagation in Reaction Mechanism Generator (RMG), an open‐source software for generating kinetic models. A framework for automatically assigning parameter uncertainties to estimated thermodynamics and kinetics was created, enabling tracking of correlated uncertainties. Local first‐order uncertainty propagation was implemented using sensitivities computed natively within RMG. Global uncertainty analysis was implemented using adaptive Smolyak pseudospectral approximations as implemented in the MIT Uncertainty Quantification Library to efficiently compute and construct polynomial chaos expansions to approximate the dependence of outputs on a subset of uncertain inputs. Cantera was used as a backend for simulating the reactor system in the global analysis. Analyses were performed for a phenyldodecane pyrolysis model. Local and global methods demonstrated similar trends; however, many uncertainties were significantly overestimated by the local analysis. Both local and global analyses show that correlated uncertainties based on kinetic rate rules and thermochemical groups drastically reduce a model's degrees of freedom and have a large impact on the determination of the most influential input parameters. These results highlight the necessity of incorporating uncertainty analysis in the mechanism generation workflow.

Gao, Connie W.↗

Advanced wind turbine control development using field test analysis for generator overspeed mitigation

Abstract Turbulent and gusty wind conditions can cause generator overspeed peaks to exceed a threshold that then lead to wind turbine shutdowns, which then decrease the energy production of the wind turbines. We derive so‐called “gust measures” that predict when generator overspeed peaks may occur. These gust measures are then used to develop advanced controllers to mitigate generator overspeed peaks so that wind turbines can operate more robustly in difficult wind conditions without exceeding generator overspeed thresholds that would lead to turbine shutdown events. The advanced controllers are demonstrated in nonlinear aeroelastic simulations using the open‐source wind turbine simulation tool OpenFAST. To increase the realism of the simulations, they are run using field‐replicated wind conditions and a wind turbine model based on data from an experimental field campaign on a downscaled demonstrator of a novel extreme‐scale, two‐bladed, downwind rotor design.

17 WIND ENERGY↗

Search for heavy neutrinos or third-generation leptoquarks in final states with two hadronically decaying $\tau$ leptons and two jets in proton-proton collisions at $ \sqrt{s}=13 $ TeV

A search for new particles has been conducted using events with two high transverse momentum (p$_{T}$) τ leptons that decay hadronically, at least two high-p$_{T}$ jets, and missing transverse energy from the τ lepton decays. The analysis is performed using data from proton-proton collisions, collected by the CMS experiment in 2015 at $ \sqrt{s}=13 $ TeV, corresponding to an integrated luminosity of 2.1 fb$^{−1}$. The results are interpreted in two physics models. The first model involves heavy right-handed neutrinos, N$_{ℓ}$ (ℓ = e, μ, τ), and right-handed charged bosons, W$_{R}$, arising in a left-right symmetric extension of the standard model. Masses of the W$_{R}$ boson below 2.35 (1.63) TeV are excluded at 95% confidence level, assuming the N$_{τ}$ mass is 0.8 (0.2) times the mass of the W$_{R}$ boson and that only the N$_{τ}$ flavor contributes to the W$_{R}$ decay width. In the second model, pair production of third-generation scalar leptoquarks that decay into ττbb is considered. Third-generation scalar leptoquarks with masses below 740 GeV are excluded, assuming a 100% branching fraction for the leptoquark decay to a τ lepton and a bottom quark. This is the first search at hadron colliders for the third-generation Majorana neutrino, as well as the first search for third-generation leptoquarks in the final state with a pair of hadronically decaying τ leptons and jets.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Search for a singly produced third-generation scalar leptoquark decaying to a τ lepton and a bottom quark in proton-proton collisions at $ \sqrt{s}=13 $ TeV

Here, a search is presented for a singly produced third-generation scalar leptoquark decaying to a τ lepton and a bottom quark. Associated production of a leptoquark and a τ lepton is considered, leading to a final state with a bottom quark and two τ leptons. The search uses proton-proton collision data at a center-of-mass energy of 13 TeV recorded with the CMS detector, corresponding to an integrated luminosity of 35.9 fb$^{–1}$. Upper limits are set at 95% confidence level on the production cross section of the third-generation scalar leptoquarks as a function of their mass. From a comparison of the results with the theoretical predictions, a third-generation scalar leptoquark decaying to a τ lepton and a bottom quark, assuming unit Yukawa coupling (λ), is excluded for masses below 740 GeV. Limits are also set on λ of the hypothesized leptoquark as a function of its mass. Above λ = 1.4, this result provides the best upper limit on the mass of a third-generation scalar leptoquark decaying to a τ lepton and a bottom quark.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

On-demand in situ generation of oxygen in a nanofluidic embedded planar microband electrochemical reactor

In situ generation of reagents and their subsequent use downstream presents new opportunities to amplify the utility of nanofluidic devices by exploiting the confined geometry to address mass transport limitations on reaction kinetics and efficiency. Oxygen, an inherently valuable reactant, can be produced from electrolysis of water, a process that can be conveniently integrated within a nanofluidic system. Here, we construct and characterize a nanofluidic device consisting of a planar microband electrode embedded within a nanochannel for in situ electrochemical generation and optical monitoring of O 2 . Fluorescein, a dye with a pH-sensitive emission intensity, was used to monitor the spatiotemporal characteristics of the oxidation of H 2 O, using the co-produced H + . Application of anodic potentials at the nanochannel-embedded electrode results in a decrease in fluorescence intensity, which reflects the decreasing solution pH. A combination of fluorescence intensity and chronoamperometric response was used to quantitatively determine proton generation, and the H + /O 2 stoichiometry was then used to determine the concentration of the O 2 in the channel. Comparison of the experimental results to finite element simulations validates the use of fluorescein emission intensity to spectroscopically determine the local oxygen concentration in the nanochannel. By varying the applied potential, spatially averaged O 2 concentrations ranging from 0.13 to 0.41 mM were generated. In conclusion, the results demonstrate a convenient route to in situ modulation of the dissolved O 2 level in a nanofluidic device and the use of an optical probe to monitor its spatial and temporal distribution under flow conditions.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Photonic generation of millimeter-wave ultra-wideband monocycle signal using up-conversion based on stimulated Brillouin scattering effect

We propose a novel scheme for photonic generation of millimeter-wave (MMW) ultra-wideband monocycle signal free of strong local oscillation (LO) and low-frequency component. A theory and a mathematical model are built to investigate the proposed scheme. Firstly, a differentiator is implemented using a dual-drive Mach–Zehnder modulator to attain monocycle pulses by differentiating a series of Gauss pulses. Subsequently, a dual-parallel Mach–Zehnder modulator and stimulated Brillouin scattering effect are employed to realize single-sideband modulation for up-converting the monocycle pulses to the MMW band. In the calculation, the generated signal is centered at 26 GHz with 10-dB bandwidth of 7 GHz and its power efficiency is about 50.08%. In addition, on–off keying modulation, amplitude modulation (PAM) and pulse position modulation monocycle pulses are generated. The spectrum of the generated signal meets with the FCC mask efficiently, so this technique has a potential application in MMW radar communication systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Generation of two-color terahertz radiation using Smith–Purcell emitter and periodic dielectric layers

This paper proposes and simulates three vacuum state devices each of which generates two-color terahertz radiation by Smith–Purcell emitter and dielectric layers. Each of the devices is a SiO{sub 2}-made vacuum tube consisting of a Smith–Purcell emitter located at the bottom of the tube and also periodic dielectric layers located at the top. Smith–Purcell structure is a metal grating above which electron beam is generated closely by the cathode and are collected by a collector in another side of the grating. The emitter generates two terahertz radiations including evanescent and coherent Smith–Purcell radiations. While the evanescent radiation is the first harmonic of the emitted radiation, coherent Smith–Purcell radiation is the second and dominant one. The coherent Smith–Purcell radiation is emitted in a specific angle calculated by Smith–Purcell relation. The emitted coherent Smith–Purcell radiation coincides with periodic grating dielectric layers made of Si and SiO{sub 2} on top of the vacuum tube, and the transmitted pulse is transformed to two-terahertz pulses. The output of each device is a two-color terahertz pulse. Two generated terahertz wavelengths are very applicable in pump–probe experiments.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Generation of inhomogeneously polarized vector vortex modes in few mode optical fiber

We have demonstrated the generation of inhomogeneously polarized vector-vortex modes in a step index, few mode fiber other than well-known zeroth order vector modes such as radial, azimuthal and hybridly polarized modes. These vector-vortex modes are generated by the combination of orthogonal linearly polarized fiber modes with diagonal and anti-diagonal polarization vector. The generation of these modes is controlled by the coupling conditions and state of polarization at the input fiber end. A single half-wave plate is used at the input end to switch between modes of orthogonal polarization for both linearly polarized modes and inhomogeneously polarized vector-vortex modes. All the generated modes are analysed using Stokes formalism by obtaining spatial polarization maps and ellipse orientation maps. The obtained experimental results are found to be in good agreement with the simulated results.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

2016 ASMS Workshop Review: Next Generation LC/MS: Critical Insights and Future Perspectives

The pilot workshop on BNext Generation LC/MS: Critical Insights and Future Perspectives was held on the evening of June 6, 2016 at the 64th ASMS Conference on Mass Spectrometry and Allied Topics held in San Antonio, TX. The workshop, chaired by Hongying Gao (Pfizer), consisted of stimulating talks from distinguished speakers and open discussion among the audience and invited presenters.The objectives of this workshop were to better understand the advances and limitations of current technologies; to exchange perspectives on the next generation LC/MS; and to discuss/debate the features of next generation LC/MS focusing on the following three questions: (1) What would the next generation LC/MS look like? (2) How would it change the way we do analysis? and (3) What fundamental issues need to be resolved? A real-world case in the biopharmaceutical industry was presented by Hongying Gao on the needs by industry for LC/MS innovation and technology advancements. The primary invited speakers were Alexander Makarov (Thermo Fisher Scientific) and Richard (Dick) Smith (Pacific Northwest National Laboratory). The open discussions started with Q&A and comments for Alexander Makarov and Dick Smith, followed by insights and perspectives from members of the audience and other invited presenters who shared their thoughts addressing the above questions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Investigation of Remanufacturing Methods Utilizing Mechanically-Generated and Gas-Atomized Feedstock Production for Directed Energy Deposition Processing Through Specific Energy Consumption Modeling

The goal of this work was to assess the energy consumption of a novel remanufacturing method that utilizes mechanically-generated feedstock for directed energy deposition. Gas-atomization is the state-of-the-art production process for directed energy deposition feedstock, and for this work was incorporated into a remanufacturing process path to provide a comparison method. Specific energy consumption models of remanufacturing utilizing both of these proposed process paths were developed and applied to a case study to investigate energy saving opportunities for future manufacturing paradigms. The energy modelling was done in three stages. First, the mechanically-generated feedstock production energy consumption model was generated from experimental observation. Second, the gas-atomized feedstock production energy consumption model was generated from a combination of experimental observation, reported estimates from the manufacturer, and data found in the literature. Lastly, the energy consumption model of directed energy deposition was derived from experimental observation and compares favorably with reported estimates in the literature. With the models, the specific energy consumption in the two process paths were compared and their application was demonstrated by estimating the energy consumption to remanufacture a bracket. The two feedstock production methods had similar specific energy consumptions. The specific energy consumption of the directed energy deposition process was the greatest component in the respective remanufacturing paths by an order of magnitude; increasing deposition rate is the most important factor for lowering the overall specific energy consumption. The analyzed remanufacturing technologies were estimated to consume less energy than replacement when repairing up to approximately 15% of the original part’s mass.

42 ENGINEERING↗

Life Cycle Analysis of Thermoelectric Power Generation in the United States

In this article, the basics of performing a life cycle analysis of thermoelectric power generation are discussed, with three examples of life cycle greenhouse gas (GHG) balances for thermoelectric power generation forms: coal, natural gas, and nuclear. The final section compares multiple electricity generation methods in the United States. Results are presented on the basis of 1 megawatt-hour (MWh) of electricity delivered to the end user. Environmental life cycle results for greenhouse gas (GHG) emissions are presented as carbon dioxide equivalents, based on 100-year global warming potentials (GWPs) established by the 6th Assessment Report from the Intergovernmental Panel on Climate Change in 2021, commonly referred to as AR6 GWP values (IPCC, 2021). Additional details on other environmental life cycle impacts from non-GHG emissions to air, emissions to water, solid waste generation, and land use are available on the Department of Energy, National Energy Technology Laboratory’s Life Cycle Analysis website: www.netl.doe.gov/LCA.

Cutshaw, Ashley↗

Generation of localized reactor point kinetics parameters using coupled neutronic and thermal fluid models for pebble-bed reactor transient analysis

The systems analysis of anticipated operating occurrences and design basis accidents for pebble-bed reactor systems requires knowledge of neutron point kinetics equations (PKE) parameters. Typically, the generation of PKE parameters is performed in a global manner using standalone neutronics calculations, without the inclusion of thermal fluid distributions. We utilize Griffin and Pronghorn for generating global and local PKE parameters which includes the use of thermal fluid distributions to account for localized effects. This work establishes a methodology for calculating PKE parameters for a pebble bed reactor with a coupled neutronics/thermal fluids analysis. PKE parameters generated on a global and local basis are compared against a diffusion solve for a typical load-following transient. Locally-generated neutron kinetic parameters are able to reduce the maximum error in the transient power level from 5% to below 1.5%; along with this, bulk temperature errors were reduced from 12 K to 4 K.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Superadiabatic scheme for optimizing the fast generation of tree-type 3D entanglement

High-dimensional entanglement has more superior security than qubit entanglement. Recently, adiabatic and fast-adiabatic schemes for generating a novel three-dimensional (3D) entanglement, tree-type 3D entanglement, were proposed. However, the previous schemes have their experimental defects, respectively. Here we give a superadiabatic scheme for optimizing the generation of tree-type 3D entanglement. Adequate numerical simulations prove that the scheme is not only fast, effective and robust, but also highly feasible in experiment. - Highlights: • The scheme for generating tree-type 3D entanglement is not only fast but also robust against the variation in the control parameters and decoherence induced by atomic spontaneous emissions and photon leakages from the cavity-fiber system. • The designed driving pulses are experimentally feasible Gaussian pulses which can reduce experimental difficulties. • The Hamiltonian used to speed up generating tree-type 3D entanglement is of the same form as the original Hamiltonian, which will greatly enhances the experimental feasibility of the scheme.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Accelerated generation of human induced pluripotent stem cells with retroviral transduction and chemical inhibitors under physiological hypoxia

Highlights: Black-Right-Pointing-Pointer Very rapid generation of human iPS cells under optimized conditions. Black-Right-Pointing-Pointer Five chemical inhibitors under hypoxia boosted reprogramming. Black-Right-Pointing-Pointer We performed genome-wide DNA methylation analysis. -- Abstract: Induced pluripotent stem (iPS) cells are generated from somatic cells by the forced expression of a defined set of pluripotency-associated transcription factors. Human iPS cells can be propagated indefinitely, while maintaining the capacity to differentiate into all cell types in the body except for extra-embryonic tissues. This technology not only represents a new way to use individual-specific stem cells for regenerative medicine but also constitutes a novel method to obtain large amounts of disease-specific cells for biomedical research. Despite their great potential, the long reprogramming process (up to 1 month) remains one of the most significant challenges facing standard virus-mediated methodology. In this study, we report the accelerated generation of human iPS cells from adipose-derived stem (ADS) cells, using a new combination of chemical inhibitors under a setting of physiological hypoxia in conjunction with retroviral transduction of Oct4, Sox2, Klf4, and L-Myc. Under optimized conditions, we observed human embryonic stem (ES)-like cells as early as 6 days after the initial retroviral transduction. This was followed by the emergence of fully reprogrammed cells bearing Tra-1-81-positive and DsRed transgene-silencing properties on day 10. The resulting cell lines resembled human ES cells in many respects including proliferation rate, morphology, pluripotency-associated markers, global gene expression patterns, genome-wide DNA methylation states, and the ability to differentiate into all three of the germ layers, both in vitro and in vivo. Our method, when combined with chemical inhibitors under conditions of physiological hypoxia, offers a powerful tool for rapidly generating bona fide human iPS cells and facilitates the application of iPS cell technology to biomedical research.

60 APPLIED LIFE SCIENCES↗