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All sourcesNASA NTRSDOE OSTI
DOE OSTI2020

Assessment of Enhanced Oil Recovery Using Carbon Dioxide in Michigan Basin Silurian Pinnacle Reefs

The Midwest Regional Carbon Sequestration Partnership (MRCSP) has incorporated the work of geologic research teams (Geoteams) in its regional characterization, project planning and carbon dioxide (CO 2 ) injection implementation work since the partnership was established by the U.S. Department of Energy (DOE) in 2003. Over this 16-year period, the cohort of Geoteams has grown from five to ten states and has contributed to the characterization of geologic sequestration opportunities, refinement of reservoir and seal data, and supported injection efforts through both predictive and post-injection assessments. The Michigan team at Western Michigan University has provided technical analysis and support of the enhanced oil recovery (EOR) using carbon dioxide (CO 2 ) in the Northern Michigan Silurian Pinnacle reefs. With Core Energy, LLC as the industry partner, this project has assessed the potential for EOR in known fields in the Michigan Pinnacle reefs and the capacity for CO2 storage in the reef reservoirs as they are depleted and after reservoir abandonment. This project managed by Core Energy, LLC, involves the only commercial CO 2 Enhanced Oil Recovery floods within the MRCSP region. The Silurian pinnacle reef trend shows significant potential for CO 2 -EOR: this play is relatively new, with approximately 60% of the wells in the largest Niagaran fields still accessible. Most wells have modern logs and there are many cores, core analyses, pressure tests and produced water analyses available for study from these fields. These carbonate reservoirs in Michigan have produced sufficient oil to warrant evaluation for additional recovery efforts. The role of the Michigan team was to collect and analyze all relevant data about reservoir properties, including lithologic and depositional characteristics of the reservoir formations and porosity and fluid flow properties through different compartments in the reservoir. The team has also developed models that represent the geological and physical characteristics of the reservoir and seal system.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2017

Large mass-dependent nickel isotope fractionation in Orgueil carbonate: implications for 60 Fe in the early Solar System

Iron-60 is a uniquely important short-lived radionuclide, because it cannot be produced by particle irradiation, and thus, high initial 60 Fe abundances inferred in early-formed Solar System objects must be attributed to injection from a stellar source. Estimates of the initial 60 Fe/ 56 Fe ratio range over a factor of 60 from 1×10 –8 , as determined by high-precision analyses of bulk meteorites, to ~6×10 –7 , from in-situ measurements of high Fe/Ni phases. The reasons for this discrepancy are not clear. To investigate this, we used the UCLA ims1270 and ims1290 ion microprobes to analyze Orgueil carbonate grains that exhibit very high Fe/Ni ratios and are known from 53 Mn- 53 Cr systematics to have formed within ~5 My of CAIs. Our SIMS investigations found two Orgueil breunnerite grains that show apparent 60 Ni excesses. Correlations with Fe/Ni are generally not well defined, but the data imply a relatively high 60 Fe/ 56 Fe ratio of ~10 –7 at the time of carbonate formation. To test the accuracy of the SIMS nickel isotope measurements, we analyzed the same carbonate grains with RIMS using CHILI, the CHicago Instrument for Laser Ionization. The data obtained on the Orgueil carbonates reveal correlations between 62 Ni/ 58 Ni and 60 Ni/ 58 Ni that are strictly mass-dependent. The range in mass fractionation is very large, up to ~35‰/u, predominantly favoring the light isotopes. Our RIMS measurements conclusively demonstrate the occurrence of mass-fractionated nickel in meteorite samples. This isotopic fractionation is large enough that elevated 60 Ni/ 62 Ni ratios could be incorrectly attributed to 60 Fe decay if this mass fractionation is not accurately accounted for.

58 GEOSCIENCES↗
DOE OSTI2025

Diagnostic Systems in the Muon $g-2$ experiment at Fermilab

The muon anomalous magnetic moment, $a_\mu=\frac{g-2}{2}$, is a low-energy observable which can be both measured and computed to high precision, making it a sensitive test of the Standard Model and a probe for new physics. This anomaly was measured with a precision of $0.20$~parts per million (ppm) by the Fermilab's Muon g-2 (E989) experiment. The final goal of the E989 experiment is to reach a precision of $0.14$~ppm. The experiment is based on the measurement of the muon spin anomalous precession frequency, $\omega_a$, based on the arrival time distribution of high-energy decay positrons observed by 24 electromagnetic calorimeters, placed around the inner circumference of a $14$~m diameter storage ring, and on the precise knowledge of the storage ring magnetic field and of the beam time and space distribution. Achieving this level of precision requires strict control over systematics, which is ensured through several diagnostic devices. At the accelerator level, these devices monitor the quality of the injected beam (e.g., verifying that it has the correct momentum), while at the detector level, they track both the magnetic field and the gain of the calorimeters. In this work the devices and techniques used by the E989 experiment will be presented.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2021

Experimental workflow to estimate model parameters for evaluating long term viscoelastic response of CO2 storage caprocks

Understanding the time-dependent behavior of reservoir and sealing formations is critical to assessing risks associated with geological carbon storage since time-dependent deformation strongly influences mechanical responses of some rock types. Many studies have evaluated the risk of CO2 leakage and induced seismicity by assuming poroelastic rheology in sealing formations. Few have considered viscoelastic or other time-dependent responses, where the existing literature adopts 1D models to represent long-term time-dependent responses. This is primarily because to date, the general form of a reasonable 3D time-dependent model for rocks remains unclear. In this paper, we address this unclear issue by proposing a new workflow to select constitutive modeling parameters to evaluate if a 3D viscoelastic model is reasonable using several-hour-long experimental data and a power-law response to extrapolate to the decades-long time frames of interest in geologic carbon storage. To provide experimental data, we conducted multi-level loading/unloading triaxial relaxation tests with four rock types. The experimental results showed that the maximum load relaxation observed is approximately 49%, with some rock types showing as little as 1.4%. Using a simple linear viscoelastic model, parameters were chosen such that a maximum deviation of 1.5 MPa in axial stress and 7 MPa in radial stress was attained with the extrapolated 30-year data. We found that a reasonable parameter range for the normalized elastic modulus is 0.1~2 for rocks with significant time-dependent responses and 0.01~0.06 for those with small time-dependent responses. No matter how significant time-dependent responses are for rocks considered, our results showed that the relaxation time has a general range of 1~10^10 s, whose time scale can be one or two orders higher than a time frame typically envisioned for CO2 injection projects.

Stress relaxation, 3D time-dependent model, viscoe↗
DOE OSTI2023

Dual-Purpose Canister Filling Demonstration Project Progress Report at ORNL, 2023

The US DOE Office of Nuclear Energy is investigating the feasibility of direct disposal of dual-purpose canisters (DPCs) in a hypothetical geological repository to offset the potential requirement to repackage spent nuclear fuel (SNF) from existing DPCs into smaller, disposal-ready canisters. Oak Ridge National Laboratory (ORNL) is currently evaluating the feasibility of filling void space in loaded DPCs with an engineered material to prevent a criticality event caused by groundwater/moderator intrusion. Metal alloys are being investigated as a filler material because of their relatively low viscosities when molten, which may facilitate their injection via an existing drainpipe that runs almost the full length of the DPC. ORNL’s strategy for evaluating filler viability includes simulations and physical demonstrations of filling and casting behavior, as well as evaluations of materials for compatibility in the repository environment. Filling of DPCs in this manner is expected to mitigate the risk associated with a post-closure criticality event during the repository performance assessment time frame (10,000 years or greater). Efforts in this fiscal year focused on (1) destructive analysis of experimental filler castings made in FY 2022, (2) a report outlining a conceptual design of a DPC filling facility (Fortner et al., 2023, M3SF 23OR010305044/ ORNL/SPR-2023/2921, May 31, 2023), (3) a report on affected features, events, and processes (FEPs) due to DPC filling (Price et al., 2023, M3SF-23SN010305093, issuance pending), (4) developing and testing a more practical alloy filler based upon a Sn-Al eutectic, and (5) modeling the heating and cooling dynamics of a DPC subjected to molten metal filling. The preliminary results from each of these tasks support the feasibility of filling DPCs with metal as a strategy against the possibility of criticality in the repository. The FY 2022 casting was found to penetrate even very small orifices in the mold and internal structures. Preliminary testing of the Sn-Al eutectic indicate little interaction of the melt with Zircaloy cladding. Thermal modelling shows that a filled DPC will cool to manageable temperatures within 2-3 days, which is likely manageable in a facility.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Ultra Efficient Light Duty Powertrain with Gasoline Low Temperature Combustion (Final Report)

This document details the work completed during Project DE-EE0006839 ‘Ultra Efficient Light Duty Powertrain with Gasoline Low Temperature Combustion’. All tasks from the project’s Statement of Project Objectives are discussed. Final demonstration data is also presented and discussed. Further project details can be found in the Quarterly Technicial Reports that were submitted during the course of the project and are stored on the EERE Project Management Center Website. The goal of this project was to develop, implement and demonstrate a low temperature combustion approach called Gasoline Direct Injection Compression Ignition (GDCI) that provides high thermal efficiency with low NOx and PM emissions. The project target was to demonstrate a 35% fuel economy improvement over the baseline vehicle while meeting Tier 3 emissions levels. At the start of this project, GDCI was a moderately mature combustion technology, due in large part to advances made during a Delphi Technologies program funded through an earlier Department of Energy Advanced Technology Powertrains (ATP) opportunity; under that earlier contract, DE-EE0003258, Delphi Technologies assembled a team with complementary industrial and academic experience, and led this team to advance the technology from the original fundamental work to the state of art embodied by a first-generation (Gen 1) multi-cylinder GDCI engine. Key activities during that project centered on engine and combustion chamber design, and development of fuel injection equipment, valvetrain and advanced controls. Performance results with the Gen 1 engine in a development vehicle demonstrated that GDCI had the capability to operate using Low Temperature Combustion (LTC) over a broad speed-load range. Based on benchmarking work, efficiency for the Gen 1 GDCI engine compared favorably overall to production light-duty diesel engines. The second DOE funded project, DE-EE0006839, focused on a number of technical risks and issues that were left to be resolved for GDCI to become a production-viable technology. These risks were:GDCI combustion system refinement to achieve near-ideal air/fuel mixture preparation for high efficiency and low HC and CO emissions; Transient control development for low temperature combustion with high EGR levels during real-world transient driving maneuvers and over a broader range of ambient conditions; Aftertreatment system design that is effective in dealing with the low-temperature challenges of a highly efficient engine. The project was executed in two phases. Phase 1 leveraged the development vehicle from the Advanced Technologies Powertrain 1 (ATP1) project, DE-EE0003258. That vehicle was used as an initial test bed in the development of a high performance low temperature exhaust aftertreatment system. The vehicle was also used to develop calibration refinements for improved exhaust emissions and fuel efficiency. Samples of a new GDCI development level engine, called Gen2 GDCI (and developed outside of the first DOE funded project), were also used during Phase 1 to develop refined controller hardware and control algorithms, as well as improved sensors and actuators. The Gen2 engine was then retrofitted into the development vehicle from the ATP1 project and used for controls refinement and calibration of GDCI to achieve improved cold start, drivability and robustness to real world environments and fuel variations. During Phase 2 of the project, Gen3 versions of the GDCI engine were designed and built specifically for this project based on experience from the earlier engines. These engines were designed to be production-like in construction and, when combined with refined control systems and project specific low temperature exhaust aftertreatment, were intended to support the goal of meeting Tier 3 emissions levels at a vehicle level. Though great progress had been made advancing the GDCI combustion process, and despite extensive presentations of our work on the technology at various conferences and in direct meetings with automotive companies, none of the US domestic automotive OEMs had shown an interest in adopting this combustion process as part of their technology planning as the project approached the Go/No-Go point at the end of Budget Period 3. As a result of this low-level of interest both the US Department of Energy and Delphi Technologies received in this technology from domestic auto manufactures, Delphi Technologies elected a ‘No-Go’ status for the gate between Budget Period 3 and Budget Period 4 which terminated the project without spending any Budget Period 4 funds. The project team concluded that the dynamometer mapping of the most recent level of hardware, combined with the vehicle level simulation by Argonne National Laboratory, was sufficient to document the capabilities and potential of the combustion process without spending the time and money to do the controls development and full calibration necessary for a demonstration vehicle.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2017

Experimental studies on metallic fuel relocation in a single-pin core structure of a sodium-cooled fast reactor

Experiments dropping molten uranium into test sections of single fuel pin geometry filled with sodium were conducted to investigate relocation behavior of metallic fuel in the core structures of sodium-cooled fast reactors during a hypothetical core disruptive accident. Metallic uranium was used as a fuel material and HT-9M was used as a fuel cladding material in the experiment in order to accurately mock-up the thermo-physical behavior of the relocation. The fuel cladding failed due to eutectic formation between the uranium and HT-9M for all experiments. The extent of the eutectic formation increased with increasing molten uranium temperature. Voids in the relocated fuel were observed for all experiments and were likely formed by sodium boiling in contact with the fuel. In one experiment, numerous fragments of the relocated fuel were found. In conclusion, it could be concluded that the injected metallic uranium fuel was fragmented and dispersed in the narrow coolant channel by sodium boiling

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2023

Coupling Thermal-Hydraulics with Reactor Pressure Vessel Fracture Models

Because of the importance of maintaining the integrity of the reactor pressure vessel (RPV) in light-water reactors, significant effort has been devoted over the last several decades to understand the potential failure mechanisms, characterize how material properties evolve due to environmental conditions, and develop tools to assess the probability of fracture in aged RPVs during potential transient events. One important aspect of this problem that has not yet been fully addressed is the effects of nonuniform cooling on the RPV inner wall due to the way low-temperature water injected into the primary coolant system is distributed within the RPV during potential loss-of-coolant accident transients. Colder temperatures are expected in the regions near the inlets, causing a “cold-plume” effect. Rapid cooling of the RPV wall increases the likelihood of fracture initiation, and localized cooling due to cold-plume effects could potentially exacerbate this problem. The Grizzly code can perform a three-dimensional simulation of the RPV thermomechanical response as well as the probabilistic assessment of fracture for a population of pre-existing flaws, which is necessary to account for spatial variations in coolant temperature. This report documents a first effort to couple Grizzly RPV fracture models with computational fluid dynamics models performed using the Cardinal code, which allows for a realistic representation of the temperature distribution. This report demonstrates this coupling approach on two test cases: a simplified proof-of-concept scenario and a realistic small-break loss-of-coolant accident scenario. In both cases, the effects of the spatially varying temperature are evident; although, because the small-break loss-of-coolant accident scenario was far from challenging the RPV’s margins, it is still inconclusive how important cold-plume effects are in realistic accident scenarios. However, this effort represents an important step toward performing realistic analyses to determine to what extent spatially nonuniform cooling might affect RPV integrity under more aggressive accident scenarios.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2021

SO3/H2SO4 continuous real-time sensor demonstration at a power plant

We present results from field testing of a new, innovative sensor developed to measure SO3/H2SO4 continuously and in real time at a coal-fired power plant. The system utilizes the sensitivity, specificity, and real-time capabilities of mid-infrared (Mid-IR) laser-based sensor technology, along with a heated, close-coupled cell mounted directly to a power plant duct. Measurements were made by the laser sensor over a 2-day period and compared to results from the accepted method, EPA 8A, which requires a 30-minute collection, labor intensive processing, and off-site analysis at a lab. In contrast to the condensation method, the laser sensor continuously samples flue gas and reports measurements of the concentration of SO3/H2SO4, SO2 ever second with unattended operation. This initial demonstration proved the sensor concept and paves the way for its use for optimizing sorbent injection used to neutralize SO3/H2SO4. Optimized sorbent injection will enable significant cost savings associated with efforts to mitigate the presence and effects of SO3/H2SO4 such as “Blue Plume”, air heater fouling, and duct corrosion. In particular, the real-time, actionable information will enable better control of additive injection in flex conditions and variable fuels.

20 FOSSIL-FUELED POWER PLANTS↗
DOE OSTI2023

Beam dynamics corrections in the measurement of the anomalous precession frequency at the Muon $g-2$ experiment at Fermilab

The Muon $g-2$ experiment at Fermilab (E989) aims to measure the anomalous magnetic moment of the muon with an accuracy of 140 ppb (parts per billions). This accuracy, obtained by adding in quadrature a statistical and a systematic contribution of comparable value (100 ppb), will allow to reduce the experimental uncertainty (from the previous E821 experiment at BNL \cite{bnl}) of a factor of 4, and represents one of the most precise tests of the Standard Model (SM) theory of elementary particles. The first result on the Run-1 dataset \cite{prl} was released on April 7, 2021, showing a very good agreement with the previous result from BNL experiment, with a slightly better uncertainty. The corresponding experimental average increases the significance of the discrepancy between the measured and Standard Model prediction of 4.2$\sigma$ \cite{white_paper}.\\ \noindent The measured quantity is the muon magnetic anomaly a$_\mu$=$\frac{g_\mu-2}{2}$ where g$_\mu$ is the gyromagnetic factor of the muon. Dirac's equation predicts g$_\mu$ = 2, while radiative corrections, dominated by the QED contribution due to an exchange of a virtual photon, causes a per-mille correction on this quantity. By including all the SM contributions, a$_\mu$ is known at 370 ppb. The E989 experiment measures $a_\mu$ injecting positive muons with momentum of 3.1 GeV/$c$ polarized longitudinally in bunches (called $fills$) with an average rate of 12 Hz, in a storage ring of 14 meters diameter. Due to the parity violation in the weak muon decay, high energy positrons produced are emitted preferably in the muon's spin direction. By counting the number of positrons with energy greater then 1.7 GeV in function of the time, the frequency precession of the muon spin is measured, that together with the measurement of the magnetic field, allows to extract $a_\mu$. The positrons are detected with 24 electromagnetic calorimeters, that measure the energy and the arrival time of the positrons, each made of 54 crystals of lead fluoride (PbF$_2$) read by silicon photomultipliers (SiPM). Together with calorimeters, two tracking detectors are used to make non-destructive measurements of the muon beam characteristic by reconstructing the muon decay position extrapolating backward the decay positrons. The knowledge of the beam motion inside the ring plays a fundamental role in the analysis of $a_{\mu}$, where the measured anomalous precession frequency $\omega_a$ must be corrected for four main beam dynamics effects. A first correction is associated with the presence of an electric field responsible of the vertical focusing on the storage ring, where vertical direction is orthogonal to the orbit and horizontal direction is along the storage ring radius. Due to the oscillations in the vertical direction, the so called vertical betatron oscillations, a second correction is necessary to account for an average angle associated with the muon motion off the ideal orbit. A third correction is caused by lost muons in the ring which have a different spin phase at the injection respect to the decay ones. Finally, due to the correlation between the vertical and horizontal beam motion of the muons and the acceptance of the calorimeter, a correction (called ``phase-acceptance") arises. In Run1, due to the presence of two damaged resistors in one electrostatic quadrupole, this correction had a prominent role. The replacement of the damaged resistors before Run2 decreased this effect by one order of magnitude, and a further reduction in Run-3 was provided by an improved orbit.\\ \noindent The work of this Thesis focuses on the beam dynamics corrections on $\omega_a$. Due to the prominent role in Run-1 a special attention has been put to the phase-acceptance correction\footnote{The effect of this correction on the E821 BNL measurement of the $g-2$ has been evaluated to be within the quoted systematic error.}. Chapter \ref{ch:anomalous_magnetic_moment} introduces the anomalous magnetic moment of the muon. Chapter \ref{ch:early_experiment} describes the history of the Muon $g-2$ experiments. Chapter \ref{ch:theory} discusses the Standard Model prediction and possible new physics scenario. Chapter \ref{ch:muon_g2_experiment} describes the E989 experiment, whose experimental technique and the apparatus are discussed focusing on the improvements needed to reach the final goal on $a_\mu$ measurement. The original work of the Thesis is discussed in the last 5 chapters. Chapter \ref{ch:experiment_technique} presents the analysis technique to extract $\omega_a$, Chapter \ref{ch:beam_dynamics} describes the beam dynamics in the E989 experiment, Chapter \ref{ch:beam_dynamics_correction} discusses the beam dynamics correction to $\omega_a$, and Chapter \ref{sec:pa_corr} focuses on the phase acceptance correction. Finally Chapter \ref{ch:run23_analysis_improvements} contains the Run-2/3 improvements which are expected to allow for an increased precision ons the beam dynamics co...

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Experimental study of fracture slip due to stress perturbation in fractured geo-resources

Anthropogenic activities such as underground fluid injection/extraction, well stimulation, and dam impoundment will perturb the state-of-stress in the subsurface, which could activate critically stressed pre-existing fractures and faults. Fault and fracture activation can induce seismicity, change flow behavior, and damage asperities on the fracture surface to alter reservoir permeability. Here, in this study, triaxial shear tests were conducted on saw cut and rough fracture Barre granite specimens to better characterize how a decrease in normal stress and increase in shear stress will influence crystalline rock fracture hydromechanical properties. In a triaxial set up, confining pressure (CP) and differential stress (DS) were used to induce normal and shear stress on a 45° oriented fracture. Fracture slip and the corresponding stress relaxation was observed when the confining stress decreased. Fracture permeability increased when the fracture slipped. Moreover, new micro-cracks observed by x-ray images indicated the creation of new flow paths for fluid movement. The experimental outcomes of this study indicate that decrease in normal stress due to stress perturbations along the faults/fractures in the extensional stress regime can induce the slip along the fracture. This could have a significant influence on slope stability in quarries, stimulation and injection strategy in deep geo-resources, and potentially minimize the risk of induced seismicity. The observed stress dependency of hydraulic aperture in rough fracture during pre- and post-slip stages could provide key inputs for field-scale simulation of geo-resources.

58 GEOSCIENCES↗
DOE OSTI2018

A 89 Zr-labeled lipoplex nanosystem for image-guided gene delivery: design, evaluation of stability and in vivo behavior

Background: With the advances in radiopharmaceutical research, the development of image-guided therapy has become a major interest. While the development of theranostic nanotherapeutics is frequently associated with cancer chemotherapy, phototherapy and radiotherapy, there is little information available on the in vivo monitoring of gene delivery systems and the application of image-guided approach in gene therapy. The goal of this work was to determine the in vivo behavior of DNA delivery nanosystems - based on cationic gemini surfactants – designed for image-guided gene therapy. We tested the feasibility of monitoring tumor accumulation of gene delivery nanoparticles by positron emission tomography. Methods: To be able to conjugate radiotracers to the nanoparticles, a deferoxamine-modified gemini surfactant was synthesized, DNA-containing lipoplex nanoparticles were formulated, and radiolabeled with Zirconium-89 ( 89 Zr). The pharmacokinetics and biodistribution of 89 Zr labeled surfactant and 89 Zr labeled nanoparticles were monitored in mice by microPET/CT imaging and ex vivo gamma counting. Results: Modification of the nanoparticles with deferoxamine did not alter their physicochemical properties. The radiolabeled nanoparticles (labeling efficiency of 95±3%) were stable in PBS and serum. The biological half-life of the 89Zr labeled nanoparticles was significantly higher compared to 89Zr labeled surfactant. As expected, the nanoparticles had significantly higher liver accumulation than the radiolabeled surfactant alone and lower kidney accumulation. Tumor uptake was detected at 2 hours post injection and decreased throughout the 3-day monitoring. Conclusion: We propose that radiolabeling DNA delivery lipoplex nanosystems is a promising approach for the design and optimization of image-guided nanomedicines, especially in the context of cancer gene therapy.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2019

Final Report – Cooperative Research and Development Agreement between National Energy Technology Laboratory and Applied Spectra, Inc.

Groundwater resources can be contaminated by a variety of surface and subsurface sources. For instance, metals can be leached from surface dumps (e.g. landfills, etc.) and reach groundwater supplies by percolation though the soil. Additionally, subsurface activities such as geologic carbon storage (GCS) could result in contamination. In the event of CO2 leakage, freshwater above the injection site can potentially be contaminated with metals either originating from the formation fluids or leached from formation rocks by CO2 acidification. Detection of these contaminating metals is critical for maintaining water safety and providing an early warning of a containment breach. Therefore, a compact, subsurface capable laser induced breakdown spectroscopy (LIBS) based sensor has been developed for groundwater quality monitoring applications. LIBS sensor technology has been advanced from benchtop feasibility studies to a custom fabricated, watertight prototype. The all optical sensor head is built using a low cost passively Q-switched (PQSW) laser, which is fiber coupled to a control unit containing the pump laser and a gated spectrometer. Separating the LIBS excitation laser from the pump and spectrometer allows the expensive and fragile components to remain in a safe, central location while only the sensor head needs to enter the subsurface. Testing of the prototype sensors show Limits of Detection (LODs) comparable to benchtop, actively Q-switched systems and has verified that the fiber coupling and triggering schemes perform as desired.

McIntyre, Dustin↗
DOE OSTI2021

Sealing of fractures in a representative CO 2 reservoir caprock by migration of fines

The impact of fines migration on fracture transmissivity reduction was investigated by injecting a brine solution containing a suspension of 0.1 wt. % kaolinite particles with a mean particle size distribution of 9.6 µm through fractured shale core samples. The fractures had apertures estimated to be approximately 100 µm. A mass balance approach was used to determine the quantity of kaolinite that was deposited within the fractures (influent – effluent = amount deposited in fractures). Large fractions (44 to 90%) of the suspended kaolinite pumped through the fractures were deposited within the fractures. Based on fracture volumes estimated with X-ray computed tomography, it was determined that approximately 10 to 17% of the fracture volume was filled with kaolinite at the point when flow was completely restricted. These results indicate that 100 µm fractures in CO 2 reservoir caprocks could be sealed within hours if the brines passing through the fractures contain a proportional volume of particulates to the tests performed in this laboratory study.

04 OIL SHALES AND TAR SANDS↗
DOE OSTI2021

Duration of tick attachment necessary for transmission of Anaplasma phagocytophilum by Ixodes scapularis (Acari: Ixodidae) nymphs

This study assessed the duration of tick attachment necessary for a successful transmission of Anaplasma phagocytophilum by an infected I. scapularis nymph. Individual nymphs were placed upon BALB/c mice and allowed to feed for predetermined time intervals of 4 to 72 h. Ticks removed from mice at predetermined intervals were tested by PCR for verification of infection and evaluation of the bacterial load. The success of pathogen transmission to mice was assessed by blood-PCR at 7, 14 and 21 days postinfestation, and IFA at 21 days postinfestation. Anaplasma phagocytophilum infection was documented in 10-30 % of mice, from which ticks were removed within the first 20 h of feeding. However, transmission success was ≥70% if ticks remained attached for 36 h or longer. Notably, none of the PCR-positive mice that were exposed to infected ticks for 4 to 8 h and only half of PCR-positive mice exposed for 24 h developed antibodies within 3 weeks postinfestation. On the other hand, all mice with detectable bacteremia after being infested for 36 h seroconverted. This suggests that although some of the ticks removed prior to 24 h of attachment succeed in injecting a small amount of A. phagocytophilum, this amount is insufficient for stimulating humoral immunity and perhaps for establishing disseminated infection in BALB/c mice. Although A. phagocytophilum may be present in salivary glands of unfed I. scapularis nymphs, the amount of A. phagocytophilum initially contained in saliva appears insufficient to cause sustainable infection in a host. Replication and, maybe, reactivation of the agent for 12-24 h in a feeding tick is required before a mouse can be consistently infected.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2025

Cyberattack Detection and Mitigation on Central Volt‐VAr Using Circuit Law and Machine Learning

ABSTRACT In a distribution grid, voltage is maintained within a nominal range through a Volt‐VAr function that controls capacitor banks, reactive power of distributed energy resources (DER), and on‐load tap changers (OLTC). Availability of communications helps with the implementation of central Volt‐VAr control; however, it also opens the system to cyberattacks, causing voltage disturbances. Previous work has shown the adverse impacts of false data injection (FDI) on the central Volt‐VAr control; however, very few works have studied methods to detect and mitigate FDI on Volt‐VAr control. This paper addresses gaps in the detection and mitigation of FDI on the measurement packets of a central Volt‐VAr control. This work uses a two‐stage algorithm for cyberattack detection since the accuracy of a single‐stage machine learning (ML)–based detection method decreases while dealing with unseen data. The first stage is based on the verification of measurements against circuit laws, and the second stage utilizes a tree search algorithm and an ML method to detect the falsified data. This paper compares long short‐term memory (LSTM) and bidirectional LSTM (BiLSTM) as the employed ML algorithms. Finally, the mitigation algorithm replaces the falsified data with the estimated output of the ML algorithm. The effectiveness of the proposed method is tested for several cases using the IEEE 13‐bus test system in PSCAD software.

Beikbabaei, Milad [Bradley Department of Electrica↗
DOE OSTI2021

Modeling Transverse Space Charge effects in IOTA with pyORBIT

The role and mitigation of space charge effects are important aspects of the beam physics research to be performed at the Integrable Optics Test Accelerator (IOTA) at Fermilab. The impact of nonlinear integrability (partial and complete) on space charge driven incoherent and coherent resonances will be a new feature of this accelerator and has the potential to influence the design of future low energy proton synchrotrons. In this report we model transverse space charge effects using the PIC code pyORBIT. First we benchmark the single particle tracking results against MADX with checks on symplecticity, tune footprints, and dynamic aperture in a partially integrable lattice realized with a special octupole string insert. Our space charge calculations begin with an examination of the 4D symplecticity. Short term tracking is done first with the initial bare lattice and then with a matching of the rms values with space charge. Next, we explore slow initialization of charge as a technique to establish steady state and reduce emittance growth and beam loss following injection into a mismatched lattice. We establish values of space charge simulation parameters so as to ensure numerical convergence. Finally, we compare the simulated space charge induced tune shifts and footprints against theory.

43 PARTICLE ACCELERATORS↗